席振峰 - 北京大学 - 化学与分子工程学院

个人简介

1983年本科毕业于厦门大学化学系 1989年硕士研究生毕业于南京大学配位化学所、郑州大学和河南化学所（导师：金斗满研究员） 1996年博士研究生毕业于日本分子科学研究所（导师：高桥保 Tamotsu Takahashi 教授）；曾先后在河南化学研究所金斗满研究室（1983年至1992年，实研、助研）、日本北海道大学触媒化学研究所高桥保研究室（1993年至1997年，博士研究生、博士后）、日本北海道大学药学部（1997年至1998年，助理教授）学习或工作 1998年北京大学化学学院副教授 1999年北京大学化学学院教授

研究领域

本研究室目前研究兴趣集中在氮气的活化与转化，致力于实现温和条件下直接从氮气高效合成含氮有机化合物。研究内容涉及金属有机化学、配位化学、光化学、电化学、有机合成化学及催化

近期论文

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Dinitrogen activation by a titanium hydride complex supported by 2-butene ligand Xianghui Shi, Yongliang Zhang, Mingdong Zhong, Rui Feng, Yuanjin Chen, Lei Yu, Yue Wu, Junnian Wei*, Zhenfeng Xi. Inorg. Chem. Front., 2024. DOI: 10.1039/D3QI01911J. Unusual Electronic Structures of an Electron Transfer Series of [Cr(μ-η1:η1-N2)Cr]0/1+/2+Gao-Xiang Wang,* Chunxiao Shan, Wang Chen, BotaoWu, Peng Zhang, Junnian Wei,* Zhenfeng Xi, Shengfa Ye*.Angew. Chem. Int. Ed., 2024. DOI: 10.1002/anie.202315386. Inverse Sandwich Arene-Bridged Titanium Complexes Supported by a Bulky Tridentate [O, P, O] Ligand Xueli Wang, Junnian Wei*, Zhenfeng Xi*. Organometallics, 2023. DOI: 10.1021/acs.organomet.2c00627. Trisyl-based multidentate ligands: synthesis and their transition-metal complexes Zhu-Bao Yin, Junnian Wei*, Zhenfeng Xi. Dalton Trans., 2022, 51, 3431-3438. DOI: 10.1039/D2DT03320H. Dinitrogen Activation and Transformation Promoted by Rare Earth and Actinide (260) Complexes Xiao Chen, Hanhua Xu, Xianghui Shi, Junnian Wei*, Zhenfeng Xi. Acta Chimica Sinica, 2022, 80(9): 1299-1308. DOI: 10.6023/a22060253. Preparation and Characterization of a 19-Electron Ni(I) Complex Bearing a Cyclopentadienyl-Phosphine Ligand Gao-xiang Wang, Wang Chen, Xuechao Yan, Fei Xie, Junnian Wei*, Shengfa Ye*, Zhenfeng Xi. Organometallics 2022, 41, 2227-2231. DOI: 10.1021/acs.organomet.2. Synthesis of Pyrimidines from Dinitrogen and Carbon Xianghui Shi#, Qianru Wang#, Chao Qin#, Li-Jun Wu, Yuanjin Chen, Gao-Xiang Wang, Yongli Cai, Wenbo Gao, Teng He, Junnian Wei*, Jianping Guo*, Ping Chen*, Zhenfeng Xi*. Natl. Sci. Rev. 2022. DOI: 10.1093/nsr/nwac168. Synthesis and isolation of dinuclear N,C-chelate organoboron compounds bridged by neutral, anionic, and dianionic 4,4′-bipyridine via reductive coupling of pyridines Hai-Jun Li#, Rui Feng#, Xianghui Shi, Junnian Wei*, Zhenfeng Xi. Dalton Trans., 2022, 51, 15696-15702. DOI: 10.1039/D2DT02650C. Cobalt Cyclopentadienyl-Phosphine Dinitrogen Complexes Gao-Xiang Wang#, Xuechao Yan#, Jianhao Yin, Zhu-Bao Yin, Junnian Wei*, Zhenfeng Xi. Chem. Eur. J. 2022. DOI: 10.1002/chem.202202803. Dinitrogen activation by a phosphido-bridged binuclear cobalt complex Hai-Jun Li#, Rui Feng#, Gao-Xiang Wang, Junnian Wei*, Zhenfeng Xi. Dalton Trans., 2022, Advance Article. DOI: 10.1039/D2DT03320H. Synthesis and Structural Analysis of Titanium-μ-Dinitrogen Complex Supported by Di-anionic Guanidinate Ligands Botao Wu, Rui Feng, Zhu-Bao Yin, Haihan Yan, Xueli Wang, Gao-Xiang Wang, Junnian Wei*, Zhenfeng Xi*.Science China Chemistry, 2022. DOI: 10.1007/s11426-022-1490-8. Dinitrogen Activation at Cyclopentadienyl-Phosphine-Iron Complexes of Three Different Valences Gao-Xiang Wang#, Jianhao Yin#, Jiapeng Li#, Zhu-Bao Yin, Botao Wu, Junnian Wei*, Wen-Xiong Zhang, and Zhenfeng Xi* CCS Chem. 2021, 3, 308–316. A Tris-spiro Metalla-aromatic System Featuring Craig-Möbius Aromaticity Zhe Huang, Yongliang Zhang, Wen-Xiong Zhang, Junnian Wei*, Shengfa Ye*, and Zhenfeng Xi* Nat. Commun. 2021, 12, 1319. Synthesis and Reactivity of Side-Arm Phosphine Functionalized Amidinatosilylene and Amidinatogermylene-supported Nickel(0) Complexes Mingdong Zhong, Junnian Wei, Wen-Xiong Zhang, and Zhenfeng Xi* Organometallics 2021, 41, accepted. Synthesis, Structure, and Magnetic Properties of Rare-Earth Bis(diazabutadiene) Diradical Complexes Haihan Yan, Botao Wu, Yin-Shan Meng*, Wen-Xiong Zhang*, and Zhenfeng Xi Inorg. Chem. 2021, 60, 1315–1319. Dinitrogen Functionalization Affording Structurally Well-Defined Cobalt Diazenido Complex Mingdong Zhong, Xianlu Cui, Botao Wu, Gao-Xiang Wang, Wen-Xiong Zhang, Junnian Wei, Lili Zhao*, and Zhenfeng Xi* CCS Chem. 2021, 3, accepted. Mono- and Bis-Titanium Complexes Bridged by 2-Butene Tetraanion: Synthesis and Structural Characterization Chao Yu, Wang Ma, Wen-Xiong Zhang, and Zhenfeng Xi* Organometallics 2020, 39, 793–796. Inverse-Sandwich Cyclobutadiene Dinickel Complexes: Synthesis and Structural Characterization Chao Yu, Botao Wu, Zhenqiang Yang, Hui Chen, Wen-Xiong Zhang, and Zhenfeng Xi* Bull. Chem. Soc. Jpn. 2020, 93, 1314–1318. Butadienyl Diiron Complexes: Nonplanar Metalla-Aromatics Involving σ-Type Orbital Overlap Chao Yu, Mingdong Zhong, Yongliang Zhang, Junnian Wei, Wangyang Ma, Wen-Xiong Zhang, Shengfa Ye*,and Zhenfeng Xi* Angew. Chem., Int. Ed. 2020, 59, 19048–19053. Dinickelaferrocene: A Ferrocene Analogue with Two Aromatic Nickeloles Realized by Electron Back-Donation from Iron Zhe Huang, Yu Zheng, Wen-Xiong Zhang, Shengfa Ye*, Liang Deng*, and Zhenfeng Xi* Angew. Chem., Int. Ed. 2020, 59, 14394–14398. Direct Transformation of Dinitrogen: Synthesis of N-Containing Organic Compounds via N−C Bond Formation Ze-Jie Lv, Junnian Wei, Wen-Xiong Zhang, Ping Chen, Dehui Deng, Zhang-Jie Shi, and Zhenfeng Xi* Natl. Sci. Rev. 2020, 7, 1564–1583. Cyclic Bis-alkylidene Complexes of Titanium and Zirconium: Synthesis, Characterization, and Reaction Yongliang Zhang, Botao Wu, Mingdong Zhong, Wen-Xiong Zhang*, and Zhenfeng Xi* Chem. Eur. J. 2020, 26, 16472–16479. Carbodiimide-Based Synthesis of N-Heterocycles: Moving from Two Classical Reactive Sites to Chemical Bond Breaking/Forming Reaction Yang Wang*, Wen-Xiong Zhang*, and Zhenfeng Xi Chem. Soc. Rev. 2020, 49, 5810–5849. Trishomoaromatic (B3N3Ph6) Dianion: Characterization and Two-Electron Reduction Nan Li#, Botao Wu#, Chao Yu, Tianyu Li, Wen-Xiong Zhang*, and Zhenfeng Xi*Angew. Chem., Int. Ed. 2020, 59, 8868–8872. 2-Butene Tetraanion Bridged Dinuclear Samarium(III) Complexes via Sm(II)-Mediated Reduction of Electron-Rich Olefins Yu Zheng#, Chang-Su Cao#, Wangyang Ma#, Tianyang Chen, Botao Wu, Chao Yu, Zhe Huang, Jianhao Yin, Han-Shi Hu*, Jun Li, Wen-Xiong Zhang*, and Zhenfeng Xi J. Am. Chem. Soc. 2020, 142, 10705–10714. Rare-earth Metal Boroxide with Formal Triple Metal-Oxygen Orbital Interaction: Synthesis from B(C6F5)3·H2O and Radical-anion Ligated Rare-earth Metal Amides Haihan Yan#, Botao Wu#, Xiao-Kun Zhao, Chao Yu, Junnian Wei, Han-Shi Hu, Wen-Xiong Zhang*, and Zhenfeng Xi CCS Chem. 2020, 2, 2772–2781. Selective Reduction of 1,5-Diazacyclooctatetraenes: Synthesis and Structures of Aromatic Diazacyclooctatetraenyl Dianions and a 2,6-Bipyrrolinyl Dianionic Co(II) Complex Zhe Huang, Gengwen Tan, Chao Chen, Wen-Xiong Zhang, Xinping Wang and Zhenfeng Xi*Chem. Commun. 2019, 37, 71–75. Tetralithio Metalla-aromatics with Two Independent Perpendicular Dilithio Aromatic Rings Spiro-fused by One Mn Atom Yongliang Zhang, Junnian Wei, Miaomiao Zhu, Yue Chi, Wen-Xiong Zhang, Shengfa Ye*, and Zhenfeng Xi*Angew. Chem., Int. Ed. 2019, 58, 9625-9631. Isolation and Characterization of Four Phosphorus Cluster Anions P73-, P144-, P162- and P264- from the Nucleophilic Functionalization of White Phosphorus with 1,4-Dilithio-1,3-Butadienes Shanshan Du, Jingyuan Hu, Zhengqi Chai, Wen-Xiong Zhang*, and Zhenfeng Xi Chin. J. Chem. 2019, 37, 71–75. Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P64- Ligand Shanshan Du, Zhengqi Chai, Jingyuan Hu, Wen-Xiong Zhang*, and Zhenfeng Xi Chin. J. Org. Chem. 2019, 39, 2338–2342. Synthesis and Characterization of Manganese(II) Complexes Supported by Cyclopentadienyl-Phosphine Ligand Gao-Xiang Wang#, Jianhao Yin#, Jiapeng Li#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi*Inorg. Chem. Front. 2019, 6, 428-433. Indacyclopentadienes and Aromatic Indacyclopentadienyl Dianions: Synthesis and Characterization Yongliang Zhang, Zhenqiang Yang, Wen-Xiong Zhang*, and Zhenfeng Xi*Chem. Eur. J. 2019, 25, 4218-4224. Dilithio Spiro Zincacyclopentadienes and Dizinco[10]cycles: Synthesis and Structural Characterization Yongliang Zhang, Liang Liu, Tianyang Chen, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi*Organometallics 2019, 38, 2174–2178. Reversible Two-Electron Redox Reactions Involving Tetralithio/Dilithio Palladole, Platinacycle, and Dicupra[10]annulene Zhe Huang, Yongliang Zhang, Wen-Xiong Zhang*, and Zhenfeng Xi*Organometallics 2019, 38, 2807–2811. Alkaline-Earth Metallacyclic Complexes Bearing a Diborane-Bridged Tetraamide Ligand: Synthesis, Structure and Fluorescence Property Nan Li, Zifeng Zhao, Chao Yu, Botao Wu, Zuqiang Bian, Wen-Xiong Zhang*, and Zhenfeng Xi Dalton Trans. 2019, 48, 9067–9071 Synthesis and Reactivity of Asymmetric Cr(I) Dinitrogen Complexes Supported by Cyclopentadienyl-Phosphine Ligands J.apeng Li#, Jianhao Yin#, Gao-Xiang Wang#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi* Chem. Commun. 2019, 55, 9641-9644. Dinitrogen Functionalization Affording Chromium Hydrazido Complex J.anhao Yin#, Jiapeng Li#, Gao-Xiang Wang#, Zhu-Bao Yin, Wen-Xiong Zhang*, and Zhenfeng Xi* J. Am. Chem. Soc. 2019, 141, 4241-4247. Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P−C Bonds Shanshan Du#, Jimin Yang#, Jingyuan Hu, Zhengqi Chai, Gen Luo, Yi Luo*, Wen-Xiong Zhang*, and Zhenfeng Xi J. Am. Chem. Soc. 2019, 141, 6843–6847. Scandium-Promoted Direct Conversion of Dinitrogen into Hydrazine Derivatives via N-C Bond Formation Ze-Jie Lv, Zhe Huang, Wen-Xiong Zhang*, and Zhenfeng Xi* J. Am. Chem. Soc. 2019, 141, 8773–8777. Well-Defined Scandacyclopropenes: Synthesis, Structure and Reactivity Ze-Jie Lv, Zhe Huang, Jinghang Shen, Wen-Xiong Zhang*, and Zhenfeng Xi J. Am. Chem. Soc. 2019, 141, 20547–20555. The Aromatic Dianion Metalloles Junnian Wei,* Wen-Xiong Zhang, and Zhenfeng Xi* Chem. Sci. 2018, 9, 560-568. (Perspective) Lewis Acid-Promoted Ring-Contraction of 2,4,6,8-Tetrasubstituted 1,5-Diazacyclooctatetraenes to 2,4,6-Trisubstituted Pyridines Zhe Huang, Wen-Xiong Zhang, and Zhenfeng Xi* Org. Lett. 2018, 20, 485-488. Rhodium-catalyzed intramolecular carbo-silylation of alkynes via C(sp3)-Si bond cleavage Qi Yang, Liang Liu, Yue Chi, Wei Hao, Wen-Xiong Zhang* and Zhenfeng Xi* Org. Chem. Front. 2018, 5, 860-863. Selective Transformation of Well-defined Alkenyllithiums to Alkenylmagnesiums via Transmetalation Miaomiao Zhu, Liang Liu, Yongliang Zhang, Hai-Tao Yu, Wen-Xiong Zhang,* and Zhenfeng Xi* Chem. Eur. J. 2018, 24, 3186-3191. The Aromatic Dianion Metalloles Junnian Wei*, Wen-Xiong Zhang, and Zhenfeng Xi* Chem. Sci. 2018, 9, 560–568. Diversified Aggregation States of Phospholyl Lithiums Shanshan Du, Wen-Xiong Zhang*, and Zhenfeng Xi Organometallics 2018, 37, 2018–2022. Well-defined Styryl and Biphenyl Calcium Complexes from Dilithio Compounds and Calcium Iodide: Synthesis, Structure and Reactivity toward Nitrous Oxide Baosheng Wei, Wen-Xiong Zhang*, and Zhenfeng Xi*Dalton Trans. 2018, 47, 12540–12545. Magnesium Compounds: Generation and Synthetic Application Miaomiao Zhu, Liang Liu, Hai-Tao Yu, Wen-Xiong Zhang*, and Zhenfeng Xi* Chem. Eur. J. 2018, 24, 19122–19135.