周鸣飞 - 复旦大学

个人简介

周鸣飞，男，1968年出生，籍贯浙江省磐安县。现为复旦大学化学系教授、系主任。复旦大学获得本科（1990年）和博士学位（1995年），毕业后留校任教，1997年-1999年美国弗吉尼亚大学化学系从事博士后研究。2000年晋升为教授，2001年获国家杰出青年科学基金资助，2002年受聘长江特聘教授。主要从事分子光谱和化学键研究。在Science、Nature、Angew. Chem. Int. Ed.和J. Am. Chem. Soc.等学术刊物发表论文320多篇。以第一完成人获上海市自然科学一等奖（2007年）和国家自然科学二等奖(2018年)，2019年入选美国物理学会会士，2020年入选中国化学会会士。教育经历 1990.91995.10复旦大学 → 物理化学 → 博士学位 → 研究生毕业 1986.91990.7复旦大学物理二系 → 应用化学 → 学士学位 → 大学毕业工作经历 2000.12至今复旦大学→化学系→教授 1999.92000.11复旦大学→化学系→讲师 1997.91999.8美国弗吉尼亚大学→化学系→博士后 1995.101997.8复旦大学→物理二系→讲师

研究领域

课题组专注于反应中间体、自由基、原子或分子团簇的光谱研究。主要使用基质隔离红外吸收光谱、质量选择的红外光解离光谱、微波光谱以及顺磁共振谱等多种谱学实验方法，并结合理论计算，来获得分子几何和电子结构、成键及反应特性等信息

近期论文

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Dingding Lv, Weixing Li*, Luca Evangelisti*, Imanol Usabiaga, Camilla Calabrese, Assimo Maris, Sonia Melandri*, Guanjun Wang, Mingfei Zhou*, Rotational Spectroscopy Probes Lone Pair···pi-Hole Interactions in Hexafluorobenzene-Tertiary Alkylamines Complexes. J. Phys. Chem. Lett. 2023, 14, 5335-5342. Xiaoyang Jin, Yangyu Zhou, Guanjun Wang, Mingfei Zhou*, Mg-Fe Bonding in the MgFe(CO)n+ (n = 4-9) Cation Complexes: An Infrared Photodissociation Spectroscopic and Theoretical Study. J. Phys. Chem. A 2023, 127, 4483-4491. Yangyu Zhou#, Wei Fang#, Lina Wang, Xiaoqing Zeng*, Dong H. Zhang*, Mingfei Zhou*, Quantum Tunneling in Peroxide O-O Bond Breaking Reaction. J. Am. Chem. Soc. 2023, 145, 8817−8821. Xiaoyang Jin, Guanjun Wang, Mingfei Zhou*, Mg(I)–Fe(–II) and Mg(0)–Mg(I) Covalent Bonding in the MgnFe(CO)4- (n = 1, 2) Anion Complexes: An Infrared Photodissociation Spectroscopic and Theoretical Study. Phys. Chem. Chem. Phys. 2023, 25, 7697–7703. Lina Wang*, Xin Jiang, Guanjun Wang, Xiaoqing Zeng*, Mingfei Zhou*, Phosphorus-Boron Multiple Bonding in the p Radical HBP. Chem. Eur. J. 2023, 29, e2022037. Weixing Li,* Cristóbal Pérez, Amanda L. Steber, Melanie Schnell,* Dingding Lv, Guanjun Wang, Xiaoqing Zeng, Mingfei Zhou*, Evolution of Solute−Water Interactions in the Benzaldehyde-(H2O)1−6 Clusters by Rotational Spectroscopy. J. Am. Chem. Soc. 2023, 145, 4119-4128. Xiaolong Li, Bo Lu, Junjie Jiang, Lina Wang, Tarek Trabelsi, Joseph S. Francisco*, Wei Fang, Mingfei Zhou, Xiaoqing Zeng*, Water Complex of Imidogen. J. Am. Chem. Soc. 2023, 145, 1982-1987. Hongmin Li, Yangyu Zhou, Guanjun Wang, Xiaoqing Zeng, Mingfei Zhou*, Formation and Infrared Spectroscopic Characterization of Carbon Suboxide Complexes TM-h1-C3O2 and the Inserted Ketenylidene Complexes OCTMCCO (TM=Cu, Ag, Au) in Solid Neon. J. Comput. Chem. 2023, 44,129-137. Yang Yang, Yangyu Zhou, Xiaoyang Jin, Guanjun Wang, Mingfei Zhou*, Infrared Spectroscopy of Be(CO2)4+ in the Gas Phase: Electron Transfer and C-C Coupling of CO2. Phys. Chem. Chem. Phys. 2022, 24, 13149-13155. 2022, 24, 13149–13155Be(CO2)4 Yangyu Zhou#, Sudip Pan#, Xuelin Dong, Lina Wang, Mingfei Zhou*, Gernot Frenking*, Generation and Characterization of the Charge-Transferred Diradical Complex CaCO2 with an Open-Shell Singlet Ground State. J. Am. Chem. Soc. 2022, 144, 8355-8361. Lina Wang, Xiaolong Li, Xin Jiang, Xiaoqing Zeng*, Mingfei Zhou*, Spectroscopic Identification of the Heterocumulenic Isocyanatoborane Radical HBNCO. J. Phys. Chem. Lett. 2022, 13, 2619-2624. Hechen Wu, Xiao-Nan Wu*, Xuegang Liu, Chonglei Ji, Wei Li, Ling Jiang, Hua Xie*, Mingfei Zhou*, Iridium Dimer Anion-Mediated Cº C Triple Bond Cleavage and Successive Dehydrogenation of Acetylene in the Gas Phase. J. Phys. Chem. A 2022, 126, 1711-1717. Ya Zhao, Tiantong Wang, Chong Wang, Zhaoyan Zhang, Huijun Zheng, Shuai Jiang, Wenhui Yan, Hua Xie, Gang Li, Jiayue Yang, Guorong Wu, Weiqing Zhang, Dongxu Dai, Xiucheng Zheng*, Hongjun Fan*, Ling Jiang*, Xueming Yang, Mingfei Zhou*, Ligand-Induced Tuning of the Electronic Structure of Rhombus Tetraboron Cluster. ChemPhysChem. 2022, 23, e202200060. Hongmin Li, Yangyu Zhou, Guanjun Wang, Xiaoqing Zeng, Mingfei Zhou*, Formation and Infrared Spectroscopic Characterization of Carbon Suboxide Complexes TM-h1-C3O2 and the Inserted Ketenylidene Complexes OCTMCCO (TM=Cu, Ag, Au) in Solid Neon. J. Comput. Chem. 2022, DOI: 10.1002/jcc.26817. Shujun Lei, Yangyu Zhou, Xiaoyang Jin, Guanjun Wang*, Mingfei Zhou*, Mononuclear Carbonyl Anion Complexes of Groups IV and V Metals. Chin. J. Chem. Phys. 2022, 35, 867-874. Xuelin Dong, Lina Wang, Guanjun Wang, Mingfei Zhou*, Carbon Dioxide Activation by Alkaline-Earth Metals: Formation and Spectroscopic Characterization of OCMCO3 and MC2O4 (M = Ca, Sr, Ba) in Solid Neon. J. Phys. Chem. A 2022, 126, 4598−4607. Yangyu Zhou, Hao Liu, Xiaoyang Jin, Xiaopeng Xing,* Xuefeng Wang, Guanjun Wang, Mingfei Zhou*, Significant π Bonding in Coinage Metal Complexes OCTMCCO− from Infrared Photodissociation Spectroscopy and Theoretical Calculations. J. Chem. Phys. 2022, 157, 014302. Lina Wang#, Sudip Pan#, Guanjun Wang, Xiaoqing Zeng, Mingfei Zhou*, Gernot Frenking*, Triple Bonding Between Beryllium and Nitrogen in HNBeCO.Chem. Commun. 2022, 58, 8532-8535. Quadruple C-H Bond Activations of Methane by Dinuclear Rhodium Carbide Cation [Rh2C3]+. Hechen Wu, Xiao-Nan Wu, Xiaoyang Jin, Yangyu Zhou, Wei Li, Chonglei Ji, Mingfei Zhou*, JACS Au 2021, 10, 1631-1638. Covalent Bonding Between Be+ and CO2 in BeOCO+ with a Surprisingly High Antisymmetric OCO Stretching Vibration. Xuelin Dong#, Chengxiang Ding#, Qingnan Zhang, Mohua Chen, Lili Zhao, Mingfei Zhou*, Gernot Frenking*, J. Am. Chem. Soc. 2021, 143, 14300-14305. Transition-Metal Chemistry of the Heavier Alkaline Earth Atoms Ca, Sr, and Ba. Mingfei Zhou*, Gernot Frenking*, Acc. Chem. Res. 2021, 54, 3071-3082. Reactive resonance and the role of electron angular momentum. Mingfei Zhou*, Kopin Liu*, Innovation 2021, 2, 100136. Infrared Spectroscopy and Bonding of the B(NN)3+ and B2(NN)3,4+ Cation Complexes. Jiaye Jin, Guanjun Wang, Mingfei Zhou*, J. Phys. Chem. A 2021,125,6246-6253. Metal-CO Bonding in Mononuclear Transition Metal Carbonyl Complexes. Gernot Frenking*, Israel Fernandez*, Nicole Holzmann*, Sudip Pan, Ingo Krossing, Mingfei Zhou, JACS Au 2021, 1, 623-645. Highly Coordinated Heteronuclear Calcium-Iron Carbonyl Cation Complexes [CaFe(CO)n]+ (n=5-12) with d-d Bonding. Xiaoyang Jin, Yuna Bai, Yangyu Zhou, Guanjun Wang, Lili Zhao, Mingfei Zhou*, Gernot Frenking*, Angew. Chem. Int. Ed. 2021, 60, 13865-13870. Formation and Characterization of BeFe(CO)4- Anion with Beryllium-Iron Bonding, Guanjun Wang#, Jing Zhao#, Han-Shi Hu*, Jun Li, Mingfei Zhou*, Angew. Chem. Int. Ed. 2021, 60, 9334-9338 Observation of Carbon-Carbon Coupling Reaction in Neutral Transition-Metal Carbonyls, Chong Wang#, Qinming Li#, Xiangtao Kong#, Huijun Zheng, Tiantong Wang, Ya Zhao, Gang Li, Hua Xie, Jiayue Yang, Guorong Wu, Weiqing Zhang, Dongxu Dai, Mingfei Zhou*, Xueming Yang, Ling Jiang*, J. Phys. Chem. Lett. 2021, 12, 1012-1017. Generation and Characterization of the C3O2- Anion with an Unexpected Unsymmetrical Structure, Lina Wang#, Sudip Pan#, Bo Lu, Xuelin Dong, Hongmin Li, Guohai Deng, Xiaoqing Zeng, Mingfei Zhou*, Gernot Frenking*, Angew. Chem. Int. Ed. 2021, 60, 4518-4523. CO-Induced Dinitrogen Fixation and Cleavage Mediated by Boron, Guohai Deng#, Sudip Pan#, Xuelin Dong, Guanjun Wang, Lili Zhao, Mingfei Zhou*, Gernot Frenking*, Chem. Eur. J. 2021, 27, 2131-2137. A Homoleptic Beryllium Carbonyl Complex with an End-On and Side-On Bridging Carbonyl Ligand, Guanjun Wang, Yangyu Zhou, Xiaoyang Jin, Jiaye Jin, Mingfei Zhou*, Angew. Chem. Int. Ed. 2021, 60, 1651-1655. Generation and Identification of the Linear OCBNO and OBNCO Molecules with 24 Valence Electrons, Guohai Deng#, Sudip Pan#, Jiaye Jin, Guanjun Wang, Lili Zhao, Mingfei Zhou*, Gernot Frenking*, Chem. Eur. J. 2021, 27, 412-418. Beryllium Atom Mediated Dinitrogen Activation via Coupling with Carbon Monoxide. Deng, G. H.; Pan, S.; Wang, G. J.; Zhao, L. L; Zhou, M. F.*; Frenking, G.* Angew. Chem. Int. Ed. 2020, 59, 18201-18207. Revisiting the Intriguing Electronic Features of the BeOBeC Carbyne and Some Isomers: A Quantum-Chemical Assessment. Li, J. L; Geng, C. Y.; Weiske, T.; Zhou, M. F.*; Li, J.*; Schwarz, H.*; Angew. Chem. Int. Ed. 2020, 59, 17261-17265. Boron-Mediated Carbon-Carbon Bond Cleavage and Rearrangement of Benzene Forming the Borepinyl Radical and Borole Derivatives. Jian, J. W.; Wu, X.; Chen, M. H.; Zhou, M. F.* J. Am. Chem. Soc. 2020, 142, 10079-10086. Side-On Bonded Beryllium Dinitrogen Complexes. Deng, G. H.; Pan, S.; Wang, G. J.; Zhao, L. L; Zhou, M. F.*; Frenking, G.* Angew. Chem. Int. Ed. 2020, 59, 10603-10609. Reactions of Transition-Metal Carbyne Cations with Ethylene in the Gas Phase. Wu, X. N.*; Liu, Z. Z.; Wu, H. C.; Zhang, D.; Li, W.; Huang, Z. J.; Wang, G. J.; Xu, F. X.; Ding, C. F.; Zhou, M. F.* J. Phys. Chem. A. 2020, 124, 2628-2633. Filling a Gap: The Coordinatively Saturated Group 4 Carbonyl Complexes TM(CO)8 (TM = Zr, Hf) and Ti(CO)7. Deng, G. H.; Pan, S.; Lei, S. J.; Jin, J. J.; Wang, G. J.; Zhao, L. L; Zhou, M. F.*; Frenking, G.* Chem. Eur. J. 2020, 26, 10487-10500. Formation and Characterization of a BeOBeC Multiple Radical Featuring a Quartet Carbyne Moiety. Li, W. L.; Zhang, Q. N.; Chen, M. H.; Hu, H. S.; Li, J.*; Zhou, M. F.* Angew. Chem. Int. Ed. 2020, 59, 6923-6928. Multiple Bonding Between Group-3 Metals and Fe(CO)3-. Wang, J. Q.; Chi, C. X.; Hu, H. S.; Li, X.; Luo, M. B.; Li, J.*; Zhou, M. F.* Angew. Chem. Int. Ed. 2020, 59, 2344-2348.