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Visible-light-promoted defluorinated alkylation of trifluoromethyl alkenes initiated by radical [1,2]-brook rearrangement: facile synthesis of gem-difluoro homoallylic alcohol derivatives Tao Qin, Chunlu Xu, Ge Zhang*, Qian Zhang Organic Chemistry Frontiers, 2023 DOI:10.1039/D2QO01964G
Cobalt-catalyzed HAT reaction for asymmetric hydrofunctionalization of alkenes and nucleophiles Ge Zhang and Qian Zhang* Chem Catalysis,2023, 3, 100526 DOI: 10.1016/j.checat.2023.100526
Copper-Catalyzed Defluorinative Boroarylation of Alkenes with Polyfluoroarenes Yue Zhao, Bin Fu, Simin Wang, Yanfei Li, Xiuping Yuan, Jianjun Yin, Tao Xiong,* and Qian Zhang Org. Lett. DOI: 10.1021/acs.orglett.3c00671
Copper-catalyzed conjugate addition of allene-derived nucleophiles to alkenyl-substituted carboxamides Bin Fua, Yue Zhao, Xiuping Yuan, Yanfei Li, Jianjun Yin, Simin Wang, Tao Xiong*, Qian Zhang Chinese Chemical Letters DOI: 10.1016/j.cclet.2023.108372
Radical Addition-Triggered Remote Migratory Isomerization of Unactivated Alkenes to Difluoromethylene-Containing Alkenes Enabled by Bimetallic Catalysis Qiao Zhang, Simin Wang, Qian Zhang, Tao Xiong,* and Qian Zhang* ACS Catal. 2022, 12, 527−535 DOI:10.1021/acscatal.1c05073
Copper-catalyzed hydroamination of polyfluoroalkyl substituted alkenes via asymmetric radical cross-coupling access to achiral tertiary alkylamines Yu-Jie Liang, Meng-Jiao Sun, Ge Zhang, Jian-Jun Yin, Wei Guan, Tao Xiong, Qian Zhang Chem Catalysis 2, 2379–2390,DOI：10.1016/j.checat.2022.08.004
Cobalt-Catalyzed Asymmetric Alkylation of (Hetero)Arenes with Styrenes Tao Qin, Guowei Lv, Huanran Miao, Meihui Guan, Chunlu Xu, Ge Zhang,* Tao Xiong, and Qian Zhang* Angew. Chem. Int. Ed. 2022, e202201967 DOI:doi.org/10.1002/anie.202201967
Cobalt-Catalyzed Enantioselective Hydroamination of Arylalkenes with Secondary Amines Huanran Miao, Meihui, Guan, Tao Xiong, Ge Zhang,* and Qian Zhang Angew. Chem. Int. Ed. 2022, e202213913 DOI:doi.org/10.1002/anie.202213913
Visible light-mediated NHCs and photoredox co-catalyzed radical 1,2- dicarbonylation of alkenes for 1,4-diketones Lihong Wang, Jiaqiong Sun, Jiuli Xia, Mingrui Li, Lianjin Zhang, Ruiyang Ma, Guangfan Zheng* and Qian Zhang* Science China Chemistry 2022 Vol.59
NHC and visible light-mediated photoredox co- catalyzed 1,4-sulfonylacylation of 1,3-enynes for tetrasubstituted allenyl ketones† Lihong Wang, Ruiyang Ma, Jiaqiong Sun, Guangfan Zheng *and Qian Zhang Chem. Sci., 2022, 13, 3169 DOI:10.1039/d1sc06100c
Synthesis of Axially Chiral Aldehydes by N-Heterocyclic-CarbeneCatalyzed Desymmetrization Followed by Kinetic Yingtao Wu, Mingrui Li, Jiaqiong Sun, Guangfan Zheng,* and Qian Zhang* Angew. Chem. Int. Ed. 2022, 61, e202117340 DOI:10.1002/anie.202117340
A copper-catalyzed four-component reaction of arylcyclopropanes, nitriles, carboxylic acids and Nfluorobenzenesulfonimide: facile synthesis of imide derivatives Shengbiao Yang, Chunyang Liu, Xiaoyan Shangguan, Yan Li *and Qian Zhang Chem. Sci., 2022, 13, 13117 DOI: 10.1039/d2sc04913a
Copper-catalyzed radical cascade reaction of simple cyclobutanes: synthesis of highly functionalized cyclobutene derivatives Chunyang Liu,a Xiaoyan Shangguan,a Yan Li * and Qian Zhang Chem. Sci., 2022, 13, 7886 DOI: 10.1039/d2sc00765g
Copper-Catalyzed Asymmetric Conjugate Addition of AlkeneDerived Nucleophiles to Alkenyl-Substituted Heteroare Ying Wang, JianJun Yin, Yanfei Li, Xiuping Yuan, Tao Xiong,* and Qian Zhang ACS Catal. 2022, 12, 9611−9620 DOI: 10.1021/acscatal.2c01629
Remote Site-Selective Asymmetric Protoboration of Unactivated Alkenes Enabled by Bimetallic Relay Catalysis Qiao Zhang, Simin Wang, Jianjun Yin, Tao Xiong,* and Qian Zhang Angew. Chem. Int. Ed. 2022, 61, e202202713 DOI: 10.1002/anie.202202713
Copper-Catalyzed Asymmetric Hydroallylation of Vinylsilanes Simin Wang, Qiao Zhang, Junbo Niu, Xiaobing Guo,Tao Xiong,* and Qian Zhang Eur. J. Org. Chem. 2022 DOI: 10.1002/ejoc.202101575
Cobalt-Catalyzed Radical Hydroamination of Alkenes with NFluorobenzenesulfonimides Tao Qin, Guowei Lv, Qi Meng, Ge Zhang, Tao Xiong, and Qian Zhang Angew. Chem. Int. Ed. 2021, 60, 25949– 25957 DOI: doi.org/10.1002/anie.202110178
Copper-catalyzed [3 + 1] cyclization of cyclopropenes/diazo compounds and bromodifluoroacetamides: facile synthesis of alpha,alpha-difluoro-beta-lactam derivatives Mengru Zhang, Hexin Li, Jinbo Zhao, Yan Li and Qian Zhang Chem. Sci., 2021, 12, 11805 DOI: 10.1039/d1sc02930d
Recent advances in the direct construction of enantioenriched stereocenters through addition of radicals to internal alkenes Tao Xiong and Qian Zhang Chem. Soc. Rev., 2021, 50, 8857 DOI: 10.1039/d1cs00208b
Transition-Metal-Catalyzed Alkylation of Polyfluoroarenes through C-F Bond Cleavage Qian Zhang, Tao Xiong and Qian Zhang SYNLETT, 32, 1379-1384 DOI: 10.1055/a-1479-8264
Organoborohydride-catalyzed Chichibabin-type C4-position alkylation of pyridines with alkenes assisted by organoboranes Ying Wang, Runhan Li, Wei Guan, Yanfei Li, Xiaohong Li, Jianjun Yin, Ge Zhang, Qian Zhang, Tao Xiong and Qian Zhang DOI：10.1039/D0SC04808A
Copper‐Catalyzed Defluorinative Hydroarylation of Alkenes with Polyfluoroarenes Xiaohong Li, Bin Fu, Qiao Zhang, Xiuping Yuan, Qian Zhang, Tao Xiong, Qian Zhang DOI：10.1002/anie.202010492
Copper-Catalyzed Asymmetric Hydroamination: an Unified Strategy for the Synthesis of Chiral β-Amino Acid and Its Derivatives Ge Zhang, Yujie Liang, Tao Qin, Tao Xiong, Shuyu Liu, Wei Guan, and Qian Zhang CCS Chem. 2020, 2, 1737-1745 DOI：10.31635/ccschem.020.202000434
Synthesis of Tetrahydropyridazines via Pd‐Catalyzed Carboamination of Alkenyl Hydrazones Yajing Guo Jinbo Zhao Qian Zhang Adv. Synth. Catal. 2020, 362, 1208– 1212 DOI：10.1002/adsc.201901378
Asymmetric Synthesis of Silicon-Stereogenic Silanes by Copper-Catalyzed Desymmetrizing Protoboration of Vinylsilanes Ge Zhang , Yanfei Li , Ying Wang, Qian Zhang, Tao Xiong,* and Qian Zhang Angew. Chem. Int. Ed. 2020, 59, 11927-11931 DOI：10.1002/anie.202005341
Copper-catalyzed non-directed hydrosilylation of cyclopropenes: highly diastereoselective synthesis of fully substituted cyclopropylsilanes Hui Wang, Ge Zhang, Qian Zhang, Ying Wang, Yanfei Li, Tao Xiong* and Qian Zhang Chem. Commun., 2020,56, 1819-1822 DOI:10.1039/C9CC09584E
Highly Enantioselective Construction of Dihydrooxazines via PdCatalyzed Asymmetric Carboetherification Na Li, Baozhen Sun, Shuang Liu, Jinbo Zhao,* and Qian Zhang Org. Lett. 2020, 22, 1, 190–193 DOI: 10.1021/acs.orglett.9b04123
Radical cascade reactions of unsaturated C–C bonds involving migration Ge Zhang, Yang Liu, Jinbo Zhao, Yan Li* & Qian Zhang* SCIENCE CHINA Chemistry 2019, 62, 1476; DOI: 10.1007/s11426-019-9629-x
Copper-Catalyzed Cyclization of 1-Aryl-1-cycloalcohols and 1,3-Dicarbonyl Compounds: Synthesis of Cycloalkane-Fused Dihydrofuran Derivatives Shengbiao Yang, Yan Li, * Qian Zhang* Chin. J. Org. Chem. 2019, 39, 2226-2234 ; DOI: 10.6023/cjoc201903040
Highly convergent modular access to poly-carbon substituted cyclopropanes via Cu(I)-catalyzed three-component cyclopropene carboallylation† Hexin Li, Mengru Zhang, Haroon Mehfooz, Dongxia Zhu, Jinbo Zhao * and Qian Zhang* Org. Chem. Front. , 2019,6, 3387-3391 DOI: 10.1039/c9qo00902g
Copper-Catalyzed Cope-Type Hydroamination of Nd Olefins toward Cyclic Nitrones: Scope, Mechanism, and Enantioselective Process Development Mengru Zhang, Shuang Liu, Hexin Li, Yajing Guo, Na Li, Meihui Guan, Haroon Mehfooz, Jinbo Zhao,* and Qian Zhang* Chem. Eur. J. 2019, 25, 12620 – 12627； DOI: 10.1002/chem.201902683
Copper-catalyzed 1,3-aminoazidation of arylcyclopropanes: a facile access to 1,3-diamine derivatives Lihong Wang, Xiaomin Wang, Ge Zhang, Shengbiao Yang, Yan Li* and Qian Zhang Org. Chem. Front., 2019,6, 2934-2938 DOI:10.1039/C9QO00638A
Multicomponent Cyclopropane Synthesis Enabled by Cu-Catalyzed Cyclopropene Carbometalation with Organoboron Reagent: Enantioselective Modular Access to Polysubstituted 2-Arylcyclopropylamines Zhanyu Li, Mengru Zhang, Yu Zhang, Shuang Liu, Jinbo Zhao,*, and Qian Zhang Org. Lett.2019,21,14,5432−5437 DOI:10.1021/acs.orglett.9b01650
Copper-Catalyzed Asymmetric Reductive Allylation of Ketones with 1,3-Dienes Bin Fu, Xiuping Yuan, Yanfei Li, Ying Wang, Qian Zhang, Tao Xiong,*, and Qian Zhang Org. Lett.2019,21,10,3576-3580 DOI:10.1021/acs.orglett.9b00979
Pd-Catalyzed carboannulation of γ,δ-alkenyl oximes: efficient access to 5-membered cyclic nitrones and dihydroazines† Baozhen Sun, Shuang Liu, Mengru Zhang, Jinbo Zhao * and Qian Zhang* Org. Chem. Front., 2019,6 , 388-392 DOI:10.1039/C8QO01076E
Copper-Catalyzed Asymmetric Aminocyanation of Arylclopropanes for Synthesis of γ-Amino Nitriles Shengbiao Yang, Lihong Wang, Hongwei Zhang, Chunyang Liu, Linli Zhang, Xiaomin Wang, Ge Zhang, Yan Li, and Qian Zhang ACS Catal.2019,9,1716-721 DOI: 10.1021/acscatal.8b03768
Enantioselective and site-specific copper-catalyzed reductive allyl-allyl cross-coupling of allenes Guo-Xing Xu, Bin Fu, Haiyan Zhao, Yanfei Li, Ge Zhang, Ying Wang, Tao Xiong and Qian Zhang Chem. Sci., 2019,10, 1802-1806 ，DOI: 10.1039/C8SC04505D
Copper-Catalyzed Diastereo- and Enantioselective Borylative Cyclization: Synthesis of Enantioenriched 2,3-Disubstituted Indolines Ge Zhang, Aijie Cang, Ying Wang, Yanfei Li, Guoxing Xu, Qian Zhang, Tao Xiong* , and Qian Zhang Org. Lett.20182071798-1801 DOI: 10.1021/acs.orglett.8b00246
Ligand-Controlled Regiodivergent and Enantioselective Copper-Catalyzed Hydroallylation of Alkynes Guoxing Xu, Haiyan Zhao, Bin Fu, Aijie Cang, Ge Zhang, Qian Zhang, Tao Xiong,* and Qian Zhang Angew. Chem. 2017, 129, 13310 –13314 DOI: 10.1002/ange.201707070
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