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Outstanding Reviewers for Organic Chemistry Frontiers in 2023 Org. Chem. Front. (IF 4.6) Pub Date : 2024-07-02
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Recent advances on carbon nitride-based photocatalysts for organic transformations in aqueous media Org. Chem. Front. (IF 4.6) Pub Date : 2024-07-02 Pengfei Zhou, Yunfei Cai, Yurong Tang
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Catalytic transformations of alkenes via nickelacycles Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-28 Meng-Ying Qian, Kai-Xiang Zhang, Li-Jun Xiao
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Facile synthesis of alkylphosphonates from 4-alkyl-1,4-dihydropyridines via photoinduced formal deformylative phosphonylation Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Huan Zhang, Zhonghe Cui, Jian Wang, Lin Zhu, Chaozhong Li
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Insights into the mechanism and origin of solvent-controlled chemodivergence in the synthesis of Au-catalyzed bicyclo[2.2.1]heptanes from 3-alkoxy-1,6-diynes: a DFT perspective Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Aili Feng, Dongju Zhang
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Nickel-catalyzed arylative cyclization of 1,6-enynes: arylation of unactivated alkene moieties Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Jian Gao, Qi Wei, Zeqing Zhang, Zhishan Su, Jialin Ming, Yongmin Zhang
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Chemoselective reaction of methoxyaminomethyl BODIPYs with unprotected carbohydrates: a powerful tool for accessing BODIPY neoglycosides Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Ana M. Gómez, Luis García-Fernández, Andrés G. Santana, Clara Uriel, Leire Gartzia-Rivero, Jorge Bañuelos, Inmaculada Garcia-Moreno, Lourdes Infantes, María Rosa Aguilar, J. Cristobal Lopez
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Stereoselective strain-release Ferrier rearrangement: the dual role of catalysts Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Huajun Zhang, Aoxin Guo, Han Ding, Yuan Xu, Yuhan Zhang, Dan Yang, Xue-Wei Liu
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Photoredox-catalyzed selective deuterodefluorination of α,α-difluoroarylacetic esters and amides Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-22 Zi-Hang Yuan, Hong Xin, Yuan Gao, Guo-Wei Sun, Rui-Ying Zhao, Xin-Hua Duan, Li-Na Guo
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A novel approach to the tetracyclic frameworks of anislactone-type sesquiterpenoids Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-26 Long He, Xiaocheng Zhang, Sen Li, Xuexue Tian, Yimeng Han, Haitao Xie, Weiqing Xie
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Green synthesis of glutaramides, piperidino[1,2-a]benzimidazol-1-ones and N-cyclopentenyl benzimidazolones enabled by microwave assisted domino reactions of cyclic 2-diazo-1,3-diketones with aniline derivatives Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-26 Cheng Zhao, Xiao-Wei Hu, Yi-Bin Xu, Xiong-Wei Liu, You-Ping Tian, Yun-Lin Liu
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A copper-catalyzed annulation reaction of diazo esters with propargyl amines for the synthesis of 2,5-dihydropyrroles Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-26 Haodong Xie, Wei Zhao, Heping Wei, Yang Yu, Lili Zhao, Jonathan B. Baell, Fei Huang
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Access to spiro-bicyclo[2.1.1]hexanes via BF3·Et2O-catalyzed formal [2π + 2σ] cycloaddition of bicyclo[1.1.0]butanes with benzofuran-derived oxa(aza)dienes Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Jia-Yi Su, Jian Zhang, Zhi-Yun Xin, Hao Li, Hanliang Zheng, Wei-Ping Deng
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Palladium(II)-catalyzed intramolecular C–H amination to carbazole: the crucial role of cyclic diacyl peroxides Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Ting Yuan, Kang Fu, Lei Shi
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Divergent pentafluoroethylation of styrene derivatives using CuCF2CF3 Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Zhengjie Fu, Gavin Chit Tsui
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Visible-light-mediated synthesis of polysubstituted pyrroles via CAr–I reduction triggered 1,5-hydrogen atom transfer process Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-25 Junlei Wang, Qinglin Xie, Guocheng Gao, Guofen Wei, Xinxin Wei, Xuemei Chen, Daohai Zhang, Hongqing Li, Binbin Huang
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Stereo-selective synthesis of complex dienes and eneynes by sequential hydroarylation and olefinic C–H functionalization Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-24 Yuhang Zhu, Xiaoli Li, Cheng Zhang, Xiuying Liu, Linzhi Huang, Yongbo Zhang, Chao Shen, Liyuan Ding, Guofu Zhong, Jian Zhang
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Benzeneseleninic acid used as an oxidizing and deprotecting reagent for the synthesis of multi-cyclic peptides constrained by multiple disulfide bonds and thioether bridges Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-18 Yueyue Xing, Tianyu Bo, Nan Zhang, Meiqi Wu, Jiawei Wang, Shigang Shen, Yafang Wang, Changying Song, Tiesheng Shi, Shuying Huo
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Site-specific DNA post-synthetic modification via fast photocatalytic allylation Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-18 Ying Huang, Yixin Zhang, Chenchen Hu, Yiyun Chen
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Elucidating the mechanism and origin of diastereoselectivity in scandium-catalyzed β-C(sp3)–H activation and transformation of an aliphatic aldimine Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Yiran Zhang, Yang Wang
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Brønsted acid-mediated selective α-alkenylation of 3,4-dihydro-2H-pyrans Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Nan Chen, Chaokun Li, Shangteng Liao, Jinglong Chen, Xingxing Ma, Qiuling Song
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Direct synthesis of gold(III)-annulated perylene diimides via multiple C–H aurations Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-21 Wei Chen, Qing-Yu Yang, Kongchuan Wu, Jianbin Lin, Hui-Jun Zhang
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Lewis acid-catalyzed phosphinoylation and halogenation of α,β-unsaturated ketones: access to γ-halo allylic phosphonates Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Xiao-Hong Wei, Ya-Wen Xue, Chun-Yuan Bai, Xuan Liu, Xiao-Hong Wang, Yan-Bin Wang, Qiong Su
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Access to chiral sulfones with an all-carbon quaternary stereocenter from sulfur dioxide Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Chunxi Huang, Xuemei Zhang, Liping Luo, Xiuwen Jia, Jian Liao, Zhong Lian
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Direct C–H sulfonylation of hydrazones involving the insertion of SO2 Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Mengzhao Yu, Shuizhen Lin, Shuoshuo Zhang, Xinkui Lin, Xiaolei Huang
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Photoredox-catalyzed oxytrifluoromethylation of alkenes toward CF3-containing five-membered cyclic carbonates Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-20 Yihui Mao, Xiangquan Wang, Chengcheng Zhong, Jinkang Jin, Zhan Lu
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Directing group controlled regioselective C–H borylation of 2-arylphenolic compounds at room temperature Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-18 Jiao Kang, Jing Liu, Zhilong Chen
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Copper/ruthenium relay catalysis for stereodivergent construction of 1,4-nonadjacent stereocenters: mechanistic investigation using DFT calculations Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-13 Congcong Huang, Biyao Yang, Keying Zhang, Juan Li
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Precision single-atom editing: new frontiers in nitrogen insertion and substitution for the generation of N-heterocycles Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Xue Li, Jia Xu, Zhi-Gang Xu
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One-pot multistep synthesis of 1-fluoroalkylisoquinolines and fused fluoroalkylpyridines from N-fluoroalkyl-1,2,3-triazoles Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-18 Anna Kubíčková, Svatava Voltrová, Adam Kleman, Blanka Klepetářová, Petr Beier
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Photocatalyzed sulfoximination/amidation of (Het)arylethenes tethered N-tosyl amide: a versatile entry to sulfoximidoyl β- and γ-lactams Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-18 Chengtan Li, Yuming Yang, Xiaolan Zheng, Cairong Zhang, Hui Cai, Weilong Lin
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Photo-induced synthesis of fluoroalkylated quinolinones via an iron-catalyzed LMCT decarboxylation process Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-18 Zhuoheng Song, Lin Guo, Chao Yang, Wujiong Xia
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Restoring the pH-responsiveness for amine-conjugated 2-propionic-3-methylmaleic anhydride linkers Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-18 Alina G. Heck, Lutz Nuhn
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A visible light-induced deoxygenative amidation protocol for the synthesis of dipeptides and amides Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Ji-Wei Ren, Cheng-Shuai Han, Huai-Xin Zhang, Qing-Hao Zhang, Xian-Ting Song, Jing-Hui Sun
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Synthesis of axially chiral biaryls via Pd(II)-catalysed direct C(sp2)–H arylation Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-17 Diksha Parmar, Rohit Kumar, Sarthi, Akhilesh K. Sharma, Upendra Sharma
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Electroreduction strategy: a sustainable tool for the generation of aryl radicals Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-15 Xiao-Qing Xie, Wei Zhou, Ruchun Yang, Xian-Rong Song, Mu-Jia Luo, Qiang Xiao
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A domino [3 + 2] cycloaddition/deamination/imine hydrolysis reaction of cyclopropyl spirooxindoles with thiourea for access to spiro-γ-thiolactone oxindoles Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-15 Hai-Ting Wang, Xiao-Lin Wen, Xiao-Lin Xu, Dong-Chao Wang, Hai-Ming Guo
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Enantioselective synthesis of unsymmetrical α,α-diarylacetates via organocatalyzed formal C–H insertion reactions of sulfoxonium ylides with indoles and pyrroles Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-11 Xin Yue, Shi-Jia Li, Tianyuan Ou, Zhenying Xiong, Feng Jiang, Ying Zhou, Lijuan Song, Yupei Zhao, Wengang Guo
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A general photochemical strategy for the oximation of activated alkenes without a catalyst Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-11 Hongyan Lan, You Su, Yikun Chen, Xiaozhi He, Dingyi Wang
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Unleashing the potentiality of metals: synergistic catalysis with light and electricity Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-10 Zhengjia Shen, Jia-Lin Tu, Binbin Huang
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Ir/Co dual catalyzed hydroacylation of electron-deficient alkenes overcoming redox potential limitations Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-14 Yi Zhou, Yong-Qin He, Xia Nie, Lin Lu, Xian-Rong Song, Zhao-Zhao Zhou, Wan-Fa Tian, Qiang Xiao
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A pyrene–calix[4]triazolium conjugate for fluorescence recognition of hydrogen sulfate Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-13 Jihee Cho, Rakesh Parida, Changhyun Lim, Jin Yong Lee, Jong Seung Kim, Sanghee Kim
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Electrochemical aminotrideuteromethylthiolation of isocyanides with anilines and CD3SSO3Na Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-12 Lin Zhao, Xinyu Zhou, Kemeng Zhang, Siyu Han, Ge Wu
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Enhancing the binding of calix[5]arene containers for ferrocenes by a fluorophobic effect through the release of high-energy perfluoro-1-iodoalkanes Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-12 Jiabin Xing, Qihan Lin, Sheng-Yi Zhuang, Gang Wu, Jiangshan Zhang, Hui Wang, Dan-Wei Zhang, Zhan-Ting Li
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Base-controlled selective cleavage of the C–F bond of difluorocarbene for the divergent assembly of indolizines Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-12 Chun-Yan Wu, Xiang-Long Chen, Dong-Sheng Yang, Yong-Xing Tang, Li-Sheng Wang, Yan-Dong Wu, Shi-Yi Zhuang, An-Xin Wu
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Pd-catalyzed relay Heck arylation of alkenyl alcohols with arylsulfonium salts Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-12 Jia-Wei Song, Fang Xia, Xiu-Lan Zhang, Cheng-Pan Zhang
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Dearomative difunctionalization of arenes via highly selective radical relay reactions Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-11 Ning Lei, Qian Zhang, Pan Tao, Cong Lu, Qian Lei, Ke Zheng
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An efficient platform for decarboxylative functionalization of carboxylic acids using sulfuryl fluoride: Pd-catalyzed decarboxylative dehydrogenation of alkanecarboxylic acids and decarboxylative cross-coupling of arenecarboxylic acids Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-06 Chenfei Guan, Huijie Qi, Linjun Han, Guofu Zhang, Jinghui Lyu, Chengrong Ding
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Synthesis of polysubstituted fused pyrrolidines via [2 + 2]/[2 + 3] cycloaddition of azomethine ylides Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-05 Chunyan Ou, Jian Wang, Pingping Yin, Bin Chen, Ping Hu, Bi-Qin Wang, Peng Cao, Minghui Xu
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Strategic convergent synthesis en route to Veratrum steroidal alkaloids Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-10 Zhuo Wang
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Photoredox-catalyzed hydrogenation of alkenes assisted by an in situ generated PPh3(OH) radical and acetic acid Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-07 Zhen-Zhen Xie, Yu Zheng, Zi-Hao Liao, Chu-Ping Yuan, Ming-Zhi Li, Ke-Yi Deng, Hao-Yue Xiang, Kai Chen, Hua Yang
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Silanes as a versatile hydride source for Ni–H catalysis: a promising tool for π-hydro functionalization Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-07 Yafia Kousin Mirza, Partha Sarathi Bera, Sachin Balaso Mohite, Ajeet Kumar Pandey, Milan Bera
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Catalytic alkane C–H functionalization by carbene insertion into unactivated C(sp3)–H bonds Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-07 Yongzhen Pan, Yeming Wang, Swastik Karmakar, Paramasivam Sivaguru, Zhaohong Liu
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An aryl-to-alkyl radical relay arylation reaction of a remote C(sp3)–H bond using 1,4-dicyanobenzene as an electrochemical redox-mediator Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-07 Weijie Yu, Hongjie Zhang, Zhipeng Shen, Lingyun Yang, Jin Luo, Wendong Li, Kuang Zhao, Xiaolong Li, Jiale Xu, Yuan Zhou, Tao Wang
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A pyridine-boryl radical mediated cascade reaction towards the synthesis of indolizines: a computational mechanistic analysis Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-06 Xinyu Zhang, Xiangxue Cao, Lanfeng Wei, Zhijun Wang, Yu Wei, Liang Xu, Genping Huang
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Reversal of enantioselectivity in cobalt(II)-catalyzed asymmetric Michael–alkylation reactions: synthesis of spiro-cyclopropane-oxindoles Org. Chem. Front. (IF 4.6) Pub Date : 2024-05-31 Jun-Hao Zhang, Wei-Jing Yang, Ning Li, Yin Tian, Ming-Sheng Xie, Hai-Ming Guo
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Selective C2 and C3 phosphorylmethylation of indoles with a phosphorylmethyl dibenzothiophenium reagent Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-05 Xiaomin Shi, Hongmei Qu, Yaxing Wu, Fei Wang, Chao Chen
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Three-component formal metathesis via remote activating strategy enabled (RASE) domino activation of two C(sp3)–O bonds in alkyl ethers Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-04 Dailin Zhuang, Le Cheng, Yichuan Yan, Yuting Tang, Zhenyang Wan, Jiahao Gu, Yuhong Lu, Xinyao Li, Ziyuan Li
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A palladium-catalyzed decarboxylative (5 + 5) cyclization reaction of vinyloxazolidine-2,4-diones: access to ten-membered N,O-containing heterocycles Org. Chem. Front. (IF 4.6) Pub Date : 2024-06-04 Xiao-Hui Fu, Juan Liao, Zhen-Hua Wang, Zhen-Zhen Ge, Ming-Qiang Zhou, Yong You, Yan-Ping Zhang, Jian-Qiang Zhao, Ji-Hong Lu, Wei-Cheng Yuan
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“On-water” defluorinative cyclization of trifluoromethyl enones with phosphine oxides: synthesis of polysubstituted furans Org. Chem. Front. (IF 4.6) Pub Date : 2024-05-29 Man-Hang Feng, Shu-Ji Gao, Xiao-Ying Li, Mengtao Ma, Zhi-Liang Shen, Xue-Qiang Chu