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From Elementary to Advanced Design of Functional Metal–Organic Frameworks: A User Guide to Deciphering the Reticular Chemistry Toolbox Adv. Mater. (IF 27.4) Pub Date : 2024-12-20 Vincent Guillerm, Hao Jiang, Dalal Alezi, Norah Alsadun, Mohamed Eddaoudi
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Guided and Space Waves Multiplexed Metasurface for Advanced Electromagnetic Functionalities in Microwave Region Adv. Mater. (IF 27.4) Pub Date : 2024-12-20 Chunsheng Guan, Tong Cai, Lei Zhu, Jianqiao Han, Chang Ding, Shah Nawaz Burokur, Qun Wu, Xumin Ding
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Bright and Efficient CsSnBr3 Light-Emitting Diodes Enabled by Interfacial Reaction-Assisted Crystallization Adv. Mater. (IF 27.4) Pub Date : 2024-12-19 Jinyi Li, Yang Liu, Jiejun Zeng, Siyu He, Xitong Zhu, Xiaoyue Sun, Yizheng Jin
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Self-Adaptive Zwitterionic Polysilazane Coatings with Mechanical Robustness, High Transparency, and Broad-Spectrum Antiadhesion Properties Adv. Mater. (IF 27.4) Pub Date : 2024-12-19 Yinjie Huang, Zhenqiang Zhang, Bin Zhang, Chunfeng Ma, Guangzhao Zhang
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A Self-Assembled Nano-Molecular Glue (Nano-mGlu) Enables GSH/H2O2-Triggered Targeted Protein Degradation in Cancer Therapy J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-20 Jie Sun, Mingxi Gu, Lvyang Peng, Jing Guo, Peng Chen, Yalei Wen, Fang Feng, Xiaojuan Chen, Tongzheng Liu, Yongheng Chen, Xiaoyun Lu, Liqian Gao, Shao Q. Yao, Peiyan Yuan
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Bidentate Lewis Base Ligand-Mediated Surface Stabilization and Modulation of the Electronic Structure of CsPbBr3 Perovskite Nanocrystals J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-20 Md. Samim Hassan, Pooja Basera, Bilawal Khan, Arsenii S. Portniagin, Kunnathodi Vighnesh, Ye Wu, Daniil A. Rusanov, Maria Babak, Jr-Hau He, Michal Bajdich, Andrey L. Rogach
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High Molecular Conductance and Inverted Conductance Decay over 3 nm in Aminium-Terminated Carbon-Bridged Oligophenylene-Vinylenes J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-20 Luisa K. I. Rieger, Susanne Leitherer, William Bro-Jo̷rgensen, Gemma C. Solomon, Rainer F. Winter
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Two Blatter Radicals Face-to-Face: A Constrained Diradical Architecture J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-20 Paulina Bartos, Dominika Pomikło, Kadin B. Sorenson, Oleksandr Hietsoi, Andrienne C. Friedli, Piotr Kaszyński
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Total Syntheses of Scabrolide B, Ineleganolide, and Related Norcembranoids J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-20 Emma J. Simmons, David B. Ryffel, Diego A. Lopez, Yaroslav D. Boyko, David Sarlah
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Oxygen Dimerization-Driven Cation Migration Induces Voltage Hysteresis in Disordered Rocksalt Cathodes J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Byunghoon Kim, Peichen Zhong, Yunyeong Choi, Shashwat Anand, Han-Ming Hau, Bowen Deng, Gerbrand Ceder
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Discovery of a Gut Bacterial Pathway for Ergothioneine Catabolism J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Chenxi Feng, Qiongxiang Yan, Xianyi Li, Hong Zhao, Hua Huang, Xinshuai Zhang
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Stereo-Differentiating Asymmetric Rh(I)-Catalyzed Pauson–Khand Reaction: A DFT-Informed Approach to Thapsigargin Stereoisomers J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Fatemeh Haghighi, Luke T. Jesikiewicz, Corrinne E. Stahl, Jordan Nafie, Amanda Ortega-Vega, Peng Liu, Kay M. Brummond
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Enriched Molecular-Level View of Saline Wetland Soil Carbon by Sensitivity-Enhanced Solid-State NMR J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Wancheng Zhao, Elizabeth C. Thomas, Debkumar Debnath, Faith J. Scott, Frederic Mentink-Vigier, John R. White, Robert L. Cook, Tuo Wang
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Controllable Active Intermediate in CO2 Hydrogenation Enabling Highly Selective N,N-Dimethylformamide Synthesis via N-Formylation J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Jieyun Zhang, Guanna Li, Jin Xie, Yang Hai, Weiming Wan, Haotian Sun, Bin Wang, Xiaojing Wu, Jiannian Cheng, Changxin He, Wei Hu, Ying Zhang, Zelong Li, Can Li
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Unraveling Hydration Shell Dynamics and Viscosity Effects Around Cyanamide Probes via 2D IR Spectroscopy J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Christopher J. Mallon, Majid Hassani, Ellia H. Osofsky, Savannah B. Familo, Edward E. Fenlon, Matthew J. Tucker
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Late-Stage Reshaping of Phage-Displayed Libraries to Macrocyclic and Bicyclic Landscapes using a Multipurpose Linchpin J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Kejia Yan, Mark Miskolzie, Fernando Banales Mejia, Chuanhao Peng, Arunika I. Ekanayake, Alexey Atrazhev, Jessica Cao, Dustin J. Maly, Ratmir Derda
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Electrostatic Control of Electronic Structure in Modular Inorganic Crystals J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Kanta Ogawa, Aron Walsh
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Highly Rigid, Yet Conformationally Adaptable, Bisporphyrin sp2-Cage Receptors Afford Outstanding Binding Affinities, Chelate Cooperativities, and Substrate Selectivities J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 A. Priscila Gia, Alberto de Juan, Daniel Aranda, Fernando G. Guijarro, Juan Aragó, Enrique Ortí, Miguel García-Iglesias, David González-Rodríguez
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Mixed Ionic and Electronic Conductivity in a Tetrathiafulvalene-Phosphonate Metal–Organic Framework J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Catarina Ribeiro, Bowen Tan, Flávio Figueira, Ricardo F. Mendes, Joaquín Calbo, Gonçalo Valente, Paula Escamilla, Filipe A. Almeida Paz, João Rocha, Mircea Dincă, Manuel Souto
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Unraveling the Bonding and Aromaticity of Pentazole, Pentaphosphole, and Cyclopentadiene Anions: A Comprehensive Study J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Shailja Jain, David Danovich, Slavko Radenković, Sason Shaik
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Lanthanum-Promoted Electrocatalyst for the Oxygen Evolution Reaction: Unique Catalyst or Oxide Deconstruction? J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Alaina C. Hartnett, Ryan J. Evenson, Agnes E. Thorarinsdottir, Samuel S. Veroneau, Daniel G. Nocera
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Galloyl Dialkyl Lipids Drive Encapsulation of Peptides into Lipid Nanoparticles by Hydrogen Bonding J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-12-19 Tingting Ye, Yong Chen, Zifu Zhong, Yi Huang, Jamie De Baere, Mark Gontsarik, Kim Deswarte, Bianka Golba, Martijn Risseeuw, Serge Van Calenbergh, Bart N. Lambrecht, Bruno G. De Geest
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Fluorination from Surface to Bulk Stabilizing High Nickel Cathode Materials with Outstanding Electrochemical Performance Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-12-19 Jieyu Yang, Guihong Mao, Tengyu Yao, Laifa Shen, Yan Yu
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Cell-Free Gene Expression: Methods and Applications Chem. Rev. (IF 51.4) Pub Date : 2024-12-19 Andrew C. Hunt, Blake J. Rasor, Kosuke Seki, Holly M. Ekas, Katherine F. Warfel, Ashty S. Karim, Michael C. Jewett
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Multiple Binding Modes of Inhibitors to Human Carbonic Anhydrases: An Update on the Design of Isoform-Specific Modulators of Activity Chem. Rev. (IF 51.4) Pub Date : 2024-12-19 Katia D’Ambrosio, Anna Di Fiore, Vincenzo Alterio, Emma Langella, Simona Maria Monti, Claudiu T. Supuran, Giuseppina De Simone
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Localized Conduction Channels in Memristors Chem. Rev. (IF 51.4) Pub Date : 2024-12-19 Kyung Seok Woo, R. Stanley Williams, Suhas Kumar
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The challenge of studying interfaces in battery materials Nat. Nanotechnol. (IF 38.1) Pub Date : 2024-12-20 Claire Villevieille
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I create routes through trees to help stop howler monkeys being electrocuted by power lines Nature (IF 50.5) Pub Date : 2024-12-20
Inés Azofeifa Rojas monitors troop behaviour to maintain canopy connectivity.
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Behind the scenes of Nature News & Views in 2024 Nature (IF 50.5) Pub Date : 2024-12-20
Listen to our reporters’ podcast highlights of 2024.
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That Christmas jumper is a marvel of complicated physics Nature (IF 50.5) Pub Date : 2024-12-20
Models and experiments demonstrate what happens when a knitted fabric is deformed.
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Stem cells head to the clinic: treatments for cancer, diabetes and Parkinson’s disease could soon be here Nature (IF 50.5) Pub Date : 2024-12-20
More than 100 clinical trials put stem cells for regenerative medicine to the test. It’s a turning point for a field beset with ethical and political controversy.
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Can novelty scores on papers shift the power dynamics in scientific publishing? Nature (IF 50.5) Pub Date : 2024-12-20
By providing measures of novelty, DeSci Publish hopes to shift the bargaining power between journals and authors.
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Is political interference causing faculty brain drain in the southern United States? Nature (IF 50.5) Pub Date : 2024-12-20
Faculty members say academic freedom is under fire, and many are seeking work outside the region.
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Daily briefing: Climate scientists determined to rise to the challenge of Trump 2.0 Nature (IF 50.5) Pub Date : 2024-12-19
We investigate how ancient humans ran and hear from climate scientists who are rising to the challenges of an impending Trump presidency.
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Self-supported NiTe@NiMo electrodes enabling efficient sulfion oxidation reaction toward energy-saving and chlorine-free hybrid seawater electrolysis at high current densities Energy Environ. Sci. (IF 32.4) Pub Date : 2024-12-20 Hao Tan, Zhipeng Yu, Chenyue Zhang, Fei Lin, Shiyu Ma, Haoliang Huang, Hong Li, Dehua Xiong, Lifeng Liu
The sulfion oxidation reaction (SOR) assisted seawater electrolysis has been proposed to be a potentially cost-effective approach to hydrogen production because SOR happens at an anodic potential significantly lower than that of the energy-demanding oxygen evolution reaction (OER). However, the key to unleash full potential of SOR for practical seawater electrolysis is to develop highly efficient and
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Oxygen-Powered Sustainable FePO4 Preparation Routines for Sodium Metal Batteries with Li Acetate Recovery Energy Environ. Sci. (IF 32.4) Pub Date : 2024-12-20 Fumiyasu Nozaki, Shaoning Zhang, Martin Hoffman Peterson, Jinkwang Hwang, Jin Hyun Chang, Juan Maria Garcia-Lastra, Kazuhiko Matsumoto
Triphylite NaFePO4 emerges as a promising solution for sodium secondary batteries due to its abundant constituent elements and high energy density, making it attractive for sustainable energy storage applications. However, the direct synthesis of triphylite NaFePO4 is hindered by its thermal metastability. In this study, we propose an oxygen-powered sustainable production method for heterosite FePO4
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The Overlooked Solvent Effects: Reconsider the Paradigm in Semiconductor Photocatalysis Energy Environ. Sci. (IF 32.4) Pub Date : 2024-12-19 Xuejiao Wu, Jonathan Van Waeyenberg, Dario Vangestel, Bert Sels
Semiconductor photocatalysis has seen decades of development, with most attention focused on two key elements: semiconductors Semiconductor photocatalysis has seen decades of development, with most attention focused on two key elements: semiconductors and solutes. However, the third “S” — solvents — which play a crucial role in condensed-phase reactions, has been surprisingly largely overlooked in
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Mixed-valence metal–organic frameworks: concepts, opportunities, and prospects Chem. Soc. Rev. (IF 40.4) Pub Date : 2024-12-20 Farzaneh Afshariazar, Ali Morsali
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From text to insight: large language models for chemical data extraction Chem. Soc. Rev. (IF 40.4) Pub Date : 2024-12-20 Mara Schilling-Wilhelmi, Martiño Ríos-García, Sherjeel Shabih, María Victoria Gil, Santiago Miret, Christoph T. Koch, José A. Márquez, Kevin Maik Jablonka
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Role of exciton delocalization in chiroptical properties of benzothiadiazole carbon nanohoops Chem. Sci. (IF 7.6) Pub Date : 2024-12-20 Kovida Kovida, Juraj Malinčík, Carlos M. Cruz, Araceli G. Campaña, Tomáš Šolomek
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Kinetics and dynamics of atomic-layer dissolution on low-defect Ag Chem. Sci. (IF 7.6) Pub Date : 2024-12-16 Yufei Wang, Roberto Garcia-Carrillo, Hang Ren
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Systematic Study of Zeolitic Imidazolate Frameworks for Enhanced Electrochemical Aldehyde Sensing Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Martyna Mańka, Wojciech Kukułka, Mateusz Wlazło, Violetta Patroniak, Artur Ciesielski, Verónica Montes-García, Paolo Samorì
Four distinct zeolitic imidazolate frameworks (ZIFs) are prepared using zinc and cobalt ions with 2-aminobenzimidazole and 2-methylimidazole as linkers to explore their electrochemical properties as platforms for aldehyde detection. The resulting ZIF-based sensors exhibit high sensitivity, low detection limits, and robust performance when applied to real-world samples.
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Photoinduced Ligand-to-Metal Charge Transfer (LMCT) in Organic Synthesis: Reaction Modes and Research Advances Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Yingying Yang, Xinxiang Huang, Yi Jin
In recent years, visible light-induced ligand-to-metal charge transfer (LMCT) has emerged as an attractive approach for synthesizing a range of functionalized molecules. Compared to conventional photoredox reactions, photoinduced LMCT activation does not depend on redox potential and offers diverse reaction pathways, making it particularly suitable for the activation of inert bonds and the functional
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Luminescent terbium(III) probes containing aromatic amino acid-based antenna for discrimination between adenine and guanine nucleotides Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Sunanda Pradhan, NITIN SHUKLA, Goutam Panigrahi, Ashis Kumar Patra
Herein we present a series of luminescent Tb(III)-probes ([Tb-Ltrp], [Tb-Ltyr], [Tb-Lphe]) for sensing and discriminating purine nucleoside polyphosphates (NPP) based on a modified DTTA chelator appended to aromatic amino acids (Laa). The optically most effective luminescent [Tb-Ltrp] probe preferentially discriminate the guanine-NPPs over the adenine-NPPs via PeT-based modulation of Tb(III) luminescence
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Recent progress of density functional theory studies on carbon-supported single-atom catalysts for energy storage and conversion Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Hengjia Shao, Li Zhong, Xingqiao Wu, Yun-Xiao Wang, Sean C. Smith, Xin Tan
Single-atom catalysts (SACs) have become the forefront and hotspot in energy storage and conversion research, inheriting the advantages of both homogeneous and heterogeneous catalysts. In particular, carbon-supported SACs (CS-SACs) are excellent candidates for many energy storage and conversion applications, due to their maximum atomic efficiency, unique electronic and coordination structures, and
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Discrimination of nucleoside phosphates using principal component analysis of spectral changes in a single europium complex Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Leila R Hill, Elizabeth J New, Stephen Faulkner
Here we present the first use of principal component analysis of the full spectrum of a single europium complex to differentiate between structurally-similar analytes. We demonstrate that it can be used to distinguish between the nucleoside phosphate guests AMP, ADP, and ATP.
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Photoredox Radical/Polar Crossover Enables Carbo-Heterofunctionalization of Alkenes: Facile Access to 1,3-Difunctionalized Nitro Compounds Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Subrata J. Patra, Vasiliki Valsamidou, Bhargav Nandasana, Dmitry Katayev
Herein, we present an efficient and practical method for multicomponent carbo-heterofunctionalization of alkenes via radical-polar crossover photoredox catalysis. Employing geminal bromonitroalkanes as redox-active reagents with a wide range of O-centered nucleophiles allows rapid access to various 1,3- difunctionalized nitro compounds, including β-nitro ketones, 1,3-nitro alcohols, 1,3-nitro ethers
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β-Stereoselective Kdo C-glycosylation by (p-Tol)2SO/Tf2O preactivation strategy Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Jing-dong Zhang, Guang-Jian Liu, Guo-Wen Xing
There was very little research on the synthesis of β-3-Deoxy-D-manno-oct-2-ulosonic acid (Kdo) C-glycosides, which restricted their wide applications. Herein, a convenient and efficient approach to synthesize β-Kdo C-glycosides was developedbased on Tf2O/(p-Tol)2SO preactivation strategy using bench stable peracetylated Kdo thioglycoside as donor via a thermodynamic SN1-like mechanism.
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An 18-connected wheel-shaped molybdenum(V) nickel-phosphate cluster for photoelectrochemical sensing of levofloxacin Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Jie-Fei Wang, Chun-Xiao Yin, Jia-Xin Qi, Yuan-Yuan Ma, Zhengguo Lin, Zhangang Han
An 18-connected {Mo16Ni16P24}-based 2-D layered network was constructed for photoelectrochemical sensing of levofloxacin, which represents the highest connection number of {Mo16Ni16P24} wheel cluster to date. The detection limit is as low as 6.46 nM with a high sensitivity of 110.87 μA·μM-1 and good practicality in a milk sample.
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High-pressure chemistry of functional materials Chem. Commun. (IF 4.3) Pub Date : 2024-12-20 Songhao Guo, Yifan Zhang, Kejun Bu, Yiqiang Zhan, Xujie Lü
Functional materials, possessing specific properties and performing particular functions beyond their mechanical or structural roles, are the foundation of modern matter science including energy, environment, and quantum sciences. The atomic and electronic structures of these materials can be significantly altered by external stimuli such as pressure. High-pressure techniques have been extensively
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Heterogenization of molecular chalcoxides for electro-& photochemical H2 production Chem. Commun. (IF 4.3) Pub Date : 2024-12-19 Mark Gray, Yu-Fei Song, Haralampos N. Miras
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Continuous activation of phenoxide and CF3I for multiple trifluoromethylations Chem. Commun. (IF 4.3) Pub Date : 2024-12-17 Yusei Nakashima, Shinjiro Kusano, Tsukasa Inishi, Yasuyuki Nitta, Takashi Nishikata
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Charge-dependent hierarchical self-assembling of fluorinated gold nanoclusters Chem. Commun. (IF 4.3) Pub Date : 2024-12-16 Yuki Saito, Duhong Sun, Hayato Kanai, Yasuhiro Ishida, Hideyuki Mitomo, Kuniharu Ijiro, Katsuaki Konishi
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Expandable Fast Li‐Ion Diffusion Network of Li‐Rich Mn‐Based Oxides via Single‐Layer LiCo(Ni)O2 Segregation Adv. Mater. (IF 27.4) Pub Date : 2024-12-20 Yali Yang, Tie Luo, Yuxuan Zuo, Hangchao Wang, Chuan Gao, Junfei Cai, Tonghuan Yang, Wukun Xiao, Yue Yu, Dingguo Xia
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Performance Enhancement of Carbon Nanotube Network Transistors via SbI3 Inner‐Doping in Selected Regions Adv. Mater. (IF 27.4) Pub Date : 2024-12-20 Qing Guo, Xiujun Wang, Pin Zhao, Zhen Zhang, Lin Geng, Ye Liu, Yu Teng, Yunlei Zhong, Lixing Kang
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Ultra‐Narrowband Green‐Emitting Transparent Composite Ceramics for Laser‐Driven Display Adv. Mater. (IF 27.4) Pub Date : 2024-12-20 Dahai Hu, Shisheng Lin, Tao Pang, Lingwei Zeng, Guoyu Xi, Fengluan You, TianShuo Wu, Xiaoshuang Li, Bo Wang, Lei Lei, Feng Huang, Daqin Chen
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Signatures of ambient pressure superconductivity in thin film La3Ni2O7 Nature (IF 50.5) Pub Date : 2024-12-19 Eun Kyo Ko, Yijun Yu, Yidi Liu, Lopa Bhatt, Jiarui Li, Vivek Thampy, Cheng-Tai Kuo, Bai Yang Wang, Yonghun Lee, Kyuho Lee, Jun-Sik Lee, Berit H. Goodge, David A. Muller, Harold Y. Hwang
Recently, the bilayer nickelate La3Ni2O7 has been discovered as a new superconductor with transition temperature Tc near 80 K under high pressure1–3. Despite extensive theoretical and experimental work to understand the nature of its superconductivity4–29, the requirement of extreme pressure restricts the use of many experimental probes and limits its application potential. Here, we present signatures
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Machine Learning in Solid‐State Hydrogen Storage Materials: Challenges and Perspectives Adv. Mater. (IF 27.4) Pub Date : 2024-12-20 Panpan Zhou, Qianwen Zhou, Xuezhang Xiao, Xiulin Fan, Yongjin Zou, Lixian Sun, Jinghua Jiang, Dan Song, Lixin Chen
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Nanoelectrode‐Mediated Extracellular Electrical Stimulation Directing Dopaminergic Neuronal Differentiation of Stem Cells for Improved Parkinson's Disease Therapy Adv. Mater. (IF 27.4) Pub Date : 2024-12-20 Liang Wang, Yuan Yao, Bojun Xie, Ming Lei, Yiwei Li, Jiaming Shi, Liyang Yu, Wenjuan Zhou, Yuanhua Sang, Liang Kong, Hong Liu, Jichuan Qiu