个人简介

Name: Richard Thomas Oakley Date of Birth: 20th January 1948 Place of Birth: Maracaibo, Venezuela Academic and Professional Experience: 1998- present, Professor of Chemistry, University of Waterloo 1989-98, Professor of Chemistry, University of Guelph 1986-89, Associate Professor of Chemistry, University of Guelph 1983-86, Assistant Professor of Chemistry, University of Guelph 1980-83, Assistant Professor of Chemistry, University of Calgary 1978-80, Research Associate, University of Calgary 1971-72, Profesor Asistente de Quimica, Universidad Industrial de Santander, Colombia Secondary and Post-secondary Education: 1977-78, NSERC Post-Doctoral Fellow (supervisor: J. P. Collman), Stanford University 1976-77, NSERC Post-Doctoral Fellow (supervisor: R. West), University of Wisconsin 1973-76, Ph.D. (supervisor: N. L. Paddock), University of British Columbia 1969-70, M.Sc. (supervisor: N. L. Paddock), University of British Columbia 1966-69, B.Sc., Honours Chemistry, University of British Columbia 1961-65, Whitgift School, South Croydon, England Academic, Scholarly and Professional Honours: 2009, Fellow of the Royal Society of Canada 2006-08, Canada Council Killam Research Fellowship 2001, CSC Award in Pure or Applied Inorganic Chemistry 1993, CSC Alcan Lecture Award 1993, Fellow of the Chemical Institute of Canada 1991, ACS Akron Section Award 1980-87, NSERC University Research Fellowship 1976-78, NSERC Post-doctoral Fellowship 1976-78, Honorary Canadian Ramsay Memorial Fellowship 1973-76, NSERC Post-graduate Scholarship 1969-70, NRC Post-graduate Scholarship

研究领域

Inorganic Chemistry

Our research work spans the three-way interface between chemistry, physics and materials science. We design, synthesize and characterize the molecular and solid state properties of neutral radlcals, radical ions and biradicals, with the long term goal of generating processable molecular materials exhibiting unusual magnetic, conductive and/or optical properties.

近期论文

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S. M. Winter, S. Hill and R. T. Oakley. “Magnetic Ordering and Anisotropy in Heavy Atom Radicals.” J. Am. Chem. Soc. 137, 3720-3730 (2015). DOI A. Mailman, S. M. Winter, J. W. L. Wong, C. M. Robertson, A. Assoud, P. A. Dube and R. T. Oakley. “Multiple Orbital Effects and Magnetic Ordering in a Neutral Radical.” J. Am. Chem. Soc. 137,1044-1047 (2015). DOI K. Thirunavukkuarasu, S. M. Winter, C. C. Beedle, A. E. Kovalev, R. T. Oakley and S. Hill. “Pressure Dependence of the Exchange Anisotropy in an Organic Ferromagnet.” Phys. Rev. B 91, 014412 (2015). DOI S. M. Winter, A. Mailman, R. T. Oakley, K. Thirunavukkuarasu, S. Hill, D. E. Graf, S. W. Tozer, J. S. Tse, M. Mito and H. Yamaguchi. “Electronic and Magnetic Structure of Neutral Radical FBBO.” Phys. Rev. B 89, 214403 (2014). DOI K. Lekin, H. Phan, S. M. Winter, J. W. L. Wong, A. A. Leitch, D. Laniel, W. Yong, R. A. Secco, J. S. Tse, S. Desgreniers, P. A. Dube, M. Shatruk and R. T. Oakley. “Heat, Pressure and Light-Induced Interconversion of Bisdithiazolyl Radicals and Dimers.” J. Am. Chem. Soc. 136, 8050-8062 (2014). DOI JACS Spotlight. J. W. L. Wong, A. Mailman, K. Lekin, S. M. Winter, W. Yong, J. Zhao, S. V. Garimella, J. S. Tse, R. A. Secco, S. Desgreniers, Y. Ohishi, F. Borondics and R. T. Oakley. "Pressure Induced Phase Transitions and Metallization of a Neutral Radical Conductor." J. Am. Chem. Soc. 136, 1070-1081 (2014). DOI J. W. L. Wong, A. Mailman, S. M. Winter, C. M. Robertson, R. J. Holmberg, M. Murugesu, P. A. Dube and R. T. Oakley. "Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor." Chem. Commun. 50, 785-787 (2014). DOI H. Phan, K. Lekin, S. M. Winter, R. T. Oakley and M. Shatruk. "Photoinduced Solid State Conversion of a Radical σ-Dimer to a π-Radical Pair." J. Am. Chem. Soc. 135, 15674-15677 (2013). DOI K. Lekin, J. W. L. Wong, S. M. Winter, A. Mailman, P. A. Dube and R. T. Oakley. “Bisdithiazolyl Radical Spin Ladders.” Inorg. Chem. 52, 2188-2198 (2013). DOI S M. Winter, A. R. Balo, R. J. Roberts, K. Lekin, A. Assoud, P. A. Dube, and R. T. Oakley. “Hybrid dithiazolothiadiazinyl radicals; versatile building blocks for magnetic and conductive materials.” Chem Commun. 49, 1603-1605 (2013). DOI K. Lekin, A. A. Leitch, J. S. Tse, X. Bao, R. A. Secco, S. Desgreniers, Y. Ohishi and R. T. Oakley. "A Pressure Induced Structural Dichotomy in Isostructural Bis-1,2,3-thiaselenazolyl Radical Dimers." Crystal Growth & Design, 12, 4676-4684 (2012). DOI A. Mailman, S. M. Winter, X. Yu, C. M. Robertson, W. Yong, J. S. Tse, R. A. Secco, Z. Liu, P. A. Dube, J. A. K. Howard and R. T. Oakley. "Crossing the Insulator-to-Metal Barrier with a Thiazyl Radical Conductor." J. Am. Chem. Soc. 134, 9886-9889 (2012). DOI, ChemPhysChem Highlight. BIMR Highlight. X. Yu, A. Mailman, K. Lekin, A. Assoud, P. A. Dube and R. T. Oakley. “A Bimodal Oxobenzene-bridged Bisdithiazolyl Radical.” Crystal Growth & Design, 12, 2485-2494 (2012). DOI S. M. Winter, R. T. Oakley, A. E. Kovalev and S. Hill. “Spin-Orbit Effects in Heavy Atom Organic Radical Ferromagnets.” Phys. Rev. B. 85, 094430 (2012). DOI X. Yu, A. Mailman, K. Lekin, A. Assoud, C. M. Robertson, B. C. Noll, C. F. Campana, J. A. K. Howard, P. A. Dube and R. T. Oakley. “Semiquinone-bridged Bisdithiazolyl Radicals as Neutral Radical Conductors.” J. Am. Chem. Soc. 134, 2264-2275 (2012). DOI, JACS Spotlight. S. M. Winter, S. Datta, S. Hill and R. T. Oakley. “Magnetic Anisotropy in a Heavy Atom Radical Ferromagnet.” J. Am. Chem. Soc. 133, 8126-8129 (2011). DOI A. A. Leitch, K. Lekin, S. M. Winter, L. E. Downie, H. Tsuruda, J. S. Tse, M. Mito, S. Desgreniers, P. A. Dube, S. Zhang, Q. Liu, C. Jin, Y. Ohishi and R. T. Oakley. “From Magnets to Metals: The Response of Tetragonal Bisdiselenazolyl Radicals to Pressure.” J. Am. Chem. Soc. 133, 6051-6060 (2011). DOI H. Tsuruda, M. Mito, H. Deguchi, S. Takagi, A. A. Leitch, K. Lekin, S. M. Winter and R. T. Oakley. “Pressure dependence of Curie temperature in a selenazyl radical ferromagnet.” Polyhedron 30, 2997-3000 (2011). DOI X. Yu, A. Mailman, P. A. Dube, A. Assoud and R. T. Oakley. “The first semiquinone-bridged bisdithiazolyl radical conductor: a canted antiferromagnet displaying a spin-flop transition.” Chem. Commun. 47, 4655-4657 (2011). DOI K. Lekin, S. M. Winter, L. E. Downie, X. Bao, J. S. Tse, S. Desgreniers, R. A. Secco, P. A. Dube and R. T. Oakley. “Hysteretic Spin Crossover between a Bisdithiazolyl Radical and its Hypervalent σ-Dimer.” J. Am. Chem. Soc. 132, 16212-16224 (2010). DOI, CLS Research Highlight, JACS Select, Nature Chem Highlight.