个人简介

2012 ~  Chairman, Department of Chemistry of NTHU 2009 ~ 2012 Director General, Department of Natural Sciences, National Science Council 2007 ~  Distinguished Professor of NTHU 2002 ~ 2007 Professor of NTHU 1994 ~ 2002 Professor of NCUE 1991 ~ 1994 Associate Professor of NCUE 1998 ~ 1991 Associate Research Fellow,Taiwan Institute of Education

研究领域

Inorganic Chemistry, Biochemistry

Current studies include the synthesis of biomimetic molecular catalysts for water splitting generating hydrogen. Of particular interest is directed at the bioinspired coordination Chemistry, i.e., small molecules (NO2-, NO3-) activation by dinitrosyl iron complexes (DNICs). Interconversion of dinitrosyl iron complexes (DNICs) and S-nitrosothiol (RSNO), and the biomimetically synthesized iron-nitrite and -thionitrite compounds ([(NO)nFe-NO2] and [Fe-(RSNO)]) are of particular interest in the ongoing studies of DNICs chemistry. Another major efforts involve DNICs, the water-soluble dinitrosyl iron complexes (DNICs) and Roussin’s red esters (RREs) may be the actively seeking new NO donor vehicles capable of delivering precise NO does directly to specific tissues for improved therapeutic output and reduced side effect.

近期论文

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1.Wen-Feng Liaw,* Jiun-Hung Lee, Hung-Bin Gau, Chien-Hong Chen, Shiou-Ju Jung, Chen-Hsiung Hung, Wen-Yuan Chen, Ching-Han Hu, Gene-Hsiang Lee “Five-Coordinate and Six-Coordinate FeII(CN)2(CO)x-Thiolate Complexes (x=1, 2): Synthetic Advances for Iron Sites of [NiFe] Hydrogenases” J. Am. Chem. Soc. 2002, 124, 1680. 2.Wen-Feng Liaw,* Chung-Hung Hsieh, Shie-Ming Peng, Gene-Hsiang Lee “ S-S Bond-Activation of Diorganyl Disulfide by Anionic [Mn(CO)5]-: Crystal Structures of [MnII(-SC5H4NO-)2]- and [(CO)3Mn(µ-SR)3Co(µ-SR)3Mn(CO)3]- (R = C6H4NHCOPh)” Inorg. Chim. Acta 2002, 332, 153. 3.Wen-Feng Liaw,* Wen-Ting Tsai, Hung-Bin Gau, Chien-Ming Lee, Shin-Yuan Chou, Wen-Yuan Chen, Gene-Hsiang Lee “Dinuclear Iron(II)-Cyanocarbonyl Complexes Linked by Two/Three Bridging Ethylthiolates: Relevance to the Active-Site of [Fe] Hydrogenases” Inorg. Chem. 2003, 42, 2783-2788. 4.Chung-Hung Hsieh, I-Jui Hsu, Chien-Ming Lee, Shyue-Chu Ke,* Tze-Yuan Wang, Gene-Hsiang Lee, Yu Wang,* Jin-Ming Chen, Jyh-Fu Lee, Wen-Feng Liaw* “Nickel Complexes of o-amidochalcogenophenolate(2-) /o-iminochalcogenobenzosemiquinonate(1-) -radical: Synthesis, Structures, Electron Spin Resonance and X-ray Absorption Spectroscopic Evidence” Inorg. Chem. 2003, 42, 3925-3933. 5.Chien-Ming Lee, Chung-Hung Hsieh, Amitava Dutta, Gene-Hsiang Lee, Wen-Feng Liaw* “Reversible Oxygen Binding to Sulfur in Nitrosylated iron-Thiolate Complexes: Relevance to the Fe-Containing Nitrile Hydratases” J. Am. Chem. Soc. 2003, 125, 11492-11493. 6.Chien-Ming Lee, Chien-Hong Chen, Shyue-Chu Ke,* Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear Nickel(III) and Nickel(II) Thiolate Complexes with Intramolecular S-H Proton Interacting with Both Sulfur and Nickel: Relevance to the [NiFe]/[NiFeSe] Hydrogeanses” J. Am. Chem. Soc. 2004, 126, 8406-8412. 7.Ming-Li Tsai, Chiao-Chun Chen, I-Jui Hsu, Shyue-Chu Ke,* Chung-Hung Hsieh, Kuo-An Chiang, Gene-Hsiang Lee, Yu Wang,* Wen-Feng Liaw* “Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(µ-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe-2S] Ferredoxins” Inorg. Chem. 2004, 43, 5159-5167. 8.Chien-Hong Chen, Yung-Su Chang, Chien-Yeh Yang, Tai-Nan Chen, Chien-Ming Lee, Wen-Feng Liaw* “Preparative and Structural Studies on Iron(II)-Thiolate Cyanocarbonyls: Relevance to the [NiFe]/[Fe]-Hydrogenases” Dalton Trans. 2004, 137-143. 9.Chien-Hong Chen, Li-Chun Wang, Wen-Feng Liaw* “Preparative and Structural Studies on Ruthenium(II)-Thiolate Cyanocarbonyls: Comparison to the [Fe(CO)x(CN)y(SR)z]n- Coordination Modes of Active Sites of Hydrogenases” J. Chin. Chem. Soc. 2004, 51, 1121-1126. 10.Hao-Wen Chen, Chin-Wei Lin, Chiao-Chun Chen, Li-Bo Yang, Ming-Hsi Chiang, Wen-Feng Liaw* “Homodinuclear Iron-Thiolate Nitrosyl Compounds [(ON)Fe(S,S-C6H4)2Fe(NO)2]– and [(ON)Fe(SO2,S-C6H4)(S,S-C6H4)Fe(NO)2]– with {Fe(NO)}7-{Fe(NO)2}9 Electronic Coupling: New Members of A Class of Dinitrosyl Iron Complexes” Inorg. Chem. 2005, 44, 3226-3232. 11.Fu-Te Tsai, Show-Jen Chiou, Ming-Che Tsai, Ming-Li Tsai, Hsiao-Wen Huang, Ming-Hsi Chiang, Wen-Feng Liaw* “Dinitrosyl Iron Complexes (DNICs) [L2Fe(NO)2]– (L = Thiolate): Interconversion among {Fe(NO)2}9 DNICs, {Fe(NO)2}10 DNICs and [2Fe-2S] Clusters, and the Critical Role of the Thiolate Ligands in Regulating NO Release of DNICs” Inorg. Chem. 2005, 44, 5872-5881. 12.Chien-Ming Lee, Chien-Hong Chen, Hao-Wen Chen, Jo-Lu Hsu, Gene-Hsiang Lee, Wen-Feng Liaw* “Nitrosylated Iron-Thiolate-Sulfinate Complexes with {Fe(NO)}6/7 Electronic Cores: Relevance to the Transformation between the Active and Inactive NO-Bound Forms of Fe-Containing Nitrile Hydratases” Inorg. Chem. 2005, 44, 6670-6679. 13.Wen-Feng Liaw, “Nickel: Models of Protein Active Sites” In Encyclopedia of Inorganic Chemistry, Second Edition., Robert A. Scott, Eds.; John Wiley & Sons: 2005. 14.Chien-Hong Chen, Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear [NiII(L)(P-(o-C6H4S)2(o-C6H4SH))]0/1– (L = Thiolate, Selenolate, PPh3, and Cl) Complexes with Intramolecular [Ni－S…H－S]/[Ni…H－S] Interactions Modulated by the Coordinated Ligand L: Relevance to the [NiFe] Hydrogenases” Inorg. Chem. 2006, 45, 2307-2316. 15.Tai-Nan Chen, Feng-Chun Lo, Ming-Li Tsai, Ko-Nien Shih,* Ming-Hsi Chiang, Gene-Hsiang Lee, Wen-Feng Liaw* “Dinitrosyl iron complexes [E5Fe(NO)2]– (E = S, Se): a precursor of Roussin’s black salt [Fe4E3(NO)7]–” Inorg. Chimi. Acta 2006, 359, 2525-2533. 16.Mu-Cheng Hung, Ming-Che Tsai, Gene-Hsiang Lee, Wen-Feng Liaw* “Transformation and Structural Discrimination between the Neutral {Fe(NO)2}10 Dinitrosyl Iron Complexes (DNICs) and the Anionic/Cationic {Fe(NO)2}9 DNICs ” Inorg. Chem. 2006, 45, 6041-6047. 17.Ming-Li Tsai, Wen-Feng Liaw* “Neutral {Fe(NO)2}9 Dinitosyl Iron Complex (DNIC) [(SC6H4-o-NHCOPh)(Im)Fe(NO)2] (Im = imidazole): Interconversion among the Anionic/Neutral {Fe(NO)2}9 DNICs and Roussin’s Red Ester ” Inorg. Chem. 2006, 45, 6583-6585. 18.Tsai-Te Lu, Show-Jen Chiou, Chun-Yu Chen, Wen-Feng Liaw* “Mononitrosyl Tris(Thiolate) Iron Complex [Fe(NO)(SPh)3]– and Dinitrosyl Iron Complex [(EtS)2Fe(NO)2]–: Formation Pathway of Dinitrosyl Iron Complexes (DNICs) from Nitrosyltion of Biomimetic Rubredoxin [Fe(SR)4]2–/1– (R = Ph, Et)” Inorg. Chem. 2006, 45, 8799-8806. 19.Chien-Ming Lee, Ya-Lan Chuang, Chao-Yi Chiang, Gene-Hsiang Lee, Wen-Feng Liaw* “Mononuclear Ni(III) Complexes [NiIII(L)(P(C6H3-3-SiMe3-2-S)3)]0/1– (L = Thiolate, Selenolate, CH2CN, Cl, PPh3): Relevance to the Nickel Site of [NiFe] Hydrogenases“ Inorg. Chem. 2006, 45, 10895-10904. 20.I-Jui Hsu, Chung-Hung Hsieh, Shyue-Chu Ke,* Kuo-An Chiang, Jenn-Min Lee, Jin-Ming Chen, Ling-Yun Jang, Gene-Hsiang Lee, Yu Wang,* Wen-Feng Liaw* “New Members of A Class of Iron-Thiolate-Nitrosyl Compounds: Trinuclear Iron-Thiolate-Nitrosyl Complexes Containing Fe3S6 Core” J. Am. Chem. Soc. 2007, 129, 1151-1159. 21.Ming-Li Tsai, Chung-Hung Hsieh, Wen-Feng Liaw* “Dinitrosyl Iron Complexes (DNICs) Containing S/N/O Ligation: Transformation of Roussin's Red Ester into the Neutral {Fe(NO)2}10 DNICs” Inorg. Chem. 2007, 46, 5110-5117. 22.Chih-Chin Tsou, Tsai-Te Lu, Wen-Feng Liaw* “EPR, UV-vis, IR and X-ray Demonstration of the Anionic Dimeric Dinitrosyl Iron Complex [(NO)2Fe(µ- StBu)2Fe(NO)2]–: Relevance to the Products of Nitrosylation of Cytosolic and Mitochondrial Aconitases, and High-Potential Iron Proteins” J. Am. Chem. Soc. 2007, 129, 12626-12627. 23.Chien-Ming Lee, Tzung-Wen Chiou, Hsin-Hung Chen, Chao-Yi Chiang, Ting-Shen Kuo, Wen-Feng Liaw* “Mononuclear Ni(II)-Thiolate Complexes with Pendant Thiol and Dinuclear Ni(III/II)-Thiolate Complexes with Ni…Ni Interaction Regulated by the Oxidation Levels of Nickels and the Coordinated Ligands” Inorg. Chem. 2007, 46, 8913-8923. 24.Hsiao-Wen Huang, Chih-Chin Tsou, Ting-Shen Kuo, Wen-Feng Liaw* “New Members of a Class of Dinitrosyl Iron Complexes (DNICs): Interconversion and Spectroscopic Discrimination of the Anionic {Fe(NO)2}9 [(NO)2Fe(C3H3N2)2]– and [(NO)2Fe(C3H3N2)(SR)]– (C3H3N2 = Deprotonated Imidazole ; R = tBu, Et, Ph)” Inorg. Chem. 2008, 47, 2196-2204. 25.Tsai-Te Lu, Chih-Chin Tsou, Hsiao-Wen Huang, I-Jui Hsu, Jin-Ming Chen, Ting-Shen Kuo, Yu Wang,* Wen-Feng Liaw* “Anionic Roussin’s Red Esters (RREs) syn-/anti-[Fe2(μ-SEt)2(NO)4]–: the Critical Role of Thiolate Ligands in Regulating the Transformation of RREs into Dinitrosyl Iron Complexes (DNICs) and the Anionic RREs” Inorg. Chem. 2008, 47, 6040-6050. 26.Tzung-Wen Chiou, Wen-Feng Liaw* “Mononuclear Nickel(III) Complexes [NiIII(OR)(P(C6H3-3-SiMe3-2-S)3)]1– (R = Me, Ph) Containing the Terminal Alkoxide Ligand: Relevance to the Nickel Site of Oxidized-Form [NiFe] Hydrogenases” Inorg. Chem. 2008, 47, 7909-7913. 27.Tzung-Wen Chiou, Wen-Feng Liaw* “Nickel-Thiolate and Iron-Thiolate Cyanocarbonyl Complexes: Modeling the Nickel and Iron Sites of [NiFe] Hydrogenase” C. R.. Chimie 2008, 11, 818-833. (Invited Review). 28.Feng-Chun Lo, Chang-Li Chen, Chien-Ming Lee, Ming-Che Tsai, Tsai-Te Lu, Wen-Feng Liaw, Steve S.-F. Yu* “A study of NO trafficking from dinitrosyl-iron complexes to the recombinant E. coli transcriptional factor SoxR” J. Biol. Inorg. Chem. 2008, 13, 961-972. 29.Yi-Ju Chen, Wei-Chi Ku, Li-Ting Feng, Ming-Li Tsai, Chung-Hung Hsieh, Wen-Hwei Hsu, Wen-Feng Liaw, Chen-Hsiung Hung,* Yu-Ju Chen* “Nitric oxide physiological responses and delivery mechanisms probed by water-soluble Roussin’s Red Ester and {Fe(NO)2}10 DNIC” J. Am. Chem. Soc. 2008, 130, 10929-10938. 30.Chia-Huei Lin, Chien-Ge Chen, Ming-Li Tsai, Gene-Hsiang Lee, Wen-Feng Liaw* “Monoanionic {Mn(NO)}5 and Dianionic {Mn(NO)}6 Thiolato Nitrosyl Manganese Complexes: [(NO)Mn(L)2]– and [(NO)Mn(L)2]2– (LH2 = 1,2-Benzenedithiol and Toluene-3,4-Dithiol)” Inorg. Chem. 2008, 47, 11435-11443. 31.Chih-Chin Tsou, Zong-Sian Lin, Tsai-Te Lu, Wen-Feng Liaw* “Transformation of Dinitrosyl Iron Complexes (DNICs) [(NO)2Fe(SR)2]– (R = Et, Ph) into [4Fe-4S] Clusters [Fe4S4(SR)4]2–: Relevance to the Repair of the Nitric Oxide-Modified Ferredoxin [4Fe-4S] Clusters” J. Am. Chem. Soc. 2008, 130, 17154-17160. 32.Fu-Te Tsai, Ting-Shen Kuo, Wen-Feng Liaw* “Reversible Transformation between the Six-Coordinate {Fe(NO)2}9 [(η2-ONO)(1-MeIm)2Fe(NO)2] (g = 2.013) and Four-Coordinate {Fe(NO)2}9 [(ONO)(1-MeIm)Fe(NO)2] (g = 2.03)” J. Am. Chem. Soc. 2009, 131, 3426-3427. 33.Tsai-Te Lu, Hsiao-Wen Huang, Wen-Feng Liaw “ Anionic Mixed Thiolate- Sulfide-Bridged Roussin’s Red Esters [(NO)2Fe(μ-SR)(μ-S)Fe(NO)2]– (R = Et, Me, Ph): A Key Intermediate for Transformation of Dinitrosyl Iron Complexes (DNICs) to [2Fe-2S] Clusters “ Inorg. Chem. 2009, 48, 9027-9035. 34.Ming-Che Tsai, Fu-Te Tsai, Tsai-Te Lu, Ming-Li Tsai, Yin-Ching Wei, I-Jui Hsu, Jyh-Fu Lee, Wen-Feng Liaw “Relative Binding Affinity of Thiolate, Imidazolate, Phenoxide and Nitrite Toward {Fe(NO)2} Motif of Dinitrosyl Iron Complexes (DNICs) : the Characteristic Pre-edge Energy of {Fe(NO)2}9 DNICs” Inorg. Chem. 2009, 48, 9579-9591. 35.Fu-Te Tsai, Pei-Lin Chen, Wen-Feng Liaw* “The Roles of Distinct Electronic Structures of the {Fe(NO)2}9 and {Fe(NO)2}10 Dinitrosyl Iron Complexes (DNICs) in Modulating Nitrite Binding Modes and Nitrite Activation Pathways” J. Am. Chem. Soc. 2010, 132, 5290-5299. 36.Tsai-Te Lu, Chih-Hao Chen, Wen-Feng Liaw* “Formation of the Distinct Redox-Interrelated Forms of Nitric Oxide from Reaction of Dinitrosyl Iron Complexes (DNICs) and Substitution Ligands” Chem. Eur. J. 2010, 16, 8088-8095. 37.Tsai-Te Lu, Li-Bo Yang, Wen-Feng Liaw* “Trigonal Bipyramidal {Fe(NO)}7 Complex [(NO)Fe(SC9H6N)2] Containing an Equatorial Nitrosyl Ligand: the Critical Role of Chelating Ligands in Regulating the Geometry and Transformation of Mononitrosyl Iron Complex (MNIC)” J. Chin. Chem. Soc. 2010, 57, 909-915. 38.Chien-Hong Chen, Wen-Feng Liaw “Iron-cyanocarbonyl Complexes [PPN][Fe(CO)4(CN)] and [PPN][FeBr(CO)3(CN)2]” Inorganic Syntheses, 2010, vol. 35, P. 129-132. 39.Chi-Ming Wu, Yen-Hao Chen, Kasala Dayananda, Tsun-Wei Shiue, Chen-Hsiung Hung, Wen-Feng Liaw, Po-Yu Chen, Yun-Ming Wang* “Sensitivity Evaluation of Rhodamine B Hydrazide Towards Nitric Oxide and its Application for Macrophage Cells Imaging” Anal. Chimi. Acta, 2011, 708, 141-148. 40.Tsai-Te Lu, Szu-Hsueh Lai, I-Jui Hsu,* Ling-Yun Jang, Jyh-Fu Lee, I-Chia Chen,* Wen-Feng Liaw* “Discrimination of the Mononuclear and Dinuclear Dinitrosyl Iron Complexes (DNICs) by S K-Edge X-ray Absorption Spectroscopy: Insight into the Electronic Structure and Reactivity of DNICs” Inorg. Chem. 2011, 50, 5396-5406. 41.Chih-Chin Tsou, Wen-Feng Liaw* “ Transformation of the {Fe(NO)2}9 Dinitrosyl Iron Complexes (DNICs) into S-nitrosothiols (RSNOs) Triggered by Acid-Base Pair“ Chem. Eur. J. 2011, 17, 13358-13366. 42.Zong-Sian Lin, Feng-Chun Lo, Chih-Hsiang Li, Chih-Hao Chen, Wei-Ning Huang, I-Jui Hsu, Jyh-Fu Lee, Jia-Cherng Horng, Wen-Feng Liaw* “Peptide-Bound Dinitrosyl Iron Complexes (DNICs) and Neutral/Reduced-form Roussin’s Red Esters (RREs/rRREs) : Understanding Nitrosylation of [Fe-S] Clusters Leading to the Formation of DNICs and RREs Using a De Novo Design Strategy” Inorg. Chem. 2011, 50, 5396-5406. 43.Tsun-Wei Shiue, Yen-Hao Chen, Chi-Ming Wu, Gyan Singh, Hsing-Yin Chen, Chen-Hsiung Hung, Wen-Feng Liaw, Yun-Ming Wang* “Nitric Oxide Turn-on Fluorescent Probe Based on Deamination of Aromatic Primary Monoamines” Inorg. Chem. 2012, 51, 5400-5408. 44.Shih-Wey Yeh, Chih-Wei Lin, Ya-Wen Li, I-Jui Hsu,* Chien-Hong Chen, Ling-Yun Jang, Jyh-Fu Lee, Wen-Feng Liaw* “Insight Into the Dinuclear {Fe(NO)2}10-{Fe(NO)2}10 and Mononuclear {Fe(NO)2}10 Dinitrosyliron Complexes (DNICs)” Inorg. Chem. 2012, 51, 4076-4087. 45.Feng-Chun Lo, Jyh-Fu Lee, Wen-Feng Liaw, I.-Jui Hsu,* Yi-Fang Tsai, Sunney I. Chan, Steve S.-F. Yu* “The Metal Core Structures in the Recombinant Escherichia coli Transcriptional Factor SoxR” Chem. Eur. J. 2012, 18, 2565-2577. 46.Wei-Chih Shih, Tsai-Te Lu, Li-Bo Yang, Fu-Te Tsai, Ming-Hsi Chiang,* Jyh-Fu Lee,Yun-Wei Chiang, Wen-Feng Liaw* “New members of a class of dinitrosyliron complexes (DNICs): The characteristic EPR signal of the six-coordinate and five-coordinate {Fe(NO)2}9 DNICs” J. Inorg. Biochem. 2012, 113, 83-93. 47.Zong-Sian Lin, Tzung-Wen Chiou, Kuan-Yu Liu, Chang-Chih Hsieh, Jen-Shiang K. Yu,* Wen-Feng Liaw* “A Dinitrosyl Iron Complex (DNIC) within the Homoleptic Fe(NO)4 Anion: NO as Nitroxyl and Nitrosyl Ligands within a Single Structure” Inorg. Chem. 2012, 51, 10092-10094. 48.Fu-Te Tsai,* Yu-Ching Lee, Ming-Hsi Chiang, Wen-Feng Liaw* “Nitrate-to-Nitrite-to-Nitric Oxide Conversion Modulated by Nitrate-Containing {Fe(NO)2}9 Dinitrosyl Iron Complex (DNIC)“Inorg. Chem. 2013, 52, 464-473. 49.Chih-Chin Tsou, Fu-Te Tsai, Huang-Yeh Chen, I-Jui Hsu,*, Wen-Feng Liaw* “Insight into One-Electron Oxidation of the {Fe(NO)2}9 Dinitrosyl Iron Complex (DNIC): Aminyl Radical Stabilized by [Fe(NO)2] Motif” Inorg. Chem. 2013, 52, 1631-1639. 50.Kuan-Ting Lai, Wei-Chieh Ho, Tzung-Wen Chiou, and Wen-Feng Liaw* “Formation of [NiIII(1-S2CH)(P(o-C6H3-3-SiMe3-2-S)3)]– via CS2 Insertion into Nickel(III)-Hydride-Containing [NiIII(H)(P(o-C6H3-3-SiMe3-2-S)3)]–" Inorg. Chem. 2013, 52, 4151-4153. 51.Ku-Kuei Lin, Shou-Cheng Wu, Kuang-Mei Hsu, Chen-Hsiung Hung, Wen-Feng Liaw, Yun-Ming Wang* “A N-(2-Aminophenyl)-5-(dimethylamino)-1- naphthalenesulfonic Amide (Ds-DAB) Based Fluorescent Chemosensor for Peroxynitrite” Org. Lett. 2013, 15, 4242-4245. 52.Chung-Yen Lu and Wen-Feng Liaw* “Formation Pathway of Roussin’s Red Ester (RRE) via Reaction of {Fe(NO)2}10 DNIC and Thiol: The Facile Synthetic Route for Synthesizing Cysteine-Containing Dinitrosyl Iron Complex (DNIC)“Inorg. Chem. 2013, 52, 13918-13926. 53.Chih-Chin Tsou, Wan-Lin Yang, and Wen-Feng Liaw* “Nitrite Activation to Nitric Oxide via Onefold Protonation of Iron(II)-O,O-nitrito Complex: Relevance to the Nitrite Reductase Activity of Deoxyhemoglobin and Deoxyhemerythrin” J. Am. Chem. Soc. 2013, 135, 18758-18761. 54.Shih-Wey Yeh, Chih-Chin Tsou, Wen-Feng Liaw* “Dinitrosyliron Complex [Fe4(3-S)2(2-NO)2(NO)6]2– Containing Bridging Nitroxyls: 15N (NO) NMR Analysis of the Bridging and Terminal NO-Coordinate Ligands” Dalton Trans. 2014, 43, 9022-9025. 55.Chih-Chin Tsou,* Wei-Chun Chiu, Chun-Hung Ke, Jia-Chun Tsai, Yun-Ming Wang, Ming-Hsi Chiang and Wen-Feng Liaw* “Iron(III) Bound by Hydrosulfide Anion ([HS]–) Ligands: NO Promoting Stabilization of [Fe(III)-SH] Motif” J. Am. Chem. Soc. 2014, 136, 9424-9433. 56.Tsai-Te Lu,* Tsu-Chien Weng,* Wen-Feng Liaw* “X-ray Emission Spectroscopy: a Spectroscopic Ruler for the Determination of NO Oxidation State in Fe-NO Complexes” Angew. Chem., Int. Ed. 2014, 53, 11562-11566. 57.Ming-Li Tsai, Chih-Chin Tsou, Wen-Feng Liaw* “Dinitrosyl Iron Complexes (DNICs): from Biomimetic Synthesis and Spectroscopic Characterization toward Unveiling the Biological and Catalytic Roles of DNICs“ Acc. Chem. Res. 2015, 48, 1184-1193. 58.Hao-Ching Chang, Feng-Chun Lo, Wen-Chi Liu, Tsung-Han Lin, Wen-Feng Liaw, Ting-Shen Kuo, Way-Zen Lee* “Ambient Stable Trigonal Bipyramidal Copper(III) Complexes Equipped with an Exchangeable Axial Ligand“ Inorg. Chem. 2015, 54, 5527-5533. 59.Shih-Wey Yeh, Chih-Wei Lin, Bai-Heng Liu, Chih-Chin Tsou, Ming-Li Tsai*, Wen-Feng Liaw* “Chelate-Thiolate-Coordinate Ligands Modulating the Configuration and Electrochemical Property of Dinitrosyliron Complexes (DNICs)” Chem. Eur. J. 2015, 21, 16035-16046. 60.Tzung-Wen Chiou,* Tsai-Te Lu,* Ying-Hao Wu, Yi-Ju Yu, Li-Kang Chu, Wen-Feng Liaw* “Development of Dinitrosyl Iron Complex from a Molecular Catalyst into a Hydrogen Evolution Cathode” Angew. Chem., Int. Ed. 2015, 54, 14824-14829. 61.Chuan-Hung Chuang, Wen-Feng Liaw*, Chen-Hsiung Hung* “Conversion of Nitric Oxide into Nitrous Oxide as Triggered by the Polarization of Coordinated NO by Hydrogen Bonding” Angew. Chem., Int. Ed. 2016, 55, 5190-5194. 62.Feng-Chun Lo, Chang-Chih Hsieh, Manuel Maestre-Reyna,* Chin-Yu Chen,* Tzu-Ping Ko, Yih-Chern Horng, Yei-Chen Lai, Yun-Wei Chiang,* Chih-Mao Chou, Cheng-Hung Chiang, Wei-Ning Huang, Yi-Hung Lin, D. Scott Bohle,* Wen-Feng Liaw* “Crystal Structure of the Repair of Iron Centers Protein YtfE and its Interaction with NO” Chem. Eur. J. 2016, 22, 9768-9776. 63.Shou-Cheng Wu, Chung-Yen Lu, Yi-Lin Chen, Feng-Chun Lo, Ting-Yin Wang, Yu-Jen Chen, Shyng-Shiou Yuan, Wen-Feng Liaw*, Yun-Ming Wang* “Water-Soluble Dinitrosyl Iron Complex (DNIC): a Nitric Oxide Vehicle Triggering Cancer Cell Death via Apoptosis” Inorg. Chem. 2016, 55, 9383-9392. 64.Chun-Chieh Wang, Hao-Ching Chang, Yei-Chen Lai, Huayi Fang, Chieh-Chin Li, Hung-Kai Hsu, Zong-Yan Li, Tien-Sung Lin, Ting-Shen Kuo, Frank Neese, Shengfa Ye,* Yun-Wei Chiang,* Ming-Li Tsai,* Wen-Feng Liaw,* Way-Zen Lee,* “A Structurally Characterized Nonheme Cobalt-Hydroperoxo Complex Derived from its Superoxo Intermediate via Hydrogen Atom Abstraction” J. Am. Chem. Soc. 2016, 138, 14186-14189. 65.Tzung-Wen Chiou,* Yen-Ming Tseng, Tsai-Te Lu, Tsu-Chien Weng, Dimosthenes Sokaras, Wei-Chieh Ho, Ting-Shen Kuo, Ling-Yun Jang, Jyh-Fu Lee, Wen-Feng Liaw* “[NiIII(OMe)]-Mediated Reductive Activation of CO2 Affording a Ni(1-OCO) Complex” Chem. Sci. 2016, 7, 3640-3644. 66.Tao-Hung Yen, Zong-Cheng He, Gene-Hsiang Lee, Mei-Chun Tseng, Yu-Hsuan Shen, Tien-Wen Tseng,* Wen-Feng Liaw,* Ming-His Chiang* “Reduced Thione Ligation is Preferred over Neutral Phosphine Ligation in Diiron Biomimics regarding Electronic Functionality: a Spectroscopic and Computation Investigation” Chem. Comm. 2017, 53, 332-335. 67.Chun-Hung Ke, Chien-Hong Chen,* Ming-Li Tsai,* Hsuan-Chi Wang, Fu-Te Tsai, Yun-Wei Chiang, Wei-Chih Shih, D. Scott Bohle, Wen-Feng Liaw* “{Fe(NO)2}9 Dinitrosyl Iron Complex Acting as a Vehicle for the NO Radical ” J. Am. Chem. Soc. 2017, 139, 67-70. 68.Chin-Yu Chen, Feng-Chun Lo, Wen-Feng Liaw, “Iron sulfur cluster repair protein YtfE (eibc2616)” in Encyclopedia of Inorganic and Bioinorganic Chemistry; Robert A. Scott, Ed.; 2018 John Wily & Sons, West Sussex, PO19 85Q, UK. (DOI: 10.1002/9781119951438.eibc2616). 69.Wei-Liang Li, Tzung-Wen Chiou,* Chien-Hong Chen, Yi-Ju Yu, Li-Kang Chu and Wen-Feng Liaw* “Electrodeposited-Film Electrodes Derived from A Precursor Dinitrosyl Iron Complex for Electrocatalytic Water Splitting” Dalton Trans. 2018, 47, 7128-7134. . 70.Hsiao-Wen Huang, Min-Hsuan Lin, Yen-Hung Lin, Ya-Rong Huang, Chih-Hung Chou, Hsiao-Chin Hong, Mei-Ren Wang, Yu-Ting Tseng, Po-Chun Liao, Min-Chuan Chung, Yu-Jie Ma, Shou-Cheng Wu, Yung-Jen Chuang,* Horng-Dar Wang,* Yun-Ming Wang,* Hsien-Da Huang,* Tsai-Te Lu,* and Wen-Feng Liaw* “Extension of C. elegans Lifespan Using the ●NO-delivery Dinitrosyl Iron Complexes” J. Biol. Inorg. Chem. 2018, 23, 775-784. 71.Fu-Te Tsai,* Hsuan-Chi Wang, Chun-Hung Ke, and Wen-Feng Liaw* “FeCo/FeCoPxOy(OH)z as Bifunctional Electrodeposited-Film Electrodes for Overall Water Splitting” ACS Appl. Energy Mater. 2018, 1, 5298-5307. 72.Tsai-Te Lu,* Yun-Ming Wang,* Chen-Hsiung Hung,* Show-Jen Chiou,* and Wen-Feng Liaw* “Bioinorganic Chemistry of Natural [Fe(NO)2] Motif: Evolution of Functional Model for NO-related Biomedical Application and Revolutionary Development of Translational Model” Inorg. Chem. 2018, 57, 12425-12443. (Viewpoint (invited)). 73.Chun-Hung Ke, Wei-Chih Shih, Fu-Te Tsai,* Ming-Li Tsai,* Wei-Min Ching, Hung-Hsi Hsieh, Wen-Feng Liaw* “Electrocatalytic Water Reduction Beginning with {Fe(NO)2}10-Reduced Dinitrosyl Iron Complex: Identification of N-Doped FeOx(OH)y as Real Heterogeneous Catalyst” Inorg. Chem. 2018, 57, 14715-14726. 74.Sathyadevi Palanisamy, Yu-Liang Wang, Yu-Jen Chen, Chiao-Yun Chen, Fu-Te Tsai, Wen-Feng Liaw, Yun-Ming Wang* “In Vitro and in Vivo Imaging of Nitroxyl with Copper Fluorescent Probe in Living Cells and Zebrafish” Molecules 2018, 23, 2551-2566. 75.Pai-Heng Liu, Fu-Te Tsai,* Bo-Hao Chen, I-Jui Hsu* Hung-Hsi Hsieh, Wen-Feng Liaw* “Insight into Chalcogenolate-Bound {Fe(NO)2}9 Dinitrosyl Iron Complexes (DNICs): Covalent Character versus Ionic Character” Dalton Trans. 2019, 48, 6040-6050. (Invitation) 76.Wun-Yan Wu, Chia-Ning Hsu, Chieh-Hsin Hsieh, Tzung-Wen Chiou,* Ming-Li Tsai,* Ming-Hsi Chiang, Wen-Feng Liaw* “NO-to-[N2O2]2−-to-N2O Conversion Triggered by {Fe(NO)2}10-{Fe(NO)2}9 Dinuclear Dinitrosyl Iron Complex” Inorg. Chem. 2019, 58, 9586-9591. 77.Shan Lu, Jin-Cheng Chiang, Tzung-Wen Chiou,* Wen-Feng Liaw* “Dinitrosyl Iron Complexes: from Molecular Electrocatalysts to Electrodeposited-Film Electrodes for Hydrogen Evolution Reaction” J. Chin. Chem. Soc. 2019, 66, 1185-1193. 78.Chien-Hong Chen,* Tzung-Wen Chiou,* Han-Chun Chang, Wei-Liang Li, Chi-Yen Tung Wen-Feng Liaw “An organic ligand promoting the electrocatalytic activity of cobalt oxide for the hydrogen evolution reaction” Sustainable Energy Fuels 2019, 3, 2205-2210. 79.Yu-Jen Chen, Shou-Cheng Wu, Hsiang-Ching Wang, Tung-Ho Wu, Shyng-Shiou F. Yuan*, Tsai-Te Lu*, Wen-Feng Liaw*, Yun-Ming Wang* “Activation of Angiogenesis and Wound Healing in Diabetic Mice Using NO-Delivery Dinitrosyl Iron Complexes” ACS Mol. Pharmaceutics 2019, 16, 4241-4251. 80.Wun-Yan Wu, Wen-Feng Liaw* “NO Reduction Forming Hyponitrite Triggered by Metal-Containing Complexes” J. Chin. Chem. Soc. 2020, 67, 206-212. (Review) 81.Yu-Ting Tseng, Wei-Min Ching, Wen-Feng Liaw,* Tsai-Te Lu* “Dinitrosyl Iron Complex [K-18-crown-6-ether][(NO)2Fe(MePyrCO2)]: Intermediate for Cooperative Conversion of Carbon Dioxide into Oxalate Promoted by Redox-Inactive Lewis Acid" Angew. Chem., Int. Ed. 2020, 59, 11819-11823. 82.Fu-TeTsai,* Yu-Ting Deng, Chih-Wen Pao, Jeng-Lung Chen, Jyh-Fu Lee, Kuan-Ting Lai, Wen-Feng Liaw* “HER/OER Mechanistic Study of FeCoNi-Based Electrocatalyst for Alkaline Water Splitting” J. Mater. Chem. A 2020, 8, 9939-9950. 83.Shan Lu, Tzung-Wen Chiou,* Wei-Liang Li, Chun-Chieh Wang, Yun-Ming Wang, Way-Zen Lee, Tsai-Te Lu,* and Wen-Feng Liaw* "Dinitrosyl Iron Complex [(PMDTA)Fe(NO)2]: Intermediate for Nitric Oxide Monooxygenation Activity in Non-Heme Iron Complex" Inorg. Chem. 2020, 59, 8308-8319.