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个人简介

在 Angew. Chem. Int. Ed.、Chem. Commun.、Chem. Eur. J.、Org. Lett.、Adv. Synth. Catal.、J. Org. Chem.、Synlett、Tetrahedron Letter等国际著名期刊上发表SCI检索论文40余篇; 主持各级别项目13项,其中国家自然科学基金 4 项目,省级项目2项目;申请发明专利1项。2008年,参与的基于多样性和性能导向的有机功能分子的设计、合成及应用研究荣获吉林省科技进步一等奖。2010年入选东北师范大学“东师学者”青年学术骨干培养计划。 1992/09 — 1996/07, 齐齐哈尔师范学院,化学系,学士 。 1999/09 — 2005/07, 东北师范大学,化学学院,博士。 2009/09 — 2012/07, 长春应用化学研究所,高分子化学与物理国家重点实验室,博士后。 2012/10 — 2013/10, 美国加州大学圣塔芭芭拉分校,化学与生物化学学院,访问学者。 2002/07 — 2016/06, 东北师范大学,化学学院,副教授,博士生导师。 2016/06 — 现在 东北师范大学,化学学院,教授,博士生导师。

研究领域

主要从事重氮化合物以及炔类化合物在有机合成中的应用研究。

近期论文

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Lei Li, Jia-Jia Chen, Yi-Jin Li, Xiu-Bin Bu, Qun Liu,* Yu-Long Zhao*, Activation of a-Diazocarbonyls by Organic Catalysts: Diazo Group Acting as a Strong N-Terminal Electrophile, Angew. Chem. Int. Ed. 2015, 54, 12107 –12111. Yi-Jin Li, Xue Li, Shao-Xiao Zhang, Yu-Long Zhao*, Qun Liu, Copper(II)-catalyzed oxidative [3+2] cycloaddition reactions of secondary amines with a-diazo compounds: a facile and efficient synthesis of 1,2,3-triazoles, Chem. Commun. 2015, 51, 11564–11567. Lei Li, Yu-Long Zhao,* Qian Wang, Tao Lin, Qun Liu*, Base-Promoted Oxidative C−H Functionalization of α‑Amino Carbonyl Compounds under Mild Metal-Free Conditions: Using Molecular Oxygen as the Oxidant, Org. Lett. 2015, 17, 370−373. Lei Li, Jia-Jia Chen, Xing-Lan Kan, Lu Zhang, Yu-Long Zhao,* Qun Liu, One-Pot Synthesis of Phenanthridinones by Using a Base-Catalyzed/Promoted Bicyclization of α,β-Unsaturated Carbonyl Compounds with Dimethyl Glutaconate, Eur. J. Org. Chem. 2015, 4892–4899. Guo-Jie Wu, Fu-She Han*, Yu-Long Zhao*, Palladacycles derived from arylphosphinamides for mild Suzuki–Miyaura cross-couplings, RSC Adv. 2015, 5, 69776–69781. Lei Li, Yu-Long Zhao,* He Wang, Yi-Jin Li, Xianxiu Xu, Qun Liu,* Base-catalyzed bicyclization of dialkyl glutaconates with cinnamoylacetamides: a synthetic strategy for isoquinolinedione derivatives, Chem. Commun. 2014, 50, 12490-12492. Jia Meng,Yi-Jin Li, Yu-Long Zhao,* Xiu-Bin Bua and Qun Liu*, A base-catalyzed cycloisomerization of 5-cyano-pentyne derivatives: an efficient synthesis of 3-cyano-4,5-dihydro-1H-pyrroles, Chem. Commun. 2014, 50, 12490-12492. He Wang, Yu-Long Zhao,* Lei Li, Qun Liu*, Metal-Free 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)- Mediated Cross-Dehydrogenative-Coupling (CDC) of Benzylic C(sp3)-H Bonds and Vinylic C(sp2)-H Bonds: Efficient One-Pot Synthesis of 1H-Indenes, Adv. Synth. Catal. 2014, 356, 3157– 3163. Guo-Jie Wu, Jing Guan, Fu-She Han,* Yu-Long Zhao*, Palladium-Catalyzed Silver-Mediated a-Arylation of Acetic Acid: A New Approach for the a-Arylation of Carbonyl Compounds, ChemCatChem. 2014, 6, 1589–1593. He Wang, Yu-Long Zhao,* Lei Li, Qun Liu,* Bicyclization of Diazomethanes: A Synthetic Strategy for Fused Pyrazoles, Adv. Synth. Catal. 2013, 355, 1540–1544. Kegong Ji, Yu-Long Zhao, Liming Zhang,* Optimizing P,N-Bidentate Ligands for Oxidative Gold Catalysis: Efficient Intermolecular Trapping of a-Oxo Gold Carbenes by Carboxylic Acids, Angew. Chem. Int. Ed. 2013, 52, 6508–6512. Chuan-Qing Ren, Chong-Hui Di, Yu-Long Zhao,* Jing-Ping Zhang,* [3+2 Cycloadditions of a-Acyl Ketene Dithioacetals with Propargylamines: Pyrrole Synthesis in Water, Tetrahedron Lett. 54, 1478–1481, 2013. Yu-Long Zhao,* Chong-Hui Di, Si-Di Liu, Jia Meng, Qun Liu, [3 + 2] Cycloaddition of Propargylamines and a-Acyl Ketene Dithioacetals: A Synthetic Strategy for Highly Substituted Pyrroles, Adv. Synth. Catal. 2012, 354, 3545–3550. Aboubacar Diallo, Yu-Long Zhao,* He Wang, Sha-Sha Li, Chuan-Qing Ren, Qun Liu, Base-Catalyzed Efficient Tandem [3 + 3] and [3 + 2 + 1] Annulation-Aerobic Oxidative Benzannulations, Org. Lett. 2012, 14, 5776–5779. Yu-Long Zhao, Guo-Jie Wu, Fu-She Han, Ni-Catalyzed Construction of C–P Bonds from Electron-Deficient PhenoHan, Yu-Long Zhao,* Jia Meng, Chuan-Qing Ren, Qun Liu, Synthesis of Acridines and Persubstituted Phenols from Cyclobutenones and Active Methylene Ketones, J. Org. Chem. 2012, 77, 5173−5178. u-Long Zhao, Guo-Jie Wu, You Li, Lian-Xun Gao, Fu-She Han, [NiCl2(dppp)]-Catalyzed Cross-Coupling of Aryl Halides with Dialkyl Phosphite, Diphenylphosphine Oxide, and Diphenylphosphine, Chem. Eur. J. 2012, 18, 9622 – 9627. He Wang, Yu-Long Zhao,* Chuan-Qing Ren, Aboubacar Diallo, Qun Liu, Tandem [5+1] Annulation–isocyanide Cyclization: Efficient Synthesis of Hydroindolones, Chem. Commun. 2011, 47, 12316–12318. Yu-Long Zhao, You Li, Yi-Guo Zhou, Feng-Yi Sun, Lian-Xun Gao, Fu-She Han, Highly Practical and Reliable Nickel Catalyst for Suzuki–Miyaura Coupling of Aryl Halides, Adv. Synth. Catal. 2011, 353, 1543–1550. Yu-Long Zhao,* Shao-Chun Yang, Chong-Hui Di, Xiao-Dan Han, Qun Liu, Highly Efficient Synthesis of 3-Amino-/Alkylthio-cyclobut-2-en-1-ones Based on the Cyclization of Acyl Ketene Dithioacetals, Chem. Commun. 2010, 46, 7614–7616.

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