张文雄 - 北京大学 - 化学与分子工程学院

个人简介

2016.8 - 至今, 北京大学化学学院教授 2009.10 - 2009.12, 日本理化学研究所客座研究员 2007.10 - 2016.7, 北京大学化学学院副教授 2004.11 - 2007.9, 日本理化学研究所协力研究员 2004.1 - 2004.3, 日本北海道大学JST 研究员 2002.10 - 2004.10, 北京大学化学学院博士后 2003.1, 获南开大学理学博士学位 1999.6, 获广西师范大学理学硕士学位 1996.7, 获湖南师范大学化学教育学士学位

研究领域

稀土金属有机杂环试剂的设计、合成及反应性研究；金属催化的碳-氮键活化；基于碳二亚胺分子的化学键活化、形成新反应构建含氮杂环化合物。在研究过程中，秉承“基于机理和金属有机活性中间体的合成化学”研究理念，不仅注重新反应的发现和发展，更注重通过对反应机理的理解和认识，有目的地发现新反应。

近期论文

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Shanshan Du, Jianhao Yin, Yue Chi, Ling Xu, and Wen-Xiong Zhang.* "Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P3 Complexes". Angew. Chem. Int. Ed. 2017, 56, 15886-15890. Liang Liu, Miaomiao Zhu, Hai-Tao Yu, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Organocopper(III) Spiro Complexes: Synthesis, Structural Characterization, and Redox Transformation". J. Am. Chem. Soc. 2017, 139, 13688-13691. Baosheng Wei, Liang Liu, Wen-Xiong Zhang,* and Zhenfeng Xi. "Synthesis and Structural Characterization of Butadienyl Calcium-based Heavy Grignard Reagents and Ca4[O] Inverse Crown Ether Complex". Angew. Chem. Int. Ed. 2017, 56, 9188-9192. Wangyang Ma, Chao Yu, Yue Chi, Tianyang Chen, Lianjun Wang, Jianhao Yin, Baosheng Wei, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi. "Formation and Ligand-Based Reductive Chemistry of Bridged Bis-alkylidene Scandium(III) Complexes". Chem. Sci. 2017, 8, 6852-6856. Yongliang Zhang, Junnian Wei, Yue Chi, Xuan Zhang, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Spiro Metallaaromatics of Pd, Pt, Rh: Synthesis and Characterization". J. Am. Chem. Soc. 2017, 139, 5039-5042. Wangyang Ma, Chao Yu, Tianyang Chen, Ling Xu, Wen-Xiong Zhang,* and Zhenfeng Xi. "Metallacyclopentadienes: Synthesis, Structure and Reactivity". Chem. Soc. Rev. 2017, 46, 1160-1192. Liang Liu, Junnian Wei, Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Structure and Reaction Chemistry of Magnesium Organocuprates Derived from Magnesiacyclopentadienes and Copper(I) Salts". Angew. Chem. Int. Ed. 2016, 55, 14762–14765. Ling Xu, Yue Chi, Shanshan Du, Wen-Xiong Zhang,* and Zhenfeng Xi. "Direct Synthesis of Phospholyl Lithium from White Phosphorus". Angew. Chem. Int. Ed. 2016, 55, 9187–9190. Kunbing Ouyang, Wei Hao, Wen-Xiong Zhang,* and Zhenfeng Xi. "Transition-Metal-Catalyzed Cleavage of C–N Single Bonds". Chem. Rev. 2015, 115, 12045-12090. Yang Wang, Yue Chi, Wen-Xiong Zhang,* and Zhenfeng Xi.* "Regioselective Ring Expansion of 2,4-Diiminoazetidines via Cleavage of C–N and C(sp3)–H bonds: Efficient Construction of 2,3-Dihydropyrimidinesulfonamides". J. Am. Chem. Soc. 2012, 134, 2926-2929. Wen-Xiong Zhang, Shaoguang Zhang, and Zhenfeng Xi.* "Zirconocene and Si-tethered Diynes: A Happy Match Directed towards Organometallic Chemistry and Organic Synthesis". Acc. Chem. Res. 2011, 44, 541-551. Yang Wang, Wen-Xiong Zhang,* Zitao Wang, and Zhenfeng Xi.* "Procedure-Controlled Selective Synthesis of 5-Acyl-2-iminothiazolines and Their Selenium and Tellurium Derivatives by Convergent Tandem Annulation". Angew. Chem. Int. Ed. 2011, 50, 8122-8126. Zitao Wang, Yang Wang, Wen-Xiong Zhang,* Zhaomin Hou, and Zhenfeng Xi.* "Efficient One-Pot Synthesis of 2,3-Dihydropyrimidinthiones via Multicomponent Coupling of Terminal Alkynes, Elemental Sulfur and Carbodiimides". J. Am. Chem. Soc. 2009, 131, 15108–15109.