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Valence-delocalized trithorium nanocluster superatoms with open-shell exalted diamagnetism Nat. Chem. (IF 19.2) Pub Date : 2025-04-11
John A. Seed, Xinglan Deng, Josef Tomeček, Adam Brookfield, David Collison, Floriana Tuna, Ashley J. Wooles, George F. S. Whitehead, Nikolas Kaltsoyannis, Stephen T. Liddle -
Universal membranization of synthetic coacervates and biomolecular condensates towards ultrastability and spontaneous emulsification Nat. Chem. (IF 19.2) Pub Date : 2025-04-10
Da Tang, Jun Zhu, Hao Wang, Nannan Chen, Hui Wang, Yongqi Huang, Lingxiang Jiang -
A photoswitchable DNA G-quadruplex ligand enables optical control of transcription Nat. Chem. (IF 19.2) Pub Date : 2025-04-08
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Nuclear spins are active in ultracold atom–molecule collisions Nat. Chem. (IF 19.2) Pub Date : 2025-04-08
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Author Correction: Monitoring the formation of infinite-layer transition metal oxides through in situ atomic-resolution electron microscopy Nat. Chem. (IF 19.2) Pub Date : 2025-04-07
Yaolong Xing, Inhwan Kim, Kyeong Tae Kang, Jinho Byun, Woo Seok Choi, Jaekwang Lee, Sang Ho OhCorrection to: Nature Chemistry https://doi.org/10.1038/s41557-024-01617-7, published online 27 August 2024.
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Hyperfine-to-rotational energy transfer in ultracold atom–molecule collisions of Rb and KRb Nat. Chem. (IF 19.2) Pub Date : 2025-04-07
Yi-Xiang Liu, Lingbang Zhu, Jeshurun Luke, Mark C. Babin, Marcin Gronowski, Hela Ladjimi, Michał Tomza, John L. Bohn, Timur V. Tscherbul, Kang-Kuen Ni -
Switchable skeletal editing of quinolines enabled by cyclizative sequential rearrangements Nat. Chem. (IF 19.2) Pub Date : 2025-04-07
Di Tian, Yu-Ping He, Lu-Sen Yang, Zhuo-Chen Li, Hua Wu -
Progress and future directions in borophene research Nat. Chem. (IF 19.2) Pub Date : 2025-04-07
Qiucheng Li, Eden B. Aklile, Albert Tsui, Mark C. Hersam -
Praseodymium in the formal +5 oxidation state Nat. Chem. (IF 19.2) Pub Date : 2025-04-07
Andrew C. Boggiano, Chad M. Studvick, Sabyasachi Roy Chowdhury, Julie E. Niklas, Haruko Tateyama, Hongwei Wu, Johannes E. Leisen, Florian Kleemiss, Bess Vlaisavljevich, Ivan A. Popov, Henry S. La Pierre -
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Milking riboflavin for all it’s worth Nat. Chem. (IF 19.2) Pub Date : 2025-04-03
Zoe A. Hoffpauir, Audrey L. LambZoe Hoffpauir and Audrey Lamb outline the history and prospects of riboflavin, also known as vitamin B2, a molecule found in food that is required for the formation of coenzymes involved in metabolic processes.
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Aliens among us Nat. Chem. (IF 19.2) Pub Date : 2025-04-03
Michelle FranclDid meteorites fall between the interdisciplinary cracks? Michelle Francl tells the nineteenth-century tale of the extraterrestrial origin of meteorites and suggests that there are lessons for those studying topics that involve multiple disciplines today.
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Activity of GPCR-targeted drugs influenced by human gut microbiota metabolism Nat. Chem. (IF 19.2) Pub Date : 2025-04-03
Qihao Wu, Deguang Song, Yanyu Zhao, Andrew A. Verdegaal, Tayah Turocy, Brianna Duncan-Lowey, Andrew L. Goodman, Noah W. Palm, Jason M. Crawford -
Optical control of gene expression using a DNA G-quadruplex targeting reversible photoswitch Nat. Chem. (IF 19.2) Pub Date : 2025-04-03
Xiaoyun Zhang, Somdutta Dhir, Larry Melidis, Yuqi Chen, Zutao Yu, Angela Simeone, Jochen Spiegel, Santosh Adhikari, Shankar Balasubramanian -
Secret action of gastric acid controlling drug Nat. Chem. (IF 19.2) Pub Date : 2025-04-01
Linghao Kong, Chu Wang -
Recyclable plastics from a manganese catalyst Nat. Chem. (IF 19.2) Pub Date : 2025-03-31
Georgina L. Gregory -
Secondary nucleation as a strategy towards hierarchically organized mesoscale topologies in supramolecular polymerization Nat. Chem. (IF 19.2) Pub Date : 2025-03-31
Sougata Datta, Hiroki Itabashi, Takuho Saito, Shiki Yagai -
Publisher Correction: High-pressure pump–probe experiments reveal the mechanism of excited-state proton-coupled electron transfer and a shift from stepwise to concerted pathways Nat. Chem. (IF 19.2) Pub Date : 2025-03-28
Daniel Langford, Robin Rohr, Stefan Bauroth, Achim Zahl, Alicja Franke, Ivana Ivanović-Burmazović, Dirk M. GuldiCorrection to: Nature Chemistry https://doi.org/10.1038/s41557-025-01772-5, published online 20 March 2025.
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Noncovalent interactions enable optical initialization of spin-based quantum states Nat. Chem. (IF 19.2) Pub Date : 2025-03-28
Subrata Ghosh, Natia L. Frank -
Bilayer covalent organic frameworks take a twist Nat. Chem. (IF 19.2) Pub Date : 2025-03-28
Cheng-Hao Liu, Dmytro F. Perepichka -
Checking out metal cluster chemistry from living libraries Nat. Chem. (IF 19.2) Pub Date : 2025-03-28
Takane Imaoka, Kimihisa Yamamoto -
Oxidation of interfacial cobalt controls the pH dependence of the oxygen evolution reaction Nat. Chem. (IF 19.2) Pub Date : 2025-03-28
Jinzhen Huang, Adam H. Clark, Natasha Hales, Kenneth Crossley, Julie Guehl, Radim Skoupy, Thomas J. Schmidt, Emiliana Fabbri -
Solid oxide electrolysis cell for the super-dry reforming of methane Nat. Chem. (IF 19.2) Pub Date : 2025-03-27
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Unravelling non-adiabatic pathways in the mutual neutralization of hydronium and hydroxide Nat. Chem. (IF 19.2) Pub Date : 2025-03-25
Alon Bogot, Mathias Poline, MingChao Ji, Arnaud Dochain, Stefan Rosén, Henning Zettergren, Henning T. Schmidt, Richard D. Thomas, Daniel Strasser -
Super-dry reforming of methane using a tandem electro-thermocatalytic system Nat. Chem. (IF 19.2) Pub Date : 2025-03-21
Houfu Lv, Xue Dong, Rongtan Li, Chaobin Zeng, Xiaomin Zhang, Yuefeng Song, Haolin Liu, Jiaqi Shao, Na Ta, Qiao Zhao, Qiang Fu, Jianping Xiao, Guoxiong Wang, Xinhe Bao -
Light-driven propane dehydrogenation by a single-atom catalyst under near-ambient conditions Nat. Chem. (IF 19.2) Pub Date : 2025-03-21
Leilei Kang, Beien Zhu, Qingqing Gu, Xinyi Duan, Lei Ying, Guodong Qi, Jun Xu, Lin Li, Yang Su, Yanan Xing, Yanlong Wang, Gang Li, Rengui Li, Yi Gao, Bing Yang, Xiao Yan Liu, Aiqin Wang, Tao Zhang -
High-pressure pump–probe experiments reveal the mechanism of excited-state proton-coupled electron transfer and a shift from stepwise to concerted pathways Nat. Chem. (IF 19.2) Pub Date : 2025-03-20
Daniel Langford, Robin Rohr, Stefan Bauroth, Achim Zahl, Alicja Franke, Ivana Ivanović-Burmazović, Dirk M. Guldi -
Stereospecific molecular rearrangement via nucleophilic substitution at quaternary stereocentres in acyclic systems Nat. Chem. (IF 19.2) Pub Date : 2025-03-19
Kaushalendra Patel, Ilan Marek -
Three-dimensional van der Waals open frameworks Nat. Chem. (IF 19.2) Pub Date : 2025-03-18
Shun Tokuda, Shuhei Furukawa -
Synthesis of triple-decker sandwich compounds featuring a M–M bond through cyclo-Bi5 and cyclo-Sb5 rings Nat. Chem. (IF 19.2) Pub Date : 2025-03-18
Yu-He Xu, Xing Yang, Ya-Nan Yang, Lili Zhao, Gernot Frenking, Zhong-Ming Sun -
Author Correction: Fused radical SAM and αKG-HExxH domain proteins contain a distinct structural fold and catalyse cyclophane formation and β-hydroxylation Nat. Chem. (IF 19.2) Pub Date : 2025-03-17
Yohei Morishita, Suze Ma, Eugenio De La Mora, He Li, Heng Chen, Xinjian Ji, Anthony Usclat, Patricia Amara, Ryosuke Sugiyama, Yi Wei Tooh, Gregory Gunawan, Julien Pérard, Yvain Nicolet, Qi Zhang, Brandon I. MorinakaCorrection to: Nature Chemistry https://doi.org/10.1038/s41557-024-01596-9, Published online 18 September 2024.
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Solution-phase synthesis of Clar’s goblet and elucidation of its spin properties Nat. Chem. (IF 19.2) Pub Date : 2025-03-17
Tianyu Jiao, Cong-Hui Wu, Yu-Shuang Zhang, Xiaohe Miao, Shaofei Wu, Shang-Da Jiang, Jishan Wu -
Photoinduced stepwise charge hopping in π-stacked perylene bisimide donor–bridge–acceptor arrays Nat. Chem. (IF 19.2) Pub Date : 2025-03-14
Leander Ernst, Hongwei Song, Dongho Kim, Frank Würthner -
Vinyl polymers with fully degradable carbon backbones enabled by aromatization-driven C–C bond cleavage Nat. Chem. (IF 19.2) Pub Date : 2025-03-13
Zhen-Hua Zhang, Yangyang Sun, Thayalan Rajeshkumar, Yuesheng Li, Laurent Maron, Miao Hong -
Publisher Correction: Amphoteric chalcogen-bonding and halogen-bonding rotaxanes for anion or cation recognition Nat. Chem. (IF 19.2) Pub Date : 2025-03-12
Yuen Cheong Tse, Andrew Docker, Igor Marques, Vítor Félix, Paul D. BeerCorrection to: Nature Chemistry https://doi.org/10.1038/s41557-025-01742-x, published online 20 February 2025.
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Aging-dependent evolving electrochemical potentials of biomolecular condensates regulate their physicochemical activities Nat. Chem. (IF 19.2) Pub Date : 2025-03-12
Wen Yu, Xiao Guo, Yu Xia, Yuefeng Ma, Zhongli Tong, Leshan Yang, Xiaowei Song, Richard N. Zare, Guosong Hong, Yifan Dai -
Designing single-polymer-chain nanoparticles to mimic biomolecular hydration frustration Nat. Chem. (IF 19.2) Pub Date : 2025-03-12
Tianyi Jin, Connor W. Coley, Alfredo Alexander-Katz -
General strategy for the synthesis of N-monofluoromethyl amides Nat. Chem. (IF 19.2) Pub Date : 2025-03-11
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Aryl halide cross-coupling via formate-mediated transfer hydrogenation Nat. Chem. (IF 19.2) Pub Date : 2025-03-11
Yoon Cho, Yu-Hsiang Chang, Kevin P. Quirion, Zachary H. Strong, Zachary J. Dubey, Nam Nguyen, Seoyoung Lee, Natalie S. Taylor, Jessica M. Hoover, Nicholas A. White, Peng Liu, Michael J. Krische -
Non-enzymatic methylcyclization of alkenes Nat. Chem. (IF 19.2) Pub Date : 2025-03-07
Immanuel Plangger, Elias Schmidhammer, Sebastian Schaar, Klaus Wurst, Maren Podewitz, Thomas Magauer -
Discovery of a fluorinated macrobicyclic antibiotic through chemical synthesis Nat. Chem. (IF 19.2) Pub Date : 2025-03-07
Ben I. C. Tresco, Kelvin J. Y. Wu, Antonio Ramkissoon, Elena V. Aleksandrova, Michael Purdy, Dominic N. Y. See, Richard Y. Liu, Yury S. Polikanov, Andrew G. Myers -
Biomimetic 1,2-amino migration via photoredox catalysis Nat. Chem. (IF 19.2) Pub Date : 2025-03-07
Weitai Fan, Yuang Cui, Beibei Zhan, Yizhou Chen, Lei Bao, Yufan Liang, Xiaheng Zhang -
The phosphate of life Nat. Chem. (IF 19.2) Pub Date : 2025-03-06
Elena De Vita, Rebecca PageElena De Vita and Rebecca Page reflect on the unique properties of phosphate, an essential building block with versatile functions in living systems. Modulating protein phosphorylation is an effective therapeutic strategy, with emerging approaches highlighting the continuous development in this area of drug discovery.
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Preparing and publishing a paper Nat. Chem. (IF 19.2) Pub Date : 2025-03-06
Shira JoudanThere are many steps to preparing a research article for publication, from generating the figures and writing the draft, to responding to reviewers. Shira Joudan explains how their group approaches this task, specifically during the preparation of the research group’s first paper.
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Supramolecular coordination cages as crystalline sponges through a symmetry mismatch strategy Nat. Chem. (IF 19.2) Pub Date : 2025-03-05
Wei He, Yikuan Yu, Kenta Iizuka, Hiroki Takezawa, Makoto Fujita -
Preparation, separation and storage of N-monofluoromethyl amides and carbamates Nat. Chem. (IF 19.2) Pub Date : 2025-03-04
Min Tao, Jiasheng Qian, Linbei Deng, David M. Wilson, Xiangsong Zhang, Jianbo Liu -
Stereoselective alkylation of saturated heterocycles Nat. Chem. (IF 19.2) Pub Date : 2025-02-28
Yan Li, Xi Lu -
Direct stereoselective C(sp3)–H alkylation of saturated heterocycles using olefins Nat. Chem. (IF 19.2) Pub Date : 2025-02-28
Zhijun Zhou, Yang Ke, Rui Miao, Fen Hu, Xiaoqin Wang, Yuanyuan Ping, Sheng Xu, Wangqing Kong -
Flexible interaction patches lead to building blocks with fluctuating valency Nat. Chem. (IF 19.2) Pub Date : 2025-02-27
Tine C. M. Stevens, Pepijn G. Moerman -
Flue gas desulfurization and SO2 recovery within a flexible hydrogen-bonded organic framework Nat. Chem. (IF 19.2) Pub Date : 2025-02-26
Lin Li, Xuan Zhang, Xin Lian, Laiyu Zhang, Zhiyuan Zhang, Xiongli Liu, Tengfei He, Baiyan Li, Banglin Chen, Xian-He Bu -
A glycan foldamer that uses carbohydrate–aromatic interactions to perform catalysis Nat. Chem. (IF 19.2) Pub Date : 2025-02-26
Kaimeng Liu, Martina Delbianco -
Enantioselective photocatalytic synthesis of bicyclo[2.1.1]hexanes as ortho-disubstituted benzene bioisosteres with improved biological activity Nat. Chem. (IF 19.2) Pub Date : 2025-02-25
Pablo Garrido-García, Irene Quirós, Paula Milán-Rois, Silvia Ortega-Gutiérrez, Mar Martín-Fontecha, Luis A. Campos, Álvaro Somoza, Israel Fernández, Thomas Rigotti, Mariola Tortosa -
A programmable biomimetic cytoskeleton Nat. Chem. (IF 19.2) Pub Date : 2025-02-24
Henrike Niederholtmeyer -
Photomediated aliphatic C–H functionalization Nat. Chem. (IF 19.2) Pub Date : 2025-02-24
Tin V. T. Nguyen, Jerome Waser -
Hydrogen transfer pathway controls selectivity in electrocatalytic CO2 reduction Nat. Chem. (IF 19.2) Pub Date : 2025-02-24
Chengzhang Wan, Joel W. Ager, Yu Huang -
Light-activated hypervalent iodine agents enable diverse aliphatic C–H functionalization Nat. Chem. (IF 19.2) Pub Date : 2025-02-24
Zhipeng Lu, John Putziger, Song Lin -
Catalytic closed-loop recycling of polyethylene-like materials produced by acceptorless dehydrogenative polymerization of bio-derived diols Nat. Chem. (IF 19.2) Pub Date : 2025-02-21
Xin Liu, Zhitao Hu, Emma M. Rettner, Katherine L. Harry, Joel Miscall, Nicholas A. Rorrer, Garret M. Miyake -
Rotaxanes with amphoteric σ-hole donors for cation or anion recognition Nat. Chem. (IF 19.2) Pub Date : 2025-02-20
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Catalytic difluorocarbene insertion enables access to fluorinated oxetane isosteres Nat. Chem. (IF 19.2) Pub Date : 2025-02-20
Tong-De Tan, Fang Zhou, Kevin P. Quirion, Yu-Qi Wang, Daniel Zhi Wei Ng, Xiaohua Luo, Eric Chun Yong Chan, Peng Liu, Ming Joo Koh -
Site-specific activation of the proton pump inhibitor rabeprazole by tetrathiolate zinc centres Nat. Chem. (IF 19.2) Pub Date : 2025-02-20
Teresa Marker, Raphael R. Steimbach, Cecilia Perez-Borrajero, Marcin Luzarowski, Eric Hartmann, Sibylle Schleich, Daniel Pastor-Flores, Elisa Espinet, Andreas Trumpp, Aurelio A. Teleman, Frauke Gräter, Bernd Simon, Aubry K. Miller, Tobias P. Dick