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有机方法学,如从事C-H键活化及官能团化的相关研究,惰性化学键的选择性断裂等。 有机功能分子的设计、合成及其应用研究。

有机化学

近期论文

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Xi Zhou, Hongyan Xu, Qiaodan Yang, Hua Chen, Shoufeng Wang, and Huaiqing Zhao* Co(II)/Cu(II)-cocatalyzed oxidative C–H/N–H functionalization of benzamides with ketones: a facile route to isoindolin-1-ones Chem. Commun. 2019, 55, 8603-8606. Ningxin Guo, Xiufen Liu, Hongyan Xu, Xi Zhou and Huaiqing Zhao * A simple route towards the synthesis of 1,4,5-trisubstituted 1,2,3-triazoles from primary amines and 1,3-dicarbonyl compounds under metal-free conditions Org. Biomol. Chem., 2019, 17, 6148-6152. Baode Shan, Qing Miao, Rui Wang, Guohui Jia, Huaiqing Zhao* Cp*Rh(III)-catalyzed C(sp3)−H alkenylation and arylation of 8-methylquinolines with quinones and thiophenes Catal. Commun. 2019, 128, 105701. Wei Zhang, Darun Yang, Wengui Wang, Shoufeng Wang, Huaiqing Zhao,* Iridium(III)-Catalyzed Directed ortho-C(sp2)–H Amidation of Arenes with Sulfonamides Eur. J. Org. Chem. 2018, 2071–2077. Huaiqing Zhao,* Xiangwen Xu, Wei Wu, Wei Zhang, Yunxian Zhang Urea-based organocatalyst catalyzed direct C-H bond arylations of unactivated arenes Catal. Commun. 2018, 111, 95–99. Huaiqing Zhao,* Xi Zhou, Bo Li, Xiufeng Liu, Ningxin Guo, Zhengliang Lu, Shoufeng Wang Rhodium(III)-Catalyzed C(sp3)-H Bond Aminocarbonylation with Isocyanates J. Org. Chem. 2018, 83, 4153–4159. Huaiqing Zhao, Jie Shen, Changliang Ren, Wei Zeng, and Huaqiang Zeng* A Foldamer-Based Organocatalyst for Direct Arylations of Unactivated Arenes Org. Lett. 2017, 19, 2190-2193. Quandi Jiang,Changlei Zhu,Huaiqing Zhao*and Weiping Su*,Rh(III)-Catalyzed C−H Olefination of Benzoic Acids under Mild Conditions using Oxygen as the Sole Oxidant,Chem. -Asian J. 2016, 11, 356-359 (VIP paper and Front Cover). Changlei Zhu, Yuanfei Zhang, Jian Kan, Huaiqing Zhao* and Weiping Su* Ambient-temperature ortho C−H arylation of benzoic acids with aryl iodides with ligand-supported palladium catalyst Org. Lett. 2015, 17, 3418-3421. Huaiqing Zhao, Shen Sheng, Yunhan Hong, and Huaqiang Zeng* Proton Gradient-Induced Water Transport Mediated by Water Wires Inside Narrow Aquapores of Aquafoldamer Molecules J. Am. Chem. Soc. 2014, 136, 14270-14276. Huaiqing Zhao, Yaping Shang, Weiping Su* Rhodium(III)-Catalyzed Intermolecular N‑Chelator-Directed Aromatic C-H Amidation with Amides Org. Lett. 2013, 15, 5106-5109. Huaiqing Zhao, Jie Shen, Juanjuan Guo, Ruijuan Ye, and Huaqiang Zeng* A macrocyclic aromatic pyridone pentamer as a highly efficient organocatalyst for the direct arylations of unactivated arenes Chem. Commun. 2013, 49, 2323-2325. Huaiqing Zhao, Wei Qiang Ong, Feng Zhou, Xiao Fang, Xueyuan Chen, Sam F. Y. Li, Haibi Su, Nam-Joon Cho, and Huaqiang Zeng* Chiral crystallization of aromatic helical foldamers via complementarities in shape and end functionalities Chem. Sci. 2012, 3, 2042-2046. Huaiqing Zhao, Wei Qiang Ong, Xiao Fang, Feng Zhou, Meng Ni Hii, Sam Fong Yau Li, Haibin Su and Zeng Huaqiang* Synthesis, structural investigation and computational modelling of water-binding aquafoldamers Org. Biomol. Chem. 2012, 10, 1172 – 1180 (Front Cover and Hot Paper). Huaiqing Zhao, Ye Wei, Jing Xu, Jian Kan, Weiping Su,* and Maochun Hong Pd/PR3 Catalyzed Cross-Coupling of Aromatic Carboxylic Acids with Electron-deficient Polyfluoroarenes via Combination of Decarboxylation and sp2 C-H bond activation J. Org. Chem. 2011, 76, 882-893. Huaiqing Zhao, Min Wang, Weiping Su,* and Maochun Hong Copper-Catalyzed Intermolecular Amination of Acidic Aryl C–H Bonds with Primary Aromatic Amines Adv. Synth. Catal. 2010, 352, 1301-1306.

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