Darensbourg, Donald J - Texas A&M University

个人简介

Education B.S. in Chemistry: California State University at Los Angeles (June, 1964). Ph.D. in Inorganic Chemistry: University of Illinois (June, 1968). Thesis title: Infrared Intensities in Substituted Metal Carbonyls under the direction of Professor Theodore L. Brown. Professional Background Distinguished Professor of Chemistry, Texas A&M University(2010 - present) Professor of Chemistry, Texas A&M University(July, 1982 - 2010) Assistant-Full Professor of Chemistry, Tulane University,(January 1973 to July, 1982) Assistant Professor of Chemistry, State University of New York at Buffalo(September, 1969 to January, 1973) Research Chemist (Infrared Spectra of Absorbed Molecules with Dr. R. P. Eischens) Texaco Research Center, Beacon, New York(September, 1968 to June, 1969) Teaching/Research Assistant in the Department of Chemistry at the University of Illinois (June, 1964 to June 1968), NIH Fellowship recipient (1967)

研究领域

Organometallic/Inorganic Chemistry of transition/main group metals, homogeneous and heterogeneous catalysis(including polymerization and biphasic processes), and applications of infrared spectroscopy.

近期论文

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Studies of the Interactions of the Tungsten Pentacarbonyl Fluoride Anion with Carbon Dioxide. Samouei, H.; Reibenspies, J.H.; Darensbourg, D.J., Polyhedron. 2022, DOI: 10.1016/j.poly.2022.115852 Amphiphilic Polycarbonate Micellar Rhenium Catalysts for Efficient Photocatalytic CO2 Reduction in Aqueous Media. Ren, F.-Y.; Chen, K.; Qiu, L-Q.; Chen, J.-M.; Darensbourg, D.J.; He, L.-N., Angew.Chem.Int.Ed. 2022, 61, DOI: 10.1002/ange.202200751 Polymerization of Epoxides. Darensbourg, D.J; Bhat, G.A.; Comprehensive Organometallic Chemistry IV, May. 2022 DOI:10.1016/B978-0-12-820206-7.00123-2 Explorations into the Sustainable Synthesis of Cyclic and Polymeric Carbonates and Thiocarbonates from Eugenol-Derived Monomers Reactions with CO2, COS, or CS2. Sengoden, M.; Bhat, G.A.; Darensbourg, D.J. Green Chem. 2022, 24, 2535-2541. DOI:10.1039/D2GC00327A Kinetic and Computational Analysis of CO Substitution in a Dinuclear Osmium Carbonyl Complex: Intersection between Dissociative and Dissociative-Interchange Mechanisms. Martinez, Z.M.; Folsom, T.M.; Tong, Y.; Archambeau, A.K.; Darensbourg, D.J; Hall, M.B; Powell, C.B; Powell, G.L.; Inorg.Chem. 2022, 61,1, 246-253 DOI: 10.1021/acs.inorgchem.1c02797 Sustainable Synthesis of CO2-derived polycarbonates from D-xylose. Tran, D.K.; Rashad, A.Z.; Darensbourg, D.J.; Wooley, K.L.; Polym.Chem.. 2021, 12, 5271-5278. DOI: 10.1039/D1PY00784J TEMPO Containing Radical Polymonothiocarbonate Polymers with Regio- and Stereo-Regularities: Synthesis, Characterization, and Electrical Conductivity Studies. Bhat, G.A.; Rashad, A.Z.; Ji, X.; Quiroz, M.; Fang, L.; Darensbourg, D.J.; Angew.Chem.Int.Ed. 2021, 60, 20734-20738. DOI: 10.1002/anie.202108041 Carbon disulfide-derived polymers. Bhat, G.A. ; Darensbourg, D.J. Contribution in Sulfur-containing Polymers: From Synthesis to Functional Materials. Eds. Xinghong Zhang and Patrick Theato. Wiley-VCH, 2021, 39 - 79. DOI: 10.1002/9783527823819.ch2 Randomly Distributed Sulfur Atoms in the Main Chains of CO2-based Polycarbonates: Enhanced Optical Properties. Yue, T.-J.; Bai-Hao Ren, B.-H.; Zhang, W.-J.; Lu, X.-B.; Ren, W.-M.; Darensbourg, D. J. Angew. Chem. Int. Ed. 2021, 60, 4315 - 4321. DOI: 10.1002/anie.202012565 Copolymerization of Propylene Oxide and 13CO2 to Afford Completely Alternating Regioregular 13C-Labelled Poly(propylene carbonate). Bhat, G. A.; Darensbourg, M. Y.; Darensbourg, D. J. Polymer Journal 2021, 53, 215-218. DOI: 10.1038/s41428-020-0391-0 Catalysis of Carbon Dioxide and Oxetanes to Produce Aliphatic Polycarbonates. Bhat, G. A.; Luo, M.; Darensbourg, D. J.Green Chem. 2020, 22, 7707 - 7724. DOI: 10.1039/D0GC03219K Synthesis of Terpyridine-Containing Polycarbonates with Post Polymerization Providing Water-Soluble and Micellar Polymers and Their Metal Complexes. Bhat, G. A.; Rashad, A. Z.; Darensbourg, D. J. Polym. Chem. 2020, 11, 4699 - 4705. DOI: 10.1039/d0py00850h CO2-Based Block Copolymers: Present and Future Designs. Zhang, Y.-Y.; Wu, G.-P.; Darensbourg, D. J. Trends in Chemistry 2020, 2, 750-763. DOI: 10.1016/j.trechm.2020.05.002/ Facile Synthesis of Well‐Defined Branched Sulfur‐Containing Copolymers via a “One‐Pot” Copolymerization of Carbonyl Sulfide and Epoxide. Yue, T.-J.; Bhat, G. A.; Zhang, W.-J.; Ren, W.-M.; Lu, X.-B.; Darensbourg, D. J. Angew. Chem. Int. Ed. 2020, 59, 13633-13637. DOI: 10.1002/anie.202005806 Zwitterionic Alternating Polymerization to Generate Semicrystalline and Recyclable Cyclic Polythiourethanes. Tan, D.; Hu, X.; Cao, Z.; Luo, M.; Darensbourg, D. J. ACS Macro Lett. 2020, 9, 866-871. DOI: 10.1021/acsmacrolett.0c00302 Synthetic Metallodithiolato Ligands as Pendant Bases in [FeIFeI], [FeI[Fe(NO)]II], and [(μ-H)FeIIFeII] Complexes. Kariyawasam Pathirana, K. D.; Ghosh, P.; Hsieh, C.-H.; Elrod, L. C.; Bhuvanesh, N.; Darensbourg, D. J.; Darensbourg, M. Y. Inorg. Chem. 2020, 59, 3753-3763. DOI: 10.1021/acs.inorgchem.9b03409 Non-Isocyanate and Catalyst-Free Synthesis of a Recyclable Polythiourethane with Cyclic Structure; Wu, S.; Luo, M.; Darensbourg, D.J.; Zeng, D.; Yao, Y.; Zuo, X.-B.; Hu, X.; Tan, D.; ACS Sustainable Chem. Eng. 2020, 8, 5693-5703 . DOI: 10.1021/acssuschemeng.0c00435 Metal-Templated, Tight Loop Conformation of a Cys-X-Cys Biomimetic Assembles a Diamanganese Complex; Le, T.; Nguyen, H.; Perez, L.M.; Darensbourg D.J.; Darensbourg, M.Y.; Angew. Chem., Int. Ed., 2020, 59, 3645-3649. DOI: 10.1002/anie.201913259 Placing Single Metal Complexes into the Backbone of CO2-Based Polycarbonate Chains, Construction of Nanostructures for Prospective Micellar Catalysis; Bhat, G.A.; Rashad, A.Z.; Folsom, T.M.; Darensbourg, D.J., Organometallics, 2020, 39, 1612-1618. DOI: 10.1021/acs.organomet.9b00704 Catalyst-Free Construction of Versatile and Functional CS2-Based Polythioureas: Characteristics from Self-Healing to Heavy Metal Absorption; Wu, S.; Luo, M.; Darensbourg, D.J.; Zuo, X.-B., Macromolecules, 2019, 52, 8596-8603. DOI: 10.1021/acs.macromol.9b01811 Approach for Introducing a Single Metal Complex into a Polymer Chain. Metallo-Chain Transfer Agents in CO2 or COS/Epoxide Copolymerization Processes; Folsom, T.M.; Bhat, G.A.; Rashad, A.Z.; Darensbourg, D.J., Macromolecules, 2019, 52, 5217-5222. DOI: 10.1021/acs.macromol.9b00906 Thermal Dehydrogenation of Dimethylamine Borane Catalyzed by a Bifunctional Rhenium Complex; Yempally, V.; Moncho, S.; Wang, Y.; Kyran, S.J.; Fan, W.Y.; Brothers, E.N.; Darensbourg, D.J.; Bengali, A.A., Organometallics, 2019, 38, 2602-2609. DOI: 10.1021/acs.organomet.9b00115 Chain transfer agents utilized in epoxide and CO2 copolymerization processes; Darensbourg, D.J., Green Chemistry, 2019, 21, 2214-2223. DOI: 10.1039/C9GC00620F