范为正 - 江南大学

个人简介

2006年6月，南京工业大学理学院，应用化学专业，获理学学士学位 2008.8-2009.8 美国GlaxoSmithKline公司，访问学者 2006.9-2012.12 上海交通大学化学化工学院，应用化学专业，获工学博士学位 2013.1-至今江南大学，校聘副教授

研究领域

1. 金属催化 2. 不对称催化 3. 药物及其中间体合成工

近期论文

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1. Tao, X.; Li, W.; Ma, X.; Li, X.; Fan, W.;Xie, X.; Ayad, T.; Ratovelomanana-Vidal, V. *; Zhang, Z.* Ruthenium-Catalyzed Enantioselective Hydrogenation of Aryl-Pyridyl Ketones, J. Org. Chem.2012, 77, 612-616. 2.Li, W.; Xie, X.; Tao, X.; Ma, X.; Fan, W.;Li, X.; Zhang, Z.* RuCl2(PPh3)(3)-catalyzed chemoselective hydrogenation of β,δ-diketo acid derivatives at the β-carbonyls, RSC Advances,2012, 2, 3214-3216. 3.Li, W.; Fan, W.;Ma, X.; Tao, X.; Li, X.; Xie, X.; Zhang, Z.* Ru-catalyzed hydrogenation of 3,5-diketo amides: simultaneous control of chemo- and enantioselectivity, Chem. Commun.2012, 48, 8976-8978. 4. Ma, X.; Li, W.; Li, X.; Tao, X.; Fan, W.;Xie, X.; Ayad, T.; Ratovelomanana-Vidal, V.; Zhang, Z.* Ru-catalyzed highly chemo- and enantioselective hydrogenation of γ-halo-γ,δ-unsaturated-β-keto esters under neutral conditions, Chem. Commun.2012, 48, 5352-5354. 5. 马欣, 李万方, 范为正, 陶晓明, 李晓明, 姚莹, 诸吕锋, 陈厚和, 谢小敏, 张兆国多官能团羰基化合物的高选择性不对称氢化, 有机化学. 2012, 31, 1353-1358. 6. Fan, W.;Li, W.; Ma, X.; Tao, X.; Li, X.;Yao, Y.; *Xie, X.; Zhang, Z.* Acid-labile δ-ketal-β-hydroxy esters by asymmetric hydrogenation of corresponding δ-ketal-β-keto esters in the presence of CaCO3, Chem. Commun.2012, 48, 4247-4249. 7. Li, X.; Ma, X.; Li, W.; Tao, X.; Meng, Q.; Fan, W.;Zhang Z.* Catalytic Asymmetric Hydrogenation of Ethyl 2-(Benzo[b]thiophen-5-yl)-2-oxoacetate with Ru-SunPhos in the Formal Synthesis of T-588, Chinese Journal of Chemistry, 2012, 29, 2581-2583. 8. Fan, W.;Li, W.; Ma, X.; Tao, X.; Li, X.;Yao, Y.; Xie, X.; Zhang, Z.* Ru-Catalyzed Asymmetric Hydrogenation of γ-Heteroatom Substituted beta-Keto Esters, J. Org. Chem.2011, 76, 9444-9451. 9.Zhu, L.; Chen, H.;* Meng, Q.; Fan, W.;Xie, X.; Zhang, Z.* Highly enantioselective hydrogenation of 2-oxo-4-arybutanoic acids to 2-hydroxy-4-arylbutanoic acids, Tetrahedron, 2011, 67, 6186-6190. 10.Li, W.; Ma, X.; Fan, W.;Tao, X.; Li, X.; Xie, X, *Zhang, Z.* Ru-Catalyzed Asymmetric Hydrogenation of 3-Oxoglutaric Acid Derivatives via Solvent-Assisted Pinpoint Recognition of Carbonyls in Close Chemical Propinquity, Org. Lett.2011, 13, 3876-3879. 11.Yao, Y.; Fan, W.;Li, W.; Ma, X.; Zhu, L.; Xie, X.; Zhang, Z.* Synthesis of (S)-7-Amino-5-azaspiro[2.4]heptane via Highly Enantioselective Hydrogenation of Protected Ethyl 1-(2-Aminoaceto)cyclopropanecarboxylates, J. Org. Chem.2011, 76, 2807-2813. 12. Zhu, L.; Meng, Q.; Fan, W.;Xie, X.; Zhang, Z.* Direct Asymmetric Hydrogenation of 2-Oxo-4-arylbut-3-enoic Acids, J. Org. Chem.2010, 75, 6027-6030. 13. Ma X.; Fan W.;Li X.;YaoY.;Zhang Z.* Asymmetric Catalytic Reactions under Solvent-Free Conditions,Progress in Chemistry, 2010, 22, 1310-1340. 14. Wan, X.; Meng Q.; Zhang H.; Sun Y.; Fan W.; Zhang Z.* An Efficient Synthesis of Chiral β-Hydroxy Sulfones via Ru-Catalyzed Enantioselective Hydrogenation in the Presence of Iodine, Org. Lett.2007, 9, 5613–5616.