Oceanologia ( IF 2.6 ) Pub Date : 2021-02-04 , DOI: 10.1016/j.oceano.2021.01.001 Marcin Stokowski , Przemysław Makuch , Krzysztof Rutkowski , Marcin Wichorowski , Karol Kuliński
Measurement of pCO2 in highly dynamic coastal zones such as the southern Baltic Sea presents many challenges. In this study, we designed a system to measure pCO2 and then validated it in a series of laboratory and seagoing tests. The fast response time of the system was shown to provide a better resolution of CO2 system gradients. In the open waters of the Baltic Sea, the accuracy of the pCO2 measurements (±1.3 µatm) met the requirements of the ICOS (±2.0 µatm). In the coastal zone, there was less consistency between pCO2, DIC and pH measurements, suggesting the need to redefine the quality assurance and control requirements for the measurement of pCO2 in dynamic regions.
中文翻译:
用于在高度可变的环境中测定地表水pCO 2的系统,例如在波罗的海南部
在高度动态的沿海地区(例如波罗的海南部)对pCO 2的测量提出了许多挑战。在这项研究中,我们设计了一种测量pCO 2的系统,然后在一系列的实验室测试和航海测试中对其进行了验证。系统的快速响应时间显示可提供更好的CO 2系统梯度分辨率。在波罗的海的公海中,pCO 2的测量精度(±1.3 µatm)满足了ICOS的要求(±2.0 µatm)。在沿海地区,pCO 2,DIC和pH测量之间的一致性较低,这表明需要重新定义动态区域中pCO 2测量的质量保证和控制要求。