何成 - 大连理工大学 - 化工与环境生命学部

研究领域

金属有机限域空间内的超分子化学研究单一手性分子材料的构筑与应用从事超分子功能配位化学方向的科研工作,利用拓扑可控的金属-有机大环和笼状结构,模拟生命体系的酶化学过程,实现对生物小分子的高选择性成像检测和精细化工反应的高立体选择性催化，并开展利用光等清洁能源驱动的化学反应研究

近期论文

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P. Y. Wu, C. He*, J. Wang, X. J. Peng, X. Z. Li, Y. L. An, and C. Y. Duan*,"Photoactive Chiral Metal?Organic Frameworks for Light-Driven Asymmetric α?Alkylation of Aldehydes" J. Am. Chem. Soc. 2012, 134, 14991. X. Jing, C. He, D. P. Dong, L. L. Yang and C. Y. Duan*, "Homochiral Crystallization of Metal–Organic Silver Frameworks:Asymmetric [3+2] Cycloaddition of an Azomethine Ylide" Angew. Chem. Int. Ed. 2012, 51, 10127 J. Wang, C. He*, P. Y. Wu, J. Wang, C. Y. Duan*, "An Amide-Containing Metal-Organic Tetrahedron Responding to a Spin-Trapping Reaction in a Fluorescent Enhancement Manner for Biological Imaging of NO in Living Cells" J. Am. Chem. Soc. 2011, 133, 12402. C. He, Z. H. Lin, Z. He, C. Y. Duan*, C. H. Xu, Z. M. Wang, C. H. Yan*, “Metal-tunable nanocages as artificial chemosensors”, Angew. Chem. Int. Ed. 2008, 47, 877-881. C. He, X. Wu, J. C. Kong, T. liu, Xi. L. Zhang and C. Y. Duan*, "A hexanuclear gadolinium–organic octahedron as a sensitive MRI contrast agent for selectively imaging glucosamine in aqueous media" Chem. Commun. 2012, 48, 9290. Y. Jiao, J. Zhang, L. J. Zhang, Z. H. Lin, C. He*, C. Y. Duan, "Metal–organic polyhedra containing 36 and 24 folds of amide groups for selective luminescent recognition of natural disaccharides" Chem. Commun 2012, 48, 6022. L. Zhao, S. Y. Qu, C. He*, R. Zhang, C. Y. Duan, "Face-driven octanuclear cerium(IV) luminescence polyhedra: synthesis and luminescent sensing natural saccharides" Chem. Commun. 2011, 47, 9387. X. Wu, C. He, X. Wu, S. Y. Qu, Chunying Duan*, "An L-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions." Chem. Commun. 2011, 47, 8415. Y. Liu, X. Wu, C. He,* Y. Jiao, C. Y. Duan, “Self-assembly of cerium-based metal-organic tetrahedrons for size-selectively luminescent sensing natural saccharides”, Chem. Commun. 2009, 48 , 7554. Y. Liu, R. Zhang, C. He*, D. B. Dang, C. Y. Duan*, “A palladium(II) triangle as building blocks of microporous molecular materials: structures and catalytic performance”Source: Chem. Commun. 2010, 46, 746-748. H. M. Wu, C. He*, Z. H. Lin, Y. Liu, C. Y. Duan*, “Metallohelical Triangles for Selective Detection of Adenosine Triphosphate in Aqueous Media” Inorg. Chem. 2009, 48, 408-410. W. Huang, C. X. Song, C. He*, G. J. Lv, X. Y. Hu, X. Zhu, C. Y. Duan*. "Recognition Preference of Rhodamine-Thiospirolactams for Mercury(II) in Aqueous Solution" Inorg. Chem. 2009, 48, 5061. G. J. He, Y. G. Zhao, C. He*, Y. Liu, C. Y. Duan*, "Turn-On" fluorescent sensor for Hg2+ via displacement approach” Inorg. Chem. 2008, 47, 5169-5176 J. Wang, H. M. Wu, C. He*, L. Zhao, C. Y. Duan, "Metal-Organic Cyclohelicates as Optical Receptors for Glutathione: Syntheses Structures and Host-Guest Behaviors" Chem. Asian J. 2011, 6, 1225. Y．Liu, Z. H. Lin, C. He*, L. Zhao, C. Y. Duan, “A symmetry-controlled and face-driven approach for the assembly of cerium-based molecular polyhedra” Dalton Trans. 2010, 39, 11122 X. Zhu, C. He*, D. Dong, Y. Liu and C. Y. Duan*, “Cerium-based triple-stranded helicates as luminescent chemosensors for the selective sensing of magnesium ions” Dalton Trans. 2010, 39, 11051 Y. Liu, X. Wu, C. He*, Z. Y. Li, C. Y. Duan*, “ Metal-organic polyhedra for selective sensing of ribonucleosides through the cooperation of hydrogen-bonding interactions” Dalton Trans. 2010, 39, 7727. W. Huang, X. Zhu, D. Y. Wu, C. He*, X. Y. Hu, C. Y. Duan*. "Structural modification of rhodamine-based sensors toward highly selective mercury detection in mixed organic/aqueous media. Dalton Transactions" 2009, 10457. W. Huang, D. Y. Wu, D. Guo*, X. Zhu, C. He*, Q. J. Meng, C. Y. Duan*, "Efficient near-infrared emission of a Ytterbium(III) compound with a green light rhodamine donor" Dalton Transactions. 2009, 2081. Y. Liu, X. Wu, C. He*, R. Zhang, C. Y. Duan*, "A truncated octahedral nanocage for fluorescent detection of nucleoside" Dalton Transactions. 2008, 5866. Q. Z. Sun, M. L. Wei, Y. Bai, C. He*, Q. J. Meng, C. Y. Duan*. "Entanglement of individual coordination polymers having helicates as building intermediates" Dalton Transactions. 2007, 36, 4089 X. Wu, Z. H. Lin, C. He* and C. Y. Duan, “Catalytic performance of lanthanide molecular solids containing well-modified metal–organic octahedral” New J. Chem. 2012, 36, 161. H. Zhang, L. X. Xie, W. B. Yan, C. He*, X. Cao, C. Y. Duan*, "Conformational switching fluorescent chemodosimeter for the selective detection of silver(I) ions" New J. Chem. 2009, 33, 1478. C. He, B. G. Zhang, L. X. Xie, Y. Liu, C. Y. Duan* "Stereoselective association of ferrocene-contained molecular clips in coordination polymers" CrystEngComm. 2008, 10, 759. C. He, Y. G. Zhao, D. Guo*, Z. H. Lin, C. Y. Duan* "Chirality transfer through helical motifs in coordination compounds" Euro. J. Inorg. Chem. 2007, 22, 3451.