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个人简介

个人履历 2011.11 — 复旦大学化学系,教授、博士生导师 2009.04 — 2011.11 复旦大学化学系,副研究员、博士生导师 2005.11 — 2009.04 德国波恩大学化学系,洪堡学者、助理研究员 2003.11 — 2005.11 加拿大蒙特利尔大学化学系,博士后 Advisor: James D. Wuest 教授 1998.09 — 2003.10 中国科学院上海有机化学研究所,博士导师:戴立信 院士 1994.09 — 1998.08 东华理工大学,本科,分析化学 获奖情况 Awards 2013年获得“Thieme Chemistry Journal Award” 2012年获“上海市浦江人才(D类)”称号 2011年获“上海曙光学者”称号 2010年获“上海市青年科技启明星(A类)”称号 2005年获德国洪堡基金会“洪堡学者”称号

研究领域

近年来研究兴趣主要集中在在以优势金属有机化合物的功能为导向,通过超分子组装策略构筑金属有机组装体,详细研究和考察了组装体功能及应用。一方面通过自组装策略制备一系列刺激响应型金属有机分子凝胶,根据其理化性质应用于超分子催化、识别及细胞成像等方面;另一方面基于金属氮杂环卡宾化合物活性高和稳定性好的特点,以刚性咪唑盐作为前体通过配位组装、超交联策略制备了一系列稳定、高效、可重复使用的固体分子催化材料,在实现优势催化就高效负载的同时,实现了二氧化碳、生物质等资源小分子高值化及能源转化方面的应用。在Adv. Mater.; Angew. Chem.; ACS Catal.; Green. Chem.; Chem. Commun.; Org. Lett.等国际知名学术期刊作为通讯作者发表SCI论文七十余篇,他引千余次,获得了国内外同行的高度评价和肯定。

近期论文

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Imidazolium carboxylates boost Ru-catalyzed hydroaminomethylation of olefins with CO2 Qian Chun,Qingshu Zheng, Jiale Ji, Guanfeng Liang, Bo Tu* and Tao Tu* Chem. Cat. 2023, 3, 100787 Selective hydrogenation of phenols to cyclohexanols catalyzed by robust solid NHC-Rh coordination assemblies in water Jie Chen, Jiale Ji, Tao Tu* Green Chem. 2023, 25, 7541-7546 Selective control of secondary alcohols upgrading using Ir-catalyzed cross-coupling strategy Siqi Yang, Zeye Lu, Jiale Ji, Qingshu Zheng, Tao Tu* Sci. China Chem. 2023, XX, XX-XX Immobilization of Proteases on Nanoflower-Like Metal Organic Framework He Li, Yunjie Tu, Tao Tu* and Qi Zhang* Chin. J. Chem. 2023, 41, 1504-1508. Selective Modular Synthesis of ortho-Substituted Phenols via Pd-Catalyzed Dehydrogenation–Coupling–Aromatization of Alcohols Guangkuo Zeng, Lingyun Shen, Qingshu Zheng, Tao Tu* ACS Catal. 2023, 13 , 6222-6229 Modular Access to Quaternary α-Hydroxyl Acetates by Catalytic Cross-Coupling of Alcohols Guangkuo Zeng,Jiajie Wu, Lingyun Shen, Qingshu Zheng, Zhening Chen, Xin Xu*, and Tao Tu* ACS Catal. 2023, 13 , 2061-2068 Magnetic core-shell composites accessed by coordination assembly boost catalytic CO2 valorization Jinpeng Li, Jie Chen, Qingshu Zheng, Bo Tu*, and Tao Tu* Chin. J. Catal. 2023, XX ,XX Direct knitting boosts the stability and catalytic activity of NHC-Au complexes towards valorization of SO2 and CO2 Daheng Wen, Qingshu Zheng, Siqi Yang, Haibo Zhu, and Tao Tu* J. Catal. 2023, 418 , 64-69 Fluorescent properties and probe features of newly synthesized acridine-terpyridyl bidentate ligand and its metalated complexes Jianhong Liu, Yueyang Ma, Tao Tu and Dongjin Qian* J. Lumin. 2022, 244, 118765. Coordination assembly enables highly selective catalytic hydroaminomethylation of olefins Chunqia,Qingshu Zheng,Jie Chen,Bo Tu* and Tao Tu*.Green Chem. 2023, XX, XXXX Directly Knitted Ruthenium Pincer Complexes as Recyclable Single-Site Catalysts for Hydrogenation of CO2 to Methanol with Enhanced Activity Daheng Wen, Jiangbo Chen, Qingshu Zheng Siqi Yang and Tao Tu*.CCS Chemistry 2022, XX, XXXX Instantaneous High-Resolution Visual Imaging of Latent Fingerprints in Water Using Color-Tunable AIE Pincer Complexes Lixin Duan, Qingshu Zheng and Tao Tu*. Adv. Mater. 2022, 34, 2202540 Hyper-Crosslinked Porous Chiral Phosphoric Acids: Robust Solid Organocatalysts for Asymmetric Dearomatization Reactions Xian-Yun Huang, Qingshu Zheng, Lei-Ming Zou, Qing Gu*, Tao Tu* and Shu-Li You*. ACS Catal. 2022, 12, 4545-4553 Acceptorless dehydrogenation of primary alcohols to carboxylic acids by self-supported NHC-Ru single-site catalysts Shenxiang Yin, Qingshu Zheng, Jie Chen and Tao Tu* J. Catal. 2022, 408 , 165-172 Selective Transformation of Vicinal Glycols to α-Hydroxy Acetates in Water via a Dehydrogenation and Oxidization Relay Process by a Self-Supported Single-Site Iridium Catalyst Lingyun Shen, ZheNing Chen, Qingshu Zheng, Jiajie Wu, Xin Xu* and Tao Tu* ACS Catal. 2021, 11 ,12833-12839 NHC-Iridium-Catalyzed Deoxygenative Coupling of Primary Alcohols Producing Alkanes Directly: Synergistic Hydrogenation with Sodium Formate Generated in Situ Zeye Lu, Qingshu Zheng, Siqi Yang, Chun Qian, Yajing Shen, and Tao Tu* ACS Catal. 2021, 11 ,10796-10801 Efficient hydrogenation of levulinic acid catalysed by spherical NHC-Ir assemblies with atmospheric pressure of hydrogen Lingyun Shen, Qingshu Zheng, Yaoqi Liu, Jiajie Wu, Zeye Lu, and Tao Tu*Green Chem. 2021, 23, 5037–5042 Highly efficient NHC-iridium-catalyzed β-methylation of alcohols with methanol at low catalyst loadings Zeye Lu, Qingshu Zheng, Guangkuo Zeng, Yunyan Kuang, James H. Clark and Tao Tu* Sci. China Chem. 2021, 64, 1361-1366 Rare-Earth-Catalyzed Transsulfinamidation of Sulfinamides with Amines Daheng Wen, Qingshu Zheng, Chaoyu Wang and Tao Tu* Org. Lett. 2021, 23, 3718–3723 Pd/NHC-catalyzed arylsulfonylation of boronic acids: A general and direct protocol to access diarylsulfones Haibo Zhu, Liu Yang, Jia Meng, Zongbo Xie, Zhang-Gao Le, Tao Tu* Tetrahedron Letters. 2021, 63, 152708 Colorimetric recognition of melamine in milk using novel pincer zinc complex stabilized gold nanoparticles Xiaoling Bao, Jianhong Liu, Qingshu Zheng, Lixin Duan, Yuzhu Zhanga , Junlong Qian, Tao Tu* Chin. Chem. Lett. 2021, 32, 3023-3026 Nickel-Catalyzed Amination of Aryl Chlorides with Amides Jinpeng Li, Changyu Huang, Daheng Wen, Qingshu Zheng, Bo Tu* and Tao Tu* Org. Lett. 2021, 23, 687–691 Highly Efficient and Selective N‐Formylation of Amines with CO2 and H2 Catalyzed by Porous Organometallic Polymers Yajing Shen, Qingshu Zheng, Zhe-Ning Chen, Daheng Wen, James H. Clark, Xin Xu* and Tao Tu* Angew. Chem. Int. Ed. 2021, 60, 4125–4132 Metallo-aerogels derived from chitosan with encapsulated metal nanoparticles as robust, efficient and selective nanocatalysts towards reduction of nitroarenes Yajing Shen, Qingshu Zheng, Jianhong Liu and Tao Tu*Nano Res. 2021, 14, 59–65 Hydrogen-bond-assisted transition-metal-free catalytic transformation of amides to esters Changyu Huang, Jinpeng Li, Jiaquan Wang, Qingshu Zheng, Zhenhua Li and Tao Tu* Sci. China Chem. 2021, 64, 66–71 Reversible stimuli-responsive chromism of a cyclometallated platinum(ii) complex Qingshu Zheng, Stefan Borsley, Tao Tu and Scott L. Cockroft* Chem. Commun. 2020, 56, 14705-14708 Selective mono-N-methylation of nitroarenes with methanol catalyzed by atomically dispersed NHC-Ir solid assemblies Jiaquan Wang, Jiajie Wu, Zhe-Ning Chen, Daheng Wen, Jiangbo Chen, Qingshu Zheng, Xin Xu* and Tao Tu* J. Catal. 2020, 389, 337–344 Selective Catalytic Dehydrogenative Oxidation of Bio‐Polyols to Lactic Acid Jiajie Wu, Lingyun Shen, Sai Duan, Zhe-Ning Chen, Qingshu Zheng, Yaoqi Liu, Zheming Sun, James H. Clark, Xin Xu* and Tao Tu* Angew. Chem. Int. Ed. 2020, 59, 13871–13878 Iridium‐Catalyzed Selective Cross‐Coupling of Ethylene Glycol and Methanol to Lactic Acid Jiajie Wu, Lingyun Shen, Zhe-Ning Chen, Qingshu Zheng, Xin Xu* and Tao Tu* Angew. Chem. Int. Ed. 2020, 59, 10421–10425 Hierarchical Porous Organometallic Polymers Fabricated by Direct Knitting: Recyclable Single‐Site Catalysts with Enhanced Activity Yajing Shen, Qingshu Zheng, Haibo Zhu and Tao Tu* Adv. Mater. 2020, 32, 1905950 Robust NHC-palladacycles-catalyzed Suzuki−Miyaura cross-coupling of amides via C-N activation QinyueDeng, Qingshu Zheng, Bin Zuo and Tao Tu*Green Synthesis and catalysis. 2020, 1, 75-78 Transition-Metal-Free Approaches to Arylsulfones using Benzylic Ammonium Salts through C−N Bond Cleavage Yishuai Liu, Dr. Haibo Zhu, Liu Yang, Prof. Zongbo Xie, Prof. Guofang Jiang, Prof. Zhang-Gao Le, Prof. Tao Tu* Asian J. Org. Chem. 2020, 9, 247 –250 Visual recognition of melamine in milk via selective metallo-hydrogel formation Xiaoling Bao, Jianhong Liu, Qingshu Zheng, Wei Pei, Yimei Yang, Yanyun Dai and Tao Tu* Chin. Chem. Lett. 2019, 30, 2266–2270 Selective Synthesis of ortho-Substituted Diarylsulfones by Using NHC-Au Catalysts under Mild ConditionsHaibo Zhu, Yajing Shen, Daheng Wen, Zhang-Gao Le, Haibo Zhu and Tao Tu*Org. Lett. 2019, 21, 974−979 Interfacial Self-Assembly of Closely Packed Nanoparticle Arrays of Silica@Multiporphyrin Hybrids as Light-Sensitizers for Dye Degradation and Viologen Photochromism Dr. Jing Wang, Prof. Tao Tu, Prof. Meng Chen, Prof. Dong-Jin Qian Chem. Asian J. 2019, 14,3035 –3045 Recent Advances in Supramolecular Gels and Catalysis Weiwei Fang, Yang Zhang, Jiajie Wu, Cong Liu, Haibo Zhu* and Tao Tu* Chem. Asian J. 2018, 13, 712–729 Chem. Asian J. 2018, 13, 712 – 729 Chem. Asian J. 2018, 13, 3018 – 3021 N-Formylation of Amines with CO2 and H2 by Using NHC–Iridium Coordination Assemblies as Solid Molecular Catalysts Yang Zhang, Jiaquan Wang, Haibo Zhu and Tao Tu* Chem. Asian J. 2018, 13, 3018–3021 A novel micro-flow system under microwave irradiation for continuous synthesis of 1,4-dihydropyridines in the absence of solvents via Hantzsch reaction WeiHe, ZhengFang, KaiZhang, TaoTu, NiuniuLv, ChuanhongQiu, KaiGuo Chemical Engineering Journal , 2018 168 , 161-331 Ruthenium-Pincer-Catalyzed Hydrogenation of Lactams to Amino Alcohols Jiangbo Chen, Jiaquan Wang and Tao Tu* Chem. Asian J. 2018, 13, 2559–2565 A Concerted Catalytic System for Sonogashira Coupling Reactions: Combination of N-Heterocyclic Carbene Palladium and Copper Complexes Ancheng Shen, Zhen Wu, Yue Fang, Prof. Jinming Yang, Dr. Haibo Zhu, Prof. Tao Tu Asian J. Org. Chem. 2018, 7, 1113–1117 An efficient and green pathway for continuous Friedel-Crafts acylation over α-Fe2O3 and CaCO3 nanoparticles prepared in the microreactors ZhengFang, WeiHe, TaoTu, NiuniuLv, ChuanhongQiu, XinLi, NingZhu, LiWan, KaiGuo Chemical Engineering Journal, 2018,331, 443–449 Visual Discrimination of Phosphate Anion via Selective Metallo-Hydrogel Formation Wu Yan, Zhang Yang, Wu Jiajie, Zhou Jun, Liu Hong and Tu Tao Chin. J. Org. Chem., 2018, 3, 705-709. Acenaphthoimidazolylidene Gold Complex-Catalyzed Alkylsulfonylation of Boronic Acids by Potassium Metabisulfite and Alkyl Halides: A Direct and Robust Protocol To Access Sulfones Haibo Zhu, Yajing Shen, Qinyue Deng, Jiangbo Chen and Tao Tu* ACS Catal. 2017, 7, 4655−4659

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