个人简介

曹志海，浙江余杭人，工学博士，教授，博士生导师。分别于2002年、2005年及2009年，在浙江大学化工系取得工学学士、工学硕士和工学博士学位，三次获得浙江大学和浙江省优秀毕业生称号。攻读博士期间，在国家留学基金委资助下，赴法国国家科研中心里昂一大聚合化学与过程实验室交流学习一年，师从有机-无机杂化材料领域的国际知名学者Bourgeat-Lami E.研究员。 2009年6月，赴德国乌尔姆大学化学系从事博士后研究工作，合作导师为细乳液聚合领域的国际级权威Landfester K.教授和Ziener U.教授。2010年12月回国，任职于杭州师范大学材料与化学化工学院。2014年10月调入浙江理工大学。 目前，以第一或通讯作者身份在Macromolecules、Nanoscale、Polymer Chemistry、Advances in Colloid and Interface Science、Langmuir、Journal of Polymer Science, Part A: Polymer Chemistry等国内外期刊上发表SCI/EI收录论文50余篇，获得国家发明专利10项。主持国家自然科学基金面上和青年项目、省自然科学基金、省公益性技术应用研究计划、企业横向等多个项目。担任浙江省自然科学基金项目、Nanoscale、JMC、Langmuir、Polymer Chemistry、Dyes and Pigments等众多国内外期刊的评审人。 指导大学生获得国家大学生创新计划3项，浙江省新苗计划4项。指导研究生获校和学科优秀硕士学位培育基金3项，指导完成浙江省优秀硕士学位论文1篇，校优秀硕士学位论文3篇，研究生获包括国家奖学金在内的各种奖项多次。 科研项目： 1. 多重响应性纳米水凝胶杂化网络结构的调控及其基因药物控释性能, 国家自然科学基金(面上项目), 2016~2019, 76.4万, 项目负责人. 2. 反相细乳液界面自由基聚合制备窄分布环境响应型聚合物纳米胶囊的研究，国家自然科学基金(青年基金), 2011~2013, 20万, 项目负责人. 3. 有机颜料的自粘纳胶囊化改性关键技术研发及示范, 浙江省公益性技术应用研究计划项目/省科技计划项目, 2015~2016, 15万, 项目负责人. 4. 双荧光示踪技术研究无机粒子参与的细乳液聚合过程中纯聚合物粒子的形成机制，浙江省自然科学基金，2016~2018，9万，项目负责人. 5. 2017年浙江省高校中青年学科带头人，30万，负责人. 6. 2018年入选湖州市“南太湖精英计划”项目，20万，负责人. 7. 企业委托项目多项. 专利 1. 曹志海, 徐畅, 戚栋明, 一种油溶性引发剂引发的细乳液聚合制备聚集诱导发光型聚合物荧光纳米粒子的方法, (申请号: 2015100184832, 申请公布日: 2015年5月20日). 2. 曹志海, 徐畅, 戚栋明, 一种水溶性引发剂引发的细乳液聚合制备聚集诱导发光型聚合物荧光纳米粒子的方法, (申请号: 2015100187313, 申请公布日:2015年5月20日). 3. 曹志海, 一种贵金属-二氧化钛纳米复合粒子的制备方法, (专利号: ZL 201310409136.3, 授权公告日: 2015年5月13日). 4. 曹志海, 一种中空无机亚微米粒子的制备方法, (专利号: ZL201210591652.8, 授权公告日: 2015年4月1日). 5. 曹志海, 一种无机亚微米胶囊的制备方法, (专利号: ZL201210028778.4, 授权公告日: 2014年2月9日). 6. 单国荣, 曹志海, 以小分子烃为模板制备温敏性纳米微胶囊的方法, (专利号: ZL200710069316.6, 授权公告日: 2009年7月15日). 7. 单国荣, 曹志海, 一种制备温敏性有机-无机杂化纳米微胶囊的方法, (专利号: ZL200710069317.0, 授权公告日: 2009年7月15日). 8. 单国荣, 曹志海, 一步法制备无机纳米微胶囊的方法, (专利号: ZL 200710160376.9, 授权公告日: 2010年6月16日). 9.

研究领域

1、(细)乳液聚合机理及应用研究； 2、功能微/纳材料的结构设计、可控合成及应用； 3、功能纺织助剂开发及其应用评价。

近期论文

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43. Hu, Y. X.; Liang, X. Q,; Wu, D. L.; Yu, B.; Wang, Y. J.; Mi, Y. F.; Cao, Z. H.(曹志海)*; Zhao, Z. J., Towards white-light emission of fluorescent polymeric nanoparticles with a single luminogen possessing AIE and TICT properties, J. Mater. Chem. C, 2020, 8, 734-741. 42. Gao, F.; Wu, X. L.; Wu, D.; Yu, J. X.; Yao, J.; Qi, Q.; Cao, Z. H.(曹志海)*; Cui, Q. M.; Mi, Y. F. Preparation of degradable magnetic temperature- and redox-responsive polymer/Fe3O4 nanocomposite nanogels in inverse miniemulsions for loading and release of 5-fluorouracil, Colloids Surf., A, 2020, 587, 124363. 41. Gao, F.; Mi, Y. F.; Wu, X. L.; Yao, J. Qi, Q.; Cao, Z. H.(曹志海)* Preparation of thermoresponsive poly(N-vinylcaprolactam-co-2-methoxyethyl acrylate) nanogels via inverse miniemulsion polymerization, J. Appl. Polym. Sci. 2019, 48237. 40. Hu, Y. X.; Liang, X. Q.; Zhuang, Z. Y.; Cao, Z. H.(曹志海)*; Qi, Q.; Wang, Y. J.; Mi, Y. F.; Zhao, Z. J.; Cui, Q. M. Cell-penetrating peptide modified AIE polymeric nanoparticles by miniemulsion polymerization and application for cell fluorescence imaging, Polym. Chem. 2019, 10, 4220-4228. 39. Yao, J.; Gao, F.; Liang, X. Q.; Li, Y. X.; Mi, Y. F.; Qi, Q.; Yao, J.; Cao, Z. H.(曹志海)* Efficient Preparation of carboxyl-functionalized magnetic polymer/Fe3O4 nanocomposite particles in one-pot miniemulsion systems, Colloids Surf., A, 2019, 570, 449-461. 38. Liang, X. Q.; Hu, Y. X.; Cao, Z. H.(曹志海)*; Xiao, L. S.; Lou, J. J.; Liu, L.; Wang, Y. J.; Zhao, Z. J.; Qi, D. M.; Cui, Q. M. Efficient synthesis of high solid content emulsions of AIE polymeric nanoparticles with tunable brightness and surface functionalization through miniemulsion polymerization, Dye Pigm., 2019, 163, 371-380. 37. Liang, X. Q.; Hu, Y. X.; Lou, J. J.; Cao, Z. H.(曹志海)*; Liu, L.; Wang, Y. J.; Zhao, Z. J.; Qi, D. M.; Cui, Q. M. Mechanistic investigation on fluorescence instability of AIE polymeric nanoparticles with a susceptible AIEgen prepared in miniemulsions, Dye Pigm., 2019, 160, 572-578. 36. Shang, Y.; Cao, Z. H.(曹志海)*; Chen, H. N.; Sun, Y. Y.; Yao, J.; Yang, L.; Qi, D. M.; Ziener, U. Influence of synthesis parameters on particle properties and catalytic activity of rice roll-like Au/SiO2 nanocatalysts prepared in inverse miniemulsions, Colloids Surf., A, 2018, 537, 1-12. 35. Qi, D. M.; Gao, F.; Chen, Z. J.; Cui, Z. L.; Wang, G.; Wang, N. N.; Zhang, Y. S.; Qu, G.; Cao, Z. H. (曹志海)*. Preparation of Composite Films with Controlled Dispersion State of SiO2 Nanoparticles by Using Polymer/SiO2 Nanocomposite Particles, Colloids Surf., A, 2017, 523, 106-117. 34. Cao, Z. H. (曹志海)*; Chen H. N.; Shang Y.; Zhang Y. S.; Qi D. M.; Ziener U. Easily Recyclable and Highly Active Rice Roll-Like Au/SiO2 Nanocatalysts from Inverse Miniemulsion. Colloids Surf., A, 2017, 517, 52-62. 33. Cao, Z. H. (曹志海)*; Chen Q.; Chen H. N.; Chen Z. J.; Yao J.; Zhao S. N.; Zhang Y. S.; Qi D. M. Preparation of polymeric/inorganic nanocomposite particles in miniemulsions: I. Particle formation mechanism in systems stabilized with sodium dodecyl sulfate, Colloids Surf., A, 2017, 516, 199-210. 32. Cao, Z. H. (曹志海)*; Liang, X. Q.; Chen, H. N.; Gao, M.; Zhao, Z. J.; Chen, X. L.; Xu, C.; Qu, G.; Qi, D. M.; Tang, B. Z., Bright and biocompatible AIE polymeric nanoparticles prepared from miniemulsion for fluorescence cell imaging. Polym. Chem. 2016, 7(35), 5571-5578. 31. Qi, D. M.; Liu, C. H.; Chen, Z. J.; Chen, H. N.; Huang, C. J.; Cao, Z. H.* (曹志海), Formation mechanism of guava-like polymer/SiO2 nanocompositeparticles in in situ emulsion polymerization systems. Colloids Surf. A 2016, 489, 265-274. 30. Cao, Z. H.(曹志海)*; Chen, H. N.; Zhu, S. D.; Chen, Z. J.; Xu, C.; Qi, D. M.*; Ziener, U., Inverse miniemulsion-based preparation of raspberry-like Au/SiO2 nanocomposite particles with high catalytic activity towardsreduction of p-nitrophenol. Colloids Surf., A 2016, 489, 223-233. 29. Sihler, S.; Schrade, A.; Cao, Z. H.(曹志海); Ziener, U. Inverse Pickering emulsions with droplets size below 500 nm. Langmuir 2015, 31(38), 10392-10401. 28. Cao, Z. H.* (曹志海); Xu, C.; Liang, L. H.; Zhao, Z. J.; Chen, B.; Chen, Z. J.; Chen, H. N.; Qu, G.; Qi, D. M.; Shan, G. R.; Ziener, U., A green miniemulsion-based synthesis of polymeric aggregation-induced emission nanoparticles. Polym. Chem. 2015, 6, 6378-6385. 27. Cao, Z. H. (曹志海); Chen, H. N.; Zhu, S. D.; Zhang, W. W.; Wu, X. F.; Shan, G. R.; Ziener, U.; Qi, D. M*. Preparation of Janus Pd/SiO2 Nanocomposite Particles in Inverse Miniemulsions. Langmuir 2015, 31, 4341-4350. 26. Cao, Z. H. * (曹志海); Xu, C.; Ding, X. X.; Zhu, S. D.; Chen, H. N.; Qi, D. M. Synthesis of Fragrance/Silica Nanocapsules through a Sol-Gel Process in Miniemulsions and Their Application as Aromatic Finishing Agents, Colloid Polym. Sci. 2015, 293(4), 1129-1139. 25. Qi, D. M.; Liu, C. H.; Chen, Z. J.; Dong, G. F.; Cao, Z. H.* (曹志海). In Situ Emulsion Copolymerization of Methyl Methacrylate and Butyl Acrylate in the Presence of SiO2 with Various Surface Coupling Densities, Colloid Polym. Sci. 2015, 293(2), 463-471. 24. Cui, Q. M.; Zhu, S. D.; Yan, Y. J.; Ye, Q. L.; Ziener, U. Cao, Z. H.* (曹志海) Superparamagnetic Fe3O4/Poly(N-isopropyl acrylamide) Nanocomposites Synthesized in Inverse Miniemulsions: Magnetic and Particle Properties, J. Nanosci. Nanotechnol., 2015, 15(6): 4608-4618. 23. Cao, Z. H.* (曹志海); Yang, L.; Chen, H. N.; Xu, C.; Qi, D. M.; Zhu, S. D.; Ziener, U. Preparation of Au/TiO2 Nanocomposite Particles with High Visible-Light Photocatalytic Activity in Inverse Miniemulsions, Colloid Polym. Sci., 2015, 293(1), 277-288. 22. Qi, D. M.; Cao, J.; Gao, Y. J.; Cao, Z. H.* (曹志海) Photocatalysis of Polysiloxane/titanium Sol Photocatalytic Composite Film, Acta Polym. Sin., 2015(1): 281~287. 21. Qi, D. M.; Huang, P.; Chen, Z. J.; Wu, M. H.; Cao, Z. H.* (曹志海) Inhibition and Retardation Effect of Silica Nanoparticles in in-situ Bulk Free-radical Polymerization of MMA, Acta Polym. Sin., 2015(2): 175-182. 20. Cao, Z. H.* (曹志海); Zhu, S. D.; Qu, H.; Qi, D. M.; Ziener, U.; Yang, L.; Yan, Y. J.; Yang, H. T. Preparation of visible-light nano-photocatalysts through decoration of TiO2 by silver nanoparticles in inverse miniemulsions, J. Colloid Interface Sci., 2014, 435, 51-58. 19. Qi, D. M.; Cao, Z. H.* (曹志海); Ziener, U. Recent advances in the preparation of hybrid nanoparticles in miniemulsions, Adv. Colloid Interface Sci., 2014, 211, 47-62. 18. Chen, Z. J.; Yang, L.; Yan, Y. J.; Qi, D. M.; Cao Z. H.* (曹志海) Preparation of silica capsules via an acid-catalyzed sol-gel process in inverse miniemulsions, Colloid Polym. Sci. 2014, 292(7): 1585-1597. 17. Cao, Z. H. (曹志海) *; Ziener, U. Synthesis of nanostructured materials in inverse miniemulsions and their applications, Nanoscale 2013, 5(21), 10093-10107. 16. Cao, Z. H. (曹志海) *; Yang, L.; Ye, Q. L.; Cui, Q. M.; Qi, D. M.; Ziener, U. Transition-metal salt-containing silica nanocapsules elaborated via salt-induced interfacial deposition in inverse miniemulsions as precursor to functional hollow silica particles, Langmuir 2013, 29(22), 6509-6518. 15. Cao, Z. H. (曹志海) *; Yang, L.; Yan, Y. J.; Shang, Y.; Ye, Q. L.; Qi, D. M.; Ziener, U.; Shan, G. R.; Landfester, K. Fabrication of nanogel core-silica shell and hollow silica nanoparticles via an interfacial sol–gel process triggered by transition-metal salt in inverse systems, J. Colloid Interface Sci. 2013, 406, 139-147. 14. Cao, Z. H.* (曹志海); Ziener, U., A Versatile Technique to Fabricate Capsules: Miniemulsion. Curr. Org. Chem. 2013, 17(1), 30-38. 13. Cao, Z. H.* (曹志海); Dong, L.; Li, L.; Shang, Y.; Qi, D.; Lv, Q.; Shan, G.; Ziener, U.; Landfester, K., Preparation of Mesoporous Submicrometer Silica Capsules via an Interfacial Sol-Gel Process in Inverse Miniemulsion. Langmuir 2012, 28, 7023-7032. 12. Cao, Z. H.* (曹志海); Landfester, K.; Ziener, U*. Preparation of dually, pH- and thermo-responsive nanocapsules in inverse miniemulsion. Langmuir 2012, 28(2), 1163-1168. 11. Cao, Z. H. (曹志海); Walter, C.; Landfester, K.; Wu, Z.; Ziener, U. Synthesis of silver/poly(2-hydroxyethyl methacrylate) particles via a combination of inverse miniemulsion and silver ion reduction in a “nanoreactor”, Langmuir 2011, 27 (16), 9849–9859. 10. Schrade, A.; Cao, Z. H.* (曹志海); Landfester, K.; Ziener, U*. Preparation of Raspberry-Like Nanocapsules by the Combination of Pickering Emulsification and Solvent Displacement Technique. Langmuir 2011, 27(11), 6689-6700. 9. Cao, Z. H. (曹志海); Schrade, A.; Landfester, K.; Ziener, U. Synthesis of Raspberry-Like Organic-Inorganic Hybrid Nanocapsules via Pickering Miniemulsion Polymerization: Colloidal Stability and Morphology. J. Polym. Sci., Part A: Polym. Chem. 2011, 49(11), 2382-2394. 8. Cao, Z. H. (曹志海); Wang, Z.; Herrmann, C.; Ziener, U.; Landfester, K. Synthesis of Narrowly Size-Distributed Metal Salt/Poly(HEMA) Hybrid Particles in Inverse Miniemulsion: Versatility and Mechanism. Langmuir 2010, 26(23), 18008-18015. 7. Cao, Z. H. (曹志海); Ziener, U.; Landfester, K. Synthesis of narrowly size-distributed thermosensitive poly(N-isopropylacrylamide) nanocapsules in inverse miniemulsion. Macromolecules 2010, 43(15), 6353–6360. 6. Cao, Z. H. (曹志海); Wang, Z.; Herrmann, C.; Ziener, U.; Landfester, K. Narrowly size-distributed cobalt salt containing poly(2-hydroxyethyl methacrylate) particles by inverse miniemulsion. Langmuir 2010, 26(10), 7054-7061. 5. Cao, Z. H. (曹志海); Shan, G. R.; Sheibat-Othman, N.; Putaux, J. L.; Bourgeat-Lami, E. Synthesis of oily core-hybrid shell nanocapsules through interfacial free radical copolymerization in miniemulsion: droplet formation and nucleation, J. Polym. Sci., Part A: Polym. Chem. 2010, 48(3), 593-603. 4. Cao, Z. H. (曹志海); Shan, G. R. Synthesis of polymeric nanocapsules with a crosslinked shell through interfacial miniemulsion polymerization, J. Polym. Sci., Part A: Polym. Chem. 2009, 47(6), 1522-1534. 3. Cao, Z. H. (曹志海); Shan, G. R.; Fevotte, G.; Sheibat-Othman, N.; Bourgeat-Lami, E. Miniemulsion copolymerization of styrene and γ-methacryloxypropyltrimethoxysilane: kinetics and mechanism, Macromolecules 2008, 41(14), 5166-5173. 2. Shan, G. R.; Cao, Z. H. (曹志海) A new polymerization method and kinetics for acrylamide: aqueous two-phase polymerization, J. Appl. Polym. Sci. 2009, 111, 1409-1416. (IF:1.395) 英文书章 1. Shan, G. R.; Cao, Z. H. (曹志海) Polymeric nanocapsules by interfacial miniemulsion polymerization. Miniemulsion Polymerization Technology (Chapter 5), Ed. Mittal V., M M Scrivener Press, USA, 2010, 97-138. 1. Cui, Q. M.; Dai, L. J.; Yang, L.; Ziener, U.; Cao, Z. H.* (曹志海) Synthesis of cross-linked chitosan-based nanohydrogels in inverse miniemulsion, J. Nanosci. Nanotechnol. 2013, 13(6), 3832-3840.