赵亮 - 大连理工大学

个人简介

教育经历 2008.92014.4 大连理工大学无机化学博士 2004.92008.7 大连理工大学无机非金属材料工程学士工作经历 2017.12至今大连理工大学副研究员 2014.52017.12 大连理工大学讲师 2008年获得大连理工大学学士学位，并保送精细化工国家重点实验室直接攻读博士学位（师从段春迎教授）。2011年获国家留学基金委公派资格，于美国University of Massachusetts联合培养，2014年获得大连理工大学博士学位。现为科技部创新人才推进计划创新团队、教育部“仿生识别与荧光传感”创新团队和辽宁省高水平创新创业团队青年骨干。2017年入选大连市高层次人才创新支持计划，荣获大连市青年五四奖章（集体）。2018、2021年连续入选大连理工大学星海人才培育计划。先后主持国家自然科学基金委面上项目、青年项目和中国博士后科学基金，参与承担国家自然科学基金重点项目、科技部重点基础研究发展计划（973计划）子课题以及国家重点研发计划子课题。在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nature Commun.等国际期刊上发表学术论文50余篇，申请/授权国家发明专利10余件。受邀J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem、Adv.Mater.、Coord. Chem. Rev.等国际期刊审稿人。

研究领域

1、金属-有机笼(MOPs)的可控组装及光催化与仿生催化 2、多功能金属-有机框架材料(MOFs)的构筑与仿生催化 3、功能化共价有机框架材料(COFs)的构筑与光催化研究 4、手性金属-有机笼状配合物的设计组装与不对称催化 5、金属-有机笼与天然酶超分子体系协同催化级联反应

近期论文

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Huali Wang, Yu Zhang, Guanfeng Ji, Jianwei Wei, Liang Zhao,* Cheng He, and Chunying Duan,* Reserving Electrons in Cofactor Decorated Coordination Capsules for Biomimetic Electrosynthesis of α-Hydroxy/amino Esters, J. Am. Chem. Soc., 2024, 146, doi.org/10.1021/jacs.4c08547. Zhonghe Wang, Yang Tang, Songtao Liu, Liang Zhao,* Huaqing Li, Cheng He, and Chunying Duan,* Energy Transfer-Mediated Multiphoton Excitation for Selective Oxidation of C(sp3)−H Bonds with Coordination Polymer, Nat. Commun., 2024, 15(1), 8813. Jianwei Wei, Liang Zhao,* Yu Zhang, Gang Han, Cheng He, Chong Wang, and Chunying Duan,* Enzyme Grafting with a Cofactor-Decorated Metal−Organic Capsule for Solar-to-Chemical Conversion, J. Am. Chem. Soc., 2023, 145(12), 6719−6729. Guanfeng Ji, Liang Zhao,* Jianwei Wei, Junkai Cai, Cheng He, Zenggang Du, Wei Cai, and Chunying Duan,* A Metal−Organic Framework as a Multiphoton Excitation Regulator for the Activation of Inert C(sp3)−H Bonds and Oxygen, Angew. Chem. Int. Ed., 2022, 61(2), e202114490. Junkai Cai, Liang Zhao,* Cheng He, Yanan Li, and Chunying Duan,* A Host−Guest Semibiological Photosynthesis System Coupling Artiﬁcial and Natural Enzymes for Solar Alcohol Splitting, Nat. Commun., 2021, 12(1), 5092. Liang Zhao,# Junkai Cai,# Yanan Li, Jianwei Wei, and Chunying Duan,* A Host−Guest Approach to Combining Enzymatic and Artificial Catalysis for Catalyzing Biomimetic Monooxygenation, Nat. Commun., 2020, 11(1), 2903. Jianwei Wei, Liang Zhao,* Cheng He, Sijia Zheng, Joost N. H. Reek, and Chunying Duan,* Metal−Organic Capsules with NADH Mimics as Switchable Selectivity Regulators for Photocatalytic Transfer Hydrogenation, J. Am. Chem. Soc., 2019, 141(32), 12707−12716. Liang Zhao, Jianwei Wei, Jing Zhang, Cheng He,* Chunying Duan,* Encapsulation of a Quinhydrone Cofactor in the Inner Pocket of Cobalt Triangular Prisms: Combined Light−Driven Reduction of Protons and Hydrogenation of Nitrobenzene, Angew. Chem. Int. Ed., 2017, 56(48), 15284−15288. Liang Zhao, Jianwei Wei, Junhua Lu, Cheng He,* Chunying Duan,* Renewable Molecular Flasks with NADH Models: Combination of Light−Driven Proton Reduction and Biomimetic Hydrogenation of Benzoxazinones, Angew. Chem. Int. Ed., 2017, 56(30), 8692−8696. Huaqing Li, Songtao Liu, Guanfeng Ji, Cheng He, Yefei Wang, Hui Gao, Liang Zhao* and Chunying Duan, In-Situ Exfoliation of Copper-Based Metal−Organic Framework for Boosting Synergistic Photoactivation of Inert C(sp3)−H Bonds and Oxygen, J. Mater. Chem. A, 2024, 12(30), 19069−19080. Hui Gao, Yang Tang, Songtao Liu, Cheng He, Huaqing Li, Liang Zhao,* and Chunying Duan, Eosin Y Post-Decorated Metal−Organic Framework as a Selectivity Regulator for the Alcohols Oxidation, ACS Appl. Mater. Interfaces, 2024, 16(29), 37896−37905. Lehua Zhao, Yu Zhang, Huali Wang, Jing Wang, Cheng He, Liang Zhao,* and Chunying Duan, Isolation of Copper Photocatalyst on Metal−Organic Cage for the Sulfonylation of Aryl Halides by Visible-Light Mediated C(sp2)−S Cross-Coupling, Chem. Commun., 2024, 60(53), 6805−6808. Zeming Wang, Qiang Song, Cheng He, Pengyu Feng, Liang Zhao,* and Chunying Duan, Naphthalene-Based Donor−Acceptor Covalent Organic Frameworks as Electron Distribution Regulator for Boosting Photocatalysis under Green Light Irradiation, Chem. Commun., 2024, 60(36), 4793−4796. Runbao Wang, Rong Zhang, Kun Jin, Yaming Li, Chunying Duan, Liang Zhao,* Ruthenium(II)-Catalyzed C-H Allylation of N,N-Dialkyl Thiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination, Synlett, 2024, 35, DOI: 10.1055/a-2415-3708. Guanfeng Ji, Liang Zhao,* Yang Tang, Songtao Liu, Yefei Wang, Cheng He, and Chunying Duan, Ultrathin Two-Dimensional Cerium-Based Metal−Organic Framework Nanosheet that Boosts Selective Oxidation of Inert C(sp3)−H Bond through Multiphoton Excitation, Small, 2023, 19(26), 2300597. Yu Zhang, Liang Zhao,* Jianwei Wei, Guanfeng Ji, Huali Wang, Cheng He, Lehua Zhao, and Chunying Duan,* Dye-Binding Metal−Organic Cage for Highly Efficient Multiphoton Activation of C(sp3)−H Bonds, ACS Mater. Lett., 2023, 5(8), 2263−2269. Yefei Wang, Liang Zhao,* Songtao Liu, Guanfeng Ji, Cheng He, Yang Tang, and Chunying Duan, A Mixed-Component Metal−Organic Framework for Boosting Synergistic Photoactivation of C(sp3)−H and Oxygen, ACS Appl. Mater. Interfaces, 2023, 15(13), 16744−16754. Yang Tang, Guanfeng Ji, Hanning Li, Hui Gao, Cheng He, Liang Zhao* and Chunying Duan, Ligand-Regulated Photoinduced Electron Transfer within Metal−Organic Frameworks for Efficient Photocatalysis, Inorg. Chem. Front., 2023, 10(18), 5439−5451. Jianwei Wei, Liang Zhao,* Yu Zhang, Peng Zhou, Guangzhou Liu, and Chunying Duan, Light-Switched Selective Catalysis with NADH Mimic Functionalized Metal−Organic Capsules, Chem. Commun., 2023, 59(1), 71−74. Guanfeng Ji, Liang Zhao,* Yefei Wang, Yang Tang, Cheng He, Songtao Liu, and Chunying Duan, A Binuclear Cerium-Based Metal−Organic Framework as an Artificial Monooxygenase for the Saturated Hydrocarbons Aerobic Oxidation with High Efficiency and High Selectivity, ACS Catal., 2022, 12(13), 7821−7832. Junkai Cai, Liang Zhao,* Yanan Li, Cheng He, Chong Wang, and Chunying Duan,* Binding of Dual-Function Hybridized Metal−Organic Capsule to Enzymes for Cascade Catalysis, JACS Au, 2022, 2(7), 1736−1746. Yefei Wang, Liang Zhao,* Guanfeng Ji, Cheng He, Songtao Liu, and Chunying Duan, Vanadium(VIV)-Porphyrin-Based Metal−Organic Frameworks for Synergistic Bimetallic Activation of Inert C(sp3)−H Bonds, ACS Appl. Mater. Interfaces, 2022, 14(2), 2794−2804. Yang Tang, Liang Zhao,* Guanfeng Ji, Yu Zhang, Cheng He, Yefei Wang, Jianwei Wei, and Chunying Duan, Ligand Regulated Metal−Organic Frameworks for Synergistic Photoredox and Nickel Catalysis, Inorg. Chem. Front., 2022, 9(13), 3116−3129. Liang Zhao,* Wei Cai, Guanfeng Ji, Jianwei Wei, Zenggang Du, Cheng He, and Chunying Duan, Anthraquinone-Based Metal−Organic Framework as a Bifunctional Photocatalyst for C−H Activation, Inorg. Chem., 2022, 61(25), 9493−9503. Liang Zhao,* Zenggang Du, Guanfeng Ji, Yefei Wang, Wei Cai, Cheng He, and Chunying Duan, Eosin Y-Containing Metal−Organic Framework as a Heterogeneous Catalyst for Direct Photoactivation of Inert C−H Bonds, Inorg. Chem., 2022, 61(19), 7256−7265. Yefei Wang, Zhen Zhou, Liang Zhao,* Cheng He, Wenlong Sun, and Chunying Duan,* Ir-Porphyrin-Based Metal−Organic Framework as a Dual Metalloand Photocatalyst for Inert Alkyl C(sp3)−H Bond Activation and Direct Functionalization, ACS Appl. Mater. Interfaces, 2021, 13(9), 10925−10932. Liang Zhao,* Shaoshuai Chu, Junkai Cai, Jianwei Wei, Yanan Li, Chunying Duan, Metal−Organic Triangles with NADH Mimics for Photocatalytic Hydrogen Production, Chinese J. Inorg. Chem., 2021, 37(5), 769−777. Yanan Li, Liang Zhao,* Junkai Cai, Chunying Duan, Coumarin-Based Metal−Organic Cage for Recognition of Glucosamine, Fine Chemicals, 2021, 38(10), 2004−2011. Liang Zhao, Xu Jing, Xuezhao Li, Xiangyang Guo, Le Zeng, Cheng He,* Chunying Duan, Catalytic Properties of Chemical Transformation within the Confined Pockets of Werner-Type Capsules, Coord. Chem. Rev., 2019, 378, 151−187. (Highly Cited) Junkai Cai, Liang Zhao,* Jianwei Wei, Cheng He, Saran Long, Chunying Duan,* Negatively Charged Metal−Organic Hosts with Cobalt Dithiolene Species: Improving PET Processes for Light−Driven Proton Reduction Through Host−Guest Electrostatic Interactions, Chem. Commun., 2019, 55(59), 8524−8527. Sijia Zheng, Liang Zhao*, Jianwei Wei, Cheng He, Guangzhou Liu, Chunying Duan, A New Cobalt Triangular Prism Supramolecular Flask: Encapsulation of a Quinhydrone Cofactor for Hydrogenation of Nitroarenes with High Selectivity and Efficiency, Inorg. Chem. Commun., 2019, 109, 107558. Xu Jing, Cheng He, Liang Zhao, and Chunying Duan,* Photochemical Properties of Host−Guest Supramolecular Systems with Structurally Confined Metal−Organic Capsules, Acc. Chem. Res., 2019, 52(1), 100−109.