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Visible-Light-Driven Rapid 3D Printing of Photoresponsive Resins for Optically Clear Multifunctional 3D Objects (Adv. Mater. 19/2024) Adv. Mater. (IF 29.4) Pub Date : 2024-05-09 Sangbin Shin, Yonghwan Kwon, Chiwon Hwang, Woojin Jeon, Youngchang Yu, Hyun-Jong Paik, Wonjoo Lee, Min Sang Kwon, Dowon Ahn
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Inflammation-Responsive Cell Membrane-Camouflaged Nanoparticles against Liver Fibrosis via Regulating Endoplasmic Reticulum Stress and Oxidative Stress (Adv. Mater. 19/2024) Adv. Mater. (IF 29.4) Pub Date : 2024-05-09 Yang Bai, Jiaqi Chen, Sitong Zhang, Guangyu Xu, Zhengwei Mao, Yuan Ding, Weilin Wang
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The Unprecedented Biodegradable Polyzwitterion: A Removal-Free Patch for Accelerating Infected Diabetic Wound Healing Adv. Mater. (IF 29.4) Pub Date : 2024-05-12 Zhuoya Wang, Danyang Chen, Hongying Wang, Siyu Bao, Liping Lang, Chunyan Cui, Haotian Song, Jianhai Yang, Wenguang Liu
Zwitterionic polymers have emerged as an important class of biomaterials to construct wound dressings and antifouling coatings over the past decade due to their excellent hydrophilicity. However, all the reported zwitterionic polymers are non-degradable because of non-cleavable carbon-carbon bonding backbones, and must be removed periodically after treatment to avoid hypoxia in the wound, thus leading
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Expanded ROS Generation and Hypoxia Reversal: Excipient-free Self-assembled Nanotheranostics for Enhanced Cancer Photodynamic Immunotherapy Adv. Mater. (IF 29.4) Pub Date : 2024-05-12 Jing Yang, Bibo Ren, Xuntao Yin, Lunli Xiang, YanQiu Hua, Xue Huang, Haibo Wang, Zhengwei Mao, Wei Chen, Jun Deng
The efficacy of photodynamic therapy (PDT)-related cancer therapies is significantly restricted by two irreconcilable obstacles, i.e., low reactive oxygen species (ROS) generation capability and hypoxia which constrains the immune response. Herein, we developed a self-assembled clinical photosensitizer indocyanine green (ICG) and the HSP90 inhibitor 17-dimethylaminoethylamino-17-demethoxygeldanamycin
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Atomic-Scale Tracking Topological Phase Transition Dynamics of Polar Vortex-Antivortex Pairs Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Ruixue Zhu, Sizheng Zheng, Xiaomei Li, Tao Wang, Congbing Tan, Tiancheng Yu, Zhetong Liu, Xinqiang Wang, Jiangyu Li, Jie Wang, Peng Gao
Non-trivial topological structures, such as vortex-antivortex (V-AV) pairs, have garnered significant attention in the field of condensed matter physics. However, the detailed topological phase transition dynamics of V-AV pairs, encompassing behaviors like self-annihilation, motion, and dissociation, have remained elusive in real space. Here, we employ polar V-AV pairs as a model system and track their
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Activating Iterative Revolutions of the Cancer-Immunity Cycle in Hypoxic Tumors with a Smart Nano-Regulator Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Junying Ding, Yang Lu, Xueze Zhao, Saran Long, Jianjun Du, Wen Sun, Jiangli Fan, Xiaojun Peng
The activation of sequential events in the cancer-immunity cycle (CIC) is crucial for achieving effective anti-tumor immunity. However, formidable challenges, such as innate and adaptive immune resistance, along with the off-target adverse effects of non-selective immunomodulators, persist. In this study, a tumor-selective nano-regulator named PNBJQ has been presented, focusing on targeting two non-redundant
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High‐Entropy Prussian Blue Analogues Enable Lattice Respiration for Ultra‐Stable Aqueous Aluminum‐Ion Batteries Adv. Mater. (IF 29.4) Pub Date : 2024-05-12 Kai Du, Yujie Liu, Yiqi Zhao, Hui Li, Hexiong Liu, Chunhao Sun, Mingshan Han, Tianyi Ma, Yuxiang Hu
Aqueous aluminum ion batteries (AAIBs) hold significant potential for grid‐scale energy storage owing to their intrinsic safety, high theoretical capacity, and abundance of aluminum. However, the strong electrostatic interactions and delayed charge compensation between high‐charge‐density aluminum ions and the fixed lattice in conventional cathodes impede the development of high‐performance AAIBs.
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Nanogalvanic Cells Release Highly Reactive Electrons in Tumors to Effectively Eliminate Tumors Adv. Mater. (IF 29.4) Pub Date : 2024-05-12 Wei‐Qiang Huang, Ya‐Qi Zhu, Fan Gao, Wei You, Guang Chen, Xuan Nie, Lei Xia, Long‐Hai Wang, Chun‐Yan Hong, Ze Zhang, Fei Wang, Yue Yu, Ye‐Zi You
External stimuli triggering chemical reactions in cancer cells to generate highly reactive chemical species are very appealing for cancer therapy, in which external irradiation activating sensitizers to transfer energy or electrons to surrounding oxygen or other molecules is critical for generating cytotoxic reactive species. However, poor light penetration into tissue, low activity of sensitizers
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Scalable Customization of Crystallographic Plane Controllable Lithium Metal Anodes for Ultralong-Lasting Lithium Metal Batteries Adv. Mater. (IF 29.4) Pub Date : 2024-05-06 Jian Tan, Longli Ma, Pengshu Yi, Yuan Wang, Zhiheng Li, Zhan Fang, Xuanyang Li, Shan He, Xuefeng Wang, Mingxin Ye, Jianfeng Shen
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Regulation of Protein Conformation Enables Cell-Selective Targeting of Virus-Mimicking Nanoparticles for siRNA Therapy of Glioblastoma Adv. Mater. (IF 29.4) Pub Date : 2024-05-06 Han Zhu, Yi-Fan Wang, Zhi-Gang Wang, Dai-Wen Pang, Shu-Lin Liu
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Atto-Scale Noise Near-Infrared Organic Photodetectors Enabled by Controlling Interfacial Energetic Offset through Enhanced Anchoring Ability Adv. Mater. (IF 29.4) Pub Date : 2024-05-06 Tae Hyuk Kim, Ji Hyeon Lee, Min Ho Jang, Gyeong Min Lee, Eun Soo Shim, Seunghyun Oh, Muhammad Ahsan Saeed, Min Jong Lee, Byoung-Soo Yu, Do Kyung Hwang, Chae Won Park, Sae Youn Lee, Jea Woong Jo, Jae Won Shim
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Accelerated Engineering of ELP-Based Materials through Hybrid Biomimetic-De Novo Predictive Molecular Design Adv. Mater. (IF 29.4) Pub Date : 2024-05-06 Timo Laakko, Antti Korkealaakso, Burcu Firatligil Yildirir, Piotr Batys, Ville Liljeström, Ari Hokkanen, Nonappa, Merja Penttilä, Anssi Laukkanen, Ali Miserez, Caj Södergård, Pezhman Mohammadi
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These parrots go on killing sprees over real-estate shortages Nature (IF 64.8) Pub Date : 2024-05-10
Scientists recorded green-rumped parrotlets pecking others’ chicks to death, probably to claim the nest space.
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Diana Wall obituary: ecologist who foresaw the importance of soil biodiversity Nature (IF 64.8) Pub Date : 2024-05-10
Environmental scientist who revealed the crucial role of underground animals in sustainability.
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All-perovskite tandem solar cells from fundamentals to technological progress Energy Environ. Sci. (IF 32.5) Pub Date : 2024-05-10 Jaekeun Lim, Nam-Gyu Park, Sang Il Seok, Michael Saliba
Organic-inorganic perovskite materials have gradually progressed from single-junction solar cells to tandem (double) or even multi-junction (triple-junction) solar cells as all-perovskite tandem solar cells (APTSCs) have advantages: (1) the tunable optical bandgap, (2) low-cost because of solution-processing, inexpensive precursors, and thin film process, (3) scalability and lightweight, and (4) an
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Semi-Crystalline Polymers with Supramolecular Synergistic Interactions: From Mechanical Toughening to Dynamic Smart Materials Chem. Sci. (IF 8.4) Pub Date : 2024-05-11 Chen-Yu Shi, Wen-Yu Qin, Dahui Qu
Semi-crystalline polymers (SCPs) with anisotropic amorphous and crystalline domains as basic skeleton are ubiquitous from natural products to synthetic polymers. The combination of chemically incompatible hard and soft phases contributes to unique thermal and mechanical properties. The further introduction of supramolecular interactions as noncovalent interacted crystal phase and soft dynamic crosslinking
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Rapidly Solar-driven Atmospheric Water Harvesting with MAF-4 Derived Nitrogen-doped Nanoporous Carbon Chem. Sci. (IF 8.4) Pub Date : 2024-05-11 MING XUE, Jinhua Feng, Feng Lu, Zhen Chen, Miaomiao Jia, Yi-Le Chen, Wei-Hai Lin, Qing-Yun Wu, Yi Li, Xiao-Ming Chen
Sorption-based atmospheric water harvesting (AWH) technology is a powerful approach for solving global fresh water scarcity. In this field, an upsurge in searching adsorbents with high water uptake capacity at low relative humidity, rapid adsorption-desorption kinetics and high thermal conductivity, which have been considered to be critical challenges in the AWH process. Herein, we report a MAF-4 (aka
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H2O2-triggered CO release based on porphyrinic covalent organic polymers for photodynamic/gas synergistic therapy Chem. Commun. (IF 4.9) Pub Date : 2024-05-11 Yang Wang, Xufeng Liang, Jian An, Jia Pu, Yujia Meng, Yiqiao Bai, Wenqiagn Yu, Yunhan Gao, Tingting Chen, Yong Yao
A novel H2O2-responsive carbon monoxide nanogenerator was designed by effectively encapsulating manganese carbonyl prodrug into porphyrinic covalent organic polymers for realizing the combined CO gas and photodynamic therapy under near infrared light irradiation.
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Functionalisation of MUF-15 Enhances CO2/CH4 Selectivity in Mixed-Matrix Membranes Chem. Commun. (IF 4.9) Pub Date : 2024-05-10 Yiming Zhang, Elnaz Jangodaz, Ben Yin, Shane Telfer
MUF-15 (MUF = Massey University Framework) is a metal-organic framework with pores that can be tuned by ligand functionalisation. Crystallites of MUF-15 and derivatives were blended with the organic polymer 6FDA-DAM to produce mixed-matrix membranes (MMMs). At a loading of 30 wt.%, membranes with MUF-15-F, MUF-15 with an appended fluoro group, exhibited a CO2 permeability of 1300 Barrer and CO2/CH4
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Evaluating the Native Oxide of Titanium as an Electrocatalyst for Oxalic Acid Reduction Chem. Commun. (IF 4.9) Pub Date : 2024-05-10 Halilu Sale, Zeliha Ertekin, Paula Laborda Lalaguna, Malcolm Kadodwala, Mark D Symes
Herein, we show that unmodified titanium electrodes bearing the naturally-forming native TixOy coating display superior activity for the electroreduction of oxalic acid to glyoxylic acid and glycolic acid compared to Ti-based electrodes that have been deliberately modified for this purpose, in terms of both oxalic acid conversion and overall yields of reduced products.
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Stereoscopic Polymer Network for Developing Mechanically Robust Flexible Perovskite Solar Cells with an Efficiency Approaching 25% Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Yeyong Wu, Guiying Xu, Yunxiu Shen, Xiaoxiao Wu, Xiaohua Tang, Chuanshuai Han, Yujin Chen, Fu Yang, Haiyang Chen, Yaowen Li, Yongfang Li
Flexible perovskite solar cells (pero‐SCs) have the potential to overturn the application scenario of silicon photovoltaic technology. However, their mechanical instability severely impedes their practical applicability, and the corresponding intrinsic degradation mechanism remains unclear. In this study, we systematically analyzed the degradation behavior of flexible pero‐SCs under mechanical stress
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A Human‐Scale Clinically‐Ready Electromagnetic Navigation System for Magnetically‐Responsive Biomaterials and Medical Devices Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Simone Gervasoni, Norman Pedrini, Tarik Rifai, Cedric Fischer, Fabian C. Landers, Michael Mattmann, Roland Dreyfus, Silvia Viviani, Andrea Veciana, Enea Masina, Buse Aktas, Josep Puigmartí‐Luis, Christophe Chautems, Salvador Pané, Quentin Boehler, Philip Gruber, Bradley J. Nelson
Magnetic navigation systems are used to precisely manipulate magnetically responsive materials enabling the realization of new minimally invasive procedures using magnetic medical devices. Their widespread applicability has been constrained by high infrastructure demands and costs. we report on a portable electromagnetic navigation system, the Navion, which is capable of generating a large magnetic
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Accumulation of Long‐Lived Photogenerated Holes at Indium Single Atom Catalysts via Two Coordinate Nitrogen Vacancy Defect Engineering for Enhanced Photocatalytic Oxidation Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Jingjing Zhang, Xuan Yang, Guofang Xu, Biswal Basanta Kumar, Rajasekhar Balasubramanian
Visible light‐driven photocatalytic oxidation by photogenerated holes has immense potential for environmental remediation applications. While the electron‐mediated photoreduction reactions are often at the spotlight, active holes possess a remarkable oxidation capacity that can degrade recalcitrant organic pollutants, resulting in non‐toxic byproducts. However, the random charge transfer and rapid
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Topology Reconfiguration of Anion‐Pillared Metal‐Organic Framework from Flexibility to Rigidity for Enhanced Acetylene Separation Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Hanting Xiong, Yong Peng, Xing Liu, Pengxiang Wang, Peixin Zhang, Longsheng Yang, Junhui Liu, Hua Shuai, Lingmin Wang, Zhenning Deng, Shixia Chen, Jingwen Chen, Zhenyu Zhou, Shuguang Deng, Jun Wang
Flexible metal‐organic framework (MOF) adsorbents commonly encounter limitations in removing trace impurities below gate‐opening threshold pressures. Topology reconfiguration can fundamentally eliminate intrinsic structural flexibility, yet remains a formidable challenge and is rarely achieved in practical applications. Herein, we present a solvent‐mediated approach to regulate the flexible CuSnF6‐dpds‐sql
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Terahertz and Infrared Plasmon Polaritons in PtTe2 Type‐II Dirac Topological Semimetal Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Salvatore Macis, Annalisa D'Arco, Lorenzo Mosesso, Maria Chiara Paolozzi, Silvia Tofani, Luca Tomarchio, Pinaka Pani Tummala, Sara Ghomi, Veronica Stopponi, Eleonora Bonaventura, Chiara Massetti, Davide Codegoni, Andrea Serafini, Paolo Targa, Michele Zacchigna, Alessio Lamperti, Christian Martella, Alessandro Molle, Stefano Lupi
Surface plasmon polaritons (SPPs) are electromagnetic excitations existing at the interface between a metal and a dielectric. SPPs provide a promising path in nanophotonic devices for light manipulation at the micro and nanoscale with applications in optoelectronics, biomedicine, and energy harvesting. Recently, SPPs have been extended to unconventional materials like graphene, transparent oxides,
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Transdermal Sensing of Enzyme Biomarker Enabled by Chemo‐Responsive Probe‐Modified Epidermal Microneedle Patch in Human skin Tissue Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Nazanin Poursharifi, Morteza Hassanpouramiri, Alexander Zink, Muhammed Ucuncu, Onur Parlak
Wearable bioelectronics represents a significant breakthrough in healthcare settings, particularly in (bio)sensing which offers an alternative way to track individual health for diagnostics and therapy. However, there has been no notable improvement in the field of cancer, particularly for skin cancer. Here, we established a wearable bioelectronic patch for transdermal sensing of the melanoma biomarker
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Near‐Infrared Luminescent Materials Incorporating Rare Earth/Transition Metal Ions: From Materials to Applications Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Hua‐hui Li, Ya‐Kun Wang, Liang‐Sheng Liao
Near‐infrared materials exhibiting high photoluminescence quantum yields present a promising avenue to broaden our capacity and threshold for detection and manipulation, extending beyond the visible emission range. The spotlight has shifted to near‐infrared (NIR) luminescent materials emitting beyond 1000 nm, with growing interest due to their unique characteristics. The ability of NIR‐II emission
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Binary Organic Solar Cells with Exceeding 19% Efficiency via the Synergy of Polyfluoride Polymer and Fluorous Solvent Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Zhilong He, Siyuan Li, Rui Zeng, Yi Lin, Yi Zhang, Zhe Hao, Shimin Zhang, Feng Liu, Zheng Tang, Hongliang Zhong
Rational molecular design and suitable device engineering are two important strategies to boost the efficiencies in organic solar cells (OSCs). Yet these two approaches are independently developed, while their synergy is believed to be more productive. Herein, a branched polyfluoride moiety, heptafluoroisopropoxyl group, is introduced into the sidechains of conjugated polymers for the first time. Compared
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Uniaxial‐Oriented Chiral Perovskite for Flexible Full‐Stokes Polarimeter Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Quanlin Chen, Zijin Ding, Li Zhang, Di Wang, Cong Geng, Yanxing Feng, Jia Zhang, Miao Ren, Saisai Li, Saif M. H. Qaid, Yuanzhi Jiang, Mingjian Yuan
Full‐Stokes polarization detection, with high integration and portability, offers an efficient path toward next‐gen multi‐information optoelectronic systems. Nevertheless, current techniques relying on optical filters create rigid and bulky configurations, limiting practicality. Here, we first report a flexible, filter‐less full‐Stokes polarimeter featuring a uniaxial‐oriented chiral perovskite film
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A Single Component, Single Layer Flexile Foam Evaporator with the Higher Efficiency for Water Generation Adv. Mater. (IF 29.4) Pub Date : 2024-05-11 Ruoxin Li, Mingrui Wu, Haijun Ma, Yongqi Zhu, Hongyi Zhang, Qiaomei Chen, Chuhong Zhang, Yen Wei
One of the greenest and promising ways to solve the problem of freshwater crisis is surface solar steam generation from seawater. A great number of photothermal materials with multi‐component and multi‐layered delicate yet complex structures often suffer from either low evaporation rate or high energy loss. Here, we present a single component foam evaporator with steam generation rate of up to 4.32
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Designed Additive to Regulated Crystallization for High Performance Perovskite Solar Cell Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-11 Yang Cao, Nan Yan, Mingzi Wang, Danyang Qi, Jiafan Zhang, Xin Chen, Ru Qin, Fengwei Xiao, Guangtao Zhao, Yucheng Liu, Xuediao Cai, Kui Zhao, Shengzhong (Frank) Liu, Jiangshan Feng
It is a crucial role for enhancing the power conversion efficiency (PCE) of perovskite solar cells (PSCs) to prepare high‐quality perovskite films, which can be achieved by delaying the crystallization of perovskite film. Hence, we designed difluoroacetic anhydride (DFA) as an additive to regulating crystallization process thus reducing defect formation during perovskite film formation. It was found
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Switching between the [2π+2σ] and Hetero‐[4π+2σ] Cycloaddition Reactivity of Bicyclobutanes with Lewis Acid Catalysts Enables the Synthesis of Spirocycles and Bridged Heterocycles Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-11 Ji-Jie Wang, Lei Tang, Yuanjiu Xiao, Wen-Biao Wu, Guoqiang Wang, Jian-Jun Feng
The exploration of the complex chemical diversity of bicyclo[n.1.1]alkanes and their use as benzene bioisosteres has garnered significant attention over the past two decades. Regiodivergent syntheses of thiabicyclo[4.1.1]octanes (S‐BCOs) and highly substituted bicyclo[2.1.1]hexanes (BCHs) using a Lewis acid‐catalyzed formal cycloaddition of bicyclobutanes (BCBs) and 3‐benzylideneindoline‐2‐thione derivatives
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Dumbbell‐Shaped, Block‐Graft Copolymer with Aligned Domains for High‐performance Hydrocarbon Polymer Electrolyte Membranes Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-11 So Youn Lee, Du Ru Kang, Jong-Gil Oh, Il Seok Chae, Jong Hak Kim
Given the environmental concerns surrounding fluoromaterials, the use of high‐cost perfluorinated sulfonic acids (PFSAs) in fuel cells and water electrolysis contradicts the pursuit of clean energy systems. Herein, we present a fluorine‐free dumbbell‐shaped block‐graft copolymer, derived from the cost‐effective triblock copolymer poly(styrene‐b‐ethylene‐co‐butylene‐b‐styrene) (SEBS), for polymer electrolyte
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Bias‐switchable Dual‐Mode Organic Photodetector with High Operational Stability Using Self‐trapped Cs3Cu2I5 Interfacial layer Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-11 Zitong Zhang, Junchuan Liu, Lin Wang, Qi Wei, Mingjie Li, Chunxiong Bao, qingzhen bian
Conventional photovoltaic (PV)‐photodetectors are hard to detect fainted signals, while photomultiplication (PM)‐capable devices indispensable for detecting weak light and are prone to degrade under strong light illumination and large bias, and it is urgent to realize highly efficient integrated detecting system with both PM and PV operation modes. In this work, one lead‐free Cs3Cu2I5 nanocrystals
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Optimizing Molecular Packing via Steric Hindrance for Reducing Non‐Radiative Recombination in Organic Solar Cells Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-11 Junzhen Ren, Shaoqing zhang, Zhihao Chen, Tao Zhang, Jiawei Qiao, Jingwen Wang, Lijiao Ma, Yang Xiao, Zi Li, Jianqiu Wang, Xiaotao Hao, Jianhui Hou
Innovative molecule design strategy holds promise for the development of next‐generation acceptor materials for efficient organic solar cells with low non‐radiative energy loss (ΔEnr). In this study, we designed and prepared three novel acceptors, namely BTP‐Biso, BTP‐Bme and BTP‐B, with sterically structured triisopropylbenzene, trimethylbenzene and benzene as side chains inserted into the shoulder
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Halogen, Chalcogen, Pnictogen, and Tetrel Bonding in Non‐Covalent Organocatalysis: An Update Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-11 Dragana Jovanovic, Meghana Poliyodath Mohanan, Stefan Matthias Huber
The use of noncovalent interactions based on electrophilic halogen, chalcogen, pnictogen, or tetrel centers in organocatalysis has gained noticeable attention. Herein, we provide an overview on the most important developments in the last years with a clear focus on experimental studies and on catalysts which act via such non‐transient interactions.
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Characterization of Deformational Isomerization Potential and Interconversion Dynamics with Ultrafast X-ray Solution Scattering J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Natalia E. Powers-Riggs, Benedikt O. Birgisson, Sumana L. Raj, Elisa Biasin, Philipp Lenzen, Diana Bregenholt Zederkof, Morten Haubro, Dagrún K. V. Tveiten, Robert W. Hartsock, Tim B. van Driel, Kristjan Kunnus, Matthieu Chollet, Joseph S. Robinson, Silke Nelson, Ruaridh Forbes, Kristoffer Haldrup, Kasper S. Pedersen, Gianluca Levi, Asmus Ougaard Dohn, Hannes Jónsson, Klaus Braagaard Mo̷ller, Adi Natan
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Photoresponsive Biomimetic Functions by Light-Driven Molecular Motors in Three Dimensionally Printed Liquid Crystal Elastomers J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Guiying Long, Yanping Deng, Wei Zhao, Guofu Zhou, Dirk J. Broer, Ben L. Feringa, Jiawen Chen
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Circular Heterochiral Titanium-Based Self-Assembled Architectures J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Pierre Mobian, David-Jérôme Pham, Alain Chaumont, Laurent Barloy, Georges Khalil, Nathalie Kyritsakas
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Resistive Memristors Using Robust Electropolymerized Porous Organic Polymer Films as Switchable Materials J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 You Tao, Hui Liu, Hui-Yuan Kong, Xin-Yue Bian, Bin-Wei Yao, Yong Jun Li, Cheng Gu, Xuesong Ding, Lianfeng Sun, Bao-Hang Han
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CO2-Based Stable Porous Metal–Organic Frameworks for CO2 Utilization J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Bo Song, Yuhang Liang, Yi Zhou, Liang Zhang, He Li, Neng-Xiu Zhu, Ben Zhong Tang, Dan Zhao, Bin Liu
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Multivariate Bayesian Optimization of CoO Nanoparticles for CO2 Hydrogenation Catalysis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Lanja R. Karadaghi, Emily M. Williamson, Anh T. To, Allison P. Forsberg, Kyle D. Crans, Craig L. Perkins, Steven C. Hayden, Nicole J. LiBretto, Frederick G. Baddour, Daniel A. Ruddy, Noah Malmstadt, Susan E. Habas, Richard L. Brutchey
The hydrogenation of CO2 holds promise for transforming the production of renewable fuels and chemicals. However, the challenge lies in developing robust and selective catalysts for this process. Transition metal oxide catalysts, particularly cobalt oxide, have shown potential for CO2 hydrogenation, with performance heavily reliant on crystal phase and morphology. Achieving precise control over these
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Modular Access to Chiral Amines via Imine Reductase-Based Photoenzymatic Catalysis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Bin Chen, Renjie Li, Jianqiang Feng, Beibei Zhao, Jiawei Zhang, Jinhai Yu, Yuanyuan Xu, Zhongqiu Xing, Yue Zhao, Binju Wang, Xiaoqiang Huang
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Darobactin Substrate Engineering and Computation Show Radical Stability Governs Ether versus C–C Bond Formation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Austin M. Woodard, Francesca Peccati, Claudio D. Navo, Gonzalo Jiménez-Osés, Douglas A. Mitchell
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A Method for Rigorously Selective Capture and Simultaneous Fluorescent Labeling of N-Terminal Glycine Peptides J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Hongxu Liu, Harnimarta Deol, Ava Raeisbahrami, Hadis Askari, Christopher D. Wight, Vincent M. Lynch, Eric V. Anslyn
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Carbene-Stabilized Phosphagermylenylidene: A Heavier Analog of Isonitrile J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Jiancheng Li, Xin-Feng Wang, Chaopeng Hu, Liu Leo Liu
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Stimulus-Induced Dynamic Behavior Regulation of Flexible Crystals through the Tuning of Module Rigidity J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-10 Han Fang, Xiao-Yi Liu, Hao-Jing Ding, Meagan Mulcair, Brian Space, Hongliang Huang, Xing-Wang Li, Shu-Ming Zhang, Mei-Hui Yu, Ze Chang, Xian-He Bu
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Superconductivity above 105 K in Nonclathrate Ternary Lanthanum Borohydride below Megabar Pressure J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Xiaoxu Song, Xiaokuan Hao, Xudong Wei, Xin-Ling He, Hanyu Liu, Liang Ma, Guangtao Liu, Hongbo Wang, Jingyu Niu, Shaojie Wang, Yanpeng Qi, Zhongyuan Liu, Wentao Hu, Bo Xu, Lin Wang, Guoying Gao, Yongjun Tian
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Structural Insights into Seeding Mechanisms of hIAPP Fibril Formation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Saba Suladze, Christian Sustay Martinez, Diana C. Rodriguez Camargo, Jonas Engler, Natalia Rodina, Riddhiman Sarkar, Martin Zacharias, Bernd Reif
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Biocompatible Tough Ionogels with Reversible Supramolecular Adhesion J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Jiaofeng Xiong, Minzhi Duan, Xiuyang Zou, Shuna Gao, Jiangna Guo, Xiaowei Wang, Qingning Li, Weizheng Li, Xiaoliang Wang, Feng Yan
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Facilitating an Ultrastable O3-Type Cathode for 4.5 V Sodium-Ion Batteries via a Dual-Reductive Coupling Mechanism J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Tianwei Cui, Longxiang Liu, Yuxuan Xiang, Chuanchao Sheng, Xiang Li, Yongzhu Fu
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Computational Insights on Structural Sensitivity of Cobalt in NO Electroreduction to Ammonia and Hydroxylamine J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Pu Guo, Dong Luan, Huan Li, Lin Li, Shaoxue Yang, Jianping Xiao
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In Situ Construction of a Multifunctional Interphase Enabling Continuous Capture of Unstable Lattice Oxygen Under Ultrahigh Voltages J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Xinru Wu, Zhihong Piao, Mengtian Zhang, Gongxun Lu, Chuang Li, Kai Jia, Zhaofeng Zhuang, Runhua Gao, Guangmin Zhou
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2D to 3D Reconstruction of Boron-Linked Covalent–Organic Frameworks J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Xue Wang, Thomas Fellowes, Mounib Bahri, Hang Qu, Boyu Li, Hongjun Niu, Nigel D. Browning, Weiwei Zhang, John W. Ward, Andrew I. Cooper
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Percolation-Induced Ferrimagnetism from Vacancy Order in [Gua]Mn1–xFe2x/3(HCOO)3 Hybrid Perovskites J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Johnathan M. Bulled, Alexandra Willis, Zoé Faure Beaulieu, Simon J. Cassidy, Jonas Bruckmoser, Hanna L. B. Boström, Andrew L. Goodwin
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Simultaneous Stereoinvertive and Stereoselective C(sp3)–C(sp3) Cross-Coupling of Boronic Esters and Allylic Carbonates J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Hong-Cheng Shen, Ze-Shu Wang, Adam Noble, Varinder K. Aggarwal
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Triplet State Radical Chemistry: Significance of the Reaction of 3SO2 with HCOOH and HNO3 J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Josep M. Anglada, Marilia T. C. Martins-Costa, Joseph S. Francisco, Manuel F. Ruiz-López
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Ionic Effect on the Microenvironment of Biomolecular Condensates J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Longchen Zhu, Yifei Pan, Ziyi Hua, Yu Liu, Xin Zhang
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CuH-Catalyzed Regio- and Enantioselective Formal Hydroformylation of Vinyl Arenes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-09 Subhash Garhwal, Yuyang Dong, Binh Khanh Mai, Peng Liu, Stephen L. Buchwald