个人简介

Ph.D. University of Washington

研究领域

Organic, Bioorganic & Medicinal Chemistry

Research Interests: Organometallic chemistry: development of new bio-inspired routes for the formation of C-C bonds that employ readily available precursors and earth abundant first row transition metal catalysts. Research in the Hoover group focuses on the development of new reaction methods for organic synthesis. We are particularly interested in developing new catalytic methods for the formation of C-C bonds using readily available precursors and earth abundant first row transition metal catalysts. Oxidative Decarboxylative Coupling We are exploring reactions that use carboxylic acids and arenes to form new C-C bonds. In particular, our interest is to use trifluoroacetic acid for the direct trifluoromethylation of arenes. Vanadium Nitrogenase Models We are interested in understanding the reduction and reductive coupling of CO and CNR by the nitrogenase enzyme. To better understand this reduction, we are synthesizing and studying new vanadium and iron complexes that are structural mimics of the enzyme.

近期论文

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Copper/TEMPO-Catalyzed Aerobic Alcohol Oxidation: Mechanistic Assessment of Different Catalyst Systems" Hoover, J. M.; Ryland, B. L.; Stahl, S. S. ACS Catal. 2013, 3, 2599-2605. "Continuous-Flow Aerobic Oxidation of Primary Alcohols with a Copper(I)/TEMPO Catalyst" Greene, J. F.; Hoover, J. M.; Mannel, D. S.; Root, T. W.; Stahl, S. S. Org. Process Res. Dev. 2013, 17, 1691247-1251. "Air Oxidation of Primary Alcohols Catalyzed by Copper(I)/TEMPO. Preparation of 2-Amino-5-bromo-benzaldehyde" Hoover, J. M.; Stahl, S. S. Org. Synth. 2013, 90, 240-250. "Mechanism of Copper(I)/TEMPO-Catalyzed Aerobic Alcohol Oxidation" Hoover, J. M.; Ryland, B. L.; Stahl, S. S. J. Am. Chem. Soc. 2013, 135, 2357-2367. "Aerobic Alcohol Oxidation Using a Copper(I)/TEMPO Catalyst System: A Green, Catalytic Oxidation Reaction for the Undergraduate Organic Chemistry Laboratory" Hill, N. J.; Hoover, J. M.; Stahl, S. S. J. Chem. Educ. 2013, 90, 102-105. "Copper(I)TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air" Hoover, J. M.; Steves, . E.; Stahl, S. S. Nature Protocols 2012, 7 1161-1166. "A Highly Practical Copper(I)/TEMPO Catalyst System for Chemoselective Aerobic Oxidation of Primary Alcohols" Hoover, J. M.; Stahl, S. S. J. Am. Chem. Soc. 2011, 133, 16901-16910. "Platinum-Catalyzed Intramolecular Hydrohydrazination; Evidence for Alkene Insertion into a Pt-N Bond" Hoover, J. M.; DiPasquale, A.; Mayer, J. M. Michael, F. E. J. Am. Chem. Soc. 2010, 132, 5043-5053. "Reactivity of Low-Valent Iridium, Rhodium, and Platinum Complexes with Di- and Tetrasubstituted Hydrazines" Hoover, J. M.; Freudenthal, J. M.; Michael, F. E.; Mayer, J. M. Organometallics 2008, 27, 2238-2245. "Synthesis and Reactivity of a Ruthenium(III) Bis(anilide) Dimer by Oxidative Addition of an N,N'-Disubstituted Hydrazine" Hoover, J. M.; DiPasquale, A.; Mayer, J. M.; Michael, F. E. Organometallics 2007, 26, 3297-3305. "Titanium complexes with chiral amino alcohol ligands: synthesis and structure of complexes related to hydroamination catalysts" Peterson, J. R.; Hoover, J. M.; Kassel, W. S.; Reingold, A. L.; Johnson, A. R., Inorganica Chimica Acta 2005, 358, 687-694. "Catalytic Intramolecular Hydroamination of Substituted Aminoallenes by Chiral Titanium Amino-Alcohol Complexes" Hoover, J. M.; Peterson, J. R.; Pikul, J. H.; Johnson, A. R. Organometallics 2004, 23 4614-4620.