王芒 - 东北师范大学

个人简介

学习简历 1987年09月－1991年07月：东北师范大学化学系，攻读学士学位 1994年09月－1997年07月：东北师范大学化学学院，攻读硕士学位 2000年09月－2003年12月：中国科学院长春应用化学研究所，攻读博士学位 2005年07月－2006年07月：瑞士洛桑联邦高工，博士后访问研究工作简历 1991年07月－1994年09月：吉林工业大学应用化学系，助教 1997年07月－2002年11月：东北师范大学化学学院，讲师 2002年12月－2011年11月：东北师范大学化学学院，副教授 2011年12月- 现在：东北师范大学化学学院，教授

研究领域

主要研究领域为有机硫化学和有机氟化学。发展了系列具潜在生物活性的杂环、碳环化合物合成的新途径，尤其是围绕着极化烯烃的alpha－官能化反应所开展的系统性研究工作，为该研究领域开辟了新方向。

近期论文

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Ying Dong, Bangyu Liu, Peng Chen, Qun Liu， Mang Wang*‘Palladium-Catalyzed C-S Activation/Aryne Insertion/Coupling Sequence: Synthesis of Functionalized 2-Quinolinones’ Angew. Chem. Int. Ed. 2014, 53, DOI:10.1002/anie.201310340. Gang Zheng, Xiaoli Ma, Bangyu Liu, Ying Dong, Mang Wang* ‘Iodine-Catalyzed Intramolecular Oxidative Thiolation of Vinylic Carbon-hydrogen via Tandem Iodocyclization and Dehydroiodination: Construction of 2-Methylene-3-Thiophenones\'Adv. Synth. Catal. 2014, 355, DOI:10.1002/adsc.201300815. Ying Dong, Yaru Guo, Jun Liu, Gang Zheng, Mang Wang*‘Annulations of -Carbamoyl Ketene Dithioacetals with Dicarboxylic Acid Dichlorides: Synthesis of Functionalized Pyrrolidinetriones and Piperidinetriones’Eur. J. Org. Chem. 2014, DOI:10.1002/ejoc.201301227. Deqiang Liang, Mang Wang,* Ying Dong, Yaru Guo，Qun Liu‘Palladium-catalyzed oxidative C–O cross-coupling of ketene dithioacetals and carboxylic acids’RSC Adv. 2014, 4, 6564. Cong Xu, Hongjuan Yuan, Yingjie Liu, Mang Wang*，Qun Liu，‘Hydrobromic acid-catalyzed Friedel–Crafts type reactions of naphthols’RSC Adv. 2014, 4, 1559. Jingxin Liu, Yingjie Liu, Wenting Du, Ying Dong, Jun Liu, Mang Wang*, ‘Pd-Catalyzed C−S Activation for [3 + 3] Annulation of 2‑(Methylthio)benzofuran-3-carboxylates and 2‑Hydroxyphenylboronic Acids: Synthesis of Coumestan Derivatives' J. Org. Chem. 2013, 78, 7293−7297. Cong Xu, Jingxin Liu, Wenbo Ming, Yingjie Liu, Jun Liu, Mang Wang,* Qun Liu, ‘In Situ Generation of PhI+CF3 and Transition-Metal-Free Oxidative sp2C- H Trifluoromethylation' Chem. Eur. J. 2013, 19, 9104–9109. Bangyu Liu, Gang Zheng, Xiaocui Liu, Cong Xu, Jingxin Liu, Mang Wang,*‘Regio- and stereoselective synthesis of 2-cyclopentenones via a hydrogenolysis-terminated Heck cyclization of beta-alkylthio dienones' Chem. Commun.,2013, 49, 2201-2203. Yingjie Liu,Jingxin Liu, Mang Wang,* Jun Liu, Qun Liu，‘Tin Tetrachloride-Catalyzed Regiospecific Allylic Substitution of Quinone Monoketals: an Easy Entry to Benzofurans and Coumestans’Adv. Synth. Catal. 2012, 354, 12678. Shaoguang Sun, Jun Liu, Mang Wang,* Qun Liu，‘Benzyl-Type Cation Initiated Nucleophilic Substitution on Furan and Thiophene by Using α-EWG Ketene S,S-Acetals as Nucleophiles’Synthesis, 2012, 2707. Dong Ying, Wang Mang,* Liu Jun, Ma Wei, Liu Qun,‘Aerobic, Cu-catalyzed desulﬁtative C–C bond- forming reaction of ketene dithioacetals/vinylogous thioesters and arylboronic acids', Chem. Commun. 2011, 47, 7380. Wang Mang,* Sun Shaoguang, Liang Deqaing, Liu Bangyu, Liu Qun, ‘Sulfuric Acid-Catalyzed Regioselective Alkylation of Indoles and beta-Naphthols with Ketene Dithioacetal-Based Allylic Alcohols’, Eur. J. Org. Chem. 2011, 2466. Wang Mang,* Fu Zhenqian, Feng Hui, Dong Ying, Liu Jun, Liu Qun, ‘Tandem [4 + 1 + 1] annulation and metal-free aerobic oxidative aromatization: straightforward synthesis of highly substituted phenols from one aldehyde and two ketones’, Chem. Commun. 2010, 46, 9061. Wang Mang*, Han Feng, Yuan Hongjuan, Liu Qun, ‘Tandem Nazarov Cyclization-Halovinylation of Divinyl Ketones under Vilsmeier Conditions: Synthesis of Highly Substituted Cyclopentadienes’, Chem. Commun. 2010, 46, 2247. Yuan Hongjuan, Wang Mang,* Liu Yingjie, Wang Lili, Liu Jun, Liu Qun, ‘Unexpected Hydrobromic Acid-Catalyzed C－C Bond-Forming Reactions and Facile Synthesis of Coumarins and Benzofurans Based on Ketene Dithioacetals’, Chem. Eur. J. 2010, 16, 13450. Liang Deqiang, Wang Mang*, Bekturhun Bahargul, Xiong Binbin, Liu Qun Liu, ‘One-Pot Synthesis of Polyfunctionalized 4H-Chromenes and Dihydrocoumarins Based on Copper(II) Bromide-Catalyzed C－C Coupling of Benzylic Alcohols with Ketene Dithioacetals’, Adv. Synth. Catal. 2010, 352, 1593. Liu Yingjie, Wang Mang*, Yuan Hongjuan, Liu Qun, ‘CuBr2/BF3Et2O-Cocatalyzed Cyclization of Ketene Dithioacetals and p-Quinones: a Mild and General Approach to Polyfunctionalized Benzofurans’, Adv. Synth. Catal. 2010, 352, 884. 巴哈尔古丽别克吐尔逊, 王芒,* 韩锋, 刘群, ‘官能化二硫缩烯酮的选择性alpha－溴代反应’,高等学校化学学报, 2010, 31, 727. Yuan Hongjun, Wang Mang*, Liu Ying Jie, Liu Qun, ‘Copper(II)-Catalyzed CC Bond-forming Reactions of alpha-EWG Ketene S,S-acetals with Carbonyl Compounds and a Facile Synthesis of Coumarins’, Adv. Synth. Catal. 2009, 351, 112. Fu Zhenqian, Wang Mang*, Ying Dong, Jun Liu, Qun Liu, ‘Direct Synthesis of Highly Substituted 2-Cyclohexenones and Sterically Hindered Benzophenones Based on a [5C + 1C] Annulation’，J. Org. Chem. 2009, 74, 6105. Liu Jun, Wang Mang*, Han Feng, Liu Yingjie, Liu Qun, ‘Direct Synthesis of Polyfunctionalized Unsaturated deta-Lactones and deta-Lactams from alpha-Alkenoyl alpha-Carboxyl/Carbamoyl Ketene S,S-Acetals under Vilsmeier Conditions’, J. Org. Chem. 2009, 74, 5090. Ma Yuhui, Wang Mang*, Li Dan, Bekturhun Bahargul, Liu Jun, Liu Qun, ‘alpha-Alkenoyl Ketene S,S-acetal-Based Multicomponent Reaction: an Efficient Approach for the Selective Construction of Polyfunctionalized Cyclohexanones’, J. Org. Chem. 2009, 74, 3116. Fu Zhenqian, Wang Mang*, Ma Yuhui, Liu Qun, Liu Jun, ‘Synthesis of Functionalized Allylic Sulfoxides and Their Use in The Construction of 2,3,4-Trisubstituted Furans via a Novel [3 + 2] Annulation’, J. Org. Chem. 2008, 73, 7625. Sun Shao Guang, Wang Mang*, Deng Hong Xia, Liu Qun, ‘Practical Route to 2,3-Di-1,2,3-Tri-substituted Indolizines from alpha-EWG Ketene S,S-acetals and Their Application in Bis(1-indolizinyl)methane’, Synthesis 2008, 573. Liu Jun, Liang De Qiang, Wang Mang*, Liu Qun, ‘Efficient One-Pot Synthesis of 1,3-Disubstituted Pyridin-2(1H)-ones from alpha-Hydroxyketene S,S-Acetals under Vilsmeier Conditions’, Synthesis 2008, 3633. Liu Jun, Wang Mang*, Li Bing, Liu Qun, Zhao Yulong, ‘A Divergent Synthesis of Functionalized Unsaturated deta-Lactones from alpha-Alkenoyl-alpha-carboxyl Ketene Dithioacetals’, J. Org. Chem. 2007, 72, 4401. Yin Yan Bing, Wang Mang*, Liu Qun, Hu Jiang Lei, Sun Shao Guang, Kang Jing, ‘A CC Bond Formation Reaction at the -Carbon Atom of alpha-Oxo Ketene Dithioacetals via the Baylis–Hillman Type Reaction’, Tetrahedron Lett. 2005, 46, 43994402. Wang Mang, Xu Xian Xiu, Liu Qun, Yang Xiao Xia, ‘Chemoselective Bromodecarboxylation of α-Carboxy- α-cinnamoyl Ketene Cyclic Dithioacetals’, Chem. Res. Chin. U. 2005, 21, 626629. Wang Mang, Gao Lian Xun, Mai Wen Peng, Xia Ai Xiang, Wang Fang, Zhang Suo Bo, ‘Enantioselective Iodolactonization Catalyzed by Chiral Quaternary Ammonium Salts Derived from Cinchonidine’, J. Org. Chem. 2004, 69, 28742876. Wang Mang, Gao Lian Xun, Yue Wei, Mai Wen Peng, ‘Reagent-Controlled Asymmetric Iodolactonization Using Cinchona Alkaloids as Chiral Sources’, Synth. Commun. 2004, 34, 10031011. Wang Mang, Xu Xian Xiu, Sun Shao Guang, Liu Qun, ‘The Alkoxy Substitution Reaction on alpha-Oxo Ketene Dithioacetals: A new Access to alpha-Oxo Ketene O,S-/O,O-Acetals’, Synth.Commun. 2004, 34, 287295. Wang Mang, Xu Xian Xiu, Liu Qun, Xiong Li, Yang Bin, Gao Lian Xun, ‘Iododecarboxylation of alpha-Carboxylate, alpha-Cinnamonyl Ketene Cyclic Dithioacetals’, Synth. Commun. 2002, 32, 34373443. Wang Mang, Ai Lin, Zhang Ji Yu, Liu Qun, Gao Liang Xun, ‘Synthesis of 2-Benzylthio-5-phenyl-3,4-disubstituted Thiophenes by Intramolecular Condensation of alpha-Oxo Ketene Dibenzylthioacetals’, Chin. J. Chem. 2002, 20, 15911597.