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Correction to “Steric and Electronic Influence of Excited-State Decay in Cu(I) MLCT Chromophores”
Accounts of Chemical Research ( IF 16.4 ) Pub Date : 2024-11-11 , DOI: 10.1021/acs.accounts.4c00720
Felix N. Castellano, Michael C. Rosko

The slope presented in Figure 11 illustrates a compelling linear correlation over an emission energy range of ∼0.4 eV (∼3200 cm–1) having a slope of −11.3 natural log units/eV, illustrating that energy gap considerations majorly influence excited state decay in this class of chromophores in the absence of donor solvent interactions, regardless of alkyl substitution pattern. This article has not yet been cited by other publications.

中文翻译:


更正“Cu(I) MLCT 发色团中激发态衰变的空间位位和电子影响”



图 11 中的斜率说明了在 ∼0.4 eV (∼3200 cm–1) 的发射能量范围内具有令人信服的线性相关性,斜率为 −11.3 自然对数单位/eV,表明在没有供体溶剂相互作用的情况下,能量隙考虑主要影响这类发色团的激发态衰变,而与烷基取代模式无关。 本文尚未被其他出版物引用。
更新日期:2024-11-12
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