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Bionic Artificial Skin Based on Self-Healable Ionogel Composites with Tailored Mechanics and Robust Interfaces Adv. Mater. (IF 27.4) Pub Date : 2024-07-05 Manwen Zhang, Lingyu Zhao, Feng Tian, Xiaojuan Zhao, Ying Zhang, Xin Yang, Wei Huang, Ran Yu
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Self-Charging Aqueous Zn//COF Battery with UltraHigh Self-Charging Efficiency and Rate (Adv. Mater. 27/2024) Adv. Mater. (IF 27.4) Pub Date : 2024-07-04 Leheng Zhong, Chunfang Wang, Jun He, Zhiqing lin, Xiaodong Yang, Ran Li, Shuai Zhan, Linwei Zhao, Dan Wu, Hui Chen, Zijie Tang, Chunyi ZHi, Haiming Lv (Lyu)
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A Rhodamine-Spiropyran Conjugate Empowering Tunable Mechanochromism in Polymers under Multiple Stimuli Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Ze-Ying Sun, Yiran Li, Mengjiao Wu, Weiye He, Yuan Yuan, Yi Cao, Yulan Chen
Mechanochromic functionality realized via the force-responsive mechanophores in polymers has great potential for damage sensing and information storage. Mechanophores with the ability to recognize multiple stimuli for tunable chromic characteristics are highly sought after for versatile sensing ability and color programmability. Nevertheless, the majority of mechanophores are based on single-component
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Pnictogen-Bonding Enzymes Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Giacomo Renno, Dongping Chen, Qing-Xia Zhang, Rosa M. Gomila, Antonio Frontera, Naomi Sakai, Thomas R. Ward, Stefan Matile
The objective of this study was to create artificial enzymes that capitalize on pnictogen bonding, a s-hole interaction that is essentially absent in biocatalysis. For this purpose, stibine catalysts were equipped with a biotin derivative and combined with streptavidin mutants to identify an efficient transfer hydrogenation catalyst for the reduction of a fluorogenic quinoline substrate. Increased
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Phosphonium Iodide Featuring Blue Thermally Activated Delayed Fluorescence for Highly Efficient X-ray Scintillator Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Jun-Hua Wei, Jian-Bin Luo, Zi-Lin He, Qing-Peng Peng, Jing-Hua Chen, Zhi-Zhong Zhang, Xiu-Xian Guo, Dai-Bin Kuang
Organic scintillators are praised for their abundant element reserves, facile preparation procedures, and rich structures. Herein, a new family of highly efficient organic phosphonium halide salts with thermally activated delayed fluorescence (TADF) are designed by innovatively adopting quaternary phosphonium as the electron acceptor, while dimethylamine group and halide anions (I-) serve as the electron
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Bifunctional Chiral Electrocatalysts Enable Enantioselective α-Alkylation of Aldehydes Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Jin-Yu He, Cuiju Zhu, Wen-Xi Duan, Ling-Xuan Kong, Na-Na Wang, Yan-Zhao Wang, Zhi-Yong Fan, Xin-Ying Qiao, Hao Xu
Herein, we describe an innovative approach to the asymmetric electrochemical α-alkylation of aldehydes facilitated by a newly designed bifunctional chiral electrocatalyst. The highly efficient bifunctional chiral electrocatalyst combines a chiral aminocatalyst with a redox mediator. It plays a dual role as a redox mediator for electrooxidation, while simultaneously providing remarkable asymmetric induction
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5,18-Dimesitylorangarin: a Stable Antiaromatic [20]Pentaphyrin(1.0.1.0.0) Displaying Remarkable Oxidative Self-Coupling Reactions Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Yutao Rao, Jiyeon Lee, Jinchao Chen, Ling Xu, Mingbo Zhou, Bangshao Yin, Jiwon Kim, Atsuhiro Osuka, Jianxin Song
5,18-Dimesitylorangarin and its BF2 complex were synthesized by double SNAr reaction of 3,5-dibromo-BODIPY with a-(pyro-2-ly)dipyrrin as the first examples of meso-aryl-substituted orangarin. These orangarins, delineated as [20]pentaphyrin(1.0.1.0.0), are strongly antiaromatic but rather stable. The free base orangarin was coupled by oxidation with MnO2 to give a 11,11’-linked dimer, a cyclooctate
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Jellyfish-inspired Polyurea Ionogel with Mechanical Robustness, Self-Healing, and Fluorescence Enabled by Hyperbranched Cluster Aggregates Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Zhipeng Zhang, Lu Qian, Bin Zhang, Chunfeng Ma, Guangzhao Zhang
Ionogels are promising for soft iontronics, with their network structure playing a pivotal role in determining their performance and potential applications. However, simultaneously achieving mechanical toughness, low hysteresis, self-healing, and fluorescence using existing network structures is challenging. Drawing inspiration from jellyfish, we propose a novel hierarchical crosslinking network structure
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Lewis Acid-Tethered (cAAC)–Copper Complexes: Reactivity for Hydride Transfer and Catalytic CO2 Hydrogenation Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Hayoung Song, Nathaniel Kolnik Szymczak
We present a series of borane-tethered cyclic (alkyl)(amino)carbene (cAAC)-copper complexes, including a borane-capped Cu(I) hydride. This hydride is unusually hydridic and reacts rapidly with both CO2 and 2,6-dimethylphenol at room temperature. Its reactivity is distinct from variants without a tethered borane, and the underlying principles governing the enhanced hydricity were evaluated experimentally
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Ribosome-Free Translation up to Pentapeptides via Template Walk on RNA Sequences Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Clemens Richert, Sabrina Reußwig
The origin of translation is one of the most difficult problems of molecular evolution. Identifying molecular systems that translate an RNA sequence into a peptide sequence in the absence of ribosomes and enzymes is a challenge. Recently, single-nucleotide translation via coupling of 5' phosphoramidate-linked amino acids to 2'/3'-aminoacyl transfer-NMPs, as directed by the sequence of an RNA template
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Embedding Single Pd Atoms on NiGa Intermetallic Surfaces for Efficient and Selective Alkyne Semi-hydrogenation Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-05 Xiaohu Ge, Yundao Jing, Nina Fei, Kelin Yan, Yijing Liang, Yueqiang Cao, Jing Zhang, Gang Qian, Lina Li, Hao Jiang, Xinggui Zhou, Weikang Yuan, Xuezhi Duan
Catalytic removal of alkynes is essential in industry for producing polymer-grade alkenes from steam cracking processes. Non-noble Ni-based catalysts hold promise as effective alternatives to industrial Pd-based catalysts but suffer from low activity. Here we report embedding of single-atom Pd onto the NiGa intermetallic surface with replacing Ga atoms via a well-defined synthesis strategy to design
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Large Scale Synthesis of a Stable Prefunctionalized Silver Nanocluster Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-04 Rui-Lin He, Feng Hu, Zong-Jie Guan, Quan-Ming Wang
Due to the stability issue, It is difficult to prepare a silver nanocluster bearing functional sites, especially at a large scale. We report the synthesis and structure of a stable silver nanocluster bearing multiple surface aldehyde groups [Ag21(Ph2PO2)10(p-CHOPhC≡C)6]SbF6, which allows for postsynthesis modification such as surface functionalization through aldimine condensation to give homochiral
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A [2.2]Isoindolinophanyl-Based Carbene (iPC) Ligand: Synthesis, Electronic and Photophysical Properties, and Application in Photocatalysis** Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-04 Sabyasachi Maity, André M. T. Muthig, Indranil Sen, Ondřej Mrózek, Andrey Belyaev, Benjamin Hupp, Andreas Steffen
Cyclic amino(alkyl) and cyclic amino(aryl) carbenes (cAACs/cAArCs) have been established as very useful ligands for catalytic and photonic applications of transition metal complexes. Herein, we describe the synthesis of a structurally related sterically demanding, electrophilic [2.2]isoindolinophanyl-based carbene (iPC) with a [2.2]paracyclophane moiety. The latter leads to more delocalized frontier
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Deciphering the Factors Controlling Hydrogen and Methyl Spillover on Rh/Cu(111) Single-Atom Alloy Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-04 Kaixuan Gu, Hua Guo, Sen Lin
Spillover of adsorbed species from one active site to another is a key step in heterogeneous catalysis. However, the factors controlling this step, particularly the spillover of polyatomic species, have rarely been studied. Herein, we investigate the spillover dynamics of H* and CH3* species on a single-atom alloy surface (Rh/Cu(111)) upon the dissociative chemisorption of methane (CH4), using molecular
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Sub-Nanosheet Induced Inverse Growth of Negative Valency Au Clusters for Tumor Treatment by Enhanced Oxidative Stress Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-04 Dong Wang, Feng Yuan, Xuliang Deng, Qingda Liu, Wenxiong Shi, Xun Wang
Cluster aggregation states are thermodynamically favored at the subnanoscale, for which an inverse growth from nanoparticles to clusters may be realized on subnanometer supports. Herein, we develop Au-polyoxometalate-layered double hydroxide (Au-POM-LDH) sub-1 nm nanosheets (Sub-APL) based on the above strategy, where sub-1 nm Au clusters with negative valence are generated by the in-situ disintegration
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Synergizing Steric Hindrance and Stacking Interactions to Facilitate the Controlled Assembly of Multiple 41 Metalla-Knots and Pseudo-Solomon Links Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-04 Guo-Xin Jin, Yan Zou, Shu-Jin Bao, Haitong Tang, Hai-Ning Zhang
In this work, a noncoplanar terphenyl served as building block to synthesize a novel 3,3'-substituted bipyridyl ligand (L1) which further reacted with binuclear half-sandwich units A/B, giving rise to two aesthetical 41 metalla-knots in high yields via coordination-driven self-assembly strategy. Furthermore, given the inherent compactness of the 41 metalla-knots, it creates favorable conditions for
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A Photocaged Microtubule-Stabilising Epothilone Allows Spatiotemporal Control of Cytoskeletal Dynamics Angew. Chem. Int. Ed. (IF 16.1) Pub Date : 2024-07-03 Carina Schmitt, Philipp Mauker, Nynke A. Vepřek, Carolin Gierse, Joyce C. M. Meiring, Jürgen Kuch, Anna Akhamanova, Leif Dehmelt, Oliver Thorn-Seshold
The cytoskeleton is essential for spatial and temporal organisation of a wide range of cellular and tissue-level processes, such as proliferation, signalling, cargo transport, migration, morphogenesis, and neuronal development. Cytoskeleton research aims to study these processes by imaging, or by locally manipulating, the dynamics and organisation of cytoskeletal proteins with high spatiotemporal resolution:
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Organic Cations Texture Zinc Metal Anodes for Deep Cycling Aqueous Zinc Batteries Adv. Mater. (IF 27.4) Pub Date : 2024-07-05 Guoqiang Ma, Wentao Yuan, Xiaotong Li, Tongqiang Bi, Linhuan Niu, Yue Wang, Mengyu Liu, Yuanyuan Wang, Zhaoxi Shen, Ning Zhang
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Ductile P-Type AgCu(Se,S,Te) Thermoelectric Materials Adv. Mater. (IF 27.4) Pub Date : 2024-07-05 Kelin Shen, Qingyu Yang, Pengfei Qiu, Zhengyang Zhou, Shiqi Yang, Tian-Ran Wei, Xun Shi
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Interplay of Cooper Pairs and Zero-Energy Quasiparticles in a Gapless Superconductor Adv. Mater. (IF 27.4) Pub Date : 2024-07-05 Jhinhwan Lee, Hae-Ryong Park, Jun Sung Kim, Han Woong Yeom
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In-Sensor Tactile Fusion and Logic for Accurate Intention Recognition Adv. Mater. (IF 27.4) Pub Date : 2024-07-05 Zijian Huang, Shifan Yu, Yijing Xu, Zhicheng Cao, Jinwei Zhang, Ziquan Guo, Tingzhu Wu, Qingliang Liao, Yuanjin Zheng, Zhong Chen, Xinqin Liao
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Glycocalyx-Mimicking Nanoparticles with Differential Organ Selectivity for Drug Delivery and Therapy (Adv. Mater. 27/2024) Adv. Mater. (IF 27.4) Pub Date : 2024-07-04 Dohyeon Kim, Chang-Hee Whang, Jungwoo Hong, Monica Celine Prayogo, Wonsik Jung, Seojung Lee, Hocheol Shin, Yujin Kim, Jiyoung Yu, Min Joong Kim, Kyunggon Kim, Hee-Seung Lee, Sangyong Jon
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A Biohybrid Self-Dispersing Miniature Machine Using Wild Oat Fruit Awns for Reforestation and Precision Agriculture (Adv. Mater. 27/2024) Adv. Mater. (IF 27.4) Pub Date : 2024-07-04 Isabella Fiorello, Marilena Ronzan, Thomas Speck, Edoardo Sinibaldi, Barbara Mazzolai
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Inherently chiral resorcinarene cavitands through ionic catalyst-controlled cross-coupling Chem (IF 19.1) Pub Date : 2024-07-05 Mingfeng Li, Clement Kim Soon Ho, Ivan Keng Wee On, Vincent Gandon, Ye Zhu
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Repurposing myoglobin into an abiological asymmetric ketoreductase Chem (IF 19.1) Pub Date : 2024-07-05 Xiang Zhang, Dongping Chen, Julian Stropp, Ryo Tachibana, Zhi Zou, Daniel Klose, Thomas R. Ward
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Mirror-image protein and peptide drug discovery through mirror-image phage display Chem (IF 19.1) Pub Date : 2024-07-05 Yun-Kun Qi, Ji-Shen Zheng, Lei Liu
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Synthetic extremophiles via species-specific formulations improve microbial therapeutics Nat. Mater. (IF 37.2) Pub Date : 2024-07-05 Miguel Jimenez, Johanna L’Heureux, Emily Kolaya, Gary W. Liu, Kyle B. Martin, Husna Ellis, Alfred Dao, Margaret Yang, Zachary Villaverde, Afeefah Khazi-Syed, Qinhao Cao, Niora Fabian, Joshua Jenkins, Nina Fitzgerald, Christina Karavasili, Benjamin Muller, James D. Byrne, Giovanni Traverso
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Quantifying mechanical forces during vertebrate morphogenesis Nat. Mater. (IF 37.2) Pub Date : 2024-07-05 Eirini Maniou, Silvia Todros, Anna Urciuolo, Dale A. Moulding, Michael Magnussen, Ioakeim Ampartzidis, Luca Brandolino, Pietro Bellet, Monica Giomo, Piero G. Pavan, Gabriel L. Galea, Nicola Elvassore
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Exploiting different electricity markets via highly rate-mismatched modular electrochemical synthesis Nat. Energy (IF 49.7) Pub Date : 2024-07-05 Rui Wang, Jiaze Ma, Hongyuan Sheng, Victor M. Zavala, Song Jin
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Blooming plants and sunken cities, Books in brief Nature (IF 50.5) Pub Date : 2024-07-05
Andrew Robinson reviews five of the best science picks.
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What causes migraines? Study of ‘brain blackout’ offers clues Nature (IF 50.5) Pub Date : 2024-07-05
The blinding headaches are poorly understood — a mouse study suggests that the content of spinal fluid is a trigger for pain.
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“Who am I if not a scientist?” How to find identity in retirement Nature (IF 50.5) Pub Date : 2024-07-05
How do scientists define themselves when they leave paid employment after an all-consuming career in academic research?
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UK election: scientists welcome Labour’s landslide win Nature (IF 50.5) Pub Date : 2024-07-05
Struggling universities should be near the top of the new government’s agenda, say researchers.
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‘Chemical recycling’: 15-minute reaction turns old clothes into useful molecules Nature (IF 50.5) Pub Date : 2024-07-04
Fast fashion creates millions of tonnes of waste each year — could clever chemistry help to tackle the problem?
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Give UK science the overhaul it urgently needs Nature (IF 50.5) Pub Date : 2024-07-04 Marie Claire Brisbois, Furaha Asani, Jon Agar, Yacine Rezgui, Maria Nedeva
Five scholars share their science-policy priorities for the incoming government as it faces urgent challenges in tackling climate change, health, inequality and more.
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Daily briefing: Western scientists get rejected papers published faster Nature (IF 50.5) Pub Date : 2024-07-03
Authors in Western countries are almost 6% more likely than those based in other parts of the world to successfully publish a paper after it has been rejected. Plus, why cancer risk declines sharply in old age and RNA-based pesticides promise precision killing.
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Phase and Interface Engineering of a Ru-Sn Nanocatalyst for Enhanced Alkaline Hydrogen Oxidation Reaction Energy Environ. Sci. (IF 32.4) Pub Date : 2024-07-05 Licheng Wei, Wei Yan, Zhongliang Huang, Ruchun Li, Qingyu Kong, Wei-Hsiang Huang, Chih-Wen Pao, Zhiwei Hu, Haixin Lin, Nanjun Chen, Yong Xu, Hongbo Geng, Xiaoqing Huang
As the anode reaction of anion exchange membrane fuel cells (AEMFCs), hydrogen oxidation reaction (HOR) has attracted great attention, however, suffers from the low kinetics in alkaline condition. In this work, we demonstrate that the strong synergy at the heterointerface of hexagonal close-packed (hcp) and face-centered cubic (fcc) phase of Ru-Sn nanoflowers can greatly contribute to accelerate the
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Insights into the defect-driven heterogeneous structural evolution of Ni-rich layered cathode in lithium-ion batteries Energy Environ. Sci. (IF 32.4) Pub Date : 2024-07-05 Zhongyuan Huang, Ziwei Chen, Maolin Yang, Mihai Chu, Zenan Li, Sihao Deng, Lunhua He, Lei Jin, Rafal E. Dunin-Borkowski, Rui Wang, Jun Wang, Tingting Yang, Yinguo Xiao
Recently, considerable efforts have been made on research and improvement for Ni-rich lithium-ion batteries to meet the demand from vehicles and grid-level large-scale energy storage. Development of next-generation high-performance lithium-ion batteries requires a comprehensive understanding on the underlying electrochemical mechanisms associated with its structural evolution. In this work, advanced
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Fabricating scattering-fluorescent luminescent solar concentrator synchronously to achieve broad-spectrum solar energy utilization and light pollution inhibition Energy Environ. Sci. (IF 32.4) Pub Date : 2024-07-05 Chenkai Jin, Chengqi Feng, Yuhua Chen, Ting Zhang, Huiwen He, Haining Na, Jin Zhu
Light pollution caused by the reflected light of buildings poses a growing threat to the global environment and human health. Currently, common luminescent solar concentrator (LSC), as an important transparent photovoltaic component for building integrated photovoltaic (BIPV), is unable to reduce light pollution due to the limited utilization of solar energy only in ultraviolet range. In this study
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One-pot chemo- and photo-enzymatic linear cascade processes Chem. Soc. Rev. (IF 40.4) Pub Date : 2024-07-05 J. M. Carceller, K. S. Arias, M. J. Climent, S. Iborra, A. Corma
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Synthesis of Macrocyclic Thiolactone Peptides via Photochemical Intramolecular Radical Acyl Thiol-Ene Ligation Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Alby Benny, Eoin M Scanlan
Photochemical acyl thiol-ene can be used to rapidly cyclise fully unprotected peptides bearing both a thioacid and alkene to form peptide thiolactones. This strategy represents the first reported synthesis of peptide thiolactones under radical-mediated conditions.
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Inverse kinetic isotope effect of ammonia decomposition over Ru/CeO2 using deuterated ammonia Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Takuya Suguro, Fuminao Kishimoto, Sota Kuramoto, William J. Movick, Kazuhiro Takanabe
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Synthesis of sterically congested unsymmetrical 1,2-dicarbonyl radicals through a stepwise approach Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Yuna Song, Hayoung Song, Yunseop Choi, Jongcheol Seo, Eunsung Lee
A SIMPLIFIED AND STEPWISE SYNTHETIC METHOD FOR PRODUCING STERICALLY CONGESTED UNSYMMETRICAL 1,2-DICARBONYL RADICALS WAS SUCCESSFULLY DEMONSTRATED INCLUDING DETAILED CHARACTERIZATION OF EACH RADICAL CATION. USING THIS APPROACH, AN ARYL- AND N-HETEROCYCLIC CARBENE-SUBSTITUTED 1,2-DICARBONYL RADICAL IN ITS NEUTRAL FORM IS GENERATED, REVEALING THE STABILIZING ROLE OF N-HETEROCYCLIC CARBENES.
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A fluorinated metal-organic framework-based quasi-solid electrolyte for stabilizing Li metal anode Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Xiang Wang, Mengxi Bai, Qiufen Li, Jiashuai Li, Dongze Li, Xiaoyan Lin, Siyuan Shao, Ziqi Wang
A fluorinated quasi-solid electrolyte (QSE) with a high conductivity of 2.3 mS cm-1 is meticulously designed for Li metal batteries. It facilitates the formation of a LiF-rich solid electrolyte interface that effectively enhances the reversibility of Li anodes. The assembled Li|QSE|LiFePO4 batteries exhibit 92.3% capacity retension after 1500 cycles and an impressive capacity of up to 45 mAh g-1 at
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Three-component cascade carbopalladation/Heck cyclization/borylation: facile access to boryl-functionalized indenes Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Fei Sun, Yiyi Zheng, Mingxia Wu, Hongsen Ji, Zhongyao Jiang, Chenglin Liu, Xin-Xing Wu
A mild Pd-catalyzed three-component cascade cyclizaiton functionalization of o-iodostyrenes, internal alkynes and boron reagents is presented. The transformation is driven by a controlled reaction sequence of intermolecular carbopalladation, intramolecular Heck-type cyclization, and borylation process to give the versatile boryl-functionalized indene skeletons in a selective fashion. Significantly,
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Ferrocene-modified covalent organic framework for efficient oxygen evolution reaction and CO2 electroreduction Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Sheng-Nan Sun, Liling He, Qing Huang, Jiang Liu, Yaqian Lan
A ferrocene-modified COF, namely Ni-Tph-COF-Fc, was synthesized and applied in OER performance. The improved performance may be attributed to the fact that the introduced ferrocene can act as electron donors and carriers to form continuous electron transfer channels with metalloporphyrin in the COFs and promote intramolecular multi-electron transfer. Moreover, the enhanced OER performance leads to
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Click assembly through selective azaylide formation Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Mayo Hamada, Gaku Orimoto, Suguru Yoshida
An efficient triple-click assembly using a newly designed trivalent platform is disclosed. We achieved the selective azaylide formation of 2,3,5,6-tetrafluorophenyl azides with o-ester-substituted triarylphosphines leaving 2,6-dichlorophenyl azides untouched. Further rapid Staudinger reaction of dichlorophenyl azides and subsequent triazole formation allowed us to prepare trifunctionalized molecules
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Engineering Valence-Mismatched Ti4+ into Fe-based Metal-organic-frameworks for enhanced Photocatalytic CO2 Reduction Chem. Commun. (IF 4.3) Pub Date : 2024-07-05 Rui Li, Xiang Xue, Minqi Wu, Xuan Zuo, Huilin Hu, Guangshan Zhou, Wang Zhang, Jun Pan, Xiangliang Pan
The incorporation of high-valence Ti4+ serves as a competitive strategy to augment CO2 adsorption and improve the photocatalytic capabilities of MOF-based photocatalysts. Herein, a series of valence-mismatched low-dose Ti ions doped MIL-53-NH2(Fe) were synthesized for photocatalytic CO2 reduction. Fe97.7/Ti2.3-MIL-NH2 shows excellent efficiency in photocatalytic CO2-to-CO conversion (7.24 mmol g-1
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Silk-based intelligent fibers and textiles: structures, properties, and applications Chem. Commun. (IF 4.3) Pub Date : 2024-07-02 Xiao-Chun Yang, Xiao-Xue Wang, Chen-Yu Wang, Hong-Long Zheng, Meng Yin, Ke-Zheng Chen, Sheng-Lin Qiao
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Chemical shaping of CPO-27-M (M = Co, Ni) through an in situ crystallization within chitosan hydrogels Chem. Commun. (IF 4.3) Pub Date : 2024-07-01 Yassine Khadiri, Christophe Volkringer, Sébastien Royer, Abdelkrim El Kadib, Thierry Loiseau, Jérémy Dhainaut
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Emerging approaches of utilizing trees to produce advanced structural and functional materials Chem. Commun. (IF 4.3) Pub Date : 2024-07-01 Siyuan Fang, Yun Hang Hu
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Harnessing Electro-Descriptors for Mechanistic and Machine Learning Analysis of Photocatalytic Organic Reactions J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-04 Luhan Dai, Yulong Fu, Mengran Wei, Fangyuan Wang, Bailin Tian, Guoqiang Wang, Shuhua Li, Mengning Ding
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Molecular Ball Joints: Mechanochemical Perturbation of Bullvalene Hardy–Cope Rearrangements in Polymer Networks J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-04 Peiguan B. Sun, Meredith N. Pomfret, Matthew J. Elardo, Adhya Suresh, Ángel Rentería-Gómez, Remy F. Lalisse, Sheila Keating, Chuqiao Chen, Shayna L. Hilburg, Progyateg Chakma, Yunze Wu, Rowina C. Bell, Stuart J. Rowan, Osvaldo Gutierrez, Matthew R. Golder
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Development of Modular Nitrenium Bipolar Electrolytes for Possible Applications in Symmetric Redox Flow Batteries J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-04 Andrii Varenikov, Mark Gandelman, Matthew S. Sigman
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Threonine Aldolase-Catalyzed Enantioselective α-Alkylation of Amino Acids through Unconventional Photoinduced Radical Initiation J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-04 Tian-Ci Wang, Zheng Zhang, Guodong Rao, Jiedong Li, Josephine Shirah, R. David Britt, Qilei Zhu, Yang Yang
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Controlling Drug Partitioning in Individual Protein Condensates through Laser-Induced Microscale Phase Transitions J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-04 Axel Leppert, Jianhui Feng, Vaida Railaite, Tomas Bohn Pessatti, Carmine P. Cerrato, Cecilia Mörman, Hannah Osterholz, David P. Lane, Filipe R. N. C. Maia, Markus B. Linder, Anna Rising, Michael Landreh
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Ultrafast Super-Resolution Imaging Exploiting Spontaneous Blinking of Static Excimer Aggregates J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-03 Cong Li, Xiaodong Xie, Mingqiang Li, Haozhi Wang, Xinyi Cheng, Jichao Zhang, Qian Li, Jiang Li, Xiaolei Zuo, Chunhai Fan, Jianlei Shen
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Heavy Water Microdroplet Surface Enriches the Lighter Isotopologue Impurities J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-03 Abhijit Nandy, Supratim Mondal, Debasish Koner, Shibdas Banerjee
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Stereospecific Enzymatic Conversion of Boronic Acids to Amines J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-03 Deirdre Hanley, Zi-Qi Li, Shilong Gao, Scott C. Virgil, Frances H. Arnold, Edwin Alfonzo
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Myelin Surfactant Assemblies as Dynamic Pathways Guiding the Growth of Electrodeposited Copper Dendrites J. Am. Chem. Soc. (IF 14.4) Pub Date : 2024-07-03 José Ferreira, Jeroen Michiels, Marty Herregraven, Peter A. Korevaar