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个人简介

學歷: 美國德州農工大學博士 (1989) 國立中興大學學士 (1981) 經歷: 2019~國立清華大學講座教授 2012~2015國立清華大學教授兼系主任 2009~2012國科會自然處處長 2007~2018國立清華大學特聘教授 2002~ 國立清華大學教授 1999~2002國立彰化師範大學化學系教授兼系主任 1994~2002國立彰化師範大學化學系教授 1991~1994國立彰化師範大學化學系副教授 1989~1991中教師副研究員 榮譽得獎: 教育部學術獎(第62屆) The College of Science Academy of Distinguished Former Students (2013), Texas A&M University 國科會傑出學者研究計畫 國科會傑出研究獎

研究领域

1.金屬蛋白質活性中心、模型化合物、構造及其功能性探討(如small molecules (CO2, N2O, O2, NO2-, NO3- ) activation等)。 2.鐵硫亞硝基(dinitrosyl iron complexes (DNICs))之研究,包括一氧化氮捕捉劑,鐵硫亞硝基化合物對氧氣的活化,RSNO/NO2-與過渡金屬之鍵結反應[M-(RSNO)/M-NO2-]及生化擬態之一氧化氮與蛋白質產生DNICs反應機制與產物之探討。 3.電與光裂解水(electrocatalytic/photocatalytic water splitting)產氫。

近期论文

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1.Wen-Feng Liaw,* Jiun-Hung Lee, Hung-Bin Gau, Chien-Hong Chen, Shiou-Ju Jung, Chen-Hsiung Hung, Wen-Yuan Chen, Ching-Han Hu, Gene-Hsiang Lee “Five-Coordinate and Six-Coordinate FeII(CN)2(CO)x-Thiolate Complexes (x=1, 2): Synthetic Advances for Iron Sites of [NiFe] Hydrogenases” J. Am. Chem. Soc. 2002, 124, 1680. 2.Wen-Feng Liaw,* Chung-Hung Hsieh, Shie-Ming Peng, Gene-Hsiang Lee “ S-S Bond-Activation of Diorganyl Disulfide by Anionic [Mn(CO)5]-: Crystal Structures of [MnII(-SC5H4NO-)2]- and [(CO)3Mn(µ-SR)3Co(µ-SR)3Mn(CO)3]- (R = C6H4NHCOPh)” Inorg. Chim. Acta 2002, 332, 153. 3.Wen-Feng Liaw,* Wen-Ting Tsai, Hung-Bin Gau, Chien-Ming Lee, Shin-Yuan Chou, Wen-Yuan Chen, Gene-Hsiang Lee “Dinuclear Iron(II)-Cyanocarbonyl Complexes Linked by Two/Three Bridging Ethylthiolates: Relevance to the Active-Site of [Fe] Hydrogenases” Inorg. Chem. 2003, 42, 2783-2788. 4.Chung-Hung Hsieh, I-Jui Hsu, Chien-Ming Lee, Shyue-Chu Ke,* Tze-Yuan Wang, Gene-Hsiang Lee, Yu Wang,* Jin-Ming Chen, Jyh-Fu Lee, Wen-Feng Liaw* “Nickel Complexes of o-amidochalcogenophenolate(2-) /o-iminochalcogenobenzosemiquinonate(1-) -radical: Synthesis, Structures, Electron Spin Resonance and X-ray Absorption Spectroscopic Evidence” Inorg. Chem. 2003, 42, 3925-3933. 5.Chien-Ming Lee, Chung-Hung Hsieh, Amitava Dutta, Gene-Hsiang Lee, Wen-Feng Liaw* “Reversible Oxygen Binding to Sulfur in Nitrosylated iron-Thiolate Complexes: Relevance to the Fe-Containing Nitrile Hydratases” J. Am. Chem. Soc. 2003, 125, 11492-11493. 6.Chien-Ming Lee, Chien-Hong Chen, Shyue-Chu Ke,* Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear Nickel(III) and Nickel(II) Thiolate Complexes with Intramolecular S-H Proton Interacting with Both Sulfur and Nickel: Relevance to the [NiFe]/[NiFeSe] Hydrogeanses” J. Am. Chem. Soc. 2004, 126, 8406-8412. 7.Ming-Li Tsai, Chiao-Chun Chen, I-Jui Hsu, Shyue-Chu Ke,* Chung-Hung Hsieh, Kuo-An Chiang, Gene-Hsiang Lee, Yu Wang,* Wen-Feng Liaw* “Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(µ-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe-2S] Ferredoxins” Inorg. Chem. 2004, 43, 5159-5167. 8.Chien-Hong Chen, Yung-Su Chang, Chien-Yeh Yang, Tai-Nan Chen, Chien-Ming Lee, Wen-Feng Liaw* “Preparative and Structural Studies on Iron(II)-Thiolate Cyanocarbonyls: Relevance to the [NiFe]/[Fe]-Hydrogenases” Dalton Trans. 2004, 137-143. 9.Chien-Hong Chen, Li-Chun Wang, Wen-Feng Liaw* “Preparative and Structural Studies on Ruthenium(II)-Thiolate Cyanocarbonyls: Comparison to the [Fe(CO)x(CN)y(SR)z]n- Coordination Modes of Active Sites of Hydrogenases” J. Chin. Chem. Soc. 2004, 51, 1121-1126. 10.Hao-Wen Chen, Chin-Wei Lin, Chiao-Chun Chen, Li-Bo Yang, Ming-Hsi Chiang, Wen-Feng Liaw* “Homodinuclear Iron-Thiolate Nitrosyl Compounds [(ON)Fe(S,S-C6H4)2Fe(NO)2]– and [(ON)Fe(SO2,S-C6H4)(S,S-C6H4)Fe(NO)2]– with {Fe(NO)}7-{Fe(NO)2}9 Electronic Coupling: New Members of A Class of Dinitrosyl Iron Complexes” Inorg. Chem. 2005, 44, 3226-3232. 11.Fu-Te Tsai, Show-Jen Chiou, Ming-Che Tsai, Ming-Li Tsai, Hsiao-Wen Huang, Ming-Hsi Chiang, Wen-Feng Liaw* “Dinitrosyl Iron Complexes (DNICs) [L2Fe(NO)2]– (L = Thiolate): Interconversion among {Fe(NO)2}9 DNICs, {Fe(NO)2}10 DNICs and [2Fe-2S] Clusters, and the Critical Role of the Thiolate Ligands in Regulating NO Release of DNICs” Inorg. Chem. 2005, 44, 5872-5881. 12.Chien-Ming Lee, Chien-Hong Chen, Hao-Wen Chen, Jo-Lu Hsu, Gene-Hsiang Lee, Wen-Feng Liaw* “Nitrosylated Iron-Thiolate-Sulfinate Complexes with {Fe(NO)}6/7 Electronic Cores: Relevance to the Transformation between the Active and Inactive NO-Bound Forms of Fe-Containing Nitrile Hydratases” Inorg. Chem. 2005, 44, 6670-6679. 13.Wen-Feng Liaw, “Nickel: Models of Protein Active Sites” In Encyclopedia of Inorganic Chemistry, Second Edition., Robert A. Scott, Eds.; John Wiley & Sons: 2005. 14.Chien-Hong Chen, Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear [NiII(L)(P-(o-C6H4S)2(o-C6H4SH))]0/1– (L = Thiolate, Selenolate, PPh3, and Cl) Complexes with Intramolecular [Ni-S…H-S]/[Ni…H-S] Interactions Modulated by the Coordinated Ligand L: Relevance to the [NiFe] Hydrogenases” Inorg. Chem. 2006, 45, 2307-2316. 15.Tai-Nan Chen, Feng-Chun Lo, Ming-Li Tsai, Ko-Nien Shih,* Ming-Hsi Chiang, Gene-Hsiang Lee, Wen-Feng Liaw* “Dinitrosyl iron complexes [E5Fe(NO)2]– (E = S, Se): a precursor of Roussin’s black salt [Fe4E3(NO)7]–” Inorg. Chimi. Acta 2006, 359, 2525-2533. 16.Mu-Cheng Hung, Ming-Che Tsai, Gene-Hsiang Lee, Wen-Feng Liaw* “Transformation and Structural Discrimination between the Neutral {Fe(NO)2}10 Dinitrosyl Iron Complexes (DNICs) and the Anionic/Cationic {Fe(NO)2}9 DNICs ” Inorg. Chem. 2006, 45, 6041-6047. 17.Ming-Li Tsai, Wen-Feng Liaw* “Neutral {Fe(NO)2}9 Dinitosyl Iron Complex (DNIC) [(SC6H4-o-NHCOPh)(Im)Fe(NO)2] (Im = imidazole): Interconversion among the Anionic/Neutral {Fe(NO)2}9 DNICs and Roussin’s Red Ester ” Inorg. Chem. 2006, 45, 6583-6585. 18.Tsai-Te Lu, Show-Jen Chiou, Chun-Yu Chen, Wen-Feng Liaw* “Mononitrosyl Tris(Thiolate) Iron Complex [Fe(NO)(SPh)3]– and Dinitrosyl Iron Complex [(EtS)2Fe(NO)2]–: Formation Pathway of Dinitrosyl Iron Complexes (DNICs) from Nitrosyltion of Biomimetic Rubredoxin [Fe(SR)4]2–/1– (R = Ph, Et)” Inorg. Chem. 2006, 45, 8799-8806. 19.Chien-Ming Lee, Ya-Lan Chuang, Chao-Yi Chiang, Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear Ni(III) Complexes [NiIII(L)(P(C6H3-3-SiMe3-2-S)3)]0/1– (L = Thiolate, Selenolate, CH2CN, Cl, PPh3): Relevance to the Nickel Site of [NiFe] Hydrogenases“ Inorg. Chem. 2006, 45, 10895-10904. 20.I-Jui Hsu, Chung-Hung Hsieh, Shyue-Chu Ke,* Kuo-An Chiang, Jenn-Min Lee, Jin-Ming Chen, Ling-Yun Jang, Gene-Hsiang Lee, Yu Wang,* Wen-Feng Liaw* “New Members of A Class of Iron-Thiolate-Nitrosyl Compounds: Trinuclear Iron-Thiolate-Nitrosyl Complexes Containing Fe3S6 Core” J. Am. Chem. Soc. 2007, 129, 1151-1159. 21.Ming-Li Tsai, Chung-Hung Hsieh, Wen-Feng Liaw* “Dinitrosyl Iron Complexes (DNICs) Containing S/N/O Ligation: Transformation of Roussin's Red Ester into the Neutral {Fe(NO)2}10 DNICs” Inorg. Chem. 2007, 46, 5110-5117. 22.Chih-Chin Tsou, Tsai-Te Lu, Wen-Feng Liaw* “EPR, UV-vis, IR and X-ray Demonstration of the Anionic Dimeric Dinitrosyl Iron Complex [(NO)2Fe(µ- StBu)2Fe(NO)2]–: Relevance to the Products of Nitrosylation of Cytosolic and Mitochondrial Aconitases, and High-Potential Iron Proteins” J. Am. Chem. Soc. 2007, 129, 12626-12627. 23.Chien-Ming Lee, Tzung-Wen Chiou, Hsin-Hung Chen, Chao-Yi Chiang, Ting-Shen Kuo, Wen-Feng Liaw* “Mononuclear Ni(II)-Thiolate Complexes with Pendant Thiol and Dinuclear Ni(III/II)-Thiolate Complexes with Ni…Ni Interaction Regulated by the Oxidation Levels of Nickels and the Coordinated Ligands” Inorg. Chem. 2007, 46, 8913-8923. 24.Hsiao-Wen Huang, Chih-Chin Tsou, Ting-Shen Kuo, Wen-Feng Liaw* “New Members of a Class of Dinitrosyl Iron Complexes (DNICs): Interconversion and Spectroscopic Discrimination of the Anionic {Fe(NO)2}9 [(NO)2Fe(C3H3N2)2]– and [(NO)2Fe(C3H3N2)(SR)]– (C3H3N2 = Deprotonated Imidazole ; R = tBu, Et, Ph)” Inorg. Chem. 2008, 47, 2196-2204. 25.Tsai-Te Lu, Chih-Chin Tsou, Hsiao-Wen Huang, I-Jui Hsu, Jin-Ming Chen, Ting-Shen Kuo, Yu Wang,* Wen-Feng Liaw* “Anionic Roussin’s Red Esters (RREs) syn-/anti-[Fe2(μ-SEt)2(NO)4]–: the Critical Role of Thiolate Ligands in Regulating the Transformation of RREs into Dinitrosyl Iron Complexes (DNICs) and the Anionic RREs” Inorg. Chem. 2008, 47, 6040-6050. 26.Tzung-Wen Chiou, Wen-Feng Liaw* “Mononuclear Nickel(III) Complexes [NiIII(OR)(P(C6H3-3-SiMe3-2-S)3)]1– (R = Me, Ph) Containing the Terminal Alkoxide Ligand: Relevance to the Nickel Site of Oxidized-Form [NiFe] Hydrogenases” Inorg. Chem. 2008, 47, 7909-7913. 27.Tzung-Wen Chiou, Wen-Feng Liaw* “Nickel-Thiolate and Iron-Thiolate Cyanocarbonyl Complexes: Modeling the Nickel and Iron Sites of [NiFe] Hydrogenase” C. R.. Chimie 2008, 11, 818-833. (Invited Review). 28.Feng-Chun Lo, Chang-Li Chen, Chien-Ming Lee, Ming-Che Tsai, Tsai-Te Lu, Wen-Feng Liaw, Steve S.-F. Yu* “A study of NO trafficking from dinitrosyl-iron complexes to the recombinant E. coli transcriptional factor SoxR” J. Biol. Inorg. Chem. 2008, 13, 961-972. 29.Yi-Ju Chen, Wei-Chi Ku, Li-Ting Feng, Ming-Li Tsai, Chung-Hung Hsieh, Wen-Hwei Hsu, Wen-Feng Liaw, Chen-Hsiung Hung,* Yu-Ju Chen* “Nitric oxide physiological responses and delivery mechanisms probed by water-soluble Roussin’s Red Ester and {Fe(NO)2}10 DNIC” J. Am. Chem. Soc. 2008, 130, 10929-10938. 30.Chia-Huei Lin, Chien-Ge Chen, Ming-Li Tsai, Gene-Hsiang Lee, Wen-Feng Liaw* “Monoanionic {Mn(NO)}5 and Dianionic {Mn(NO)}6 Thiolato Nitrosyl Manganese Complexes: [(NO)Mn(L)2]– and [(NO)Mn(L)2]2– (LH2 = 1,2-Benzenedithiol and Toluene-3,4-Dithiol)” Inorg. Chem. 2008, 47, 11435-11443. 31.Chih-Chin Tsou, Zong-Sian Lin, Tsai-Te Lu, Wen-Feng Liaw* “Transformation of Dinitrosyl Iron Complexes (DNICs) [(NO)2Fe(SR)2]– (R = Et, Ph) into [4Fe-4S] Clusters [Fe4S4(SR)4]2–: Relevance to the Repair of the Nitric Oxide-Modified Ferredoxin [4Fe-4S] Clusters” J. Am. Chem. Soc. 2008, 130, 17154-17160. 32.Fu-Te Tsai, Ting-Shen Kuo, Wen-Feng Liaw* “Reversible Transformation between the Six-Coordinate {Fe(NO)2}9 [(η2-ONO)(1-MeIm)2Fe(NO)2] (g = 2.013) and Four-Coordinate {Fe(NO)2}9 [(ONO)(1-MeIm)Fe(NO)2] (g = 2.03)” J. Am. Chem. Soc. 2009, 131, 3426-3427. 33.Tsai-Te Lu, Hsiao-Wen Huang, Wen-Feng Liaw “ Anionic Mixed Thiolate- Sulfide-Bridged Roussin’s Red Esters [(NO)2Fe(μ-SR)(μ-S)Fe(NO)2]– (R = Et, Me, Ph): A Key Intermediate for Transformation of Dinitrosyl Iron Complexes (DNICs) to [2Fe-2S] Clusters “ Inorg. Chem. 2009, 48, 9027-9035. 34.Ming-Che Tsai, Fu-Te Tsai, Tsai-Te Lu, Ming-Li Tsai, Yin-Ching Wei, I-Jui Hsu, Jyh-Fu Lee, Wen-Feng Liaw “Relative Binding Affinity of Thiolate, Imidazolate, Phenoxide and Nitrite Toward {Fe(NO)2} Motif of Dinitrosyl Iron Complexes (DNICs) : the Characteristic Pre-edge Energy of {Fe(NO)2}9 DNICs” Inorg. Chem. 2009, 48, 9579-9591. 35.Fu-Te Tsai, Pei-Lin Chen, Wen-Feng Liaw* “The Roles of Distinct Electronic Structures of the {Fe(NO)2}9 and {Fe(NO)2}10 Dinitrosyl Iron Complexes (DNICs) in Modulating Nitrite Binding Modes and Nitrite Activation Pathways” J. Am. Chem. Soc. 2010, 132, 5290-5299. 36.Tsai-Te Lu, Chih-Hao Chen, Wen-Feng Liaw* “Formation of the Distinct Redox-Interrelated Forms of Nitric Oxide from Reaction of Dinitrosyl Iron Complexes (DNICs) and Substitution Ligands” Chem. Eur. J. 2010, 16, 8088-8095. 37.Tsai-Te Lu, Li-Bo Yang, Wen-Feng Liaw* “Trigonal Bipyramidal {Fe(NO)}7 Complex [(NO)Fe(SC9H6N)2] Containing an Equatorial Nitrosyl Ligand: the Critical Role of Chelating Ligands in Regulating the Geometry and Transformation of Mononitrosyl Iron Complex (MNIC)” J. Chin. Chem. Soc. 2010, 57, 909-915. 38.Chien-Hong Chen, Wen-Feng Liaw “Iron-cyanocarbonyl Complexes [PPN][Fe(CO)4(CN)] and [PPN][FeBr(CO)3(CN)2]” Inorganic Syntheses, 2010, vol. 35, P. 129-132. 39.Chi-Ming Wu, Yen-Hao Chen, Kasala Dayananda, Tsun-Wei Shiue, Chen-Hsiung Hung, Wen-Feng Liaw, Po-Yu Chen, Yun-Ming Wang* “Sensitivity Evaluation of Rhodamine B Hydrazide Towards Nitric Oxide and its Application for Macrophage Cells Imaging” Anal. Chimi. Acta, 2011, 708, 141-148. 40.Tsai-Te Lu, Szu-Hsueh Lai, I-Jui Hsu,* Ling-Yun Jang, Jyh-Fu Lee, I-Chia Chen,* Wen-Feng Liaw* “Discrimination of the Mononuclear and Dinuclear Dinitrosyl Iron Complexes (DNICs) by S K-Edge X-ray Absorption Spectroscopy: Insight into the Electronic Structure and Reactivity of DNICs” Inorg. Chem. 2011, 50, 5396-5406. 41.Chih-Chin Tsou, Wen-Feng Liaw* “ Transformation of the {Fe(NO)2}9 Dinitrosyl Iron Complexes (DNICs) into S-nitrosothiols (RSNOs) Triggered by Acid-Base Pair“ Chem. Eur. J. 2011, 17, 13358-13366. 42.Zong-Sian Lin, Feng-Chun Lo, Chih-Hsiang Li, Chih-Hao Chen, Wei-Ning Huang, I-Jui Hsu, Jyh-Fu Lee, Jia-Cherng Horng, Wen-Feng Liaw* “Peptide-Bound Dinitrosyl Iron Complexes (DNICs) and Neutral/Reduced-form Roussin’s Red Esters (RREs/rRREs) : Understanding Nitrosylation of [Fe-S] Clusters Leading to the Formation of DNICs and RREs Using a De Novo Design Strategy” Inorg. Chem. 2011, 50, 5396-5406. 43.Tsun-Wei Shiue, Yen-Hao Chen, Chi-Ming Wu, Gyan Singh, Hsing-Yin Chen, Chen-Hsiung Hung, Wen-Feng Liaw, Yun-Ming Wang* “Nitric Oxide Turn-on Fluorescent Probe Based on Deamination of Aromatic Primary Monoamines” Inorg. Chem. 2012, 51, 5400-5408. 44.Shih-Wey Yeh, Chih-Wei Lin, Ya-Wen Li, I-Jui Hsu,* Chien-Hong Chen, Ling-Yun Jang, Jyh-Fu Lee, Wen-Feng Liaw* “Insight Into the Dinuclear {Fe(NO)2}10-{Fe(NO)2}10 and Mononuclear {Fe(NO)2}10 Dinitrosyliron Complexes (DNICs)” Inorg. Chem. 2012, 51, 4076-4087. 45.Feng-Chun Lo, Jyh-Fu Lee, Wen-Feng Liaw, I.-Jui Hsu,* Yi-Fang Tsai, Sunney I. Chan, Steve S.-F. Yu* “The Metal Core Structures in the Recombinant Escherichia coli Transcriptional Factor SoxR” Chem. Eur. J. 2012, 18, 2565-2577. 46.Wei-Chih Shih, Tsai-Te Lu, Li-Bo Yang, Fu-Te Tsai, Ming-Hsi Chiang,* Jyh-Fu Lee,Yun-Wei Chiang, Wen-Feng Liaw* “New members of a class of dinitrosyliron complexes (DNICs): The characteristic EPR signal of the six-coordinate and five-coordinate {Fe(NO)2}9 DNICs” J. Inorg. Biochem. 2012, 113, 83-93. 47.Zong-Sian Lin, Tzung-Wen Chiou, Kuan-Yu Liu, Chang-Chih Hsieh, Jen-Shiang K. Yu,* Wen-Feng Liaw* “A Dinitrosyl Iron Complex (DNIC) within the Homoleptic Fe(NO)4 Anion: NO as Nitroxyl and Nitrosyl Ligands within a Single Structure” Inorg. Chem. 2012, 51, 10092-10094. 48.Fu-Te Tsai,* Yu-Ching Lee, Ming-Hsi Chiang, Wen-Feng Liaw* “Nitrate-to-Nitrite-to-Nitric Oxide Conversion Modulated by Nitrate-Containing {Fe(NO)2}9 Dinitrosyl Iron Complex (DNIC)“Inorg. Chem. 2013, 52, 464-473. 49.Chih-Chin Tsou, Fu-Te Tsai, Huang-Yeh Chen, I-Jui Hsu,*, Wen-Feng Liaw* “Insight into One-Electron Oxidation of the {Fe(NO)2}9 Dinitrosyl Iron Complex (DNIC): Aminyl Radical Stabilized by [Fe(NO)2] Motif” Inorg. Chem. 2013, 52, 1631-1639. 50.Kuan-Ting Lai, Wei-Chieh Ho, Tzung-Wen Chiou, and Wen-Feng Liaw* “Formation of [NiIII(1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]– via CS2 Insertion into Nickel(III)-Hydride-Containing [NiIII(H)(P(o-C6H3-3-SiMe3-2-S)3)]–" Inorg. Chem. 2013, 52, 4151-4153. 51.Ku-Kuei Lin, Shou-Cheng Wu, Kuang-Mei Hsu, Chen-Hsiung Hung, Wen-Feng Liaw, Yun-Ming Wang* “A N-(2-Aminophenyl)-5-(dimethylamino)-1- naphthalenesulfonic Amide (Ds-DAB) Based Fluorescent Chemosensor for Peroxynitrite” Org. Lett. 2013, 15, 4242-4245. 52.Chung-Yen Lu and Wen-Feng Liaw* “Formation Pathway of Roussin’s Red Ester (RRE) via Reaction of {Fe(NO)2}10 DNIC and Thiol: The Facile Synthetic Route for Synthesizing Cysteine-Containing Dinitrosyl Iron Complex (DNIC)“Inorg. Chem. 2013, 52, 13918-13926. 53.Chih-Chin Tsou, Wan-Lin Yang, and Wen-Feng Liaw* “Nitrite Activation to Nitric Oxide via Onefold Protonation of Iron(II)-O,O-nitrito Complex: Relevance to the Nitrite Reductase Activity of Deoxyhemoglobin and Deoxyhemerythrin” J. Am. Chem. Soc. 2013, 135, 18758-18761. 54.Shih-Wey Yeh, Chih-Chin Tsou, Wen-Feng Liaw* “Dinitrosyliron Complex [Fe4(3-S)2(2-NO)2(NO)6]2– Containing Bridging Nitroxyls: 15N (NO) NMR Analysis of the Bridging and Terminal NO-Coordinate Ligands” Dalton Trans. 2014, 43, 9022-9025. 55.Chih-Chin Tsou,* Wei-Chun Chiu, Chun-Hung Ke, Jia-Chun Tsai, Yun-Ming Wang, Ming-Hsi Chiang and Wen-Feng Liaw* “Iron(III) Bound by Hydrosulfide Anion ([HS]–) Ligands: NO Promoting Stabilization of [Fe(III)-SH] Motif” J. Am. Chem. Soc. 2014, 136, 9424-9433. 56.Tsai-Te Lu,* Tsu-Chien Weng,* Wen-Feng Liaw* “X-ray Emission Spectroscopy: a Spectroscopic Ruler for the Determination of NO Oxidation State in Fe-NO Complexes” Angew. Chem., Int. Ed. 2014, 53, 11562-11566. 57.Ming-Li Tsai, Chih-Chin Tsou, Wen-Feng Liaw* “Dinitrosyl Iron Complexes (DNICs): from Biomimetic Synthesis and Spectroscopic Characterization toward Unveiling the Biological and Catalytic Roles of DNICs“ Acc. Chem. Res. 2015, 48, 1184-1193. 58.Hao-Ching Chang, Feng-Chun Lo, Wen-Chi Liu, Tsung-Han Lin, Wen-Feng Liaw, Ting-Shen Kuo, Way-Zen Lee* “Ambient Stable Trigonal Bipyramidal Copper(III) Complexes Equipped with an Exchangeable Axial Ligand“ Inorg. Chem. 2015, 54, 5527-5533. 59.Shih-Wey Yeh, Chih-Wei Lin, Bai-Heng Liu, Chih-Chin Tsou, Ming-Li Tsai*, Wen-Feng Liaw* “Chelate-Thiolate-Coordinate Ligands Modulating the Configuration and Electrochemical Property of Dinitrosyliron Complexes (DNICs)” Chem. Eur. J. 2015, 21, 16035-16046. 60.Tzung-Wen Chiou,* Tsai-Te Lu,* Ying-Hao Wu, Yi-Ju Yu, Li-Kang Chu, Wen-Feng Liaw* “Development of Dinitrosyl Iron Complex from a Molecular Catalyst into a Hydrogen Evolution Cathode” Angew. Chem., Int. Ed. 2015, 54, 14824-14829. 61.Chuan-Hung Chuang, Wen-Feng Liaw*, Chen-Hsiung Hung* “Conversion of Nitric Oxide into Nitrous Oxide as Triggered by the Polarization of Coordinated NO by Hydrogen Bonding” Angew. Chem., Int. Ed. 2016, 55, 5190-5194. 62.Feng-Chun Lo, Chang-Chih Hsieh, Manuel Maestre-Reyna,* Chin-Yu Chen,* Tzu-Ping Ko, Yih-Chern Horng, Yei-Chen Lai, Yun-Wei Chiang,* Chih-Mao Chou, Cheng-Hung Chiang, Wei-Ning Huang, Yi-Hung Lin, D. Scott Bohle,* Wen-Feng Liaw* “Crystal Structure of the Repair of Iron Centers Protein YtfE and its Interaction with NO” Chem. Eur. J. 2016, 22, 9768-9776. 63.Shou-Cheng Wu, Chung-Yen Lu, Yi-Lin Chen, Feng-Chun Lo, Ting-Yin Wang, Yu-Jen Chen, Shyng-Shiou Yuan, Wen-Feng Liaw*, Yun-Ming Wang* “Water-Soluble Dinitrosyl Iron Complex (DNIC): a Nitric Oxide Vehicle Triggering Cancer Cell Death via Apoptosis” Inorg. Chem. 2016, 55, 9383-9392. 64.Chun-Chieh Wang, Hao-Ching Chang, Yei-Chen Lai, Huayi Fang, Chieh-Chin Li, Hung-Kai Hsu, Zong-Yan Li, Tien-Sung Lin, Ting-Shen Kuo, Frank Neese, Shengfa Ye,* Yun-Wei Chiang,* Ming-Li Tsai,* Wen-Feng Liaw,* Way-Zen Lee,* “A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from its Superoxo Intermediate via Hydrogen Atom Abstraction” J. Am. Chem. Soc. 2016, 138, 14186-14189. 65.Tzung-Wen Chiou,* Yen-Ming Tseng, Tsai-Te Lu, Tsu-Chien Weng, Dimosthenes Sokaras, Wei-Chieh Ho, Ting-Shen Kuo, Ling-Yun Jang, Jyh-Fu Lee, Wen-Feng Liaw* “[NiIII(OMe)]-Mediated Reductive Activation of CO2 Affording a Ni(1-OCO) Complex” Chem. Sci. 2016, 7, 3640-3644. 66.Tao-Hung Yen, Zong-Cheng He, Gene-Hsiang Lee, Mei-Chun Tseng, Yu-Hsuan Shen, Tien-Wen Tseng,* Wen-Feng Liaw,* Ming-His Chiang* “Reduced Thione Ligation is Preferred over Neutral Phosphine Ligation in Diiron Biomimics regarding Electronic Functionality: a Spectroscopic and Computation Investigation” Chem. Comm. 2017, 53, 332-335. 67.Chun-Hung Ke, Chien-Hong Chen,* Ming-Li Tsai,* Hsuan-Chi Wang, Fu-Te Tsai, Yun-Wei Chiang, Wei-Chih Shih, D. Scott Bohle, Wen-Feng Liaw* “{Fe(NO)2}9 Dinitrosyl Iron Complex Acting as a Vehicle for the NO Radical ” J. Am. Chem. Soc. 2017, 139, 67-70. 68.Chin-Yu Chen, Feng-Chun Lo, Wen-Feng Liaw, “Iron sulfur cluster repair protein YtfE (eibc2616)” in Encyclopedia of Inorganic and Bioinorganic Chemistry; Robert A. Scott, Ed.; 2018 John Wily & Sons, West Sussex, PO19 85Q, UK. (DOI: 10.1002/9781119951438.eibc2616). 69.Wei-Liang Li, Tzung-Wen Chiou,* Chien-Hong Chen, Yi-Ju Yu, Li-Kang Chu and Wen-Feng Liaw* “Electrodeposited-Film Electrodes Derived from A Precursor Dinitrosyl Iron Complex for Electrocatalytic Water Splitting” Dalton Trans. 2018, 47, 7128-7134. . 70.Hsiao-Wen Huang, Min-Hsuan Lin, Yen-Hung Lin, Ya-Rong Huang, Chih-Hung Chou, Hsiao-Chin Hong, Mei-Ren Wang, Yu-Ting Tseng, Po-Chun Liao, Min-Chuan Chung, Yu-Jie Ma, Shou-Cheng Wu, Yung-Jen Chuang,* Horng-Dar Wang,* Yun-Ming Wang,* Hsien-Da Huang,* Tsai-Te Lu,* and Wen-Feng Liaw* “Extension of C. elegans Lifespan Using the ●NO-delivery Dinitrosyl Iron Complexes” J. Biol. Inorg. Chem. 2018, 23, 775-784. 71.Fu-Te Tsai,* Hsuan-Chi Wang, Chun-Hung Ke, and Wen-Feng Liaw* “FeCo/FeCoPxOy(OH)z as Bifunctional Electrodeposited-Film Electrodes for Overall Water Splitting” ACS Appl. Energy Mater. 2018, 1, 5298-5307. 72.Tsai-Te Lu,* Yun-Ming Wang,* Chen-Hsiung Hung,* Show-Jen Chiou,* and Wen-Feng Liaw* “Bioinorganic Chemistry of Natural [Fe(NO)2] Motif: Evolution of Functional Model for NO-related Biomedical Application and Revolutionary Development of Translational Model” Inorg. Chem. 2018, 57, 12425-12443. (Viewpoint (invited)). 73.Chun-Hung Ke, Wei-Chih Shih, Fu-Te Tsai,* Ming-Li Tsai,* Wei-Min Ching, Hung-Hsi Hsieh, Wen-Feng Liaw* “Electrocatalytic Water Reduction Beginning with {Fe(NO)2}10-Reduced Dinitrosyl Iron Complex: Identification of N-Doped FeOx(OH)y as Real Heterogeneous Catalyst” Inorg. Chem. 2018, 57, 14715-14726. 74.Sathyadevi Palanisamy, Yu-Liang Wang, Yu-Jen Chen, Chiao-Yun Chen, Fu-Te Tsai, Wen-Feng Liaw, Yun-Ming Wang* “In Vitro and in Vivo Imaging of Nitroxyl with Copper Fluorescent Probe in Living Cells and Zebrafish” Molecules 2018, 23, 2551-2566. 75.Pai-Heng Liu, Fu-Te Tsai,* Bo-Hao Chen, I-Jui Hsu* Hung-Hsi Hsieh, Wen-Feng Liaw* “Insight into Chalcogenolate-Bound {Fe(NO)2}9 Dinitrosyl Iron Complexes (DNICs): Covalent Character versus Ionic Character” Dalton Trans. 2019, 48, 6040-6050. (Invitation) 76.Wun-Yan Wu, Chia-Ning Hsu, Chieh-Hsin Hsieh, Tzung-Wen Chiou,* Ming-Li Tsai,* Ming-Hsi Chiang, Wen-Feng Liaw* “NO-to-[N2O2]2−-to-N2O Conversion Triggered by {Fe(NO)2}10-{Fe(NO)2}9 Dinuclear Dinitrosyl Iron Complex” Inorg. Chem. 2019, 58, 9586-9591. 77.Shan Lu, Jin-Cheng Chiang, Tzung-Wen Chiou,* Wen-Feng Liaw* “Dinitrosyl Iron Complexes: from Molecular Electrocatalysts to Electrodeposited-Film Electrodes for Hydrogen Evolution Reaction” J. Chin. Chem. Soc. 2019, 66, 1185-1193. 78.Chien-Hong Chen,* Tzung-Wen Chiou,* Han-Chun Chang, Wei-Liang Li, Chi-Yen Tung Wen-Feng Liaw “An organic ligand promoting the electrocatalytic activity of cobalt oxide for the hydrogen evolution reaction” Sustainable Energy Fuels 2019, 3, 2205-2210. 79.Yu-Jen Chen, Shou-Cheng Wu, Hsiang-Ching Wang, Tung-Ho Wu, Shyng-Shiou F. Yuan*, Tsai-Te Lu*, Wen-Feng Liaw*, Yun-Ming Wang* “Activation of Angiogenesis and Wound Healing in Diabetic Mice Using NO-Delivery Dinitrosyl Iron Complexes” ACS Mol. Pharmaceutics 2019, 16, 4241-4251. 80.Wun-Yan Wu, Wen-Feng Liaw* “NO Reduction Forming Hyponitrite Triggered by Metal-Containing Complexes” J. Chin. Chem. Soc. 2020, 67, 206-212. (Review) 81.Yu-Ting Tseng, Wei-Min Ching, Wen-Feng Liaw,* Tsai-Te Lu* “Dinitrosyl Iron Complex [K-18-crown-6-ether][(NO)2Fe(MePyrCO2)]: Intermediate for Cooperative Conversion of Carbon Dioxide into Oxalate Promoted by Redox-Inactive Lewis Acid" Angew. Chem., Int. Ed. 2020, 59, 11819-11823. 82.Fu-TeTsai,* Yu-Ting Deng, Chih-Wen Pao, Jeng-Lung Chen, Jyh-Fu Lee, Kuan-Ting Lai, Wen-Feng Liaw* “HER/OER Mechanistic Study of FeCoNi-Based Electrocatalyst for Alkaline Water Splitting” J. Mater. Chem. A 2020, 8, 9939-9950. 83.Shan Lu, Tzung-Wen Chiou,* Wei-Liang Li, Chun-Chieh Wang, Yun-Ming Wang, Way-Zen Lee, Tsai-Te Lu,* and Wen-Feng Liaw* "Dinitrosyl Iron Complex [(PMDTA)Fe(NO)2]: Intermediate for Nitric Oxide Monooxygenation Activity in Non-Heme Iron Complex" Inorg. Chem. 2020, 59, 8308-8319.

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