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Liyan Song*, Yufei Meng, Tongchao Zhao, Lifang Liu, Xiaohong Pan, Binbin Huang, Hongliang Yao, Ran Lin* and Rongbiao Tong*, Unified and Green Oxidation of Amides and Aldehydes for Hofmann and Curtius Rearrangements. Green Chem. 2023, (under revision). Liang, L.; Wang, W.; Li; M., Xu, Y.; Lu, Z.; Wei, J.; Tang, B. Z.; Sun*, F.; Tong*, R. Water-Soluble Chlorophyll Protein as Efficient Photosensitizer for Cancer Photodynamic Therapy. 2023, (submitted). Wai Fung Cheng+, Shiqiang Ma+, Yin Tung Lai, Yuen Tsz Cheung, Kornkamon Akkarasereenon, Yiqin Zhou, and Rongbiao Tong*, Bismuth-Mediated Intramolecular Aza-Prins Cyclization of Aza-Achmatowicz Rearrangement Products and Asymmetric Total Syntheses of Suaveoline and Sarpagine Alkaloids. Angew. Chem. Int. Ed., 2023, 62, e202311671. Wenjun Wang#, Foqing Ma#, Yuen Tsz Cheung, Guihua Zeng, Yiqin Zhou, Zijing Chen, Lixin Liang, Tuoping Luo*, Rongbiao Tong*, Marine Alkaloid Lepadins E and H Induce Ferroptosis for Cancer Chemotherapy. J. Med. Chem. 2023, 66, 11201-11215. DOI: 10.1021/acs.jmedchem.3c00659. Liyan Song, Gang Li, Wen Guan, Zhijun Zeng, Yanghui Ou, Jiayu Li, Dengqin He, Xiangxiang Fang, Yali Zhang, Jia-qiang Wu, Rongbiao Tong*, Hongliang Yao*. Design, synthesis, and anti-inflammatory activity study of lansiumamide analogues for treatment of acute lung injury. Biomed. Pharmacother. 2023, 166, 115412. DOI: 10.1016/j.biopha.2023.115412. Yuchen Wang, Shumin Liang, Michael Le Breton, Qiong Qiong Wang, Qianyun Liu, Chin Hung Ho, Bin Yu Kuang, Cheng Wu, Mattias Hallquist, Rongbiao Tong, Jian Zhen Yu*. Field observations of C2 and C3 organosulfates and insights into their formation mechanisms at a suburban site in Hong Kong. Sci. Total Environ. 2023, 904, 166851. Wei, W.; Cheung, K. K.; Lin, R.; Kong, L. C.; Chan, K. L.; Sung, H.; Williams*, I.; Tong*, R.; Lin*, Z.; Jia*, G. [2+2+1+1] cycloaddition for de novo synthesis of densely functionalized phenols. Angew. Chem. Int. Ed., 2023, 62, e202307251. Tao Zheng, Jun Xu,* Shaojun Cheng, Jianghai Ye, Shiqiang Ma,* Rongbiao Tong*, Green Halogenation of Indoles with Oxone-Halide. J. Org. Chem. 2023, 88, 11497-11503. DOI: 10.1021/acs.joc.3c00638. Rongbiao Tong*, The Untold Journey of Total Synthesis of Natural Products. Synlett, 2023, accepted (invited Account). Peilin Tian, Rongbiao Tong*, In-water Oxidative Suzuki Coupling of Arenes and Arylboronic Acids Using H2O2 as Terminal Oxidant. Green Chem. 2023, Accepted. Liyan Song*, Yiqin Zhou, Hanbin Liang, Hongzuo Li, Yunrong Lai, Hongliang Yao, Ran Lin* and Rongbiao Tong*, Two Green Protocols for Halogenative Semipinacol Rearrangement. J. Org. Chem. 2023, 88, 504-512. DOI: 10.1021/acs.joc.2c02496. Peilin Tian, Wenkang Ye, Xiayan Zhang, Yi Tong, Pei-Yuan Qian*, and Rongbiao Tong*. Ten-step Asymmetric Total Syntheses of Potent Antibiotics Anthracimycin and Anthracimycin B. Chem. Sci. 2022, 13, 12776-12781. DOI: 10.1039/d2sc05049h. Highlighted in Synfacts 2023, 19(01), 0090. DOI: 10.1055/s-0042-1751771. Yiting Zheng†, Yuen Tsz Cheung#, Lixin Liang†, Huiying Qiu, Lei Zhang, Anson Tsang, Qing Chen* & Rongbiao Tong*, Electrochemical Oxidative Rearrangement of Tetrahydro-β-carbolines in Zero-gap Flow Cell. Chem. Sci. 2022, 13, 10479-10485. DOI: 10.1039/D2SC03951F. Lixin Liang†, Liandong Guo†, and Rongbiao Tong*, Achmatowicz Rearrangement-inspired Development of Green Chemistry, Organic Methodology, and Total Synthesis of Natural Products. Acc. Chem. Res. 2022, 55. 2326-2340. DOI: 10.1021/acs.accounts.2c00358. Liyan Song*, Yunrong Lai, Hongzuo Li, Jipeng Ding, Hongliang Yao, Qian Su, Binbin Huang, Ming-An Ouyang, and Rongbiao Tong*, Environmentally Benign and User-friendly in situ Generation of Nitrile Imine from Hydrazone for 1,3-Dipolar Cycloaddition. J. Org. Chem. 2022, 87, 10550-10554. DOI: 10.1021/acs.joc.2c01391. Xiayan Zhang, Yi Tong, Gang Li, Hao Zhao, Guanye Chen, Hongliang Yao*, Rongbiao Tong*. [1,5]-Allyl Shift by a Sequential Achmatowicz/Oxonia‒Cope/Retro-Achmatowicz Rearrangement. Angew. Chem. Int. Ed. 2022, 61, e202205919. DOI:10.1002/anie.202205919. Chenxi He, Foqing Ma, Wei Zhang, and Rongbiao Tong,* Reinvestigating FeBr3-Catalyzed Alcohol Oxidation with H2O2: Is High-valent Iron Species (HIS) or Reactive Brominating Species (RBS) Responsible for Alcohol Oxidation? Org. Lett. 2022, 24, 3499-3503. DOI: 10.1021/acs.orglett.2c01133. Zhao*, G-D.; Wang, Y.; Wang, C.; Lei, H.; Yi, B.; Tong*, R. Fenton-like Chemistry Enables Catalytic Oxidative Desulfurization of Thioacetals and Thioketals with Hydrogen Peroxide. Green Chem. 2022, 24, 4041-4049. DOI: 10.1039/D2GC01050J. Guo, L.-D.; Xu, Z.; Tong*, R. Asymmetric Total Synthesis of Indole Diterpenes Paspalicine, Paspalinine, and Paspalinine-13-ene. Angew. Chem. Int. Ed. 2021, Accepted. DOI: 10.1002/anie.202115384. Marquez-Cadena, M. A.; Zhang*, W.; Tong*, R. Synthetic Studies toward the Berkeleyacetal Core Architecture. Org. Lett. 2021, 23, ASAP. DOI: 10.1021/acs.orglett.1c03559. Liang, L.; Zhou, S.; Zhang*, W.; Tong*, R. Catalytic Asymmetric Alkynylation of 3,4-Dihydro-beta-carbolinium Ions Enables Collective Total Syntheses of Indole Alkaloids. Angew. Chem. Int. Ed. 2021, ASAP. DOI: 10.1002/ange.202112383. Wang, Y.-C.; Tong*, R.; Yu*, J.-Z. Chemical Synthesis of Multifunctional Air Pollutants: Terpene-derived Nitroxyl Organosulfates. Environ. Sci. Tech. 2021, ASAP. DOI:10.1021/acs.est.1c00348. Zhao, G.; Wang, E.; Tong*, R. From Reactive Oxygen Species to Reactive Brominating Species: Fenton Chemistry for Oxidative Bromination. ACS Sustain. Chem. Eng., 2021, 9, 6118-6125. DOI: 10.1021/acssuschemeng.1c01709. Zhao, G.; Liang, L.; Wang, E.; Wang, Y.; Tong*, R. Fenton Chemistry for Achmatowicz rearrangement. ACS Catal. 2021, 11, 3740-3748. DOI:10.1021/acscatal.1c00219. Zhao, G.; Liang, L.; Wang, E.; Lou, S.; Qi, R.; Tong*, R. Fenton Chemistry Enables Catalytic Oxidative Rearrangement of Indoles using Hydrogen Peroxide. Green Chem. 2021, 23, 2300-2307. DOI: 10.1039/d1gc00297. Selected by editor as a 2021 HOT Green Chemistry Article. Wang, J.; Márquez-Cadena,† M. A.; Tong*, R. Asymmetric Total Syntheses of (+)-Penostatins A and C. Org. Lett. 2020, 22, 5074-5078. **Highlight in ChemBeanGo 2020-07-06. Liaw, M. W.; Cheng, W. F.; Tong*, R. C-Aryl Glycosylation: Palladium-catalyzed Aryl-Allyl Coupling of Achmatowicz Rearrangement Products with Arylboronic Acids. J. Org. Chem. 2020, 85, 6663-6674. ** Highlighted in Organic Chemistry Portal (ID: J42-Y2020). Song*, L.; Su, Q.; Lin, X.; Du, Z.; Xu, H.; Ouyang, M.-A.; Yao, H.; Tong*, R. Cascade Claisen and Meinwald Rearrangement for One-Pot Divergent Synthesis of Benzofurans and 2H-Chromenes. Org. Lett. 2020, 22, 3004-3009. DOI: 10.1021/acs.orglett.0c00770. Zhao, G.; Canterbury, D. P.; Taylor, A. P.; Cheng, X.; Mikochik, P.; Bagley, S. W.; Tong*, R. Synthesis of 2-Arylpiperidines via Pd-Catalyzed Arylation of Aza-Achmatowicz Rearrangement Products with Arylboronic Acids. Org. Lett. 2020, 22, 458-463. DOI: 10.1021/acs.orglett.9b04220. **Highlighted in Synfacts 2020, 16(4), 0383. Highlighted in Organic Chemistry Portal (ID: J54-Y2020). Márquez-Cadena,† M. A.; Ren,† J.; Ye, W.; Qian*, P.; Tong*, R. Asymmetric Total Synthesis Enables Discovery of Antibacterial Activity of Siladenoserinols A and H. Org. Lett. 2019, 21, ASAP. DOI: 10.1021/acs.orglett.9b03857. (†equal contribution). Xu#, J.; Liang#, L.; Zheng, H.; Chi, Y. R.; Tong*, R. Green Oxidation of Indoles using Halide Catalysis. Nat. Commun., 2019, 10: 4754. DOI: https://doi.org/10.1038/s41467-019-12768-4. (#equal contribution). Wang, Y.-C.; Ma, Y.; Li, X.; Kuang, B. Y.; Huang, C.; Tong*, R; Yu*, J. Z. Monoterpene and sesquiterpene α-hydroxy organosulfates: Synthesis, MS/MS characteristics, and ambient presence. Environ. Sci. Tech. 2019, 53, 12278-12290. DOI: 10.1021/acs.est.9b04703. Zhang, Z.; Zhang, W.; Kang, F.; Ip, F. C. F.; Ip*, N. Y.; Tong*, R. Asymmetric Total Syntheses of Rhynchophylline and Isorhynchophylline. J. Org. Chem. 2019, 84, 11359-11365. DOI: 10.1021/acs.joc.9b01977. Zhao, G.; Liang, L.; Wen, C. H. E.; Tong*, R. Efficient in situ Generation of Nitrile Oxides from NaCl-Oxone Oxidation of Various Aldoximes and their 1,3-Dipolar Cycloaddition. Org. Lett., 2019, 21, 315-319. DOI: 10.1021/acs.orglett.8b03829. Zhao, G.; Tong*, R. Silica gel enables Achmatowicz rearrangement using KBr/Oxone under “anhydrous” condition for one-pot functionalization. Tetrahedron, 2019, 75, 1669-1675. DOI: 10.1016/j.tet.2018.12.022. (Invited contribution)

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