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Mechanistic insights into rhodium-catalyzed C–H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-13 Yuqin Wang, Yiling Zeng, Ya-Nan Tian, Zheng Liu, Jinhua Wang, Shuyou Chen, Shiqing Li
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Intermolecular defluorinative 1,2-diamination of fluoroalkenyl iodides with sulfonamides: synthesis of acyclic and cyclic fluorinated 1,2-enediamines Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-13 Xue-Qiang Chu, Yu-Lan Chen, Chi Zhang, Xue-Ying Huang, Yu Ding, Danhua Ge, Zhi-Liang Shen
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One-pot synthesis of 2,2′-biquinolines from aromatic amines using oxygen as an oxidant under metal-free conditions Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-14 Yunfeng Liao, Hualan Gao, Hongrui Qi, Jia Chen, Chang Liu, Yanjun Xie, Weijie Zhang, Jiyong Deng, Bing Yi, Guo-Jun Deng
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A visible light-mediated deoxygenation protocol for the synthesis of dipeptides, amides and esters without racemization Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-14 Ji-Wei Ren, Qing-Long Tan, Jian Zuo, Yan-Fei Miao, Pan Zhang, Jing-Hui Sun, Yin-Feng Han
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A catalytic atroposelective Friedel–Crafts alkylation to access axially chiral C2-arylindoles via dynamic kinetic resolutions Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-13 Jiang Deng, Wei Li, Chenhao Zhou, Zhiming Li, Haibo Zhou, Junyuan Yan, Zhouyu Wang, Shan Qian, Xiao-Long He
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π-Extended regioisomeric dithienoacene-fused pyrenes: structures, properties, and application in field-effect transistors Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-13 Bin Lu, Shiqian Zhang, Dong Liu, Wendong Jin, Dalin Li, Zhiqiang Liu, Tao He
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Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-12 Peng Wang, Qiang Wang, Meng Wang, Liang Wang, Lubin Xu, Xiong-Li Liu, Fangzhi Hu, Shuai-Shuai Li
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Transition-metal-free skeletal editing of benzoisothiazol-3-ones to 2,3-dihydrobenzothiazin-4-ones via single-carbon insertion Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-07 Ke Yang, Qin Li, Yanqi Luo, Dan Yuan, Chunjian Qi, Zhengyi Li, Bijin Li, Xiaoqiang Sun
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Rhodium-catalyzed synthesis of N-substituted 3-acylpyrroles from enaminones and vinylene carbonate Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-12 Jian-Bo Ma, Yi-Mai Yin, Xing-Mei Hu, Bi-Na Shao, Kun Huang, Qing-Sheng Zhao, Sheng-Jiao Yan
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Hemilabile P,N-ligand-assisted gold catalyzed Hiyama allylation to access allylarenes and 1,4-diene derivatives Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-12 Yuanhao He, Wanping Ma, Yu Zhong, Yanfei Hu, Mingou Li, Fen Zhao, Zhonghua Xia, Baomin Fan
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PIFA-mediated cyclization of methyl(2-(1-phenylvinyl)phenyl)sulfane for the concise, flexible, and scalable de novo synthesis of C3-arylated benzo[b]thiophenes Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-12 Xinya Liu, Olivier Provot, Christine Tran, Jean François Soulé, Abdallah Hamze
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Rh-Catalysed hydroacyloxylation of cyclopropenes: regio- and diastereoselective synthesis of acyloxycyclopropanes Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-12 Ángel Manu Martínez, Gema Domínguez, Inés Alonso, Marta Palaín, Javier Pérez-Castells
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Integrating electrocatalysis with biocatalysis for asymmetric synthesis Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-06 Yuqi Lin, Jiage Yu, Ke-Yin Ye
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Stereocontrolled synthesis of heterocycles from unactivated alkynes by photoredox/nickel dual-catalyzed cyclization Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-06 Bo-Rong Leng, Feng Yang, Jin-Lian Bai, Yu-Wen Huang, Qing-Quan Liu, Ping Wei, De-Cai Wang, Yi-Long Zhu
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Iridium-catalyzed asymmetric cascade allylation/lactonization of methyl salicylates: enantioselective construction of chiral benzodioxepinones Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-05 Bendu Pan, Yunru Wu, Yaqi Zhang, Xiaobo He, Long Jiang, Liqin Qiu
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Nickel-catalyzed reductive 1,2-alkylarylation of alkenes via a 1,5-hydrogen atom transfer (HAT) cascade Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-05 Xi Chen, Qiang Wang, Xiao-Ping Gong, Rui-Qiang Jiao, Xue-Yuan Liu, Yong-Min Liang
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Probing intersystem crossing in multi-brominated eumelanin through transient absorption and surface hopping dynamics Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-08 Kavya Vinod, Lukhmanul Hakeem K., Diana Thomas, Pallavi Panthakkal Das, Mahesh Hariharan
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Thiocyanoalkylation of alkenes via dual photoredox and copper catalysis Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-07 Xu Wang, Bi-Yin Xiao, Qi-Xuan Jiang, Wei Huang, Feng-Hua Zhang
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A stereoselective organocatalyzed C-glycosylation of indole: implications of acceptor–catalyst–donor interactions Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-07 Lihuang Xie, Wenchao Liu, Zhenbo Guo, Qinbo Jiao, Xiaomin Shen, Tianfei Liu, Chunfa Xu
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Regio- and stereoselective azidation of activated N-allenamides: an entry to α, β, γ and δ-amido-azides Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-04 Dorian Schutz, Maxime Hourtoule, Laurence Miesch
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Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-06 Jiale Li, Lingfei Wang, Pei-Nian Liu, Xingguang Li
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Mechanism and origins of regioselectivity of selenium-catalyzed allylic amination reactions Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-05 Xiaoxiao Hu, Dengmengfei Xiao, Yu Chen, Yi Lu, Zhihan Zhang, Peiyuan Yu
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DABSO-mediated Pummerer reaction enables one-pot synthesis of pyrroloquinolines for accessing marinoquinolines: mechanistic, photophysical and pharmacological investigations Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-05 Rahimuddin Khan, Dipun Kumar Penthi, Aditi Chatterjee, Chandrakanta Sahoo, Shanti Gopal Patra, Viswanathan Arun Nagaraj, Tabrez Khan
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Palladium-catalyzed cascade decarboxylative cyclization of alkyne-tethered aryl iodides with o-bromobenzoic acids for the synthesis of fused isoquinolinones Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-05 Zhaolin Quan, Yubo Duan, Zhengkai Chen
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Enantioselective addition of 3-hydroxyquinolin-2(1H)-one to isatin and pyrazole-4,5-dione derived ketimines Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-05 Yue Wei, Guishun Bai, Jiamin Wu, Yi Hua, Tao Zhang, Congyong Yue, Hong Wang, Xiaoze Bao
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Copper-catalyzed alkynyldisulfuration of arynes: efficient access to unsymmetrical disulfides Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-05 Shuai Huang, Yumin Zhang, Yuekai Li, Chen-Ho Tung, Xin Li, Zhenghu Xu
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Impact of boron desymmetrization on supramolecular polymerization of BODIPY dyes Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-04 Tobias B. Tischer, Zulema Fernández, Lorenz Borsdorf, Constantin G. Daniliuc, Shigehiro Yamaguchi, Soichiro Ogi, Gustavo Fernández
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Photocatalytic arylation/alkylation of olefins/alkynes via halogen-atom transfer mediated by NHC-BH3 Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Xinhan Li, Yao Zhong, Fengsong Tan, Yusong Fei, Xiaohan Zhao, Jianbin Xu, Baomin Fan
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Synthesis of bambusurils with perfluoroalkylthiobenzyl groups as highly potent halide receptors Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Matúš Chvojka, Hennie Valkenier, Vladimír Šindelář
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Palladium-catalyzed synthesis of indene-1-acetates via sequential double carbopalladation and aryloxycarbonylation Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-28 Fei Sun, Yiyi Zheng, Zhongyao Jiang, Mingxia Wu, Zeng Lv, Hongsen Ji, Xin-Xing Wu
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Mechanistic insight into the dehydrogenation reaction catalyzed by an MLC catalyst with dual ancillary ligand sites Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Gui-Xiang Zhou, Cheng Hou
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Visible-light responsive defluorination-acyl fluoride exchange for photoclick labeling based on phenoxazine chromophores Org. Chem. Front. (IF 4.6) Pub Date : 2024-11-01 Lijun Deng, Sitong Li, Cefei Zhang, Yuqiao Zhou, Zhishan Su, Changwei Hu, Xiaohu Zhao, Zhipeng Yu
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Facile one-pot synthesis of novel imidates as multifunctional organic fluorescent materials Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-30 Feng-Ting Liu, Shuo Wang, Yong-Shun Chen, Jun-Ying Miao, Bao-Xiang Zhao, Zhao-Min Lin
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HSAB theory guiding electrophilic substitution reactions of o-carborane Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-26 Yan Wang, Yi-Ge Li, Feijing Chen, Yan-Na Ma, Xuenian Chen
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Metal–ligand cooperation and synergistic palladium catalysis for the dual ligand system [2,2′-bipyridin]-6(1H)–one/PCy3: milder conditions for the undirected C–H arylation of arenes Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-30 Cintya Pinilla, Mario García-Zarza, Ana C. Albéniz
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Iron-catalyzed thiolation of C(sp3)–H with sulfonyl chlorides via photoinduced ligand-to-metal charge transfer Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Sheng-Ping Liu, Lan Yang, Yan-Hong He, Zhi Guan
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Shaping cycles with light: a regiodivergent approach to tetracyclic aza-aromatic compounds Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-28 Clara Mañas, Belén Ibarra, Estíbaliz Merino
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C–H acylation as an enabling tool to tag phenolic drugs Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-28 Carlota Girón-Elola, Arkaitz Correa
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The reactivity of alkenyl boron reagents in catalytic reactions: recent advances and perspectives Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Ya-Li Feng, Bo-Wen Zhang, Youzhi Xu, Shengnan Jin, Daniele Mazzarella, Zhong-Yan Cao
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Recent advances in carbon atom addition for ring-expanding single-atom skeletal editing Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Ting Yuan, Lei Shi
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Copper(II)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Hong Xu, Jie Liao, Fei Ren, Chuan-Rong Zhou, Xiao-Zhuo Liu, Yao Xiao, Dong-Wei Hang, Fuyu Li, Bei Wang, Ji-Yu Wang
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Photoinduced cobaloxime catalysis for allylic mono- and diphosphinylation of alkenes with hydrogen evolution Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Aijun Zhang, Miao-Miao Li, Lei Guo, Huaixiang Yang, Jiefei Guo, Da Xu, Wei Ding
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Facile single-step synthesis of pentaaryl-substituted pyrano[3,2-b]pyrrol-5(1H)-ones showing aggregation-induced emission Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Yongfeng Wang, Ruijun Chu, Yanxiao Wang, Mengyuan Zhou, Yuan Chen, Cheng Xu, Jingyu Sun, Guodong Yin
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Stereoselective access to furan-fused [5.5.0] bicyclic heterocycles enabled by gold-catalyzed asymmetric [8 + 4] cycloaddition Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-29 Xunhua Wang, Jianhua Wang, Xiaoxun Li
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A two-step Kinugasa/Conia-ene-type sequential reaction for the asymmetric synthesis of 8-methylene-2,6-diazaspiro[3.4]octane-1,5-diones Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-28 Shanyue Li, Qicai Ma, Bohua Wu, Haowen Ma, Wei Zhou, Qian Cai
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Magic effect of diphenylprolinol silyl ether for the enantioselective allenation of 2-alkynals Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-28 Guolin Wu, Zhen Liu, Shiwen Fan, Wenyao Li, Xue Zhang, Hui Qian, Shengming Ma
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Photocatalytic hydrotrichloromethylation of unactivated alkenes with chloroform Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-22 Dawei Gong, Caiyu Gao, Qixuan Li, Yufei Li, Lina Zhao, Degong Kong
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Pyrrolylsulfonium salts: stable, accessible and versatile pseudohalides for Stille couplings Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-24 Jodie L. Hann, Catherine L. Lyall, Gabriele Kociok-Köhn, Simon E. Lewis
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I2-Promoted oxidative annulation of three different amines to access diverse biheteroaryls Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-25 Guangping Fan, Penghui Cao, Fang Bai, Yanyan Yin, Xueyan Hou, Yani Liu, Zhenzhen Xing, Yanhui Wang, Tangqiang Sun, Qinghe Gao
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Manganese(III) acetate in organic synthesis: a review of the past decade Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-24 Jian Wang, Yan Zhang, Ying Zhou, Xin Gu, Bingxu Han, Xuelu Ding, Shuai Liang
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Synergy of prediction rule and total synthesis in solving the stereochemical puzzle of eucalactam B Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-24 Chenqi Wang, Junyang Liu, Tao Ye
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Mechanistic insight into Ni(I)-catalyzed regioselective alkene hydroarylation: is it carbonickelation or hydronickelation? Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-23 Wen-Yan Tong, Zhizheng Chen, Shuanglin Qu, Xiaotai Wang
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Regioselective syn-1,2-hydroarylation of internal alkynes Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-19 Shubham Dutta, Manoj Sethi, Avijit Maity, Aradhana Sahoo, Vincent Gandon, Akhila K. Sahoo
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Intermediate diradical character and thermal cis–trans isomerization of near-infrared absorbing thionated squaraine dyes Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-23 Taishi Oka, Takeshi Maeda, Daisuke Sakamaki, Naoya Suzuki, Shigeyuki Yagi, Shintaro Kodama, Hideki Fujiwara
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Electrochemically promoted diamidation of alkenes to dihydroimidazole skeleton Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-17 Guo-Ao Wang, Kai-Wei Chen, Yu-Da Huang, Yu-Yuan Zhang, Xiu-Jin Meng, Fei-Hu Cui, Ying-Ming Pan, Hai-Tao Tang
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Palladium-catalyzed hydrocarbonylative cross-coupling with two different alkenes Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-22 Yi Chen, Jianing Wu, Yongzheng Ding, Hanmin Huang
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Lewis acid-controlled Pd-catalyzed chemodivergent hydrocyanation of cyclopropenes Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-22 Rongrong Yu, Song-Zhou Cai, Xianjie Fang
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Metal-free visible-light-induced borylative/silylative pyridylation of vinylarenes Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-22 Yiting Zhou, Bin Liu
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Multi-step chirality transfer and racemization kinetics of pillar [5]arenes by tuning the halogen substituents on the rims Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-22 Lizhi Fang, Xiaowen Guan, Yanling Shen, Dayang Zhou, Long Chen, Xiaochuan Chen, Wanhua Wu, Leyong Wang, Cheng Yang
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State-of-the-art strategies for Lewis acid-catalyzed strain-release cycloadditions of bicyclo[1.1.0]butanes (BCBs) Org. Chem. Front. (IF 4.6) Pub Date : 2024-10-21 Xiang Liu, Jiawei He, Keyu Lin, Xingyue Wang, Hua Cao
更新日期：2024-11-08
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