黄汉民 - 中国科学技术大学 - 化学与材料科学学院

个人简介

2016年3月至今，教授，博导，中国科学技术大学化学系和合肥微尺度国家研究中心 2008年4月-2016年2月, 研究员，博导，国家重点实验室常务副主任，中科院兰州化学物理研究所 2004年9月-2008年3月，JSPS fellow，日本名古屋大学物质科学国际研究中心 2000年9月-2003年10月，博士，中国科学院大连化学物理研究所 1997年9月-2000年7月，硕士，华中科技大学化学系 1993年9月-1996年7月，湖北农学院，土壤化学

研究领域

本课题组主要基于金属有机化学的基本原理，开展过渡金属催化的合成方法及应用研究，着重发展惰性C-H和C-N键的活化新策略和C-C、C-N键构建新模式和新方法，在此基础上建立烃类物质和资源小分子高效转化的催化新反应。专注于反应机理的研究，从而能够更深入的了解金属催化的反应机制，获得更多的规律性认识，解决合成化学面临的基础性科学难题。近期主要开展三个方面的研究工作：（1）基于惰性C-N和C-H键活化的催化新反应及机理研究；（2）资源小分子的直接转化反应研究；（3）高效手性催化剂及不对称催化研究。

近期论文

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Yu-Hua Deng, Wen-Dao Chu, Xiang-Zhi Zhang, Xu Yan, Ke-Yin Yu, Liang-Liang Yang, Hanmin Huang, Chun-An Fan*, Cinchona Alkaloid Catalyzed Enantioselective [4+2] Annulation of Allenic Esters and in Situ Generated ortho-Quinone Methides: Asymmetric Synthesis of Functionalized Chromans, J. Org. Chem. 2017, 82, 5433-5440.. Yue Hu, Yinjun Xie, Zhiqiang Shen, and Hanmin Huang*, Palladium-Catalyzed Ring-Forming Aminoalkenylation of Alkenes with Aldehydes Initiated by Intramolecular Aminopalladation, Angew. Chem. Int. Ed. 2017, 56, 2473-2477.. Qiming Zhu*, Qinghe Yuan, Mingwei Chen, Mengping Guo, and Hanmin Huang*, Multicomponent Reactions with Cyclic Tertiary Amines Enabled by Facile C-N Bond Cleavage, Angew. Chem. Int. Ed. 2017, 56, 5101-5105.. Jinping Zhu, Bao Gao, and Hanmin Huang*, Palladium-Catalyzed Highly Regioselective Hydroaminocarbonylation of Aromatic Alkenes to Branched Amides, Org. Biomol. Chem. 2017, 15, 2910-2913.. Xiangning Chen, Bao Gao, Yijin Su, and Hanmin Huang*, Enantioselective Epoxidation of Electron-Deficient Alkenes Catalyzed by Manganese Complexes with Chiral N4 Ligands Derived from Rigid Chiral Diamines, Adv. Synth. & Catal. 2017, 359, 2535-2541.. Hui Yu, Bao Gao, Bin Hu*, and Hanmin Huang*, Charge-Transfer Complex Promoted C-N Bond Activation for Ni-Catalyzed Carbonylation, Org. Lett. 2017, 19, 3520-3523.. Han Zhou and Hanmin Huang*, 2017. 2,2′,3,3′-Tetrahydro-1S,1′S-bi-1H-Isoindole. e-EROS Encyclopedia of Reagents for Organic Synthesis. 1–2.. Lixin Li, Xibing Zhou, Bangkui Yu, and Hanmin Huang*, Palladium-Catalyzed Dehydrogenative Difunctionalization of Aminoalkenes with Aminals as Oxidants and Electrophiles, Org. Lett. 2017, 19, 4600-4603. . Yue Hu, and Hanmin Huang*, Highly Selective Construction of Medium-Sized Lactams by Palladium-Catalyzed Intramolecular Hydroaminocarbonylation of Aminoalkynes, Org. Lett. 2017, 19, 5070-5073.. Bao Gao, and Hanmin Huang*, Palladium-Catalyzed Hydroaminocarbonylation of Alkynes with Tertiary Amines via C-N Bond Cleavage, Org. Lett. 2017, 19, 6260-6263. Guiping Qin, Yong Wang, and Hanmin Huang*, Copper-Catalyzed Dehydrogenative Formal [4 + 2] and [3 + 2] Cycloadditions of Methylnaphthalenes and Electron-Deficient Alkenes, Org. Lett. 2017, 19, 6352-6355.. Yang Liu, Guoying Zhang, and Hanmin Huang*, Ni-Catalyzed Dimerization and Arylation of Diarylacetylenes with Arylboronic Acids, Org. Lett. 2017, 19, 6674-6677.. Bao Gao, Guoying Zhang, Xibing Zhou, and Hanmin Huang*, Palladium-Catalyzed Regiodivergent Hydroaminocarbonylation of Alkenes to Primary Amides with Ammonium Chloride, Chem. Sci. 2018, 9, 380-386.. Xibing Zhou(#); Guoying Zhang; Bao Gao; Hanmin Huang(*), Palladium-Catalyzed Hydrocarbonylative C−N Coupling of Alkenes with Amides, Organic Letters, 2018.03.30, 20(8): 2208~2212 . Hui Yu(#); Bin Hu(*); Hanmin Huang(*), Nickel-Catalyzed Alkylarylation of Activated Alkenes with Benzylamines via C-N Bond Activation, Chemistry - A European Journal, 2018.04.26, 24(28): 7114~7117 . Xiaolei Ji(#); Bao Gao(#); Xibing Zhou; Zongjian Liu; Hanmin Huang(*), Palladium-Catalyzed Regioselective Hydroaminocarbonylation of Alkynes to α,β-Unsaturated Primary Amides with Ammonium Chloride, The Journal of Organic Chemistry, 2018.06.28, 83(17): 10134~10141 . Peipei Liu(#); Suchen Zou(#); Bangkui Yu; Lin Li; Hanmin Huang(*), Catalyst-Free Aminomethylamination of o‑Hydroxystyrenes with Aminals to 1,3-Diamines, Organic Letters, 2018.06.07, 20(12): 3601~3604 . Xuexia Zhang(#); Hanmin Huang(*), Copper-Catalyzed Oxidative Coupling of AIBN and Ketone-Derived Enoxysilanes to γ‑Ketonitriles, Organic Letters, 2018.08.03, 20(16): 4998~5001. Cuifang Qiao(#); Anrong Chen; Bingjian Gao; Yang Liu; Hanmin Huang(*), Palladium-Catalyzed Cascade Double C—N Bond Activation: A New Strategy for Aminomethylation of 1,3-Dienes with Aminals, Chinese Journal of Chemistry, 2018.08.20, 36(10): 929~933 . Jiawen Li(#); Bo Qian; Hanmin Huang(*), Silver-Catalyzed Olefination of Acetals and Ketals with Diazoesters to β‑Alkoxyacrylates, Organic Letters, 2018.10.26, 20(22): 7090~7094. Hui Yu(#); Bin Hu(*); Hanmin Huang(*), Nickel-Catalyzed Benzylation of Aryl Alkenes with Benzylamines via C−N Bond Activation, The Journal of Organic Chemistry, 2018.10.29, 83(22): 13922~13929. Yanchen Zhang(#); Bangkui Yu; Tianze Zhang; Hanmin Huang(*), Triple-Bond Insertion Triggers Highly Regioselective 1,4-Aminomethylamination of 1,3-Enynes with Aminals Enabled by Pd-Catalyzed C-N Bond Activation, Organic Letter, 2019.01.09, 21(2): 535~539. Jiawen Li(#); Siyuan Wang; Suchen Zou; Hanmin Huang(*), Palladium-catalyzed relay hydroaminocarbonylation of alkenes with hydroxylamine hydrochloride as an ammonia equivalent, Communications Chemistry, 2019.02.01, 2(14): 1~9 . Bao Gao, Yinjun Xie, Zhiqiang Shen, Lei Yang, and Hanmin Huang*, Decarboxylative Alkylcarboxylation of α,β-unsaturated Acids Enabled by Copper-Catalyzed Oxidative Coupling, Org. Lett. 2015, 17, 4968-4971.. Guiping Qin, Lixin Li, Jiawen Li, and Hanmin Huang*, Palladium-Catalyzed Formal Insertion of Carbenoids into Aminals via C-N Bond Activation, J. Am. Chem. Soc. 2015, 137, 12490-12493.. Maorong Wang, Bao Gao, and Hanmin Huang*, Catalytic Nucleophilic Addition of Olefinic C-H Bond to α,β-Unsaturated-γ-Lactams, Tetrahedron Letters, 2015, 56, 5533-5536.. Hui Yu, Guoying Zhang, and Hanmin Huang*, Palladium-Catalyzed Dearomative Cyclocarbonylation via C-N Bond Activation, Angew. Chem. Int. Ed. 2015, 54, 10912-10916.. Cuifang, Qiao, Jianhua, Hu, and Hanmin Huang*, Lewis acid-catalyzed Difunctionalization of Enol Ethers with Aminals and Alcohols to β-Amino Acetals, Journal of Molecular Catalysis (China), 2015, 29(2), 103-110.. Guoying Zhang, Bao Gao, and Hanmin Huang*, Palladium-Catalyzed Hydroaminocarbonylation of Alkenes with Amines: A Strategy to Overcome Basicity-Barrier Imparted by Aliphatic Amines, Angew. Chem. Int. Ed. 2015, 54, 7657-7661.. Guiping Qin, Xiangning Chen, Lei Yang, and Hanmin Huang*, Copper-Catalyzed Benzylation of Enones via Radical-Triggered Oxidative Coupling of Two C-H Bonds, ACS Catal. 2015, 5, 2882-2885.. Yinjun Xie, Shengmei Guo, Longmin Wu, Chungu Xia, and Hanmin Huang*, Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN, Angew. Chem. Int. Ed. 2015, 54, 5900-5904.. Lei Yang, and Hanmin Huang*, Transition-Metal-Catalyzed Direct Addition of Unactivated C−H Bonds to Polar Unsaturated Bonds, Chem. Rev. 2015, 115(9), 3468-3517.. Guoying Zhang, Yinjun Xie, Zhengkun Wang, Yang Liu, and Hanmin Huang*, Diboron as Reductant for Nickel-Catalyzed Reductive Coupling: Rational Design and Mechanistic Studies, Chem. Comm. 2015, 51, 1850-1853..