研究领域

Coordination and Bioinorganic Chemistry/Biophysical Chemistry/Supramolecular Chemistry

Professor Raymond's research interests range from biochemistry and metals in medicine to physical inorganic chemistry. The underlying theme of the research projects is the question of metal-ligand specificity of interaction in coordination and bioinorganic chemistry.

近期论文

查看导师新发文章 （温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Tiffany A. Pham, Jide Xu and Kenneth N. Raymond, "A Macrocyclic Chelator with Unprecedented Th4+ Affinity," J. Am. Chem. Soc., 2014, ASAP. Joseph I. Pacold, David S. Tatum, Gerald T. Seidler, Kenneth N. Raymond, Xiaoyi Zhang, Andrew B. Stickrath and Devon R. Mortensen, "Direct Observation of 4f Intrashell Excitation in Luminescent Eu Complexes by Time-Resolved X-ray Absorption Near Edge Spectroscopy" J. Am. Chem. Soc., 2014, 136, 4186–4191. Courtney J. Hastings, Robert G. Bergman and Kenneth N. Raymond, "Origins of Large Rate Enhancements in the Nazarov Cyclization Catalyzed by Supramolecular Encapsulation," Chem. Eur. J. 2014, 20, 3966 – 3973. Christopher J. Chang and Kenneth N. Raymond, "Preface for the Forum on Imaging and Sensing: Probing and Utilizing the Elements of Life for Studying and Improving Health and Society," Inorg. Chem., 2014, 53, 1791–1793. Forum article for the Imaging and Sensing special issue. Chen Zhao, Qing-Fu Sun, William M. Hart-Cooper, Antonio G. DiPasquale, F. Dean Toste, Robert G. Bergman, and Kenneth N. Raymond, "Chiral Amide Directed Assembly of a Diastereo- and Enantiopure Supramolecular Host and its Application to Enantioselective Catalysis of Neutral Substrates," J. Am. Chem. Soc. 2013, 135, 18802–18805. Hemant Naikare, James Butcher, Annika Flint, Jide Xu, Kenneth N. Raymond, and Alain Stintzi, "Campylobacter jejuni ferric-enterobactin receptor CfrA is TonB3 dependent and mediates iron acquisition from structurally different catechol siderophores," Metallomics 2013, 5, 988-996. Tatsuya Fukushima, Benjamin E. Allred, Allyson K. Sia, Rita Nichiporuk, Ulla N. Andersen, and Kenneth N. Raymond, "Gram-positive siderophore-shuttle with iron-exchange from Fe-siderophore to apo-siderophore by Bacillus cereus YxeB," Proc. Natl. Acad. Sci. U.S.A. 2013, 110, 13821-13826. Benjamin E. Allred, Colin Correnti, Matthew C. Clifton, Roland K. Strong, and Kenneth N. Raymond, "Siderocalin Outwits the Coordination Chemistry of Vibriobactin, a Siderophore of Vibrio cholera," ACS Chem. Biol. 2013, 8, 1882–1887. Benjamin E. Allred, Allyson K. Sia and Kenneth N. Raymond, "Siderocalin Combats Mycobacterial Infections," in Iron Acquisition by the Genus Mycobacterium, Vol. 92, B.R. Byers, Ed., SpringerBriefs in Biometals, Springer International Publishing AG, Gewerbestrasse, 2013, pp. 53-64. Jeffrey S. Mugridge, Achim Zahl, Rudi van Eldik, Robert G. Bergman, and Kenneth N. Raymond, "Solvent and Pressure Effects on the Motions of Encapsulated Guests: Tuning the Flexibility of a Supramolecular Host," J. Am Chem. Soc. 2013, 135, 4299-4306. Michael B. Winter, Piper J. Klemm, Christine M. Phillips-Piro, Kenneth N. Raymond, and Michael A. Marletta, "Porphyrin-Substituted H-NOX Proteins as High-Relaxivity MRI Contrast Agents," Inorg. Chem. 2013, 52, 2277–2279. Allyson K. Sia, Benjamin E. Allred and Kenneth N. Raymond, "Siderocalins: Siderophore binding proteins evolved for primary pathogen host defense," Curr. Opin. Chem. Biol. 2013, 17,150-157. Z. Jane Wang, Kristen N. Clary, Robert G. Bergman, Kenneth N. Raymond, and F. Dean Toste "A Supramolecular Approach to Combining Enzymatic and Transition Metal Catalysis," Nature Chemistry 2013, 5, 100–103. Christopher M. Andolina, Piper J. Klemm, William C. Floyd, III, Jean M. J. Fréchet, and Kenneth N. Raymond, "Analysis of Lanthanide Complex Dendrimer Conjugates for Bimodal NIR and MRI Imaging," Macromolecules 2012, 45, 8982−8990. William M. Hart-Cooper, Kristen N. Clary, F. Dean Toste, Robert G. Bergman, and Kenneth N. Raymond, "Selective Monoterpene-like Cyclization Reactions Achieved by Water Exclusion from Reactive Intermediates in a Supramolecular Catalyst," J. Am. Chem. Soc. 2012, 134, 17873–17876. Tatsuya Fukushima, Allyson K. Sia, Benjamin E. Allred, Rita Nichiporuk, Zhongrui Zhou, Ulla N. Andersen, and Kenneth N. Raymond, "Bacillus cereus Iron Uptake Protein Fishes Out an Unstable Ferric Citrate Trimer," Proc. Natl. Acad. Sci. 2012, 109, 16829-16834. Featured in 10/8/12 issue of C&N. Ga-Lai Law, Christopher M. Andolina , Jide Xu, Vinh Luu, Philip X. Rutkowski, Gilles Muller, David K. Shuh, John K. Gibson, and Kenneth N. Raymond, "Circularly Polarized Luminescence of Curium: A New Characterization of the 5f Actinide Complexes," J. Am Chem Soc. 2012, 134, 15545–15549. Colin Correnti, Vera Richardson, Allyson K. Sia, Ashok D. Bandaranayake, Mario Ruiz, Yohan Suryo Rahmanto, Žaklina Kovačevic´, Matthew C. Clifton, Margaret A. Holmes, Brett K. Kaiser, Jonathan Barasch, Kenneth N. Raymond, Des R. Richardson, and Roland K. Strong, "Siderocalin/Lcn2/NGAL/24p3 Does Not Drive Apoptosis Through Gentisic Acid Mediated Iron Withdrawal in Hematopoietic Cell Lines." PLoS ONE 2012, 7, e43696. Alexandra K. Duncan, Piper J. Klemm, Kenneth N. Raymond, and Christopher C. Landry, "Silica Microparticles as a Solid Support for Gadolinium Phosphonate Magnetic Resonance Imaging Contrast Agents," J. Am. Chem. Soc. 2012, 134, 8046–8049. Piper J. Klemm, William C. Floyd III, Christopher M. Andolina, Jean M. J. Fréchet, and Kenneth N. Raymond, "Conjugation to Biocompatible Dendrimers Increases Lanthanide T2 Relaxivity of Hydroxypyridinone Complexes for Magnetic Resonance Imaging," Eur. J. Inorg. Chem. 2012, Early View. Invited for the Metal-Based MRI Probes Issue. Piper J. Klemm, William C. Floyd III, Danil E. Smiles, Jean M. J. Fréchet, and Kenneth N. Raymond, "Improving T1 and T2 Magnetic Resonance Imaging Contrast Agents through the Conjugation of an Esteramide Dendrimer to High-Water-Coordination Gd(III) Hydroxypyridinone Complexes," Contrast Media Mol. Imaging 2012, 7, 95-99.