李志铭 - 复旦大学

个人简介

学习工作经历 1992.9−1993.7 大连陆军学院复旦大学92级军训学员 1993.9−1997.7 复旦大学化学系应化专业获得理学学士学位 1997.9−2003.1 复旦大学化学系有机专业获得理学博士学位。 2003.3−至今复旦大学化学系讲师 2009.9−2010.7 日内瓦大学化学生物系访问学者获奖情况 2011年获得了复旦大学复华奖教金三等奖

研究领域

利用DFT方法对环加成反应和金属有机催化反应进行机理研究，以及对手性化合物进行绝对构型的确定

近期论文

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Pd/Xu-Phos-catalyzed asymmetric elimination of fully substituted enol triflates into axially chiral trisubstituted allenes. JIE HAN, SIYUAN LIU, HUANAN WANG, JIE WANG, HUI QIAN, ZHIMING LI, SHENGMING MA, AND JUNLIANG ZHANG. Sci. Adv. 9, eadg1002 Palladium/PC-Phos-Catalyzed Asymmetric Heck/Tsuji–Trost Reactions of Amino-Tethered 1,3-Cyclohexadiene with Aryl and Alkenyl Halides. Juan Feng, Jiayi Shi, Lan Wei, Mingqing Liu, Dr. Zhiming Li, Prof. Dr. Yuanjing Xiao, Prof. Dr. Junliang Zhang. Angew. Chem. Int. Ed. 2022, e202215407 Access to axially chiral styrenes via a photoinduced asymmetric radical reaction involving a sulfur dioxide insertion. Author links open overlay panelChun Zhang, Zhimei Tang, Yanjie Qiu, Jie Tang, Shengqing Ye, Zhiming Li, Jie Wu. doi.org/10.1016/j.checat.2021.12.008 Palladium/GF-Phos-catalyzed asymmetric carbenylative amination to access chiral pyrrolidines and piperidines. Yue Sun,Chun Ma,Zhiming Li and Junliang Zhang. Chem. Sci., 2022, 13, 11150. doi.org/10.1039/D2SC03999K Modular and stereoselective synthesis of tetrasubstituted vinyl sulfides leading to a library of AIEgens. Xun-Shen Liu, Zhiqiong Tang, Zhiming Li, Mingjia Li, Lin Xu & Lu Liu. doi.org/10.1038/s41467-021-27167-x Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation. Pei-Chao Zhang, Yin-Lin Li, Jiafeng He, Hai-Hong Wu, Zhiming Li & Junliang Zhang. 10.1038/s41467-021-24678-5 Efficient access to aliphatic esters by photocatalyzed alkoxycarbonylation of alkenes with alkyloxalyl chlorides. Jian-Qiang Chen, Xiaodong Tu, Qi Tang, Ke Li, Liang Xu, Siyu Wang, Mingjuan Ji, Zhiming Li & Jie Wu. doi.org/10.1038/s41467-021-25628-x Han ZM, Zhang L, Li ZM*, Fan RH*, Direct Assembly of 3,4-Difunctionalized Benzofurans and Polycyclic Benzofurans by Phenol Dearomatization and Palladium-Catalyzed Domino Reaction Angew. Chem. Int. Edit., 2014, DOI: 10.1002/anie.201404155. (SCI, IF: 13.734) Liu YH, Zhang L, Xu XN, Li ZM*, Zhang DW, Zhang X*, Li ZT*, Intramolecular C–H•••F hydrogen bonding-induced 1,2,3-triazole-based foldamers Org. Chem. Front.2014, DOI: 10.1039/c4qo00047a. (SCI, IF: ) Wang WW*, Li ZM*, Su L, Wang QR, Wu YL Insight into the role of fluorinated dendrimers in ruthenium(II) catalyst for asymmetric transfer hydrogenation: the stabilizing effects from experimental and DFT approach J. Mol. Catal. A-Chem.2014, 387, 92-102. (SCI, IF: 3.319) Zhang L, Li ZM*, Fan RH*, Org. Lett., 2013, 15(10), 2482-2485. Metal-Controlled Cycloaddition of 2-Alkynyl-1,4-benzoquinones and Styrenyl Systems: Lewis Acid versus π Acid Wang JM,Li ZM*, Wang QR, Tao FG, J. Mol. Model.,2013, 19, 83-95. A DFT Study on the mechanisms for the cycloaddition reactions between 1-Aza-2-azoniaallene cations and acetylenes Zhang L, Li ZM*, Fan RH*, Org. Lett., 2012, 14(23), 6076-6079. 1,2 and 1,4 Additions of 2-Alkynyl Cyclohexadienimines with Aromatic Amines to Access 4-Amino N-Arylindoles and Azepinoindoles Wang JM, Li ZM*, Wang QR, Tao FG, Int. J. Quan. Chem.,2012, 112, 809-822. A DFT study on the mechanisms for the cycloaddition reactions between 1-aza-2-azoniallene cations and carbodiimides Li ZM, Wang QR*, Int. J. Quan. Chem., 2011, 111, 3805-3815. A density functional theory study on the Diels-Alder Reactions with vinylallenes as dines Li ZM, Wang QR*, Int. J. Quan. Chem.,2008, 108, 1067-1075. A theoretical investigation on the cycloaddition reaction between azocarbenium ions and nitriles Li ZM, WANG B, TAO FG, LIN GQ, Chinese Chem. Lett.,2004, 15(2), 138-140. Studies on the synthesis of Penazetidine A, an Alkaloid Inhibitor of Protein Kinase C