李晓芳 - 北京理工大学 - 化学与化工学院

个人简介

教育背景 2000.09-2003.12 中国科学院长春应用化学研究所，有机化学专业，理学博士 1997.09-2000.07 东北师范大学，有机化学专业，理学硕士 1993.09-1997.07 东北师范大学，化学教育专业，理学学士工作履历 2008.02-至今北京理工大学化学与化工学院，长聘教授/博士生导师/有机所所长 2014.10-2014.12 香港科技大学化学与化工学院唐本忠课题组，访问学者 2004.04-2009.04 日本理化学研究所，有机金属实验室，博士后十年来，我们立足于基础和应用研究，以“新催化剂，新聚合反应，新材料”为宗旨，致力于开发新型的、高效、高选择性的稀土/过渡金属有机配合物，并探索其在高分子合成（特别是配位聚合反应）和有机合成（特别是有机方法学）中的催化作用，合成出许多具有潜在工业应用前景的聚烯烃或者难以用以往催化剂制备的新型高分子材料和有机合成试剂。主持国家自然科学基金项目 6 项、承担企业合作项目 1 项；参与国家自然科学基金项目等1 项。迄今在国内外学术刊物及会议上发表学术论文 60 余篇，其中 SCI 收录61 篇，EI 收录 0 篇，获授权专利 9 项。

研究领域

稀土/过渡金属有机化学高分子合成化学烯/炔烃配位聚合反应有机方法学

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

H. Liu,a S.-W. Zhang,a X.-Q. Yan,a C. Song,a J.-P. Chen,a Y.-P. Dong*b and X.-F. Li*a. Silylium Cations Initiated Sergeants-and-Soldiers Type Chiral Amplification of Helical Aryl Isocyanide Copolymers. Polymer Chemistry, 2020, 11, 6017-6028. L. Zhang,a Q.-B. Cao,a F. Gao,a Y.-P. Dong*b and X. - F. Li*. Self-Supported Rhodium Catalysts Based on a Microporous Metal-Organic Framework for Polymerization of Phenylacetylene and Its Derivatives. Polymer Chemistry, 2020, 11, 2904-2913. X.-L. Wu, X.-W. Yan, Z. Yang, S.-W. Zhang, Y.-P. Dong*, J.-G. Zhi* and X.- F. Li*. AliBu3: Unprecedented Main-Group Metal Catalyst for Helical-Sense- Selective Polymerization of Chiral Aryl Isocyanides and Copolymerization with Achiral Aryl Isocyanides. Mater. Chem. Front.2019, 3, 1192-1198. X.-L. Wu, P.-F. Zhang, S.-W. Zhang, Z. Yang, W.-J. Chi, G. Guo, H. Liu, Y.-P. Dong*, N.-N. Qiu*, L. Yan and X. - F. Li*. Polymerization of phenylacetylenes by binuclear rhodium catalysts with different para- binucleating phenoxyiminato linkages. Polymer Chemistry, 2019, 10, 4163- 4172. G. Guo, X.-L. Wu, X.-Q. Yan, Y. Li, X. - F. Li*, S.-W. Zhang* and N.-N. Qiu*. Unprecedentedly High Activity and/or High Regio-/Stereoselectivity of Fluorenyl-Based CGC Allyl-Type η3: η1-tert-Butyl (dimethylfluorenylsilyl) amido Ligated Rare Earth Metal Monoalkyl Complexes in Olefin Polymerization. Polymers, 2019, 5, 836. X.-W. Yan, S.-W. Zhang, P.-F. Zhang, X.-L. Wu, A. Liu, G. Guo, Y.-P. Dong* and X.- F. Li*.[Ph3C][B(C6F5)4]: A Highly Efficient Metal‐Free Single‐ Component Initiator for the Helical ‐ Sense ‐ Selective CationicCopolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides.Angewandte Chemie International Edition, 2018, 57, 8947–8952. X.-L. Wu, Z. Yang, X.-W. Yan, P.-F. Zhang, L. Wang, G. Guo, Y.-P. Dong and X. - F. Li *. Polymerization of 1-Chloro-2-Phenylacetylenes by Cationic Monoanionic Tridentate (S,S)-Bis(oxazolinylphenyl)amido-Ligated Palladium Catalysts: Is It Coordination-Insertion Mechanism? Polymer Chemistry, 2018, 9, 4856-4865. F. Gao L. Zhang C. Yu X.-W. Yan S.-W. Zhang X. - F. Li *. Controlled Polymerization of Isoprene with Chromium ‐ Based Metal ‐ Organic Framework Catalysts: Switching from Cyclic to cis ‐ 1,4 ‐ Selectivity Depending on Activator. Macromolecular Rapid Communications, 2018, 39, 1800002 D.-Q. Peng, X.-W. Yan, S.-W. Zhang*, X. - F. Li *. Polymerization of Styrene and Copolymerization with Ethylene Catalyzed by Chiral Half-sandwich Rare-earth Metal Dialkyl Complexes. Chinese Journal of Polymer Science, 2018, 36, 222-230. C. Yu, P.-F. Zhang, F. Gao, S.-W. Zhang* and X.- F. Li*. A Displacement-type Fluorescent Probe Reveals Active Species in the Coordinative Polymerization of Olefins. Polymer Chemistry, 2018, 9, 603–610. X.-W. Yan, S.-W. Zhang, D.-Q. Peng, P.-F. Zhang, J.-G. Zhi, X.-L.Wu, L. Wang, Y.-P. Dong * and X. -F. Li *. Cationic Half-sandwich Rare-earth Metal Alkyl Species Catalyzed Polymerization Copolymerization of Aryl Isocyanides Possessing Polar, Bulky, or Chiral Substituents. Polymer Chemistry, 2018, 9, 984–993. X.-Q. Yan, F.-Z. Yang*, G.-L. Cai, Q.-W. Meng, and X. - F. Li*. Nickel(0)- Catalyzed Inert C-O Bond Functionalization: Organo Rare-Earth Metal Complex as the Coupling Partner. Organic Letters, 2018, 20, 624-627. P.-F. Zhang, H.-Y. Liao, H.-H. Wang, X.- F. Li *. F.-Z. Yang*, and S.-W. Zhang*. Cis-1,4-Polymerization of Isoprene Catalyzed by 1,3-Bis(2- pyridylimino)isoindoline-Ligated Rare-Earth-Metal Dialkyl Complexes .Organometallics, 2017, 36, 2446–2451. C. Yu, D.-H. Zhou, X.-Q. Yan, F. Gao, L. Zhang, S.-W. Zhang* and X. - F. Li *. Cis-1,4-Polymerization of Isoprene by 1,3- Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. Polymers, 2017, 9, 531-542. F.-Z. Yang, X. - F. Li *. Novel Cationic Rare Earth Metal Alkyl Catalysts for Precise Olefin Polymerization. Journal of Polymer Science, Part A: Polymer Chemistry. 2017, 55, 2271–2280. Y. Tian, X. - F. Li *, J.-B. Shi, B. Tong, Y.-P. Dong*. Monomer-induced Switching of Stereoselectivity and Limitation of Chain Growth in the Polymerization of Amine-containing Para-substituted Phenylacetylenes by [Rh(norbornadiene)Cl]2. Polymer Chemistry, 2017, 8, 5761-5768. Y.-D. Huang, J.-Y He, Z.-X. Liu, P.-F. Zhang, G.-L. Cai, S.-W. Zhang, and X. - F. Li *. A Highly Active Chiral (S, S)-Bis(oxazoline) Pd(II) Alkyl Complex/Activator Catalytic System for Vinyl Polymerization of Norbornene in Air and Water. Polymer Chemistry, 2017, 8, 1217-1222. Y.-D. Huang, J.-Y. He, G.-L. Cai, Z.-X. Liu, T.-T. Li, T.-T. Du, S.-W. Zhang, B. Yao, and X. - F. Li *. cis-1,4-Specific Carbocationic Polymerization and Copolymerization of 1,3-Dienes Initiated by (S,S)- Bis(oxazolinylphenyl)amine Chromium Complexes. Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55, 1250–1259. G.-X. Du, X.-W. Yan, P.-F. Zhang, H.-H. Wang, Y.-P. Dong, X.- F. Li*. 1,4-Specific Copolymerization of 1,3-Cyclohexadiene with Isoprene and Their Terpolymerization with Styrene by Cationic Half-Sandwich Fluorenyl Rare Earth Metal Alkyl Catalysts, Polymer Chemistry, 2017, 8, 698-707. P.-F. Zhang, H.-H. Wang, X.-S. Shi, X.-W. Yan, X.-L. Wu, S.-W. Zhang, B. Yao, X. Feng, J.-G. Zhi, X.- F. Li* , B. Tong, J.-B. Shi, L. Wang, Y.-P. Dong*. On-Water Polymerization of Phenylacetylene Catalyzed by Rh Complexes Bearing Strong π-Acidic Dibenzo[a,e]cyclooctatetraene Ligand. Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55, 716–725, Special Issue for Prof. Ben Zhong Tang. G.-L. Cai, Y.-D. Huang, T.-T. Du, S.-W. Zhang, B. Yao*, X.- F. Li*, Palladium-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Homoleptic Rare- Earth Metal Trialkyl Complexes with Aryl Bromides: Efficient Synthesis of Functionalized Benzyltrimethylsilanes, Chemical Communications, 2016, 52, 5425-5427. G.-l. Cai, Z.-B. Zhou, W.-C. Wu, B. Yao,* S.-W. Zhang, X. - F. Li*. Pd- Catalyzed C(sp3)–C(sp2) Cross-Coupling of Y(CH2SiMe3)3(THF)2 with Vinyl Bromides and Triflates, Organic & Biomolecular Chemistry, 2016, 14, 8702– 8706. D.-Q. Peng, X.-W. Yan, C. Yu, S.-W. Zhang, X.- F. Li* . Transition Metal Complexes Bearing Tridentate Ligands for Precise Olefin Polymerization, Polymer Chemistry, 2016, 7, 2601–2634. D.-Q. Peng, G.-X. Du, P.-F. Zhang, B. Yao, X.- F. Li*, S.-W. Zhang*. Regio- and Stereochemical Control in Ocimene Polymerization by Half-Sandwich Rare-Earth Metal Dialkyl Complexes, Macromolecular Rapid Communications, 2016, 37, 987-992. G.-X. Du, Y.-Y. Long, J.-P. Xue, S.-W. Zhang, Y.-P. Dong, X. - F. Li*. 1,4-Selective Polymerization of 1,3-Cyclohexadiene and Copolymerization with Styrene by Cationic Half-Sandwich Fluorenyl Rare Earth Metal Alkyl Catalysts, Macromolecules, 2015, 48, 1627-1635. G.-X. Du, J.-P. Xue, D.-Q. Peng, C. Yu, H.-H. Wang, Y.-N. Zhou, J.-J. Bi, S.-W. Zhang, Y.-P. Dong, X. - F. Li*. Copolymerization of Isoprene with Ethylene Catalyzed by Cationic Half-Sandwich Fluorenyl Scandium Catalysts, Journal of Polymer Science, Part A: Polymer chemistry, 2015, 53, 2898–2907. S.-Q. Liu, G.-X. Du, J.-Y. He, Y.-Y. Long, S.-W. Zhang*, X.- F. Li*. Cationic Tropidinyl Scandium Catalyst: A Perfectly Acceptable Substitute for Cationic Half-Sandwich Scandium Catalysts in cis-1,4-Polymerization of Isoprene and Copolymerization with Norbornene, Macromolecules, 2014, 47, 3567-3573. H. Liu, J.-Y. He, Z.-X. Liu, Z.-G. Lin, G.-X. Du, S.-W. Zhang,* and X.- F. Li *. Quasi-Living trans-1,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Bearing a Chiral (S,S)- Bis(oxazolinylphenyl)amido Ligand, Macromolecules 2013, 46, 3257-3265. 以第一作者发表的代表性论文 (2004-2010) X. - F. Li , Z.-M. Hou*. Scandium-Catalyzed Regio- and Stereospecific cis- 1,4-Polymerization of 1,3-Cyclohexadiene and Copolymerization with Ethylene, Macromolecules, 2010, 43, 8904-8909. X. - F. Li, M. Nishiura, L.-H. Hu, K. Mori, Z.-M. Hou*. Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls, Journal of the American Chemical Society, 2009, 131, 13870-13882. X. - F. Li , Z.-M. Hou*. Organometallic Catalysts for Copolymerization of Cyclic Olefins, Coordination Chemistry Reviews, 2008, 252, 1842-1869. X. - F. Li, M. Nishiura, K. Mori, T. Mashiko, Z.-M. Hou*. Cationic Scandium Aminobenzyl Complexes. Synthesis, Structure and Unprecedented Catalysis of Copolymerization of 1-Hexene and Dicyclopentadiene, Chemical Communications, 2007, 40, 4137-4139. X. - F. Li, J. Baldannis, M. Nishiura, O. Tardif, Z.-M. Hou*. Cationic Rare- Earth Polyhydrido Complexes: Synthesis, Structure, and Catalytic Activity for the cis-1,4-Selective Polymerization of 1,3-Cyclohexadiene, Angewandte Chemie International Edition, 2006, 45：8184-8188. X. - F. Li , J. Baldamus, Z.-M. Hou*. Alternating Ethylene-Norbornene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes, Angewandte Chemie International Edition, 2005, 44, 962-965. X. - F. Li , Z.-M. Hou*. Scandium-Catalyzed Copolymerization of Ethylene with Dicyclopentadiene and Terpolymerization of Ethylene, Dicyclopentadiene, and Styrene, Macromolecules, 2005, 38, 6767-6769. X. - F. Li, K. Dai, W.-P. Ye, L. Pan, Y.-S. Li*. New Titanium Complexes with Two Beta-Enaminoketonato Chelate Ligands: Syntheses, Structures, and Olefin Polymerization Activities, Organometallics, 2004, 23, 1223-1230.