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个人简介

Education 1988.09 – 1991.07 Ph. D. in Inorganic Chemistry, Peking University Thesis Title: Structures and properties of rare earth polynuclear complexes Thesis Advisor: Professor XU Guang-Xian (徐光宪) 1985.09 – 1988.07 M. Sc. in Inorganic Chemistry, Peking University Thesis Title: Countercurrent extraction theory & its application on rare earth separation Thesis Advisor: Professor XU Guang-Xian (徐光宪) and Biao-Guo LI (李标国) 1981.09 – 1985.07 Bc. S. in Chemistry, Peking University Thesis Title: Synthesis and structure of rare earth complexes of amino acids Thesis Advisor: Professor JIN Tian-Zhu (金天柱) Professional Positions 2016.06 - Vice President, China Association for Science and Technology (CAST, 中国科学技术协会) 2013.09 - Vice President, Provost of Peking University 2013.04 - Provost, Peking University 2002.09 - Cheung Kong Professor (长江教授), College of Chemistry and Molecular Engineering, Peking University 1999.09 - Professor, College of Chemistry and Molecular Engineering, Peking University 2011.01 - 2011.02 Visiting Professor, the National University of Singapore 2006.06 - 2010.11 Dean, College of Chemistry and Molecular Engineering, Peking University 2005.05 - present Deputy Director, Beijing National Laboratory for Molecular Sciences 2002.05 - 2006.05 Deputy Dean, College of Chemistry and Molecular Engineering, Peking University 1998.09 - 1999.01 Croucher Visiting Professor, the University of Hong Kong 1995.05 - 1997.01 Humboldt Research Fellow, Inst. Inorg. Chem., RWTH Aachen 1992.07 - 1999.07 Associate Professor, College of Chemistry and Molecular Engineering, Peking University 1988.07 - 1992.07 Lecturer, Department of Chemistry, Peking University

研究领域

Magnetic ordered coordination polymers, molecular nanomagnets, and multifunctional molecular materials.

近期论文

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Yang, K.+, Sun, R.+, Zhao, J., Deng, C., Wang, B.*, Gao, S.; Huang, W.*, A Combined Synthetic, Magnetic, and Theoretical Study on Enhancing Ligand-Field Axiality for Dy(III) Single-Molecule Magnets Supported by Ferrocene Diamide Ligands. Inorganic Chemistry, 2023, 62 9892-9903. DOI : 10.1021/acs.inorgchem.3c00896 Huang, H., Sun, R., Wu, X.-F., Liu, Y., Zhan, J.-Z., Wang, B.-W.*, Gao, S.* Circularly polarized luminescence and magneto-optic effects from chiral Dy(iii) single molecule magnets, Dalton Transactions, 2023, 52, 7646-7651. DOI:10.1039/D3DT00625E Pan, F., Sun, R., Wang, B.-W.*, Gao, S*. Adaptability to Crystal Fields in a Series of COT/Monodentate Ligand-Based Dy and Er Single Ion Magnets, Inorganic Chemistry, 2023, 62, 8010-8018. DOI: 10.1021/acs.inorgchem.3c00922 Sun, R.+, Wang, C.+, Wang, B.-W.*, Wang, Z.-M., Chen, Y.-F., Tamm, M., Gao, S*. Low-coordinate bis(imidazolin-2-iminato) dysprosium(iii) single-molecule magnets, Inorganic Chemistry Frontiers, 2023, 10, 485-492. DOI: 10.1039/d2qi02180c Liu, C.-M.*+, Sun, R.+, Wang, B.-W., Hao, X., Li, X.-L. Effects of Counterions, Coordination Anions, and Coordination Solvent Molecules on Single-Molecule Magnetic Behaviors and Nonlinear Optical Properties of Chiral Zn2Dy Schiff Base Complexes, Inorganic Chemistry, 2022, 61, 18510-18523. DOI : 10.1021/acs.inorgchem.2c02743 Fu, P.-X.+, Zhou, S.+, Liu, Z., Wu, C.-H., Fang, Y.-H., Wu, Z.-R., Tao, X.-Q., Yuan, J.-Y., Wang, Y.-X., Gao, S., Jiang, S.-D.*, Multiprocessing Quantum Computing through Hyperfine Couplings in Endohedral Fullerene Derivatives, Angewandte Chemie (International ed. in English), 2022, e202212939-e202212939. DOI : 10.1002/anie.202212939. Fang, Y.-H.+, Liu, Z.+, Zhou, S.+, Fu, P.-X., Wang, Y.-X., Wang, Z.-Y., Wang, Z.-M., Gao, S. Jiang, S.-D.*, Spin-Electric Coupling with Anisotropy-Induced Vanishment andEnhancement in Molecular Ferroelectrics, Journal of the American Chemical Society 2022, 144 (19), 8605-8612. doi.org/10.1021/jacs.2c00484 Sun, A.-H.+, Liu, X.-X.+, Sun, R., Xiong, J., Sun, H.-L.*, Gao, S.*, The rational construction of diamond-like dysprosium-hexacyanometallate frameworks featuring dynamic magnetic behaviour. Inorganic Chemistry Frontiers 2022, 9 (2), 231-240. DOI: 10.1039/d1qi01173a Ai, Y.+, Sun, R.+, Liao, W.-Q., Song, X.-J., Tang, Y.-Y., Wang, B.-W., Wang, Z.-M.*, Gao, S.. Xiong, R.-G.*, Unprecedented Ferroelectricity and Ferromagnetism in a Cr2+ -Based Two-Dimensional Hybrid Perovskite. Angewandte Chemie (International ed. in English) 2022, e202206034-e202206034. doi.org/10.1002/anie.202206034 Yuan, Q., Meng, Y. S., Zhang, Y. Q., Gao, C., Liu, S. S., Wang, B. W.*, Gao, S.*, Synthesis and structures of fluoride-bridged dysprosium clusters: influence of fluoride ions on magnetic relaxation behaviors. Inorganic Chemistry Frontiers 2022, 9 (10), 2336-2342. DOI: 10.1039/d1qi01422f Zhou, S.+, Yuan, J.+, Wang, Z.-Y., Ling, K., Fu, P.-X., Fang, Y.-H., Wang, Y.-X., Liu, Z., Porfyrakis, K.*, Briggs, G. A. D., Gao, S.; Jiang, S.-D.*, Implementation of Quantum Level Addressability and Geometric Phase Manipulation in Aligned Endohedral Fullerene Qudits. Angewandte Chemie-International Edition 2022, 61 (8). DOI: 10.1002/anie.202115263 Fang, Y.+, Sun, R.+, Sun, A.-H., Sun, H.-L.*, Gao, S.* The construction of dynamic dysprosium-carboxylate ribbons by utilizing the hybrid-ligand conception, Dalton Transactions, 2021, 50, 1246-1252. DOI: 10.1039/d0dt03589k Wang, Y.-X., Liu, Z., Fang, Y.-H., Zhou, S.*, Jiang, S.-D.*, Gao, S., Coherent manipulation and quantum phase interference in a fullerene-based electron triplet molecular qutrit. Npj Quantum Information, 2021, 7 (1). DOI: 10.1038/s41534-021-00362-w Ai, Y.+, Sun, R.+, Zeng, Y.-L., Liu, J.-C., Tang, Y.-Y., Wang, B.-W., Wang, Z.-M., Gao, S.*; Xiong, R.-G.*, Coexistence of magnetic and electric orderings in a divalent Cr2+-based multiaxial molecular ferroelectric. Chemical Science, 2021, 12 (28), 9742-9747. DOI: 10.1039/d1sc01871j Xiao, Y.+, Sun, R.+, Liang, J., Fang, Y., Liu, Z., Jiang, S., Wang, B.*, Gao, S.; Huang, W.*, Homoleptic tris(6,6 '-dimethyl-2,2 '-bipyridine) rare earth metal complexes. Inorganic Chemistry Frontiers, 2021, 8 (10), 2591-2602. DOI: 10.1039/d1qi00240f Xiong, L.-H., Zhao, T.-M., Wang, B.-W., Wang, Z.-M.*; Gao, S., Neutral polar hybrid perovskites of (CH3)(2)SO RE(HCOO)(3) (RE = Lu and Y): Phase transitions driven by transformation of weak C-HO interactions. Apl Materials, 2021, 9 (2). DOI: 10.1063/5.0038907 Xu, Q., Zhang, R., Zhang, H., Jin, G.-Q., Wang, B.-W., Zhu, M., Zhang, J., Gao, S.; Zhang, J.-L., Porpholactam-cinnamaldehyde conjugates for promoting ROS generation in photodynamic therapy. Journal of Porphyrins and Phthalocyanines, 2021, 25 (10N12), 1111-1118. DOI: 10.1142/s1088424621501054 Zhuo, W., Tian, Y.-M., Chen, P., Sun, W.-B., Wang, B.-W.; Gao, S., A series of counter cation-dependent tetra beta-diketonate mononuclear lanthanide(iii) single-molecule magnets and immobilization on pre-functionalised GaN substrates by anion exchange reaction. Journal of Materials Chemistry C, 2021, 9 (21), 6911-6922. DOI: 10.1039/d1tc01263k Liu, J., Li, J., Xu, Z., Zhou, X., Xue, Q., Wu, T. H., Zhong, M. J., Li, R. N., Sun, R., Shen, Z. Y., Tang, H., Gao, S., Wang, B. W., Hou, S. M.; Wang, Y. F., On-surface preparation of coordinated lanthanide-transition-metal clusters. Nature Communications, 2021, 12 (1). DOI: 10.1038/s41467-021-21911-z Liu, C.-M., Sun, R., Hao, X.; Wang, B., Chiral Co-Crystals of (S)- or (R)-1,1 '-Binaphthalene-2,2 '-diol and Zn2Dy2 Tetranuclear Complexes Behaving as Single-Molecule Magnets. Crystal Growth & Design, 2021, 21 (8), 4346-4353. DOI: 10.1021/acs.cgd.1c00246 Ji, X.-Q., Sun, R., Xiong, J., Sun, H.-L.. Gao, S., Tuning the dynamic magnetic behaviour and proton conductivity via water-induced reversible single-crystal to single-crystal structural transformation. Journal of Materials Chemistry C 2021, 9 (44), 15858-15867. DOI: 10.1039/d1tc03920b Peng, M., Wu, X.-F., Wang, L.-X., Chen, S.-H., Xiang, J., Jin, X.-X., Yiu, S.-M., Wang, B.-W., Gao, S.. Lau, T.-C., Slow magnetic relaxation in high-coordinate Co(II) and Fe(II) compounds bearing neutral tetradentate ligands. Dalton Transactions 2021, 50 (42), 15327-15335. DOI: 10.1039/d1dt02575a Su, Q.-Q., Yuan, Q., Wu, X.-F., Chen, S.-H., Xiang, J., Jin, X.-X., Wang, L.-X., Wang, B.-W., Gao, S.. Lau, T.-C., Slow magnetic relaxation in structurally similar mononuclear 8-coordinate Fe(ii) and Fe(iii) compounds. Chemical Communications 2021, 57 (6), 781-784. DOI: 10.1039/d0cc07004a Liu, Z., Wang, Y.-X., Fang, Y.-H., Qin, S.-X., Wang, Z.-M., Jiang, S.-D.; Gao, S., Electric field manipulation enhanced by strong spin-orbit coupling: promoting rare-earth ions as qubits. 2020, 7 (10), 1557-1563. DOI: 10.1093/nsr/nwaa148 Meng, Y.-S., Qiao, Y.-S., Yang, M.-W., Xiong, J., Liu, T., Zhang, Y.-Q., Jiang, S.-D., Wang, B.-W.; Gao, S., Weak exchange coupling effects leading to fast magnetic relaxations in a trinuclear dysprosium single-molecule magnet. Inorganic Chemistry Frontiers, 2020, 7 (2), 447-454. DOI: 10.1039/c9qi01252d Wu, Z. Q., Wang, Z. K., Wang, B. W., Peng, C. H.; Fu, X. F., Visible-Light-Induced Living/Controlled Radical Copolymerization of 1-Octene and Acrylic Monomers Mediated by Organocobalt Complexes. Macromolecules, 2020, 53 (1), 212-222. DOI: 10.1021/acs.macromol.9b02066 Chen, S., Shang, R., Wang, B., Wang, Z.; Gao, S., An Anisotropic Diluted Magnetic Hybrid Perovskite Series of CH3NH3 CoxZn1-x(HCOO)(3). Acta Physico-Chimica Sinica, 2020, 36 (1). DOI: 10.3866/pku.Whxb201907012 Chen, S.-M., Zhang, Y.-Q., Xiong, J., Wang, B.-W.; Gao, S., Adducts of Tris(alkyl) Holmium(III) Showing Magnetic Relaxation. Inorganic Chemistry, 2020, 59 (9), 5835-5844. DOI: 10.1021/acs.inorgchem.9b03264 Meng, Y.-S., Xiong, J., Yang, M.-W., Qiao, Y.-S., Zhong, Z.-Q., Sun, H.-L., Han, J.-B., Liu, T., Wang, B.-W.; Gao, S., Experimental Determination of Magnetic Anisotropy in Exchange-Bias Dysprosium Metallocene Single-Molecule Magnets. Angewandte Chemie-International Edition, 2020, 59 (31), 13037-13043. DOI: 10.1002/anie.202004537 Ning, Y., Huo, Y., Xue, H., Du, Y., Yao, Y., Sedgwick, A. C., Lin, H., Li, C., Jiang, S.-D., Wang, B.-W., Gao, S., Kang, L., Sessler, J. L.; Zhang, J.-L., Tri-Manganese(III) Salen-Based Cryptands: A Metal Cooperative Antioxidant Strategy that Overcomes Ischemic Stroke Damage In Vivo. Journal of the American Chemical Society, 2020, 142 (22), 10219-10227. DOI: 10.1021/jacs.0c03805 Sui, Q., Li, P., Sun, R., Fang, Y.-H., Wang, L., Wang, B.-W., Gao, E.-Q.; Gao, S., Effects of Different Counter Anions on Solid-State Electron Transfer in Viologen Compounds: Modulation of Color and Piezo- and Photochromic Properties. Journal of Physical Chemistry Letters, 2020, 11 (21), 9282-9288. DOI: 10.1021/acs.jpclett.0c02690 Wang, Y., Xiong, J., Su, J., Hu, Z., Ma, F., Sun, R., Tan, X., Sun, H.-L., Wang, B.-W., Shi, Z.; Gao, S., Dy-2@C79N: a new member of dimetalloazafullerenes with strong single molecular magnetism. Nanoscale, 2020, 12 (20), 11130-11135. DOI: 10.1039/d0nr02519d Yang, Z.-S., Yao, Y., Sedgwick, A. C., Li, C., Xia, Y., Wang, Y., Kang, L., Su, H., Wang, B.-W., Gao, S., Sessler, J. L.; Zhang, J.-L., Rational design of an "all-in-one" phototheranostic. Chemical Science, 2020, 11 (31), 8204-8213. DOI: 10.1039/d0sc03368e Yin, H.-Y., Gao, J.-J., Chen, X., Ma, B., Yang, Z.-S., Tang, J., Wang, B.-W., Chen, T., Wang, C., Gao, S.; Zhang, J.-L., A Gallium(III) Complex that Engages Protein Disulfide Isomerase A3 (PDIA3) as an Anticancer Target. Angewandte Chemie-International Edition, 2020, 59 (45), 20147-20153. DOI: 10.1002/anie.202008432 Ma, F., Sun, R., Sun, A.-H., Xiong, J., Sun, H.-L.; Gao, S., Regulating the structural dimensionality and dynamic properties of a porous dysprosium coordination polymer through solvent molecules. Inorganic Chemistry Frontiers, 2020, 7 (4), 930-938. DOI: 10.1039/c9qi01440c Wang, C., Sun, R., Chen, Y., Wang, B-W., Wang, Z-M., Gao, S., Assembling High-Temperature Single-Molecule Magnets with Low-Coordinate Bis(amido) Dysprosium Unit [DyN2]+ via Cl–K–Cl Linkage, CCS Chem., 2020, 2, 362–368. DOI: 10.31635/ccschem.020.202000138 Xu, M.-X., Liu, Z., Dong, B.-W., Cui, H.-H., Wang, Y.-X., Su, J., Wang, Z., Song, Y., Chen, X.-T., Jiang, S.-D.; Gao, S., Single-Crystal Study of a Low Spin Co(II) Molecular Qubit: Observation of Anisotropic Rabi Cycles. Inorganic Chemistry, 2019, 58 (4), 2330-2335. DOI: 10.1021/acs.inorgchem.8b02685 Zhao, Y. H., Liu, S., Wang, B. W., Wang, Z. M.; Gao, S., Three New Niccolites: High-Temperature Phase Transitions, Prominent Anisotropic Thermal Expansions, Dielectric Anomalies, and Magnetism. Chemistry-a European Journal, 2019, 25 (39), 9303-9314. DOI: 10.1002/chem.201901655 Meng, Y.-S., Ouyang, Z., Yang, M.-W., Zhang, Y.-Q., Deng, L., Wang, B.-W.; Gao, S., Multiple magnetic relaxation pathways in T- shaped N- heterocyclic carbene- supported Fe(I) single-ion magnets. Inorganic Chemistry Frontiers, 2019, 6 (4), 1050-1057. DOI: 10.1039/c9qi00073a Chen, S.-M., Xiong, J., Zhang, Y.-Q., Ma, F., Sun, H.-L., Wang, B.-W.; Gao, S., Dysprosium complexes bearing unsupported Dy-III-Ge-II/Sn-II metal-metal bonds as single-ion magnets. Chemical Communications, 2019, 55 (57), 8250-8253. DOI: 10.1039/c9cc00388f Meng, Y.-S., Yang, M.-W., Xu, L., Xiong, J., Hu, J.-Y., Liu, T., Wang, B.-W.; Gao, S., Design principle of half-sandwich type erbium single-ion magnets through crystal field engineering: a combined magnetic and electronic structure study. Dalton Transactions, 2019, 48 (28), 10407-10411. DOI: 10.1039/c9dt01954e Zhao, Y.-H., Liu, S., Wang, B.-W., Wang, Z.-M.; Gao, S., Three New Niccolites: High-Temperature Phase Transitions, Prominent Anisotropic Thermal Expansions, Dielectric Anomalies, and Magnetism. Chemistry-a European Journal, 2019, 25 (39), 9303-9314. DOI: 10.1002/chem.201901655 Fang, Y., Xu, M.-X., Hul, Y.-C., Sun, H.-L., Yan, X.; Jiang, S.-D., Determination of the magnetic principal axes of a dysprosium complex with slow relaxation on a single crystal. Journal of Magnetism and Magnetic Materials, 2019, 490. DOI: 10.1016/j.jmmm.2019.165475 Ferentinos, E., Xu, M., Grigoropoulos, A., Bratsos, I., Raptopoulou, C. P., Psycharis, V., Jiang, S.-D.; Kyritsis, P., Field-induced slow relaxation of magnetization in the S=3/2 octahedral complexes trans- Co8(2)(dmf)(2) , E = S, Se: effects of Co-Se vs. Co-S coordination. Inorganic Chemistry Frontiers, 2019, 6 (6), 1405-1414. DOI: 10.1039/c9qi00135b Chen, S., Shang, R., Wang, B.-W., Wang, Z.-M.; Gao, S., Electric and magnetic transitions with 90 degrees turning of polarizations in a layered perovskite of NH4Cl (2) Ni(HCOO)(2)(NH3)(2). Apl Materials, 2018, 6 (11). DOI: 10.1063/1.5040688 Chen, X.-X., Ma, F., Xu, M.-X., Bi, J.-C., Sun, H.-L., Wang, B.-W.; Gao, S., A neutral auxiliary ligand enhanced dysprosium(iii) single molecule magnet. Dalton Transactions, 2018, 47 (22), 7395-7398. DOI: 10.1039/c8dt01102h Jin, X.-X., Chen, X.-X., Xiang, J., Chen, Y.-Z., Jia, L.-H., Wang, B.-W., Cheng, S.-C., Zhou, X., Leung, C.-F.; Gao, S., Slow Magnetic Relaxation in a Series of Mononuclear 8-Coordinate Fe(II) and Co(II) CompleXes. Inorganic Chemistry, 2018, 57 (7), 3761-3774. DOI: 10.1021/acs.inorgchem.7b03071 Chen, S.-M., Xiong, J., Zhang, Y.-Q., Yuan, Q., Wang, B.-W.; Gao, S., A soft phosphorus atom to "harden" an erbium(iii) single-ion magnet. Chemical Science 2018, 9(38), 7540-7545. DOI10.1039/c8sc01626g Meng Yinshan, Xu Ling, Xiong Jin, Yuan Qiong, Liu Tao, Wang Bing-Wu, Gao Song, Angewandte Chemie-International Edition, 2018,DOI: 10.1002/anie.201801223. Xu Mei-Xing, Meng Yin-Shan, Xiong Jin, Wang Bing-Wu, Jiang Shang-Da, Gao Song, Dalton Transactions, 2018, 47, 1966-1971

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