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研究领域

The overall theme of our laboratory is to use our expertise in coordination chemistry, materials science, electrochemistry, and photochemistry to address two frontier challenges: Energy and Health. Our programs are highly multidisciplinary; students will be trained in a broad set of skills and inspired to become critical-thinking scientists with a passion on solving urgent problems from a fundamental science perspective.

近期论文

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Jiang, N.; You, B.; Sheng, M.; Sun, Y.* "Electrodeposited cobalt-phosphorous-derived films as competent bifunctional catalysts for overall water splitting" Angew. Chem. Int. Ed. 2015, DOI: 10.1002/anie.201501616R1. [html] [pdf] You, B.; Jiang, N.; Sheng, M.; Sun, Y.* "Microwave vs solvothermal synthesis of hollow cobalt sulfide nanoprisms for electrocatalytic hydrogen evolution and supercapacitor" Chem. Commun. 2015, 51, 4252-4255. [html] [pdf] Jiang, N.; Bogoev, L.+; Popova, M.; Gul, S.; Yano, J.; Sun, Y.* "Electrodeposited nickel-sulfide films as competent hydrogen evolution catalysts in neutral water" J. Mater. Chem. A 2014, 2, 19407-19414. [html] [pdf] Sun, Y.; Liu, C.; Grauer, D. C.; Yano, J.; Long, J. R.; Yang, P.; Chang, C. J. “Electrodeposited cobalt-sulfide catalyst for electrochemical and photoelectrochemical hydrogen generation from water” J. Am. Chem. Soc. 2013, 135, 17699-17702. [html] [pdf] Sun, Y.; Sun, J.; Long, J. R.; Yang, P.; Chang, C. J. “Photocatalytic generation of hydrogen from water using a cobalt pentapyridine complex in combination with molecular and semiconductor nanowire photosensitizers” Chem. Sci. 2013, 4, 118-124. [html] [pdf] Thoi, V. S.; Sun, Y.; Chang, C. J. “Electrochemical hydrogen generation catalyzed by earth-abundant metal complexes under aqueous conditions” Chem. Soc. Rev. 2013, 42, 2388-2400. [html] [pdf] Karunadasa, H. I.; Montalvo, E.; Sun, Y.; Majda, M.; Long, J. R.; Chang, C. J. “A molecular MoS2 edge site mimic for catalytic hydrogen generation.” Science 2012, 335, 698-702. [html] [pdf] Sun, Y.; Bigi, J. P.; Piro, N. A.; Tang, M. L.; Long, J. R.; Chang, Christopher J. “Molecular cobalt pentapyridine catalysts for generating hydrogen from water.” J. Am. Chem. Soc. 2011, 133, 9212-9215. [html] [pdf] Sun, Y.; Joyce, L. E.; Dickson, N. M.; Turro, C. “DNA photocleavage by an Os(II) complex in the PDT window” Chem. Commun. 2010, 46, 6759-6761. [html] [pdf] Sun, Y.; El Ojaimi, M.; Hammitt, R.; Thummel, R. P.; Turro, C. “Effect of ligand extended pi-system on the photophysical properties of Ru(II) complexes” J. Phys. Chem. B 2010, 114, 14664-14670. [html] [pdf] Sun, Y.; Turro, C. “Highly solvent dependent luminescence from [Ru(bpy)n(dppp2)3-n]^2+ (n = 0 – 2)” Inorg. Chem. 2010, 49, 5025-5032. [html] [pdf] Sun, Y.; Liu, Y.; Turro, C. “Ultrafast dynamics of the low-lying 3MLCT States of [Ru(bpy)2(dppp2)]^2+” J. Am. Chem. Soc. 2010, 132, 5594-5595. [html] [pdf] Sun, Y.; Collins, S. N.; Joyce, L. E.; Turro, C. “Unusual photophysical properties of a Ru(II) complex related to [Ru(bpy)2(dppz)]^2+” Inorg. Chem. 2010, 49, 4257-4262. [html] [pdf] Sun, Y.; Joyce, L. E.; Dickson, N. M.; Turro, C. “Efficient DNA photocleavage by [Ru(bpy)2(dppn)]^2+ with visible light” Chem. Commun. 2010, 46, 2426-2428. [html] [pdf] Sun, Y.; Lutterman, D. A.; Turro, C. “Role of electronic structure on DNA light-switch behavior of Ru(II) intercalators” Inorg. Chem. 2008, 47, 6427-6434. [html] [pdf] Lutterman, D. A.; Chouai, A.; Liu, Y.; Sun, Y.; Stewart, C. D.; Dunbar, K. R.; Turro, C. “Intercalation is not required for DNA light-switch behavior” J. Am. Chem. Soc. 2008, 130, 1163-1170. [html] [pdf] Sun. Y. “Water Splitting Catalysts and Associated Methods” US Provisional Patent Application No: 62/056,357 Long, J. R.; Chang, C. J.; Sun, Y. “Molecular cobalt pentapyridine catalysts for generating hydrogen from water" US Patent 2012/0296092 A1. [html]

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