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研究领域

新的有机合成反应的发现,绿色有机合成化学方法的开发; 过渡金属纳米材料的制备和在有机合成中的催化应用研究; 依靠精细化工绿色新技术研究中心多年工艺研发和产业化经验,开展包括杂环、手性、天然化合物分离在内的重要医药中间体和原料药的开发及产业化研究。

近期论文

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Lingfeng Gao, Haoming Tang and Zhiyong Wang, Oxidative coupling of methylamine with an aminyl radical: direct amidation catalyzed by I2/TBHP with HCl, Chem. Commun., 2014, 50, 4085. Lingfeng Gao, Shunshun Xiong, Changfeng Wan, Zhiyong Wang, An Expedition Through the Last Decade of Heterocycle Construction by Using Palladium, Iron, Copper, or Iodine/tert-Butyl Hydroperoxide, Syn. Lett., 2013, 24, 1322. Lingfeng Gao, Kai Fu and Gengxiu Zheng, Quickly FeCl3-catalyzed highly chemo- and stereoselective [3 + 2] dipolar cycloaddition of aziridines with isothiocyanates, RSC Advances, 2016, 6, 47192. Jinmin Fan, Lingfeng Gao and Zhiyong Wang, Facile Construction of highly Functionalized 2-Pyrrolines via FeCl3-catalyzed reaction of Aziridines with Arylzlkynes, Chem. Commun., 2009, 45, 5021. Wei Sun, Shiguo Sun, Na Jiang, Lingfeng Gao,* Gengxiu Zheng,* Study of highly efficient heterodinuclear Ir-Os ECL complexes, Journal of Organometallic Chemistry, 2017, 846, 367. Wei Li, Lingfeng Gao,* Wenyun Zhuge, Xu Sun and Gengxiu Zheng*, Catalyst-free synthesis of 3-sulfone nitrile from sulfonyl hydrazides and acrylonitrile in water, Org. Biomol. Chem., 2017, 15, 7819. Wei Sun, Lingfeng Gao*, Xue Feng, Xu Sun, and Gengxiu Zheng*,High-Efficiency Catalytic Oxidation of Inert C(sp3)−H Bond Functionalization with Oxygen by Synergetic Cu NPs/N-Doped Graphene,Eur. J. Org. Chem., 2017, 9, 1121. Wei Sun, Lingfeng Gao *, Xu Sun, Gengxiu Zheng, A novel route with a Cu(II)-MOF-derived structure to synthesize Cu/Cu2O NPs@graphene: the electron transfer leads to the synergistic effect of the Cu(0)–Cu(I) phase for an effective catalysis of the Sonogashira cross-coupling reactions, Dalton Transactions, 2018, 47, 5538. (封面文章) One-pot Sequential Route of 2,4-2-Thiazole via a Metal-Free-Catalyzed Cascade Cyclization,第十届江淮有机化学论坛。 一种无催化剂氧化合成3-乙酰基吡啶的方法,高令峰,郑庚修,孙旭,中国专利,ZL201610240411.7。 一种3-砜基腈类化合物的合成方法,高令峰,郑庚修,李薇 冯雪,韩歆雨,付凯,中国专利,实审。 一种3-磺酰基丙酸化合物的合成方法,高令峰,李薇,郑庚修,冯雪,韩歆雨,韩秀娇,中国专利,实审。 一种石墨烯负载钯铜纳米胶囊催化Suzuki偶联反应制备联苯的方法,高令峰,韩歆雨,郑庚修,冯雪,李薇,韩秀娇,中国专利,实审。

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