自国甫 - 北京师范大学

研究领域

Organic Synthesis, Asymmetric Synthesis, Organometallic Synthesis and Homogenous Catalysis. Work in Dr. Zi's research group is directed toward the synthesis and study of new and unusual molecular organometallic compounds of the p-, d- and f-block elements. The emphasis is on preparing compounds that exhibit novel reactivity, selectivity (including stereoselectivity and enantioselectivity) and/or catalytic behavior (homogeneously), with the discovery of new applications (new chemical reactions) of these compounds to catalysis and organic synthesis. In addition to the dry-box and Schlenk techniques used to prepare and manipulate compounds, we exploit a variety of characterization methods, including NMR, IR, elemental analysis and X-ray crystallography.

近期论文

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Shichun Wang, Tongyu Li, Yi Heng, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the reactivity of the Uranium Phosphinidene [h5-1,3-(Me3Si)2C5H3]2U(=P-2,4,6-iPr3C6H2)(OPPh3)”, Organometallics 2021, 40, 2149-2165. Deqiang Wang, Shichun Wang, Tongyu Li, Yi Heng, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Reactivity Studies Involving a Lewis Base Supported Terminal Uranium Phosphinidene Metallocene [h5-1,3-(Me3C)2C5H3]2U(=P-2,4,6-iPr3C6H2)(OPMe3)”, Dalton Trans. 2021, 50, 8349-8363. Deqiang Wang, Wanjian Ding, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Uranium versus Thorium: Synthesis and Reactivity of [h5-1,2,4-(Me3C)3C5H2]2U[h2-C2Ph2]”, Chem. Eur. J. 2021, 27, 6767-6782. Deqiang Wang, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Influence of the Lewis Base Ph3PO on the Reactivity of the Uranium Phosphinidene (h5-C5Me5)2U(=P-2,4,6-iPr3C6H2)(OPPh3)”, Organometallics 2021, 40, 383-396. Deqiang Wang, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “(h5-C5Me5)2U(=P-2,4,6-tBu3C6H2)(OPMe3) Revisited – Its Intrinsic Reactivity towards Small Organic Molecules”, Organometallics 2020, 39, 4085-4101. Deqiang Wang, Shichun Wang, Guohua Hou, Guofu Zi*, Marc D. Walter*. “A Lewis Base Supported Terminal Uranium Phosphinidene Metallocene”, Inorg. Chem. 2020, 59, 14549-14563. Deqiang Wang, Wanjian Ding, Guohua Hou, Guofu Zi*, Marc D. Walter*. “Experimental and Computational Studies on a Base-Free Terminal Uranium Phosphinidene Metallocene”, Chem. Eur. J. 2020, 26, 16888-16899. Qiaozhi Yan, Xin Shen, Guofu Zi, and Guohua Hou*. “Rh-Catalyzed Asymmetric Hydrogenation of α,β- and β,β-Disubstituted Unsaturated Boronate Esters”, Chem. Eur. J. 2020, 26, 5961-5964. Xiufen Li, Chaoqiong Wang, Jianqiao Song; Zhihong Yang, Guofu Zi, and Guohua Hou*. “Copper-Catalyzed Asymmetric Hydroboration of 2H-Chromenes Using a Chiral Diphosphine Ligand”, J. Org. Chem. 2019, 84, 8638-8645. Yongsong Wang, Congcong Zhang, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “Preparation of a potassium chloride bridged thorium phosphinidiide complex and its reactivity towards small organic molecules”, New J. Chem. 2019, 43, 9527-9539. Congcong Zhang, Yongsong Wang, Guohua Hou, Wanjian Ding, Guofu Zi*, and Marc D. Walter*. “Experimental and computational studies on a three-membered diphosphido thorium metallaheterocycle [h5-1,3-(Me3C)2C5H3]2Th[h2-P2(2,4,6-iPr3C6H2)2]”, Dalton Trans. 2019, 48, 6921-6930. Suna Han, Xin Shen, Duanyang Kong, Guofu Zi, Guohua Hou,* and Jiaxin Zhang*. “Cu-Catalyzed Asymmetric Hydroboration of Naphthylallylic Compounds for Enantioselective Synthesis of Chiral Boronates”, J. Org. Chem. 2019, 84, 4318-4329. Congcong Zhang, Guohua Hou, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “An Alkali-Metal Halide-Bridged Actinide Phosphinidiide Complex”, Inorg. Chem. 2019, 58, 1571-1590. Qiaozhi Yan, Guiying Xiao, Ying Wang, Guofu Zi, Zhanbin Zhang, and Guohua Hou*. “Highly Efficient Enantioselective Synthesis of Chiral Sulfones by Rh-Catalyzed Asymmetric Hydrogenation”, J. Am. Chem. Soc. 2019, 141, 1749-1756. Congcong Zhang, Guohua Hou, Guofu Zi*, and Marc D. Walter. “A base-free terminal thorium phosphinidene metallocene and its reactivity toward selected organic molecules”, Dalton Trans. 2019, 48, 2377-2387. Congcong Zhang, Guohua Hou, Guofu Zi,* Wanjian Ding,* and Marc D. Walter*. “A Base-Free Terminal Actinide Phosphinidene Metallocene: Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem. Soc. 2018, 140, 14511-14525. Guofu Zi*. “Recent developments in actinide metallacycles”, Chem. Commun. 2018, 54, 7412-7430. Duanyang Kong, Suna Han, Guofu Zi, Guohua Hou,* and Jiaxin Zhang*. “Enantioselective Synthesis of Boryl Tetrahydroquinolines via Cu-Catalyzed Hydroboration”, J. Org. Chem. 2018, 83, 1924-1932. Congcong Zhang, Pikun Yang, Enwei Zhou, Xuebin Deng, Guofu Zi,* and Marc D. Walter*. “Reactivity of a Lewis Base Supported Thorium Terminal Imido Metallocene towards Small Organic Molecules”, Organometallics 2017, 36, 4525-4538. Lei Zhang, Congcong Zhang, Guohua Hou, Guofu Zi,* and Marc D. Walter*. “Small Molecule Activation Mediated by a Uranium Bipyridyl Metallocene”, Organometallics 2017, 36, 1179-1187. Lei Zhang, Guohua Hou, Guofu Zi,* Wanjian Ding,* and Marc D. Walter*. “Preparation of a uranium metallacyclocumulene and its reactivity towards unsaturated organic molecules”, Dalton Trans. 2017, 46, 3716-3728. Lei Zhang, Bo Fang, Guohua Hou, Guofu Zi,* Wanjian Ding* and Marc D. Walter*. “Experimental and Computational Studies on a Uranium Metallacyclocumulene”, Organometallics 2017, 36, 898-910. Ying Zhang, Qiaozhi Yan, Guofu Zi, Guohua Hou*. “Enantioselective Direct Synthesis of Free Cyclic Amines via Intramolecular Reductive Amination”, Org. Lett. 2017, 19, 4215-4218. Duanyang Kong, Suna Han, Rui Wang, Meina Li, Guofu Zi, and Guohua Hou*. “Kinetic resolution of racemic 2-substituted 1,2-dihydroquinolines via asymmetric Cu-catalyzed borylation”, Chem. Sci. 2017, 8, 4558-4564. Meina Li, Duanyang Kong, Guofu Zi and Guohua Hou*. “Rh-Catalyzed Asymmetric Hydrogenation of 1,2-Dicyanoalkenes”, J. Org. Chem. 2017, 82, 680-687. Lei Zhang, Guohua Hou, Guofu Zi,* Wanjian Ding,* and Marc D. Walter*. “Influence of the 5f Orbitals on the Bonding and Reactivity in Organoactinides: Experimental and Computational Studies on a Uranium Metallacyclopropene”, J. Am. Chem. Soc. 2016, 138, 5130-5142. Pikun Yang, Enwei Zhou, Guohua Hou, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “Experimental and Computational Studies on the Formation of Thorium-Copper Heterobimetallics”, Chem.-Eur. J. 2016, 22, 13845-13849. Pikun Yang, Enwei Zhou, Bo Fang, Guohua Hou, Guofu Zi*, and Marc D. Walter*. “Preparation of (h5-C5Me5)2Th(bipy) and Its Reactivity toward Small Molecules” Organometallics 2016, 35, 2129-2139. Lei Zhang, Bo Fang, Guohua Hou, Lin Ai, Wanjian Ding*, Marc D. Walter*, and Guofu Zi*. “Intrinsic reactivity of a uranium metallacyclopropene toward unsaturated organic molecules”, Dalton Trans. 2016, 45, 16441-16452. Duanyang Kong, Meina Li, Guofu Zi, Guohua Hou*, and Yong He*. “Enantioselective Hydrogenation of Diarylmethanimines for Synthesis of Chiral Diarylmethylamines”, J. Org. Chem. 2016, 81, 6640-6648. Duanyang Kong, Meina Li, Rui Wang, Guofu Zi and Guohua Hou.* “Asymmetric Hydrogenation of β-Aryloxy/Alkoxy Cinnamic Nitriles and Esters”, Org. Lett. 2016, 18, 4916-4919. Duanyang Kong, Meina Li, Guofu Zi and Gouhua Hou*. “Synthesis of Chiral Lactams via Asymmetric Hydrogenation of α,β-Unsaturated Nitriles”, Org. Biomol. Chem. 2016, 14, 4046-4053. Qiaozhi Yan, Duanyang Kong, Wei Zhao, Guofu Zi, Guohua Hou*. “Enantioselective Hydrogenation of β,β-Disubstituted Unsaturated Carboxylic Acids under Base-Free Conditions”, J. Org. Chem. 2016, 81, 2070-2077. Duanyang Kong, Meina Li, Rui Wang, Guofu Zi, Guohua Hou*. “Highly Efficient Asymmetric Hydrogenation of Cyano-substituted Acrylate Esters for Synthesis of Chiral γ-Lactams and Amino Acids”, Org. Biomol. Chem. 2016, 14, 1216-1220. Bo Fang, Guohua Hou, Guofu Zi*, Wanjian Ding*, and Marc D. Walter*. “Steric and Electronic Influences of Internal Alkynes on the Formation of Thorium Metallacycles: A Combined Experimental and Computational Study”, Organometallics 2016, 35, 1384-1391. Bo Fang, Lei Zhang, Guohua Hou, Guofu Zi,* De-Cai Fang* and Marc D. Walter*. “C-H bond activation induced by thorium metallacyclopropene complexes: A combined experimental and computational study”, Chem. Sci. 2015, 6, 4897-4906. Bo Fang, Lei Zhang, Guohua Hou, Guofu Zi,* De-Cai Fang* and Marc D. Walter*. “Experimental and Computational Studies on an Actinide Metallacyclocumulene Complex”, Organometallics 2015, 34, 5669-5681. Enwei Zhou, Wenshan Ren, Guohua Hou, Guofu Zi,* De-Cai Fang* and Marc D. Walter*. “Small Molecule Activation Mediated By a Thorium Terminal Imido Metallocene”, Organometallics 2015, 34, 3637-3647. Ann Christin Fecker, Matthias Freytag, Peter G. Jones, Ning Zhao, Guofu Zi* and Marc D. Walter*. “Preparation of enantiomerically pure open calcocene and strontocene complexes and their application in ring opening polymerizations of rac-lactide”, Dalton Trans. 2015, 44, 16325-16331. Qiaozhi Yan, Duanyang Kong, Meina, Li, Guohua Hou,* and Guofu Zi. “Highly Efficient Rh-Catalyzed Asymmetric Hydrogenation of α,β-Unsaturated Nitriles”, J. Am. Chem. Soc. 2015, 137, 10177-10181. Man Liu, Duanyang Kong, Meina Li, Guofu Zi and Guohua Hou*. “Iridium-Catalyzed Enantioselective Hydrogenation of β,β-Disubstituted Nitroalkenes”, Adv. Synth. Catal. 2015, 357, 3875-3879. Dao Zhang,* and Guofu Zi*. “N-Heterocyclic carbene (NHC) complexes of group 4 transition metals”, Chem. Soc. Rev. 2015, 44, 1898-1921. Bo Fang, Guohua Hou, Guofu Zi,* De-Cai Fang* and Marc D. Walter*. “A thorium metallacyclopentadiene complex: a combined experimental and computational study”, Dalton Trans. 2015, 44, 7927-7934. Bo Fang, Wenshan Ren, Guohua Hou, Guofu Zi,* De-Cai Fang,* Laurent Maron,* and Marc D. Walter* “An Actinide Metallacyclopropene Complex: Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem. Soc. 2014, 136, 17249-17261. Wenshan Ren, Enwei Zhou, Bo Fang, Guohua Hou, Guofu Zi*, De-Cai Fang*, and Marc D. Walter*. “Experimental and Computational Studies on the Reactivity of a Terminal Thorium Imido Metallocene towards Organic Azides and Diazoalkanes”, Angew. Chem. Int. Ed. 2014, 53, 11310-11314. Qiaozhi Yan, Man Liu, Duanyang Kong, Guofu Zi, and Guohua Hou*. “Highly Efficient Iridium-Catalyzed Asymmetric Hydrogenation of β-Acylamino Nitroolefins”, Chem. Commun. 2014, 50, 12870-12872. Wenshan Ren, Enwei Zhou, Bo Fang, Guofu Zi*, De-Cai Fang*, and Marc D. Walter*. “Si-H Addition followed by C-H bond activation induced by a terminal thorium imido metallocene: A combined experimental and computational study”, Chem. Sci. 2014, 5, 3165-3172. Ning Zhao, Guohua Hou, Xuebin Deng, Guofu Zi*, and Marc D. Walter*. “Group 4 metal complexes with new chiral pincer NHC-ligands: Synthesis, structure and catalytic activity”, Dalton Trans. 2014, 43, 8261-8272. Ning Zhao, Qiuwen Wang, Guohua Hou, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of aluminum chloride complexes with chiral biaryl Schiff-base ligands”, Inorg. Chem. Commun. 2014, 44, 86-90. Wenshan Ren, Liang Chen, Ning Zhao, Qiuwen Wang, Guohua Hou, and Guofu Zi*. “Synthesis, structure, and catalytic activity of organolanthanide complexes with chiral biaryl Schiff-base ligands”, J. Organomet. Chem. 2014, 758, 65-72. Ning Zhao, Qiuwen Wang, Guohua Hou, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of organoaluminum complexes with chiral biaryl Schiff-base ligands”, Inorg. Chim. Acta 2014, 413, 128-135. Ning Zhao, Qiuwen Wang, Guohua Hou, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of binuclear aluminum complexes with chiral biaryl-based N2O ligands”, J. Organomet. Chem. 2014, 754, 51-58. Ning Zhao, Qiuwen Wang, Guohua Hou, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of binuclear aluminum choride complexes with chiral biaryl-based ligands”, Inorg. Chem. Commun. 2014, 41, 6-10. Wenshan Ren, Wayne W. Lukens, Guofu Zi*, Laurent Maron*, and Marc D. Walter*. “Is the bipyridyl thorium metallocene a low-valent thorium complex? A combined experimental and computational study”, Chem. Sci. 2013, 4, 1168-1174. Liang Chen, Ning Zhao, Qiuwen Wang, Guohua Hou, Haibin Song, Guofu Zi*. “Synthesis, structure, and catalytic activity of titanium complexes with chiral biaryl Schiff-base ligands”, Inorg. Chim. Acta 2013, 402, 140-155. Wenshan Ren, Ning Zhao, Liang Chen, and Guofu Zi*. “Synthesis, structure, and catalytic activity of benzyl thorium metallocenes”, Inorg. Chem. Commun. 2013, 30, 26-28. Liang Chen, Yuqiao Liu, Guohua Hou, Haibin Song, Guofu Zi*. “Synthesis, structure, and catalytic activity of a new chiral NHC-iridium(III) complex”, Inorg. Chem. Commun. 2013, 29, 141-144. Haibin Song*, Dongna Fan, Yuqiao Liu, Guohua Hou, Guofu Zi*. “Synthesis, structure, and catalytic activity of nickel complexes with new chiral binaphthyl-based NHC-ligands”, J. Organomet. Chem. 2013, 729, 40-45. Ning Zhao, Liang Chen, Wenshan Ren, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of trinuclear zinc complexes with new chiral biaryl-based NO2 ligands”, J. Organomet. Chem. 2012, 712, 29-36. Wenshan Ren, Haibin Song, Guofu Zi*, and Marc D. Walter*. “A bipyridyl thorium metallocene: synthesis, structure and reactivity”, Dalton Trans. 2012, 41, 5965-5973. Zhanbin Zhang, Ning Zhao, Wenshan Ren, Liang Chen, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of a new zinc complex derived from a chiral hydroxyazetidine ligand”, Inorg. Chem. Commun. 2012, 20, 234-237. Wenshan Ren, Guofu Zi,* and Marc D. Walter*. “Synthesis, Structure and Reactivity of a Thorium Metallocene Containing a 2,2’-Bipyridyl Ligand”, Organometallics 2012, 31, 672-679. Wenshan Ren, Guofu Zi*, De-Cai Fang*, and Marc D. Walter*. “A Base-Free Thorium Terminal Imido Metallocene: Synthesis, Structure and Reactivity”, Chem.-Eur. J. 2011, 17, 12669-12682. Wenshan Ren, Xuebin Deng, Guofu Zi*, and De-Cai Fang*. “The Th=C double bond: an experimental and computational study of thorium poly-carbene complexes”, Dalton Trans. 2011, 40, 9662-9664. Haibin Song*, Yuqiao Liu, Dongna Fan, and Guofu Zi*. “Synthesis, structure, and catalytic activity of rhodium complexes with new chiral binaphthyl-based NHC-ligands”, J. Organomet. Chem. 2011, 696, 3714-3720. Wenshan Ren, Ning Zhao, Liang Chen, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of an organothorium hydride complex”, Inorg. Chem. Commun. 2011, 14, 1838-1841. Wenshan Ren, Guofu Zi*, De-Cai Fang*, and Marc D. Walter*. “Thorium Oxo and Sulfido Metallocenes: Synthesis, Structure, Reactivity and Computational Studies”, J. Am. Chem. Soc. 2011, 133, 13183-13196. Furen Zhang, Haibin Song, and Guofu Zi*. “Synthesis and catalytic activity of group 5 metal amides with chiral biaryldiamine-based ligands”, Dalton Trans. 2011, 40, 1547-1566. Qiuwen Wang, Furen Zhang, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of organolanthanides with chiral biphenyl-based tridentate amidate ligands”, J. Organomet. Chem. 2011, 696, 2186-2192. Haiyan Zhang, Liang Chen, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of chiral silver(I) and copper(II) complexes with biaryl-based nitrogen-containing ligands”, Inorg. Chim. Acta 2011, 366, 320-336. Furen Zhang, Jiaxin Zhang, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of organoyttrium complexes with chiral binaphthyl-based amidate ligands”, Inorg. Chem. Commun. 2011, 14, 72-74. Guofu Zi*. “Asymmetric hydroamination/cyclization catalyzed by group 4 metal complexes with chiral biaryl-based ligands”, J. Organomet. Chem. 2011, 696, 68-75. (Invited Review Article) Guofu Zi*, Furen Zhang and Haibin Song. “Highly enantioselective hydroaminoalkylation of secondary amines catalyzed by group 5 metal amides with chiral biarylamidate ligands”, Chem. Commun. 2010, 46, 6296-6298. Furen Zhang, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of titanium complexes with new chiral 11,12-diamino-9,10-dihydro-9,10-ethanoanthracene-based ligands”, J. Organomet. Chem. 2010, 695, 1993-1999. Guofu Zi*, Furen Zhang, Li Xiang, Yue Chen, Weihai Fang*, and Haibin Song. “Synthesis and characterization of group 4 metal amides with new C2-symmetric binaphthyldiamine-based ligands and their use as catalysts for asymmetric hydroamination/cyclization”, Dalton Trans. 2010, 39, 4048-4061. Qiuwen Wang, Haibin Song, Guofu Zi*. “Synthesis, structure, and catalytic activity of group 4 metal complexes with new chiral biaryl-based NO2 ligands”, J. Organomet. Chem. 2010, 695, 1583-1591. Li Xiang, Furen Zhang, Jiaxin Zhang, Haibin Song, and Guofu Zi*. “Synthesis, structure, and catalytic activity of group 4 complexes with new chiral binaphthyldiamine-based ligands”, Inorg. Chem. Commun. 2010, 13, 666-670. Guofu Zi*, Li Xiang, Xue Liu, Qiuwen Wang, and Haibin Song. “Synthesis, structure, and reactivity of yttrium complexes with chiral biaryldiamine-based N4-ligands”, Inorg. Chem. Commun. 2010, 13, 445-448. Guofu Zi*, Furen Zhang, Xue Liu, Lin Ai, and Haibin Song. “Synthesis, structure, and catalytic activity of titanium(IV) and zirconium(IV) amides with chiral biphenyldiamine-based ligands”, J. Organomet. Chem. 2010, 695, 730-739. Guofu Zi*. “Asymmetric hydroamination/cyclization catalyzed by organolanthanide complexes with chiral biaryl-based ligands”, Dalton Trans. 2009, 9101-9109. (Invited Perspective Article) Guofu Zi*, Xue Liu, Li Xiang, Haibin Song. “Synthesis of Group 4 Metal Amides with New Chiral Biaryldiamine-Based Ligands and Their Use as Catalysts for Asymmetric Hydroamination/Cyclization” Organometallics 2009, 28, 1127-1137. Haibin Song*, Li-Na Gu, Guofu Zi*. “Synthesis and X-ray structures of rhodium complexes with new chiral biaryl-based NHC-ligands”, J. Organomet. Chem. 2009, 694, 1493-1502. Qiuwen Wang, Li Xiang, Haibin Song, Guofu Zi*. “Synthesis, structure, and catalytic activity of binuclear lanthanide complexes with chiral NOBIN-based NNO ligands”, J. Organomet. Chem. 2009, 694, 691-695. Zhanbin Zhang, Xuemei Bai, Ruochen Liu, Guofu Zi*. “Synthesis of new chiral cis-3-aminoazetidines and their use in catalytic asymmetric reactions”, Inorg. Chim. Acta 2009, 362, 1687-1691. Xin-Fang Duan,* Jian-Xia Feng, Guo-Fu Zi, Zhan-Bin Zhang. “A Convenient Synthesis of Unsymmetrical Pinacols by Coupling of Structurally-Similar Aromatic Aldehydes Mediated by Low Valent Titanium”, Synthesis 2009, 277-282. Guofu Zi*, Qiuwen Wang, Li Xiang, Haibin Song. “Lanthanide and group 4 metal complexes with new chiral biaryl-based NNO-donor ligands”, Dalton Trans. 2008, 5930-5944. Qiuwen Wang, Li Xiang, Haibin Song, and Guofu Zi*. “Synthesis of Amidolanthanides with New Chiral Biaryl-Based NNO Ligands and Their Use as Catalysts for Enantioselective Hydroamination/Cyclization”, Inorg. Chem. 2008, 47, 4319-4328. Guofu Zi*, Li Xiang, and Haibin Song. “Enantioselective Hydroamination/Cyclization Catalyzed by Organolanthanide Amides Derived from a New Chiral Ligand, (S)-2-(Pyrrol-2-ylmethyleneamino)-2’-dimethylamino-1,1’-binaphthyl”, Organometallics 2008, 27, 1242-1246. Li Xiang, Haibin Song, and Guofu Zi*. “Synthesis, Structure, and Catalytic Activity of Ti(IV) and Zr(IV) Complexes Derived from (R)-2,2'-Diamino-1,1'-binaphthyl Based N4-Donor Ligands”, Eur. J. Inorg. Chem. 2008, 1135-1140. Yadong Zhang, Li Xiang, Qiuwen Wang, Xin-Fang Duan, and Guofu Zi*. “Synthesis, structure, and catalytic activity of chiral Cu(II) and Ag(I) complexes with (S,S )-1,2-diaminocyclohexane-based N4-donor ligands”, Inorg. Chim. Acta 2008, 361, 1246-1254. Qiuwen Wang, Li Xiang, and Guofu Zi*. “Synthesis, structural characterization, and reactivity of organolanthanides derived from a new chiral ligand (S)-2-(pyrrol-2-ylmethyleneamino)-2'-hydroxy-1,1'-binaphthyl”, J. Organomet. Chem. 2008, 693, 68-76. Xin-Fang Duan*, Jing Zeng, Zhan-Bin Zhang, and Guo-Fu Zi. “A Facile Two-Step Synthesis of 2-Arylbenzofurans Based on the Selective Cross McMurry Couplings”, J. Org. Chem. 2007, 72, 10283-10286. Li Xiang, Qiuwen Wang, Haibin Song, and Guofu Zi*. “Synthesis, Structural Characterization, and Reactivity of Organolanthanides Derived from a New Chiral Ligand, (R)-Bis(pyrrol-2-ylmethyleneamino)-1,1’-binaphthyl”, Organometallics 2007, 26, 5323-5329. Zhanbin Zhang, Min Li, and Guofu Zi*. “Synthesis of New Chiral cis-3-Hydroxyazetidines and Their Application in Diethylzinc Addition to Aldehydes”, Chirality 2007, 19, 802-808. Noémi Barros, Daniel Maynau, Laurent Maron, Odile Eisenstein, Guofu Zi, and Richard A. Andersen. “Single but Stronger UO, Double but Weaker UNMe Bonds: The Tale Told by Cp2UO and Cp2UNR”, Organometallics 2007, 26, 5059-5065. Guofu Zi*, Li Xiang, Yadong Zhang, Qiuwen Wang, Xiaofang Li, Yuan Yang, and Zhanbin Zhang. “Synthesis and X-ray structures of new chiral Ag(I) complexes with biaryl-based N4-donor ligands”, J. Organomet. Chem. 2007, 692, 3949-3956. Guofu Zi, Laura L. Blosch, Li Jia, and Richard A. Andersen. “Preparation and Reactions of Base-free Bis(1,3,4-tri-t-butylcyclopentadienyl)uranium Methylimide, Cp’2U=NMe, and Related Compounds”, Organometallics 2005, 24, 4602-4612. Guofu Zi, Li Jia, Evan L. Werkema, Marc D. Walter, Jochen P. Gottfriedsen, and Richard A. Andersen. “Preparation and Reactions of Base-free Bis(1,3,4-tri-t-butylcyclopentadienyl)uranium Oxide, Cp’2UO”, Organometallics 2005, 24, 4251-4264. Chi Wu, Zuowei Xie, Guangzhao Zhang, Guofu Zi, Yingfeng Tu, Yali Yang, Ping Cai, and Ting Nie. “Self-assembly assisted polymerization (SAAP): approaching long multi-block copolymers with an ordered chain sequence and controllable block length”, Chem. Commun. 2002, 2898-2899. Guofu Zi, Hung-Wing Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Reactivity of ‘Carbons-Adjacent’ nido- and arachno-Carborane Anions of C2B10 Systems and Their Metal Complexes”, Organometallics 2002, 21, 5415-5427. Guofu Zi, Hung-Wing Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Catalytic Property of Group 4 Metal Carborane Complexes with a iPr2NB-bridged Constrained-Geometry Ligand”, Organometallics 2002, 21, 3850-3855. Guofu Zi, Hung-Wing Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Reactivity of Lanthanacarboranes Incorporating ‘Carbons-Adjacent’ nido- and arachno-Carborane Anions of C2B10 System”, Organometallics 2002, 21, 3464-3470. Guofu Zi, Hung-Wing Li, and Zuowei Xie. “Synthesis, Structural Characterization, and Reactivity of Organolanthanide Complexes Derived from A New, Versatile Boron-Bridged Ligand, iPr2NB(C9H7)(C2B10H11)”, Organometallics 2002, 21, 1136-1145. Guofu Zi, Hung-Wing Li, and Zuowei Xie. “A Novel Carbons-Adjacent arachno-C2B10 Carborane Tetraanion Bearing Both Hexagonal and Pentagonal Bonding Face”, Organometallics 2001, 20, 3836-3838. Guofu Zi, Hung-Wing Li, and Zuowei Xie. “The First Full-sandwich Potassacarborane and a Novel ‘Carbons-Adjacent’ R2C2B10H11- Monoanion”, Chem. Commun. 2001, 1110-1111. Guofu Zi, Qingchuan Yang, Thomas C. W. Mak, and Zuowei Xie. “Tetramethylcyclopentadienyl vs Cyclopentadienyl Substituents. Synthesis and Structural Characterization of Organolanthanide Compounds Derived from the Versatile Ligand Me2Si(C5Me4H)(C2B10H11)”, Organometallics 2001, 20, 2359-2366.

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