Schrobilgen, Gary - McMaster University - Department of Chemistry & Chemical Biology

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McMaster University Department of Chemistry & Chemical Biology
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个人简介

B.S. Loras College, Iowa (Chemistry) 1967 M.Sc. Brock University (Inorganic Chemistry) 1971 Ph.D. McMaster University (Inorganic Chemistry) 1974 (defended 1973) HONOURS AND AWARDS: 1980-90 Natural Sciences and Engineering Research Council of Canada, University Research Fellowship, McMaster University 1986 International Union of Pure and Applied Chemistry, Young Scientist Travel Award 1996 President's Award for Excellence in Graduate Supervision, McMaster University (honorable mention) 1997 President's Award for Excellence in Graduate Supervision, McMaster University 1998, 1999 Canada Council Killam Research Fellow 1998 Award for Creative Work in Fluorine Chemistry, American Chemical Society 1999 Elected a Fellow of the Royal Society of Canada 1999 Recipient of the Kazuo Nakamoto Distinguished Lectureship 2002 Award for Pure or Applied Inorganic Chemistry, Canadian Society for Chemistry (for outstanding contributions to industrial or academic inorganic chemistry) 2002 Alcan Lecture Award, Canadian Society for Chemistry (for a distinguished contribution in the fields of inorganic chemistry or electrochemistry) 2003 E.W.R. Steacie, Canadian Society for Chemistry (for a distinguished contribution to chemistry) 2007 Brock University Alumni Association’s “Thirty from the Past Thirty Award” (recognizes alumni who have built upon their Brock experience and enjoyed further significant achievements through their contributions to Canada and beyond) 2010 Humboldt Forschungspreis (Senior Research Award), Alexander von Humboldt Foundation (tenured at the Albert-Ludwigs Universität, Freiburg and the Freie Unversität, Berlin) 2011 Visiting Professor, Graduate School of Energy Science, Kyoto University (sponsored by the Kyoto University Foundation), February-March, 2011. 2011 Distinguished Alumni Award in the Sciences (recognizes McMaster graduates who have attained a high level of distinction and achievement through scholarship, research, teaching, creative contributions and through service to society). 2012 Lifetime Achievement Award in Fluorine Chemistry sponsored by SciFluor (Cambridge, MA) and awarded March 24, 2012 at the 243rd National ACS Meeting, San Diego, CA. 2013 Elected a Fellow of the American Chemical Society (recognizes members of the American Chemical Society for outstanding achievements in and contributions to Science, the Profession, and the Society). 2014 Symposium honoring the lifetime achievements of Gary J. Schrobilgen entitled “Exploring the Frontiers of Fundamental and Applied Fluorine Chemistry, 248th National ACS Meeting, San Francisco, CA, August 10-14, 2014 (a 3.5 day symposium with 51 speakers from 14 countries). 2014 Distinguished Mathematics and Science Alumni Award, Brock University, St. Catharines, Ontario (recognizes Brock University graduates who have attained a high level of distinction and achievement through scholarship, research, teaching, creative contributions and through service to society).

研究领域

Our research encompasses the fluorine chemistry of the main-group and transition elements, polyatomic anions of the main-group elements and radiochemistry, which also span the extremes of oxidizing and reducing properties. The main philosophy is to target compounds that challenge current theories of stereochemistry and bonding, or those previously thought not to exist and/or those which have unusual chemical or physical properties. The chemical systems we deal with are at the fringes of stability and existence and are among the most reactive, energetic and fragile species known. Our work also exploits the synergism of theory and synthesis and greatly benefits from a diverse range of physical and spectroscopic techniques and quantum-chemical methods we use to understand structure and bonding. Our main interest is in the field of synthetic inorganic fluorine chemistry with special emphases on noble-gas chemistry and high oxidation states of the elements. Our achievements include the syntheses and structural characterizations of a significant number of the known noble-gas compounds as well as fluoro- and oxofluoro-derivatives of the main-group and transition elements in their highest oxidation states and at the limits of coordination. In a number of cases, noble-gas species have been used as synthons to generate high-oxidation state transition metal species and carbocations. Multi-nuclear magnetic resonance (NMR) and Raman spectroscopies and X-ray crystallography are routinely applied to the elucidation of the structures of highly unstable compounds. Our work has made important contributions to understanding of structure and chemical bonding, including so-called "hypervalent" species. We have also made significant contributions to the syntheses and understanding of the structures and bonding in main-group ring, cage and cluster molecules/ions of groups 13 and 14. These research contributions are of wide and fundamental interest, and are often quoted in the major textbooks of inorganic chemistry.

近期论文

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D. Brock, Jonathan J. Casalis de Pury, H.P.A. Mercier, G.J. Schrobilgen, B. Silvi, "A Rare Example of a KrF2 Coordination Compound; [BrOF2][AsF6]·2KrF2", J. Am. Chem. Soc., 2010, 132, 3533-3542 (highlighted in (1) Nature Chemistry, Research Highlights, N. Withers, "Group 18 Compounds: The Krypton Factor", 2010, 2, 342. M. Hughes, H.P.A. Mercier, G.J. Schrobilgen, "Syntheses, Raman Spectra, and X-ray Crystal Structures of [XeF5][µ-F(OsO3F2)2] and [M][OsO3F3] (M = XeF5+, Xe2F11+)", Inorg. Chem., 2010, 49, 3501-3515. M. Hughes, H.P.A. Mercier, G.J. Schrobilgen, "Syntheses and Multi-NMR Study of fac-OsO3F2(NCCH3) and mer-OsO3F2(NCCH3) and the X-Ray Crystal Structure (n = 2) and Raman Spectrum (n = 0) of fac-OsO3F2(NCCH3).nCH3CN, Inorg. Chem. 2010, 49, 4768-4780 (Inorganic Chemistry journal cover article). D. Brock, Jonathan J. Casalis de Pury, H.P.A. Mercier, G.J. Schrobilgen, B. Silvi, "XeF2 Coordination to a Main Group Center; Raman Spectra (n = 1, 2) and X-ray Crystal Structures (n = 1) of [BrOF2][AsF6]·nXeF2 and [XOF2][AsF6] (X = Cl, Br)", Inorg. Chem., 2010, 49, 6673-6689. D. Brock, H.P.A. Mercier, G.J. Schrobilgen, "An Example of an AX3YE2 VSEPR Arrangement; Syntheses and Structural Characterizations of [M][XeOF3] (M = Cs, N(CH3)4)", J. Am. Chem. Soc., 2010, 132, 10935-10943. H. Elliot, J. Lehmann, H.P.A. Mercier, H.D. Jenkins, G.J. Schrobilgen, "X-ray Crystal Structures of [XeF][MF6] (M = As, Sb, Bi), [XeF][M2F11] (M = Sb, Bi) and Estimated Thermochemical Data and Predicted Stabilities for Noble-Gas Fluorocation Salts using Volume-based Thermodynamics", Inorg. Chem., 2010, 49, 8504-8523. N. Vasdev, M.D. Moran, H.M. Tuononen, R. Chirakal, R.J. Suontamo, A.D. Bain, G.J. Schrobilgen, "NMR Spectroscopic Evidence for the Intermediacy of XeF3–; in XeF2/F–; Exchange, Attempted Syntheses and Thermochemistry of XeF3–; Salts, and Theoretical Studies of the XeF3–; Anion in the Gas-Phase and in Solution", Inorg. Chem., 2010, 49, 8997-9004. M.D. Moran, D. Brock, G.J. Schrobilgen, "Xe3OF3+, a Precursor to a Noble-Gas Nitrate; Syntheses and Structural Characterizations of FXeONO2, XeF2·HNO3, and XeF2·N2O4", J. Am. Chem. Soc., 2010, 132, 13823-13839. D.S. Brock, G.J. Schrobilgen, "The Missing Oxide of Xenon, XeO2, & Its Implications for the Earth’s Missing Xenon", J. Am. Chem. Soc., 2011, 133, 6265-6269 (Journal of the American Chemical Society journal cover article; also highlighted in: (1) Chemical & Engineering News, "The Case of the Missing Xenon", 2011, 89 (9), 10; (2) Nature, Research Highlights, "Chemistry: Where did the xenon go?", 2011, 471, 138; (3) Chemistry World, News, "Earth's missing xenon could be hiding in quartz", 2011, March); (4) Canadian Chemical News, "Xenon Dioxide May Help to Solve One of Earth’s Mysteries", 2011, May, 9; (5) Aktuel Naturvidenskab, "På Sporet af den Forsvundne Xenon", 2011, June, 6; (6) Nachrichten aus der Chemie, "XeO2, ein Edelgasoxid mit Kovalenter Netzwerstruktur". M. Hughes, D.S. Brock, H.P.A. Mercier, G.J. Schrobilgen, "A Raman Spectroscopic Study of the XeOF4/XeF2 System and the X-ray Crystal Structure of a-XeOF4·XeF2", J. Fluorine Chem., 2011, 132, 660-668. G.L. Smith, H.P.A. Mercier, G.J. Schrobilgen, "Ennobling an Old Molecule: Thiazyl Trifluoride (N=SF3), a Versatile Synthon for Xe_N Bond Formation", Inorg. Chem., 2011, 49, 12359-12373 (Forum Article). R. Betz, G.J. Schrobilgen, "The Synthesis of XeF2: a Predictable Outcome with a Significant Chemistry", Z. Anorg. Allg. Chem., 2012, 638, 1385-1388. D.S. Brock, H.P.A. Mercier, G.J. Schrobilgen, "[H(OXeF2)n][AsF6] and [FXeII(OXeIVF2)n][AsF6] (n = 1, 2); Examples of Xenon(IV) Hydroxide Fluoride and Oxide Fluoride Cations; and the Crystal Structures of [F3Xe---FH][Sb2F11] and [H5F4][SbF6]·2[F3Xe---FH][Sb2F11]", J. Am. Chem. Soc., 2013, 135, 5089-5104. M.V. Ivanova, T. Kochner, H.P.A. Mercier, G.J. Schrobilgen, "The Synthesis and Lewis Acid Properties of ReO3F; the X-ray Crystal Structures of FO3Re(FH)2·HF and [N(CH3)4]2[µ3-O(FReO3)3]·CH3CN", Inorg. Chem., 2013, 52, 6806-6819. I.M. Shlyapnikov, E.A. Goreshnik, H.P.A. Mercier, G.J. Schrobilgen, Z. Mazej, "Synthesis and Characterization of Imidazolium Poly[perfluorotitanate(IV)] Salts Containing the [TiF6]2–, ([Ti2F9]–)inf, [Ti2F11]3–, and the New [Ti4F20]4– and [Ti5F23]3– Anions", Inorg. Chem., 2013, 52, 8315-8326. J.R. Debackere, H.P.A. Mercier, G.J. Schrobilgen, "Noble-Gas Difluoride Complexes of Mercury(II); the Structures and Syntheses of Hg(OTeF5)2·1.5NgF2 (Ng = Xe, Kr) and Hg(OTeF5)2", J. Am. Chem. Soc., 2014, 136, 3888-3903 (also highlighted in "Anorganische Chemie 2014" Nachrichten aus der Chemie, 2015, 63, 227-255). G. Wang, M. Zhou, J. T. Goettel, G.J. Schrobilgen, J. Su, J. Li, T. Schlöder, S. Riedel " Identification of an Iridium-Containing Compound with a Formal Oxidation State of IX", Nature, 2014, 514, 475-477 (also highlighted in: (1) S. K. Ritter, "Iridium Dressed to the Nines", Chemical & Engineering News - News of the week 2014, 92, 7; (2) E. Stove, "Chemistry World: Iridium Forms Compound in +9 Oxidation State", Chemistry World News 2014, October; (3) T. Lougheed, "It's all Relative when Rewriting Oxidation States Limits", Canadian Chemical News, 2015, January/February, 21; (4) P. Pyykkö, W-H. Xu, " The Formal Oxidation States of Iridium Now Run from -III to + IX", Angew. Chem. Int. Ed. 2015, 54, 1080-1081; (5) S. K. Ritter, " Iridium Dressed to the Nines", Chemical & Engineering News, Top Chemistry Research of 2014; (6) S. Herres-Pawlis, "Oxidationsstufenrekord fur Ir", Nachrichten aus der Chemie, Notizen 2014, 62, 1159). K. Koppe, J. Haner, H.P.A. Mercier, H.-J. Frohn, G.J. Schrobilgen, "Xenon(IV)-Carbon Bond of [C6F5XeF2]+; Structural Characterization and Bonding of [C6F5XeF2][BF4], [C6F5XeF2][BF4]·2HF, [C6F5XeF2][BF4]·nNCCH3 (n = 1, 2), and the Fluorinating Properties of [C6F5XeF2][BF4]", Inorg. Chem., 2014, 53, 11640-11661 (also highlighted in "Anorganische Chemie 2014" Nachrichten aus der Chemie, 2015, 63, 227-255). J. Haner, G. J. Schrobilgen, "The Chemistry of Xenon(IV)", Chem. Rev. 2015, 115, 1255-1925. J.R. Debackere, H.P.A. Mercier, G.J. Schrobilgen, "Pentafluoro-oxotellurate(VI) Anions of Mercury(II); the Syntheses and Structures of [Hg(OTeF5)4]2-, [Hg(OTeF5)5]3-, [Hg2(OTeF5)6]2-, [Hg(OTeF5)4]2-·Hg(OTeF5)2, and [Hg2(OTeF5)7]3-·Hg(OTeF5)2", Inorg. Chem., 2015, 54, 1606-1626.

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