个人简介
1953-56 Acton Technical College, University of London, B.Sc Hons.
Chemistry
1956-59 Imperial College of Science and Technology, London; D.I.C.
Ph.D. in chemistry. Supervisor Professor Sir G. Wilkinson
1959-60 Post-doctoral Research Associates Fellow. Imperial College
of Science and Technology
1960-63 Assistant Lecturer in Inorganic Chemistry at Cambridge University
1961 Fellow of Corpus Christi College, Cambridge
1963 Sepcentenary Fellow of Inorganic Chemistry, Balliol College,
Oxford and Departmental Demonstrator, University of Oxford
1965 University Lecturer, University of Oxford
1971 Visiting Professor, University of Western Ontario (Spring Term)
1972 Visiting Professor, Ecole de Chimie and Institute des
Substances Naturelles, Paris (six months)
1973 A.P. Sloan Visiting Professor, Harvard University, (Spring
Semester)
1979-84 Appointed to the British Gas Royal Society Senior Research
Fellowship
1981 Sherman Fairchild Visiting Scholar at the California Institute of Technology(4 months)
1984 Re-appointed British Gas Royal Society Senior Research Fellow
(1984-6)
1987 Vice-master, Balliol College, Oxford (T.T.)
1989 Appointed Professor of Inorganic Chemistry and Head of Department,
Oxford University
Fellow of St Catherine's College, Oxford
2004- present Emeritus Research Professor in the Inorganic Chemistry Laboratory,
Oxford University
Emeritus Fellow of Balliol College and St Catherine’s College
Honours
1974 Corday-Morgan Medal and Prize in Inorganic Chemistry (Royal
Society of Chemistry)
1977 Pacific West Coast Lecturer in Inorganic Chemistry
1978 Awarded the Chemistry Society Medal in Transition Metal
Chemistry
1982 Royal Society of Chemistry Tilden Lectureship and Prize;
A.R. Gordon Lecturer, Toronto University
1983 Karl Ziegler Gastprofessor (Max Plank Institute, Mulheim)
J.C. Bailar Lecturer and Medal (Illinois University)
Hutchinson Lectureship (University of Rochester)
1984 American Chemical Society Annual Award for Inorganic Chemistry
The University Lecturer in Chemistry, University of Western Ontario
1985 Elected Fellow of The Royal Society
Debye Lecturer, Cornell University
Visiting-Professor, Wuhan University, P.R.C.
1986 Julius Stieglitz Lecturer, University of Chicago
Awarded Royal Society of Chemistry Medal in Organometallic
Chemistry
1987 Frontiers of Science Lecturer, Texas A & M University
1989 Sir Edward Frankland Prize Lecturer
1991 The Glenn T. Seaborg Lecturer in Inorganic Chemistry, University of
California, Berkeley
The South-East Lecturer in Inorganic Chemistry, U.S.A.
The Walter Heiber Gastprofessor, University of Munich, Germany
1992 The Karl-Ziegler Prize of the Gesellschaft Deutscher
Chemiker, Germany
1994 Pacific Coast Lecturer, in Organic Chemistry USA, Spring, 1994
1995 Rayson Huang Visiting Lecturer, Hong Kong
Humphry Davy Medal of the Royal Societof London.
1996 Dow Lecturer, Ottawa-Carleton Chemistry Institute, Canada
1997 American Chemical Society award in Organometallic Chemistry
Doutor Honoris Causa, University of Lisbon, Portugal
Frank Dyer Medal, (U of New South Wales)
1998 The Fred Basolo Medal and Lecture, Northwestern University
Ernest H. Swift Lectureship, California Institute of Technology
2000 Sir Geoffrey Wilkinson Medal and Prize, (Royal Society of Chemistry)
2001 Lewis Lecture, Cambridge UK FMC Lecturer, Princeton
2002- 2014 Distinguished Visiting Professor, Hong Kong University.
2002 Distinguished Lecturer in Inorganic Chemistry, University of North Carolina
34th Canille and Henry Dreyfus Lecturer, Dartmouth College
2004 Honorary Professor of the University of Wuhan (PRC)
Bert and KeggieVallee Visiting Professor, Harvard University, March 2004
2006 Falk Plaut Lectureship, 2006. Columbia University NY
Honorary Doctorate Southampton University.
2007 Prix Franco-Briitannique, Societé, Francaise de Chemie.
2014 Doctor of Science honoris causa 14/7/2014, University of Warwick.
研究领域
Inorganic Chemistry
New Heterogeneous Catalysts for the Petrochemical and Green Energy Industries
The first catalyst for the selective Partial Oxidation of Methane to synthesis gas was discovered in Oxford in 1990. (324 C. 341, 326 C. 160, 353 C. 266) This work attracted worldwide attention and many patents. References to patents are listed in the Publications section below. A survey of the Web of Science showed that there have been 4628 articles under the search term “partial oxidation of methane” since the original report and that these publications came from >30 different countries.
The Oxford work also includes the discovery of the excellence of transition metal carbides as catalysts for hydrocarbon reforming reactions and Fischer-Tropsch Cataysts. (472, 503, 511 C. 68, 520, 559, 563, 577, 587, 589, 632)
New carbide catalysts for hydrodesulphurisation have been discovered and patented. A superior catalyst for the oxidative removal of benzthiophenes from diesel has been identified and is being patented jointly with the company Saudi Aramco. Previously the Oxford Wolfson Catalysis Laboratory was set up in Oxford and has been supported for over 18 years by industrial collaborations. These were with the Gas Research Institute, then CANMET Energy Technology Centre - Ottawa (CETC-Ottawa), the Wolfson Foundation and most recently with Saudi Aramco.
An exceptionally active, stable, and selective cobalt carbide catalyst for the conversion of synthesis gas to hydrocarbons (Fischer-Tropsch catalysis) was discovered in Oxford and patented. A spin-off company, originally called Oxford Catalysts Ltd, but has now changed to Velocys (http://www.velocys.com) has been established to exploit the Fischer-Tropsch catalyst which produces gasoline and diesel from methane with greatly reduced sulphur content, as required by new legislation. In 2012 British Airways announced they will invest an estimate £500M over eight years to develop a plant in London to convert London rubbish into jet fuels. This plant is now under construction and Velocys is providing the equipment for the required conversion of syngas derived from the rubbish into the jet fuel (http://www.velocys.com). Recently the US government gave $72 million Velocys to build a related plant which will convert wood chips from Minnesota forests into transport fuels.
Pioneering studies on the chemistry of carbon nanotubes
This is the most recent new area of research.
It began with the discovery in Oxford of methods to open the ends of multi- and single-walled carbon nanotubes and then their subsequent filling with many materials. (Patent 415, 423 C. 461, 440 C. 71, 490 C.55, 496 C. 55, 523 C. 93, 587 C.79, 540 C. 114)
It has been shown that nano-crystals inside single wall carbon nanotubes (the worlds smallest crystals) have quite different properties from those of the bulk form of the filling material. The exceptional number of citations gathered in a short period shows the interest in this work. This programme was further supported by the British Government (EPSRC) by a £1,006,000 grant entitled “Molography”. This is a new concept whereby single wall carbon nanotubes are used to allow the determination of the relative atom positions of a single molecule in solution using modified transmission electron microscopy (with Professor A. Kirkland).
Most recently the use of wall-functionalized single wall carbon nanotubes filled with a radio isotope of iodine has been shown to locate selectively in the lungs of a mouse (with Benjamin Davis). This paper is highly cited (718).
The development of the Covalent Bond Classifiction (CBC) method.
The conception and proposal of a revolutionary approach to the classification of all covalent compounds of the elements. (444 C. 164) The ideas behind this work have a slowly but steadily received increasing acceptance and they are now taught to university students in many USA, UK and other countries. For example ,lectures are now given to stiudents at Harvaed, MIT, Caltech, Yale, Cornell, Boston inter alia and in10 of the iop UK chemistry departments. The CBC method is now used and cited in well-known text books. A recent CBC based classification of two-electron three-centre bonds has attracted attention (with G Parkin and J.C. Green). 729 It was foundthat there are four different 3c-2e bonds two of which were not previoulsy recognized. An article to assist the teaching of the CBC methodhas recently appeared..731 A website has been established to assist further expansion (http://www.covalentbondclass.org).
近期论文
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Synthesis and Characterization of WS2 Inorganic Nanotubes withEncapsulated/Intercalated CsI.Nano Research, 2010, 3, 170-173.S.Y. Hong, R. Popovitz-Biro, G. Tobias, B. Ballasteros, B.G. Davis,M.L.H. Green and R. Tenne.
Understanding the mechanical reinforcement of uniformly dispersed multiwalled carbonnanotubes in alumino-borosilicate glass ceramic.Acta Materiala, 2010, 58, 2685-2697.A. Mukhonadhay, B.B.T. Chu, M.L.H. Green and R. Todd.
Synthesis and structural investigations of Ni(II)- and Pd(II)-coordinated alpha-diimineswith chlorinated backbones.Inorg, Chim. Acta, 2010, 363.1157-1172.S. I. Pascu, G. Balazs. J.C. Green, M.L.H. Green, I.C. Vei, J.E. Warren and C. Windsor.
Oxidative desulfurization offers route to ultralow-sulfur diesel.OIil & Gas Journal, 2010, 108, 41-47.F. Al-Shanrani, T. Xiao and M.L.H. Green.
Filled and glycosylated carbon nanotubes for in vivo radioemitter localization andimaging.Nature Materials, 2010, 9, 485-490.S.Y. Hong, G. Tobias, K.T. Al-Jamal, B. Ballesteros, H. Ali-Boucetta, S. Lozano-Perez, P.D. Nellist, R.B. Sim, C. Fincane, S.J. Mather, M.L.H. Green and B.G. Davis …..more.
pH-triggered release of materials from single-walled carbon nanotubes usingdimethylamino-functionalized fullerenes as removable ""corks"".Carbon, 2010, 48, 1912-1917.P. Luksirikul, B. Ballesteros, G. Tobias, M.G. Moloney and M.L.H. Green.
Large-scale synthesis of n-type gallium nitride nanowires using NiI2-decorated carbonnanotubes as a reactant.Carbon, 2010, 48, 2401-2408.T-W. Lin, S.Y. Choi, Y.H. Kim and M.L.H. Green.
One- and Two-Dimensional Inorganic Crystals inside Inorganic Nanotubes.Eur, J, Inorg. Chem., 2010, 27, 4233-4243.S.Y. Hong, R. Kreizman, R. Rosentsveig, A. Zak, J. Sloan, A.N. Enxashin. N. Andrey, G.Seifert, M.lL.H. Green and R. tTenne.
Mixtures of oppositely charged polypeptides as high-performance dispersing agents forsingle-wall carbon nanotubes.Chem. Commun., 2010, 7013-7015.G.K. C. Lee, C. Sach, M.L.H. Green, L-L Wong and C.G. Salzmann.
Synthesis, Structure, and Temperature-Dependent Dynamics of Neutral Palladium AllylComplexes of Annulated Diaminocarbenes and Their Catalytic Application for C-C and C-NBond Formation Reactions.Organometallics, 2010, 29, 4858-4870.S. Dastgir, K.S. Coleman, A,R. Cowley and M.L.H. Green.
Sidewall functionalisation of carbon nanotubes by addition of diarylcarbene derivatives.J. Mat .Chem., 2011, 2119080-19085.P. Luksirikul, B. Ballestoros, G. Tobias. M. Moloney and M.L.H. Green.
Heterogenised N-heterocyclic carbene complexes: synthesis, characterisation andapplication for hydroformylation and C-C bond formation reactions.Dalton Trans., 2011, 40, 661-672.S, Dastgir, K.S. Coleman and M.L.H. Green.. 726 Ferromagnetism of double-walled carbon nanotubes (vol 96, 242503, 2010).Applied Physics Letters, 2011, 98,: article number 069901.D.C. Yan, S.Y. Chen, M.K. Wu, C.C. Chi, M.L.H. Green and B.T.T. Chu.
Thermal and electrical properties of aluminoborosilicate glass-ceramics containingmultiwalled carbon nanotubes.Scripta Materialia, 2011, 65, 408-411.A. Mukhonadddhyay, G. Otiero, B.T,T, Chu, A. Wallwork, M.L.H.Green and R.Todd.
Electron Promotion by Surface Functional Groups of Single Wall Carbon Nanotubes toOverlying Metal Particles in a Fuel-Cell Catalyst.Angew. Chem. Internatl Edition, 2012, 51, 6998-7001.P. Luksirikul, K. Tedsree, M. Moloney, M.L.H.Green and S.C.E. Tsang.
The Occurrence and Representation of Three-centre two-electron bonds in CovalentInorganic Compounds.Chem. Commun, 2013, 48. 11481-11503. J.C. Green, M.L.H. Green and G.Parkin.
Exploring Pathways for Activation of Carbon Monoxide by PalladiumIminophosphines.CHEMPLUSCHEM, 2013, 78, 1413-1420. N. Kuganathabm, E.Veal, M.L.H. Green, J.C Green and S.I. Pasci.
Application of the Covalent Bond Classification Method for theTeaching of InorganicChemistry.M.L.H. Green and Ged Parkin.J. Chem. Ed., 2014, 91 , 806 – 816. :
Deep hydrotreating of different feedstocks over a highly active Al2O3-supportedNiMoW sulfide catalystApplied Catalysis A: General, 2014, 475, 270–281.S.L. González-Cortés, S. Rugmini, T. Xiao, M.L.H. Green, S.M. Rodulfo-Baechler, F.E.Imbert.
Deep oxidative desulfurization of liquid transportation fuels by oxidation with peroxide. PCT Int. Appl. (2007), 35pp. Al-Shahrani, Farhan M.; Xiao, Tiancun; Martinie, Gary D.