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Experimental and theoretical study on performance of Cu-Fe spinel supported with certain inerts during chemical looping combustion Chem. Eng. J. (IF 13.3) Pub Date : 2024-07-02 Yu Li, Li Wang, Daifen Chen, Jing Liu, Wei Fan, Junjun Sun
CuFeO spinel oxygen carriers supported with certain inerts (CuFO@Support, Support = MgO, ZrO and TiO) were investigated for their reactivity and redox performance. The experimental results show that the main reduction peak temperature of CuFO@ZrO with CO is about 448 °C. The uniform distribution of nanocrystalline CuFO grains on ZrO is responsible for the increase of the low-temperature reactivity
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A Tetracarbene Iron(II) Complex with a Long‐lived Triplet Metal‐to‐ligand Charge Transfer State due to a Triplet‐Triplet Barrier Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Thomas Reuter, Dimitri Zorn, Robert Naumann, Jan Klett, Christoph Förster, Katja Heinze
Mixed N‐heterocyclic carbene (NHC) / pyridyl iron(II) complexes have attracted a great deal of attention recently because of their potential as photocatalysts and light sensitizers made from Earth‐abundant elements. The most decisive challenge for their successful implementation is the lifetime of the lowest triplet metal‐to‐ligand charge transfer state (3MLCT), which typically decays via a triplet
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Structural Elucidation of a Metagenomic Urethanase and Its Engineering Towards Enhanced Hydrolysis Profiles Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Thomas Bayer, Gottfried J. Palm, Leona Berndt, Hannes Meinert, Yannick Branson, Louis Schmidt, Clemens Cziegler, Ina Somvilla, Celine Zurr, Leonie G. Graf, Una Janke, Christoffel P.S. Badenhorst, Stefanie König, Mihaela Delcea, Ulrike Garscha, Ren Wei, Michael Lammers, Uwe Bornscheuer
While plastics like polyethylene terephthalate can already be degraded efficiently by the activity of hydrolases, other synthetic polymers like polyurethanes (PUs) and polyamides (PAs) largely resist biodegradation. In this study, we solved the first crystal structure of the metagenomic urethanase UMG‐SP‐1, identified highly flexible loop regions to comprise active site residues, and targeted a total
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Enhancing Effect of Fullerene Guest and Counterion on the Structural Stability and Electrical Conductivity of Octahedral Metallo‐Supramolecular Cages Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Shuai Lu, Ziang Zhang, Yiying Zhu, Ye Tao, Quanjie Lin, Qian Zhang, Xin Lv, Lei Hua, Zhi Chen, Heng Wang, Gui-Lin Zhuang, Qian-Chong Zhang, Cunlan Guo, Xiaopeng Li, Xiujun Yu
Metallo‐supramolecular cages have garnered tremendous attention for their diverse yet molecular‐level precision structures. However, physical properties of these supramolecular ensembles, which are of potential significance in molecular electronics, remain largely unexplored. We herein constructed a series of octahedral metallo‐cages and cage‐fullerene complexes with notably enhanced structural stability
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Mechanically Interlocked Polyrotaxane Networks with Collective Motions of Multiple Main‐Chain Mechanical Bonds Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Li Yang, Yuanhao Wang, Guoquan Liu, Jun Zhao, Lin Cheng, Zhaoming Zhang, Ruixue Bai, Yuhang Liu, Mengling Yang, Wei Yu, Xuzhou Yan
Type I main‐chain polyrotaxanes (PRs) with multiple wheels threaded onto the axle are widely employed to design slide‐ring materials. However, Type II main‐chain PRs with axles threading into the macrocycles on the polymer backbones have rarely been studied, although they feature special topological structures and dynamic characteristics. Herein, we report the design and preparation of Type II main‐chain
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Single‐Crystal Cage Framework with High Selectivity and Reversibility in Fullerene Binding Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Shaofeng Huang, Simon J. Teat, Lacey J. Wayment, Nicholas S. Settineri, Hongxuan Chen, Zepeng Lei, Wei Zhang
Host‐guest chemistry, a pivotal branch of supramolecular chemistry, plays an essential role in understanding and constructing complex structures through non‐covalent interactions. Organic molecular cages, characterized by their intrinsic confined cavities, can selectively bind a variety of guest molecules. Their host‐guest chemistry has been well studied in the solution phase, and several attempts
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In Situ Analysis of Interfacial Morphological and Chemical Evolution in All‐Solid‐State Lithium‐Metal Batteries Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Xu-Sheng Zhang, Jing Wan, Zhen-Zhen Shen, Shuang-Yan Lang, Sen Xin, Rui Wen, Yu-Guo Guo, Li-Jun Wan
Visualizing lithium (Li) ions and understanding Li plating/stripping processes as well as evolution of solid electrolyte interface (SEI) are critical for optimizing all‐solid‐state Li metal batteries (ASSLMB). However, the buried solid‐solid interfaces present a challenge for detection which preclude the employment of multiple analysis techniques. Herein, by employing complementary in situ characterizations
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Highly Anisotropic Pd2Lab2Lcc2 and Pd2Lab2Lcd2 Type Cages by Heteromeric Completive Self‐Sorting Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Minaz Parbin, Vellaiyadevan Sivalingam, Dillip Kumar Chand
Pd(II)‐based low‐symmetry coordination cages possessing anisotropic cavities are of great interest. The common strategies employed to achieve such cages utilize either more than one type of symmetrical ligands (e.g., Laa, Lbb, etc.) or only one type of unsymmetrical ligand (e.g., Lab). To significantly enhance the anisotropy, we have designed two unsymmetrical bidentate ligands i.e., Lab and Lcd, aiming
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Tris(triazolo)triazine‐based Covalent Organic Frameworks for Efficiently Photocatalytic Hydrogen Peroxide Production Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Xiaoming Liu, Zhenwei Zhang, Qi Zhang, Yuxin Hou, Jiali Li, Shanshan Zhu, Hong Xia, Huijuan Yue
Two‐dimensional covalent organic frameworks (2D‐COFs) have recently emerged as fascinating scaffolds for solar‐to‐chemical energy conversion because of their customizable structures and functionalities. Herein, two tris(triazolo)triazine‐based COF materials (namely COF‐JLU51 and COF‐JLU52) featuring large surface area, high crystallinity, excellent stability and photoelectric properties were designed
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Highly Selective Photocatalytic Synthesis of Acetic Acid at 0‐25oC Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Xupeng Zong, Yi-Chun Chu, Yu Tang, Yuting Li, Xin-Ping Wu, Zaicheng Sun, Franklin (Feng) Tao
Acetic acid (AA), a vital compound in chemical production and materials manufacturing, is conventionally synthesized by starting with coal or methane through multiple steps including high‐temperature transformations. Here we present a new synthesis of AA from ethane through photocatalytic selective oxidation of ethane by H2O2 at 0‐25°C. The catalyst designed for this process comprises g‐C3N4 with anchored
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Classifieds: Jobs and Awards, Products and Services Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01
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A Conductive Binder Based on Mesoscopic Interpenetration with Polysulfides Capturing Skeleton and Redox Intermediates Network for Lithium Sulfur Batteries Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Wenqiang Wang, Lan Hua, Yifan Zhang, Gengchao Wang, Chunzhong Li
The practical application of lithium‐sulfur batteries with high theoretical energy density and readily available cathode active materials is hampered by problems such as sulfur insulation, dramatic volume changes, and polysulfide shuttling. The targeted development of novel binders is the most industrialized solution to the problem of sulfur cathodes. Herein, an aqueous conductive emulsion binder with
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Unlocking the Power of Human Ferritin: Enhanced Drug Delivery of Aurothiomalate in A2780 Ovarian Cancer Cells Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Lucrezia Cosottini, Andrea Geri, Veronica Ghini, Michele Mannelli, Stefano Zineddu, Giorgio Di Paco, Andrea Giachetti, Lara Massai, Mirko Severi, Tania Gamberi, Antonio Rosato, Paola Turano, Luigi Messori
Aurothiomalate (AuTM) is an FDA‐approved antiarthritic gold drug with unique anticancer properties. To enhance its anticancer activity, we prepared a bioconjugate with human apoferritin (HuHf) by attaching some AuTM moieties to surface protein residues. The reaction of apoferritin with excess AuTM yielded a single adduct, that was characterized by ESI MS and ICP‐OES analysis, using three mutant ferritins
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Fully Optical Control of Polarization Current Direction in a Cyanide‐Bridged Trinuclear Complex Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Yu-Bo Huang, Sheng-Qun Su, Wen-Huang Xu, Wen-Wei Zheng, Kai-Ge Gao, Tian-Chi Ji, Xiao-Peng Zhang, Qi-Rui Shui, Zi-Qi Zhou, Taisuke Ikeda, Shu-Qi Wu, Osamu Sato
As a remote and non‐contact stimulus, light offers the potential for manipulating the polarization of ferroelectric materials without physical contact. However, in current research, the non‐contact write‐read (erase) process lacks direct observation through the stable current as output signal. To address this limitation, we investigated the photoinduced polarization switching capabilities of the cyanide‐bridged
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Electrophilic C(sp2)–H Cyanation with Inorganic Cyanate (OCN–) by PIII/PV=O‐Catalyzed Phase Transfer Activation Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Shicheng Hu, Alexander T. Radosevich
An organophosphorus redox‐catalyzed method for the direct electrophilic cyanation of C(sp2)–H nucleophiles with sodium cyanate (NaOCN) is reported. The catalytic deoxyfunctionalization of the OCN– anion is enabled by the use of a small‐ring phosphacyclic (phosphetane) catalyst in combination with a terminal hydrosilane O‐atom acceptor and a malonate‐derived bromenium donor. In situ spectroscopy under
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Lattice Strain Engineering Boosts CO2 Electroreduction to C2+ Products Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Jiapeng Jiao, Xinchen Kang, Jiahao Yang, Shuaiqiang Jia, Xiao Chen, Yaguang Peng, Chunjun Chen, Xueqing Xing, Zhongjun Chen, Mingyuan He, Haihong Wu, Buxing Han
Regulating the binding effect between the surface of an electrode material and reaction intermediates is essential in highly efficient CO2 electro‐reduction to produce high‐value multicarbon (C2+) compounds. Theoretical study reveals that lattice tensile strain in single‐component Cu catalysts can reduce the dipole–dipole repulsion between *CO intermediates and promotes *OH adsorption, and the high
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Large‐Area Layered Membranes with Precisely Controlled Nano‐Confined Channels Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Mingjie Liu, Can Zhou, Chuangqi Zhao, Zhidong Nie, Tianxu Zhou, Shengwen Kong, Yingzhi Sun, Cheng Qian, Tianyi Zhao
Two‐dimensional (2D) nanosheets‐based membranes, which have controlled 2D nano‐confined channels, are highly desirable for molecular/ionic sieving and confined reactions. However, it is still difficult to develop an efficient method to prepare large‐area membranes with high stability, high orientation, and accurately adjustable interlayer spacing. Here, we present a strategy to produce metal ion cross‐linked
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Stereodivergent Total Synthesis of Tacaman Alkaloids Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Xiangtao Chen, Huijing Wang, Jie Zeng, Qiuhong Li, Tonghui Zhang, Qiaoyun Yang, Pei Tang, Fener Chen
: This paper describes a concise, asymmetric and stereodivergent total synthesis of tacaman alkaloids. A key step in this synthesis is the biocatalytic Baeyer‐Villiger oxidation of cyclohexanone, which was developed to produce seven‐membered lactones and establish the required stereochemistry at the C14 position (92% yield, 99% ee, 500 mg scale). Cis‐ and trans‐tetracyclic indoloquinolizidine scaffolds
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Experimental and theoretical elucidation of the luminescence quenching mechanism in highly efficient Hg2+ and sulfadiazine sensing by Ln‐MOF Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Xiaolin Yu, Dmitry I. Pavlov, Alexey A. Ryadun, Konstantin A. Kovalenko, Tatiana Y. Guselnikova, Enrico Benassi, Andrei S. Potapov, Vladimir P. Fedin
Heavy metal ions and antibiotic contamination have become a major environmental concern worldwide. The development of efficient recognition strategies of these pollutants at ultra‐low concentrations in aqueous solutions as well as the elucidation of the intrinsic sensing mechanism are challenging tasks. In this work, unique luminescent Ln‐MOF materials (NIIC‐3‐Ln) were assembled by rational ligand
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A Functional Switch Between Asperfumene and Fusicoccadiene Synthase and Entrance to Asperfumene Biosynthesis through a Vicinal Deprotonation‐Reprotonation Process Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Jing-Yuan Liu, Fu-Long Lin, Kizerbo A. Taizoumbe, Jian-Ming Lv, Yong-Heng Wang, Gao-Qian Wang, Guo-Dong Chen, Xin-Sheng Yao, Dan Hu, Hao Gao, Jeroen S. Dickschat
The diterpene synthase AfAS was identified from Aspergillus fumigatiaffinis. Its amino acid sequence and – according to a structural model – active site architecture are highly similar to those of the fusicocca‐2,10(14)‐diene synthase PaFS, but AfAS produces a structurally much more complex diterpene with a novel 6‐5‐5‐5 tetracyclic skeleton called asperfumene. The cyclisation mechanism of AfAS was
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Symmetric Electron Transfer Coordinates are Intrinsic to Bridged Systems: An ab Initio Treatment of the Creutz–Taube Ion Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Adam Šrut, Benjamin J. Lear, Vera Krewald
A long‐standing question in electron transfer research concerns the number and identity of collective nuclear motions that drive electron transfer or localisation. It is well established that these nuclear motions are commonly gathered into a so‐called electron transfer coordinate. In this theoretical study, we demonstrate that both anti‐symmetric and symmetric vibrational motions are intrinsic to
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Cycloadditions of Diazoalkenes with P4 and tBuCP: Access to Diazaphospholes Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Sebastian Hauer, Justus Reitz, Taichi Koike, Robert Wolf, Max M. Hansmann
Diazoalkenes readily react with tert‑butylphosphaalkyne (tBuCP) and white phosphorus (P4) to afford novel phosphorus heterocycles, 3H‑1,2,4‐diazamonophospholes and 1,2,3,4‐diazadiphospholes. Both species represent rare examples of neutral heterophospholes. The mechanism of formation and the electronic structures of these formal (3+2) cycloaddition products were analyzed computationally. The new phospholes
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A Cost‐Effective Sulfide Solid Electrolyte Li7P3S7.5O3.5 with Low Density and Excellent Anode Compatibility Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Hui Li, Qiaosong Lin, Jinzhu Wang, Lv Hu, Fang Chen, Zhihua Zhang, Cheng Ma
The commercialization of all‐solid‐state Li batteries (ASSLBs) demands solid electrolytes with strong cost‐competitiveness, low density (for enabling satisfactory energy densities), and decent anode compatibility (the need for cathode compatibility can be circumvented by the cathode coating techniques that are widely applied in sulfide‐based ASSLBs). However, none of the reported oxide, sulfide, or
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Unravelling White Phosphorus: Experimental and Computational Studies Reveal the Mechanisms of P4 Hydrostannylation Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Daniel J Scott, Jose Cammarata, Franz F. Westermair, Peter Coburger, Daniel Duvinage, Marvin Janssen, Maria K. Uttendorfer, Jens Beckmann, Ruth M. Gschwind, Robert Wolf
The hydrostannylation of white phosphorus (P4) allows this crucial industrial precursor to be easily transformed into useful P1 products via direct, ‘one pot’ (or even catalytic) procedures. However, a thorough mechanistic understanding of this transformation has remained elusive, hindering attempts to use this rare example of successful, direct P4 functionalization as a model for further reaction
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Graphical Abstract: Angew. Chem. Int. Ed. 28/2024 Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01
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Frontispiece: Enrooted‐Type Metal‐Support Interaction Boosting Oxygen Evolution Reaction in Acidic Media Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Wenjuan Wang, Cheng Li, Chuan Zhou, Xin Xiao, Fayan Li, Ning‐Yu Huang, Lei Li, Meng Gu, Qiang Xu
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Synthesis of a Metalla[2]catenane, Metallarectangles and Polynuclear Assemblies from Di(N‐Heterocyclic Carbene) Ligands Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Jin-Ping Chang, Ya-Wen Zhang, Li-Ying Sun, Le Zhang, F. Ekkehardt Hahn, Ying-Feng Han
The 2,7‐fluorenone‐linked bis(6‐imidazo[1,5‐a]pyridinium) salt H2‐1(PF6)2 reacts with Ag2O in CH3CN to yield the [2]catenane [Ag4(1)4](PF6)4. The [2]catenane rearranges in DMF to yield two metallamacrocycles [Ag2(1)2](PF6)2. 2,7‐Fluorenone‐bridged bis‐(imidazolium) salt H2‐L(PF6)2 (L = 2a, 2b) react with Ag2O in CH3CN to yield metallamacrocycles [Ag2(L)2](PF6)2 with interplanar distances between the
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Atomically Dispersed Fe‐Cu Dual‐Metal Sites Synergistically Boost Carbonylation of Methane Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-01 Qingpeng Cheng, Xueli Yao, Guanna Li, Lirong Zheng, Guanxin Li, Kaijie Yang, Abdul-Hamid Emwas, Xingang Li, Yu Han, Jorge Gascon
The production of acetic acid, an important industrial chemical traditionally obtained through the carbonylation of methanol using noble metal‐based homogeneous catalysts, encounters challenges arising from high equipment costs and sustainability concerns. The direct liquid‐phase oxidative carbonylation of methane emerges as a promising alternative, capitalizing on abundant natural gas resources and
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A two-photon fluorescent probe sensitive to NADPH reveals metabolic aberrations in brain cells arising from mitochondrial dysfunction in Alzheimer’s disease Chem. Eng. J. (IF 13.3) Pub Date : 2024-07-01 Xueao Wang, Yani Liu, Subin Kim, Chenrun Zhang, Zheng Li, Chen Xu, Hai-Liang Zhu, Yong Qian
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Characteristics and mechanism of low-temperature NO adsorption by activated carbon Chem. Eng. J. (IF 13.3) Pub Date : 2024-07-01 Zhongwei Li, Xingyu Yang, Yutong Wang, Hairui Yang, Qiang Song
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Innovative microkinetic modelling-supported structure–activity analysis of Ni/ZSM-5 during vapor-phase hydrogenation of levulinic acid Chem. Eng. J. (IF 13.3) Pub Date : 2024-07-01 Hue-Tong Vu, Žan Lavrič, Andrii Kostyniuk, Goran Dražić, Miha Grilc, Blaž Likozar, Nataša Zabukovec Logar, Petar Djinović, Nataša Novak Tušar
The study examines Ni/ZSM-5 catalysts in vapor phase hydrogenation of levulinic acid (LA) under continuous flow conditions (ambient pressure, 210–250 °C). Advanced characterization revealed the interplay between Al and Ni. This was further reinforced by new approach of microkinetic modeling, which demonstrates a pioneering work on mathematical description of pulse H sorption, TPD kinetics, DRIFT-supported
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Filtered reaction rate and interphase mass transfer models in reactive gas‐solid flows AlChE J. (IF 3.5) Pub Date : 2024-07-01 Zheqing Huang, Zheng Zhang, Lingxue Wang, Qiang Zhou
This work pursues the closure for the effective reaction rate based on fine‐grid two‐fluid model (TFM) simulations in reactive gas‐solid flows. It is found that the mesoscale mechanism in the solid‐catalyzed reaction is constrained by the kinetic regime (KR) and the external mass transfer‐controlled regimes (EMTR). Thus, a filtered reaction rate model ηsubgrid considered two different regimes is proposed
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Ultrafast and highly‐selective upcycling of plastic polylactic acid waste driven by ZnInFe‐mixed metal oxide AlChE J. (IF 3.5) Pub Date : 2024-07-01 Jianchi Zhou, Jibo Qin, Biao Li, Congjia Luo, Jingbin Han, Yanqing Hu, Wenjing Zhang, Yibo Dou
Chemical upcycling of waste plastics represents an appealing way to achieve a circular economy and mitigate environmental problems but remains a huge challenge. Herein, we report a heterojunction photocatalyst (ZnInFe‐mixed metal oxide, denoted as ZnInFe‐MMO) for the rapid valorization of polylactic acid (PLA) via a developed alkali‐assisted photocatalysis system. The ZnInFe‐MMO featured with a double
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Na-Modified Al2O3-Supported Nickel-Based Catalysts for Liquid-Phase Hydrogenation of Adiponitrile: Effect of Acidity Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-26 Lide Zhou, Cheng Xu, Xiaoping Wang, Xin Tang, Jianfei Zhang, Xianming Gao, Dongxu Hua, Xin Yao, Yaowen Liu, Dianhua Liu
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Enhanced ethanol synthesis from CO2 hydrogenation over Fe and Na co-modified Rh/CeO2 catalysts Chem. Eng. J. (IF 13.3) Pub Date : 2024-06-30 Shuangtao Ji, Fei Hong, Dongsen Mao, Qiangsheng Guo, Jun Yu
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Highly efficient acetylene semi-hydrogenation over Cun cluster stabilized Pd1 single-atom catalysts Chem. Eng. J. (IF 13.3) Pub Date : 2024-06-30 Longyu Xu, Yingxue Qin, Qianjun Zhang, Jing Zhou, Jia Zhao, Feng Feng, Tulai Sun, Xiaoliang Xu, Yihan Zhu, Chunshan Lu, Qunfeng Zhang, Qingtao Wang, Xiaonian Li
The single-atom catalysts (SACs) with the maximum metal utilization efficiency exhibits the advantage of high ethylene selectivity compared with the cluster catalyst in the acetylene semi-hydrogenation reaction, however, the SACs also possess the disadvantages of poor activity and high-temperature stability. Thus, maintaining high reactivity and stability while achieving high ethylene selectivity faces
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Ultrafine CoNi alloy nanoparticles anchored on surface-roughened halloysite nanotubes for highly efficient catalytic hydrogenation of 4-nitrophenol Chem. Eng. J. (IF 13.3) Pub Date : 2024-06-30 Pan Wang, Dongyang Li, Longqian Wang, Shu Guo, Yafei Zhao, Huishan Shang, Dan Wang, Bing Zhang
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Modulating the morphology and protonation degree of chitosan coatings for enabling controlled fabric functionalization Chem. Eng. J. (IF 13.3) Pub Date : 2024-06-30 Zhao Wei, Zoe Gunter, Zhe Qiang, Jie Ren
Chitosan (CS), a versatile biopolymer known for its diverse bioactivity, is commonly used as a coating or finishing agent to enhance fabric performance and broaden their applications. However, conventional methods for introducing CS coating layer on the fabrics often relies on using composition to control their functionality, limiting the ability to tailor properties for specific needs. In this study
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Continuous alkylation of 1,3,5-trihydroxy-2,4,6-trinitrobenzene in microreactor: Process intensification and reaction kinetics Chem. Eng. J. (IF 13.3) Pub Date : 2024-06-30 Xuan Liu, Lixia Yang, Rao Chen, Mei Han, Chaoqun Yao, Guangwen Chen
1,3,5-triamino-2,4,6-trinitrobenzene (TATB) is an essential insensitive energetic material. The alkylation of 1,3,5-trihydroxy-2,4,6-trinitrobenzene (Trinitrophloroglucinol, TNPG), which yields 1,3,5-triethoxy-2,4,6-trinitrobenzene (TETNB), is a pivotal step for the synthesis of TATB. The conventional synthetic process has suffered from long reaction time (∼165 min), intricate procedures, and intensive
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Empowering Capacitive Devices: Harnessing Transfer Learning for Enhanced Data-Driven Optimization Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-29 Teslim Olayiwola, Revati Kumar, Jose A. Romagnoli
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Superstable Mineralization Coupled with Photocatalysis toward Cr(VI) Remediation Using Layered Double Hydroxide Material Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-29 Yawen Wang, Jing Ren, Huijie Liu, Shihua Liu, Nuo Xu, Xianggui Kong, Vishnu D. Rajput, Yong Peng, Yufei Zhao
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“Two Birds One Stone” Strategy: PTFE Nanorods for Assembling Nanomaterials and Constructing Hydrophobic Porous Membranes for High-Performance Membrane Distillation Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Chenyu Lai, Haoran Wang, Zhou Qu, Sinan Cheng, Hongwei Fan, Hong Meng
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Tailoring the Microstructure of Biodegradable PLA/PBS Melt-Blown Nonwovens with Enhanced Mechanical Performance by In Situ PBS Fibrils Formation Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Lin Meng, Mingjing Chen, Xiaoxia Sun, Zhimin Li, Ning Liu, Xinhou Wang
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Synthesis of 2,5-Furandicarboxylic Acid from Fructose Employing a “One-Pot and Two-Step” Approach with Biotar-Derived Functional Catalysts Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Qi Li, Lixiao Zheng, Xinyu Cui, Bilal Patel, Donghai Xu, Yang Guo
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Experimental, Kinetics, and Reactor Modeling Studies of the Direct Dehydrogenation of Ethylbenzene to Styrene in the Fixed-Bed Reactor Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Renshi Tang, Yonghua Zhou, Le Xie
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In Situ Tailoring the Crystalline Defects of Titanium Silicalite-1 (TS-1) to Improve the 1-Butene Epoxidation Performance Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Tao Guo, Baorong Wang, Chenlong Xue, Xiaomeng Liu, Chunhua Lin, Xianqing Xie, Yibin Luo, Weilin Liao, Xingtian Shu
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Assessing Thermodynamics Models for Phase Equilibria and Interfacial Properties Relevant to the Hydrogenation of Carbon Dioxide Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Esteban Cea-Klapp, Bastián González-Barramuño, Nicolás F. Gajardo-Parra, Alejandro Karelovic, Héctor Quinteros-Lama, Roberto I. Canales, José Matías Garrido
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Separation of Liquid Xylene Isomers Using Thin-Film Composite Carbon Molecular Sieve Hollow Fiber Membranes Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Min-Jun Jang, Hyeokjun Seo, Dong-Yeun Koh
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Enhancing Hydrothermal Stability of ZSM-5 Cracking Additives with Aluminum Phosphates Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-28 Vladislav Timoshev, Liane A. Haufe, Markus Seifert, Oliver Busse, Yufei Wu, Thomas Wiegand, Jan J. Weigand
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Integration of Scheduling and Control for Plants Controlled by Distributed MPC Systems Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-27 Daniela Dering, Christopher L.E. Swartz
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Controllable Microfluidic System through Intelligent Framework: Data-Driven Modeling, Machine Learning Energy Analysis, Comparative Multiobjective Optimization, and Experimental Study Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-27 Afshin Kouhkord, Faridoddin Hassani, Moheb Amirmahani, Ali Golshani, Naser Naserifar, Farhad Sadegh Moghanlou, Ali Tarlani Beris
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Study on Desulfurization and Regeneration Performance of Nanofluid System Based on Heteropoly Compound/Ionic Liquid Solutions Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-27 Futang Liu, Yuejia Deng, Lijun Niu, Shihui Wang, Bingquan Wang, Mengzhao Li, Penghao Gao, Rui Wang, Zhaorui Zhou, Xinpeng Liu
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Theoretical Study on the Influence of the Multistage Throttling Structure during the Venting Operation Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-26 Shuai Yu, Xingqing Yan, Yifan He, Jianliang Yu, Lei Chen, Shaoyun Chen
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Kinetics of Methyl Methacrylate Polymerization in the Presence of Initiating Systems “Peroxide + Zirconocene Dichloride” When the Methyl Methacrylate Adhesive is Cured Ind. Eng. Chem. Res. (IF 3.8) Pub Date : 2024-06-26 Konstantin A. Tereshchenko, Daria A. Shiyan, Andrey A. Osipov, Vera P. Bondarenko, Nikolai V. Ulitin, Elina M. Sabitova, Anton V. Bekker, Yana L. Lyulinskaya, Nikolay A. Novikov, Natalia M. Nurullina, Svetlana N. Tuntseva, Tatyana L. Puchkova, Yaroslav O. Mezhuev, Kharlampii E. Kharlampidi, Sergey V. Kolesov
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Identifying the Active Site and Structure–Activity Relationship in Hydrodeoxygenation of Ester to Alcohols over an Al2O3@CuZn Core–Shell Catalyst ACS Sustain. Chem. Eng. (IF 7.1) Pub Date : 2024-06-29 Yuhan Cui, Songyin Yu, Zhichao Sun, Hongyu Niu, Changhai Liang, Chuang Li
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Effects of Surfactants on the Size Distribution and Electrocatalytic Nitrite Reduction of Uniformly Dispersed Au Nanoparticles ACS Sustain. Chem. Eng. (IF 7.1) Pub Date : 2024-06-28 Wei Zhang, Tianyi Wang, Xiujing Xing, Huhu Yin, Jin Li, Wei Xiong, Hao Li
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Multiscale Equation-Oriented Optimization Decreases the Carbon Intensity of Shale Gas to Liquid Fuel Processes ACS Sustain. Chem. Eng. (IF 7.1) Pub Date : 2024-06-28 Kanishka Ghosh, Santiago D. Salas, Alejandro Garciadiego, Jennifer B. Dunn, Alexander W. Dowling
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Improved Reversible and Selective SO2 Absorption by a Stable Phosphonium Carboxylate Ionic Liquid ACS Sustain. Chem. Eng. (IF 7.1) Pub Date : 2024-06-28 Nicolas Scaglione, Luke Wylie, Agilio Padua, Margarida Costa Gomes
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Heteroatom-Rich Hierarchical Porous Biomass Carbon for Vanadium Redox Flow Batteries ACS Sustain. Chem. Eng. (IF 7.1) Pub Date : 2024-06-28 Yuling Chen, Hu Fu, Wu Yang, Linxin Zhong, Qi Wang, Bo Lu, Ning Wang, Zehong Chen, Ge Shi, Chuankun Jia, Mei Ding, Ruidong Xia, Emmanuel Iheanyichukwu Iwuoha, Usisipho Feleni, Shimelis Admassie, Xinwen Peng
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Conceptual Process Design, Techno-Economics, and Greenhouse Gas Analysis of Furfuryl Alcohol Production via Transfer Hydrogenation ACS Sustain. Chem. Eng. (IF 7.1) Pub Date : 2024-06-28 Gabriel Fraga, Jerome Ramirez, Marguerite Renouf, Nuno Batalha