巽和行 - 同济大学 - 化学科学与工程学院

个人简介

Scientific Career 1971 B.Sc. Osaka University 1976 Ph.D. Osaka University 1977 Postdoctoral Fellow, Texas A&M University (USA, with Prof. Minoru Tsutsui) 1979 Postdoctoral Fellow, Cornell University (USA, with Prof. Roald Hoffmann) 1982 Assistant Professor, Facul ty of Science, Osaka University 1991 Associate Professor, Faculty of Engineering Science, Osaka University 1994 Professor, Department of Chemistry, Faculty of Science, Nagoya University 1998 Professor, Research Center for Materials Science, and Department of Chemistry, Graduate School of Science, Nagoya University 2013- Honorary Professor, Nagoya University 2013- Designated Professor, Research Center for Materials Science, Nagoya University 2014- Member, The Japan Academy 2019- Disitinguished Chair Professor, Tongji University Scientific Activities and Professional Recognitions Ordinary Member: Executive Board of International Council for Science (2014- )(国际科学理事会十位执行委员之一) Member, The Japan Academy (2014- ) (日本学士院院士) Program Officer: Japanese Society for the Promotion of Science (2013- )(日本学术振兴会程序负责人) Vice-Chair of Section III, Science Council of Japan (2013-2014)(日本科学理事会第三委员会副主席) President, IUPAC (2012-2013)(全球最大最权威的化学学术组织-国际纯粹与应用化学联合会主席) Head Investigator: Grant-in-Aid for Specifically Promoted Research of MEXT (Japan) Bioinorganic Chemistry of Oxidoreductases having UniqueActive Site Clusters (2011-2016) Vice President (President-elected), IUPAC (2010-2011) Council Member: Science Council of Japan (2008-2014) President: Division II (Inorganic Chemistry Division), IUPAC (2008-2009) President: Organometallic Division, The Kinki Chemical Society, Japan (2007-2009) Awards and Honors Corresponding Member: Nordrhein-Westf?lischenAkademie der Wissenschaften und der Künste (2015) Honorary Member, The Chemical Society of Japan (2015) The Luigi Sacconi Memorial Lecture in Chemistry, Firenze, Italy (2013) The Japan Academy Prize (2013) The Prize for Science and Technology: The Commendation for Science and Technologyby the Ministry of Education, Culture, Sports, Science and Technology (2013) CUSO Lectureship, Switzerland (2011) The Eugen and IlseSeibold Prize, DFG, Germany (2011) Honorary Doctorate, University of Münster, Germany (2011) Frontiers in Chemistry Lecturer, Texas A&M University, USA (2010) The Chemical Society of Japan Award (2006) Humboldt Award, Alexander von Humboldt Foundation, Germany (2004)

研究领域

1. Bioinorganic Chemistry of Oxidoreductases such as Nitrogenase, Hydrogenase, Acetyl-CoA Synthase, CO-Dehydrogenase, and Oxygen-Evolving Center of PSII 2. Organometallic Chemistry of Coordinatively Unsaturated Transition Metal Complexes 主要从事合成无机化学、有机金属化学以及生物无机化学领域的研究。在该领域的具体研究内容包括探索各种过渡金属酶的结构和反应活性位点，开发具有催化活性的新型有机金属化合物，以及与材料化学相关的无机超分子的合成。科研团队致力于研究金属元素在各种无机系统中的作用，使之对其有全面的了解，从而能够更好地设计和有效地合成所需要的化合物。在过渡金属与有机官能团的配位作用和相关基础理论，过渡金属硫系簇合物生物酶的含金属活性中心的构建与合成等方面进行了开创性的、深入而全面的工作。

近期论文

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Synthesis of an All-Ferric Cuboidal Cluster [FeIII4S4(SAr)4], G. Moula, T. Matsumoto, M. E. Miehlich, K. Meyer, and K. Tatsumi*, Angew. Chem. Int. Ed., 2018, 57, 11594-11597. Structure and Reactivity of an Asymmetric Synthetic Mimic of Nitrogenase Cofacto, K. Tanifuji, N. Sickerman, C. C. Lee, T. Nagasawa, K. Miyazaki, Y. Ohki*, K. Tatsumi*, Y. Hu*, and M. W. Ribbe*, Angew. Chem. Int. Ed., 2016, 55, 15633-15636. Coupling of an N-Heterocyclic Carbene on Iron with Alkynes Forming 5-Cyclopentadienyl-Diimine Ligand, T. Hatanaka, Y. Ohki*, and K. Tatsumi*, Angew. Chem. Int. Ed., 2014, 53, 2727-2729. Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane, T. Stahl, K. Müther, Y. Ohki*, K. Tatsumi*, and M. Oestreich*, J. Am. Chem. Soc., 2013, 135, 10978-10981. Cooperative Catalytic Activation of Si-H Bonds by a Polar Ru-S Bond: Regioselective Low-Temperature C-H Silylation of Indoles under Neutral Conditions by a Friedel-Crafts Mechanism, H. F. T. Klare, M. Oestreich*, J. Ito, H. Nishiyama, Y. Ohki*, and K. Tatsumi*, J. Am. Chem. Soc., 2011, 133, 3312-3315. Synthetic analogues of [Fe4S4(Cys)3(His)] in hydrogenases and [Fe4S4(Cys)4] in HiPIP derived from all-ferric [Fe4S4{N(SiMe3)2}4, Y. Ohki, K. Tanifuji, N. Yamada, M. Imada, T. Tajima, and K. Tatsumi*, Proc. Natl. Acad. Sci. USA, 2011, 108, 12635-12640. A model for the CO-inhibited form of [NiFe] hydrogenase: synthesis of (CO)3Fe(μ-StBu)3Ni{SC6H3-2;6-(mesityl)2} and reversible CO addition at the Ni site, Y. Ohki, K. Yasumura, M. Ando, S. Shimokata, and K. Tatsumi*, Proc. Natl. Acad. Sci. USA, 2010, 107, 3994-3997. Synthesis, Structures, and Electronic Properties of [8Fe-7S] Cluster Complexes Modeling the Nitrogenase P-Cluster, Y. Ohki*, M. Imada, A. Murata, Y. Sunada, S. Ohta, M. Honda, T. Sasamori, N. Tokitoh, M. Katada, and K. Tatsumi*, J. Am. Chem. Soc., 2009, 131, 13168-13178. C-H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene, Y. Ohki*, T. Hatanaka, and K. Tatsumi*, J. Am. Chem. Soc., 2008, 130, 17174-17186. Reversible Heterolysis of H2 Mediated by an M-S(thiolate) Bond (M = Ir, Rh): A Mechanistic Implication for [NiFe] Hydrogenase, Y. Ohki*, M. Sakamoto, and K. Tatsumi*, J. Am. Chem. Soc., 2008, 130, 11610-11611. A Functional Hydrogenase Model: Reversible Interconversion of H2 and H2O by a Hydroxo/Sulfido-Bridged Dinuclear Ruthenium-Germanium Complex, T. Matsumoto, Y. Nakaya, N. Itakura, and K. Tatsumi*, J. Am. Chem. Soc., 2008, 130, 2458-2459. Heterolytic Dihydrogen Activation by a Sulfido- and Oxo-Bridged Dinuclear Germanium-Ruthenium Complex, T. Matsumoto, Y. Nakaya, and K. Tatsumi*, Angew. Chem. Int. Ed., 2008, 47, 1913-1915. Thiolate-bridged dinuclear iron(tris-carbonyl)–nickel complexes relevant to the active site of [NiFe] hydrogenase, Y. Ohki, K. Yasumura, K. Kuge, S. Tanino, M. Ando, Z. Li, and K. Tatsumi*, Proc. Natl. Acad. Sci. USA, 2008, 105, 7652-7657. Synthesis of New [8Fe-7S] Clusters: A Topological Link Between the Core Structures of P-Cluster, FeMo-co, and FeFe-co of Nitrogenases, Y. Ohki, Y. Ikagawa, and K. Tatsumi*, J. Am. Chem. Soc., 2007, 129, 10457-10465. Dithiolato-Bridged Dinuclear Iron-Nickel Complexes [Fe(CO)2(CN)2 (SCH2CH2CH2S)Ni(S2CNR2)] Modeling the Active Site of [NiFe] Hydrogenase, Z. Li, Y. Ohki, and K. Tatsumi*, J. Am. Chem. Soc., 2005, 127, 8950-8951. A half-sandwich ruthenium(II) complex containing a coordinatively unsaturated 2,6-dimesitylphenyl thiolate ligand, Y. Ohki, H. Sadohara, Y. Takikawa, and K. Tatsumi*, Angew. Chem. Int. Ed., 2004, 43, 2290-2293. Heterolytic Cleavage of Dihydrogen Promoted by Sulfido-Bridged Tungsten-Ruthenium Dinuclear Complexes, Y. Ohki, N. Matsuura, T. Marumoto, H. Kawaguchi, and K. Tatsumi*, J. Am. Chem. Soc., 2003, 125, 7978-7988. Synthesis of the P-Cluster Inorganic Core of Nitrogenases, Y. Ohki, Y. Sunada, M. Honda, M. Katada, and K. Tatsumi*, J. Am. Chem. Soc., 2003, 125, 4052-4053. Unusual Coordination Modes of Arylthiolates in Mo{5-SC6H3-2,6-(SiMe3)2}{7-SC6H3-2,6-(SiMe3)2}, T. Komuro, T. Matsuo, H. Kawaguchi*, and K. Tatsumi*, J. Am. Chem. Soc., 2003, 125, 2070-2071. Spontaneous Formation of a Diamond-crown Structure of Re8 Polyselenide and a Cage Structure of Re3 Polytelluride, G. X. Jin, Y. Arikawa, and K. Tatsumi*, J. Am. Chem. Soc., 2001, 123, 735-736.