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Do-Nothing Prebiotic Chemistry: Chemical Kinetics as a Window into Prebiotic Plausibility Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-19 Skyla B. White, Paul B. Rimmer
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Use of Intramolecular Quinol Redox Couples to Facilitate the Catalytic Transformation of O2 and O2-Derived Species Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-17 Byron H. Farnum, Christian R. Goldsmith
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Transforming Highly Oxidized and Reduced Carbon Feedstocks: Strategies for Catalytic CO2 and CH4 Valorization Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-17 Nilay Hazari, Hannah S. Shafaat, Jenny Y. Yang
Carbon is a ubiquitous element in society as a critical component of materials, medicines, commodity chemicals, and fuels. A primary reason for the broad utility of carbon-containing compounds is the redox and chemical versatility of carbon. Remarkably, a carbon atom can span 9 oxidation states (+4 to −4), with fuels typically consisting of highly reduced carbon-based compounds (−1 to −4), (1) biological
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From the Chemistry of Life’s Emergence to the Chemistry of Life Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-17 Claudia Bonfio, Martina Preiner
Enzymes catalyze cellular chemistry, ultimately enabling life to exist. They are complex and specialized protein catalysts formed by millions of years of evolution. In modern cells, enzymes, and the metabolic reactions accelerated by them, are often localized within highly specialized and organized membrane-bound or membrane-less cellular compartments. In short, catalysis and compartmentalization are
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Lipid Trafficking in Diverse Bacteria Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-16 Jonathan Chiu-Chun Chou, Laura M. K. Dassama
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Triftosylhydrazone in Single-Atom Skeletal Editing Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-16 Zhaohong Liu, Xiaolong Zhang, Paramasivam Sivaguru, Xihe Bi
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Space Exploration of Metal–Organic Frameworks in the Mesopore Regime Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-13 Gaoli Hu, Qi Liu, Hexiang Deng
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Electroreductive Cross-Coupling Reactions: Carboxylation, Deuteration, and Alkylation Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-13 Pengfei Li, Yanwei Wang, Hanying Zhao, Youai Qiu
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Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-12 Xuehua Dong, Ling Huang, Guohong Zou
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Photoresponsive Chemistries for User-Directed Hydrogel Network Modulation to Investigate Cell–Matrix Interactions Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-12 Monica L. Ohnsorg, Ella A. Hushka, Kristi S. Anseth
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N-Acyl-N-alkyl/aryl Sulfonamide Chemistry Assisted by Proximity for Modification and Covalent Inhibition of Endogenous Proteins in Living Systems Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-11 Tomonori Tamura, Itaru Hamachi
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Physics and Chemistry of Two-Dimensional Triangulene-Based Lattices Acc. Chem. Res. (IF 16.4) Pub Date : 2024-12-10 Hongde Yu, Yu Jing, Thomas Heine
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Enhancing Biocatalysis: Metal–Organic Frameworks as Multifunctional Enzyme Hosts Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-28 Fanrui Sha, Xiaoliang Wang, Kent O. Kirlikovali, Omar K. Farha
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Bioinspired Total Synthesis of Natural Products Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-27 Lijun Chen, Peng Chen, Yanxing Jia
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Controlling Hydrogen Evolution and CO2 Reduction at Transition Metal Hydrides Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-26 Andrew D. Cypcar, Jenny Y. Yang
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All-in-One CO2 Capture and Transformation: Lessons from Formylmethanofuran Dehydrogenases Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-25 Olivier N. Lemaire, Tristan Wagner
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n-Type Conjugated Polymers Based on Double B←N Bridged Bipyridine Unit Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-23 Bin Meng, Jun Liu
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Chemical Synthesis and Multihybridization of Small-Sized Hollow Mesoporous Organosilica Nanoparticles Toward Advanced Theranostics Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-22 Yuhang Huang, Cheng Zhang, Liyuan Zhang, Xiaoyuan Chen, Wenpei Fan
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Renewable Fuels and Chemical Recycling of Plastics via Hydrothermal Liquefaction Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-20 Phillip E. Savage
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Emergence of Low-Cost and High-Performance Nonfused Ring Electron Acceptors Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-20 Pengcheng Jiang, Yahui Liu, Jinsheng Song, Zhishan Bo
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Bridging Neuroscience and Engineering with Nano-Neurotechnology Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-19 David Maresca, Arnd Pralle, Bozhi Tian
The past decade has seen an increasing number of technological advances to interface with single neurons and neuronal circuits being applied in vivo. These methods have greatly accelerated our understanding of neural pathways in the brain in health and disease. Additionally, these neurotechnologies hold exciting promise for future neurotherapies. This issue of Accounts of Chemical Research discusses
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The Emerging Roles of Multimolecular G-Quadruplexes in Transcriptional Regulation and Chromatin Organization Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-18 Naura Fakhira Antariksa, Marco Di Antonio
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Adsorption Structure–Activity Correlation in the Photocatalytic Chemistry of Methanol and Water on TiO2(110) Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-13 Shucai Xia, Tianjun Wang, Zefeng Ren, Xueming Yang, Qing Guo, Chuanyao Zhou
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Photocatalysis Meets Copper Catalysis: A New Opportunity for Asymmetric Multicomponent Radical Cross-Coupling Reactions Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-13 Peng-Zi Wang, Bin Zhang, Wen-Jing Xiao, Jia-Rong Chen
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Correction to “Steric and Electronic Influence of Excited-State Decay in Cu(I) MLCT Chromophores” Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-11 Felix N. Castellano, Michael C. Rosko
The slope presented in Figure 11 illustrates a compelling linear correlation over an emission energy range of ∼0.4 eV (∼3200 cm–1) having a slope of −11.3 natural log units/eV, illustrating that energy gap considerations majorly influence excited state decay in this class of chromophores in the absence of donor solvent interactions, regardless of alkyl substitution pattern. This article has not yet
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Origin of the Difference in Proton Transport Direction between Inward and Outward Proton-Pumping Rhodopsins Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-07 Taito Urui, Yasuhisa Mizutani
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Challenges and Opportunities in 2D Materials Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-05 Christopher E. Shuck, Xu Xiao, Zhiyong Wang
Since their discovery in 2004, beginning with graphene, the field of two-dimensional (2D) materials has expanded tremendously as additional families of materials are discovered. These families include MXenes, transition metal dichalcogenides (TMDs), 2D metal–organic frameworks (MOFs) and covalent organic frameworks (COFs), 2D polymers, perovskites, oxides, and many others. 2D materials experience quantum
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[Pd(NHC)(μ-Cl)Cl]2: The Highly Reactive Air- and Moisture-Stable, Well-Defined Pd(II)-N-Heterocyclic Carbene (NHC) Complexes for Cross-Coupling Reactions Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-06 Shiyi Yang, Tongliang Zhou, Xiang Yu, Steven P. Nolan, Michal Szostak
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Chemical-Driven Amyloid Clearance for Therapeutics and Diagnostics of Alzheimer’s Disease Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-04 Hye Yun Kim, YoungSoo Kim
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Misfit Layered Compounds: Insights into Chemical, Kinetic, and Thermodynamic Stability of Nanophases Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-04 Azat Khadiev, M. B. Sreedhara, Simon Hettler, Dmitri Novikov, Raul Arenal, Reshef Tenne
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Nickel-Catalyzed Reductive Alkenylation of Enol Derivatives: A Versatile Tool for Alkene Construction Acc. Chem. Res. (IF 16.4) Pub Date : 2024-11-01 Zhen-Zhen Zhao, Peng Guo, Xiaobo Pang, Xing-Zhong Shu
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Revisiting Pyrimidine-Embedded Molecular Frameworks to Probe the Unexplored Chemical Space for Protein–Protein Interactions Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-31 Jeong Yeon Yoo, Yoona Choi, Heejun Kim, Seung Bum Park
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Design, Exploitation, and Rational Improvements of Diazirine-Based Universal Polymer Crosslinkers Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-31 Mathieu L. Lepage, Stefania F. Musolino, Jeremy E. Wulff
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Surface Structure and Chemistry of CeO2 Powder Catalysts Determined by Surface-Ligand Infrared Spectroscopy (SLIR) Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-30 Chengwu Yang, Hicham Idriss, Yuemin Wang, Christof Wöll
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Controlling Guest Diffusion by Local Dynamic Motion in Soft Porous Crystals to Separate Water Isotopologues and Similar Gases Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-29 Yan Su, Jia-Jia Zheng, Ken-ichi Otake, Nobuhiko Hosono, Susumu Kitagawa, Cheng Gu
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Insulin Stabilization Designs for Enhanced Therapeutic Efficacy and Accessibility Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-28 Yanxian Zhang, Maxwell Jack Austin, Danny Hung-Chieh Chou
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Anion Recognition-Directed Supramolecular Catalysis with Functional Macrocycles and Molecular Cages Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-25 Qi-Qiang Wang
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Two-Dimensional Covalent Organic Frameworks: Structural Insights across Different Length Scales and Their Impact on Photocatalytic Efficiency Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-22 Islam E. Khalil, Prasenjit Das, Arne Thomas
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Sequential Linker Installation in Metal–Organic Frameworks Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-16 Zongsu Han, Yihao Yang, Joshua Rushlow, Rong-Ran Liang, Hong-Cai Zhou
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Broadband Rotational Spectroscopy in Uniform Supersonic Flows: Chirped Pulse/Uniform Flow for Reaction Dynamics and Low Temperature Kinetics Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-15 Nureshan Dias, Nicolas Suas-David, Shameemah Thawoos, Arthur G. Suits
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Conversion of Carbon Dioxide into Molecular-based Porous Frameworks Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-14 Kentaro Kadota, Satoshi Horike
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Mechanisms of Controllable Growth and Ohmic Contact of Two-Dimensional Molybdenum Disulfide: Insight from Atomistic Simulations Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-11 Liang Ma, Xiaoshu Gong, Ruikang Dong, Jinlan Wang
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Activating Metal–Organic Cages by Incorporating Functional M(ImPhen)3 Metalloligands: From Structural Design to Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-09 Yu-Lin Lu, Ya-Ping Wang, Kai Wu, Mei Pan, Cheng-Yong Su
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MOF-on-MOF Growth: Inducing Naturally Nonpreferred MOFs and Atypical MOF Growth Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-10 Sujeong Lee, Gihyun Lee, Moonhyun Oh
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Hierarchical Equations of Motion for Quantum Chemical Dynamics: Recent Methodology Developments and Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-09 Shuming Bai, Shuocang Zhang, Chenghong Huang, Qiang Shi
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Surface Science and Engineering for Electrochemical Materials Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-08 Zhiming Liang, Mohammad Sufiyan Nafis, Dakota Rodriguez, Chunmei Ban
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Superlattice Assembly for Empowering Metal Nanoclusters Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-07 Hao Li, Xi Kang, Manzhou Zhu
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From Catalysis of Evolution to Evolution of Catalysis Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-07 Rotem Edri, Loren Dean Williams, Moran Frenkel-Pinter
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Small Molecule Activation at the acriPNP Pincer-Supported Nickel Sites Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-07 Sanha Park, Kunwoo Lee, Sudakar Padmanaban, Yunho Lee
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Porous Metal Phosphonate Frameworks: Construction and Physical Properties Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-07 Tao Zheng, Wenzhuo Tan, Li-Min Zheng
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Photocatalysis with Covalent Organic Frameworks Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-07 Yongzhi Chen, Donglin Jiang
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Pinpointing Conditions for a Metabolic Origin of Life: Underlying Mechanisms and the Role of Coenzymes Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-05 Joris Zimmermann, Emilie Werner, Shunjiro Sodei, Joseph Moran
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Magnetoelectrics for Implantable Bioelectronics: Progress to Date Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-04 Fatima Alrashdan, Kaiyuan Yang, Jacob T. Robinson
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Chiral Organometallic Complexes Derived from Helicenic N-Heterocyclic Carbenes (NHCs): Design, Structural Diversity, and Chiroptical and Photophysical Properties Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-03 Debsouri Kundu, Natalia Del Rio, Jeanne Crassous
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Emergent Research Trends on the Structural Relaxation Dynamics of Molecular Clusters: From Structure–Property Relationship to New Function Prediction Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-03 Binghui Xue, Yuyan Lai, Linkun Cai, Yuan Liu, Jia-Fu Yin, Panchao Yin
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Selective Functionalization of Alkenes and Alkynes by Dinuclear Manganese Catalysts Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-02 Fei Wang, Guichao Dong, Suqi Yang, Cheng-Long Ji, Kai Liu, Jie Han, Jin Xie
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Solid-Solution MXenes: Synthesis, Properties, and Applications Acc. Chem. Res. (IF 16.4) Pub Date : 2024-10-02 Arunoda Lakmal, Pratiksha B. Thombre, Christopher E. Shuck
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Hydroxylamines: From Synthetic Intermediates to Synthetic Targets Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-30 Roderick W. Bates
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Toward Quantum Noses: Quantum Chemosensing Based on Molecular Qubits in Metal–Organic Frameworks Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-26 Akio Yamauchi, Nobuhiro Yanai
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Building Catalytic Reactions One Electron at a Time Acc. Chem. Res. (IF 16.4) Pub Date : 2024-09-24 Julian G. West