何晓明 - 陕西师范大学 - 化学化工学院

个人简介

2019.04-：教授，博导，陕西师范大学化学化工学院 2016.12-：特聘研究员，博导，同济大学化学科学与工程学院 2014.11－2016.11: 玛丽居里学者，布里斯托大学（导师：Ian Manners） 2013.12－2014.11: 博士后，阿尔伯塔大学（导师：Jillian Buriak） 2012.01－2013.11: 博士后，卡尔加里大学（导师：Thomas Baumgartner） 2011.02－2012.01: 博士后，密西根大学（导师：Mi Hee Lim） 2006.09－2010.11：博士，香港大学（导师：任咏华院士） 2003.09－2006.07：硕士，中科院兰州化学物理研究所（导师：邵士俊研究员） 1999.09－2003.07: 本科，合肥工业大学（导师：姚日生教授）

研究领域

Our research group will focus on the development of the new functional organic/inorganic materials with multiple sizes (small molecules, polymers, self-assembled nano-to-micro materials) for applications in sensing, energy storage, photocatalysis and organic light-emitting devices. Research in our group is highly multidisciplinary, spanning the areas of synthetic organic and inorganic chemistry, polymer science, applied physics, and nanotechnology. Students in our group will gain skills in organic and organometallic synthesis, polymer chemistry, and nanoscience, as well as a variety of characterization techniques for electronic and nanostructured materials.

近期论文

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Construction of Naphthalene Diimide Derived Nanostructured Cathodes through Self-assembly for High-performance Sodium-Organic Batteries Fangfang Xing, Shan Li, Ling Chen, Jing-Shuang Dang, Xiaoming He* ACS Nano 2023, 17, DOI:10.1021/acsnano.3c06189. Modified Viologen- and Carbonylpyridinium-based Electrodes for Organic Batteries Xiaoming He*, Ling Chen, Thomas Baumgartner* ACS Appl. Mater. Inerfaces 2023, Accepted. (Invited Spotlight article for Forum on 'Organic Battery Materials') Naphthalenediimide-carbonylpyridiniums: Stable Six Electron Acceptors for Organic Cathodes Qiting Lin, Heyang Li, Ling Chen, Xiaoming He* Mater. Chem. Front. 2023, 7, 3747-3753. Supramolecular Polymerization of Chiral Platinum(II) Complexes: Transformable Nanoassemblies and Their Amplified Circularly Polarized Luminescence Xiaolin Zhu,* Zhen Wang, Yihui Jia, Fang Yang, Youzhi Zhang, Shirui Zhao, Xiaoming He* J. Mater. Chem. C 2023, DOI:10.1039/d3tc02375c. Bio-Inspired Non-Conjugated Poly (Carbonylpyridinium) as Anode Materials for High-Performance Alkali-Ion (Li+, Na+, and K+) Batteries Xiujuan Wang†, Ling Chen†, Xiaoming He* J. Colloid Interface Sci. 2023, 643, 541-550. Anthrazoline photocatalyst for promoting esterification and etherification reactions via photoredox/nickel dual catalysis Xiaolin Zhu*, Qiujin Fan, Wei Luo, Danfeng Wang, Yihui Jia, Heyang Li, Zhen Wang, Qi Xiao*, Xiaoming He* Chin. J. Chem. 2023, 41, 411-416. Cost-Effective Vat Orange 3-Derived Organic Cathodes for Electrochemical Energy Storage Ling Chen, Fangfang Xing, Qiting Lin, Ahsan Waqas,Xiujuan Wang, Thomas Baumgartner*, Xiaoming He* Batteries & Supercaps 2022, 5, DOI:10.1002/batt.202200406. Synthesis of 4-electron-accepting carbonyl-N-methylpyridinium species for lithium-organic batteries Qiting Lin, Ling Chen, Xiujuan Wang, Xiaoming He* STAR Protocols 2022, 3, 101851. Modifiable Dimensionality of Aggregates of Silicon to Optimize the Volume Effect for Lithium Storage Xiujuan Wang, Jian Qin, Xiaoming He* Chem. Eng. J. 2022, 452, 139639. Anthraquinone Porous Polymers with Different Linking Patterns for High Performance Zinc-Organic Battery Xiujuan Wang, Gang Wang, Xiaoming He* J. Colloid Interface Sci. 2023, 629, 434-444. Two-dimensional Janus Film with Au Nanoparticles Assembled on Trinuclear Gold(I) Pyrazolate Coordination Nanosheet for Photocatalytic H2 Evolution Xiaolin Zhu, Hongya Miao, Yong Shan. Guangyuan Gao, Quan Gu, Qi Xiao,* Xiaoming He* Inorg. Chem. 2022, 61, 13591-13599. Effect of Hydrophobic Hydration on the Self-Assembling Behaviour of Poly (L-lactide) Homopolymer with an Ionic End Group Zhen Liu, Xinjie Shi, Wenchao Shu, Shuo Qi, Xiaoming He,* Xiaosong Wang,* Xiaohua He* Macromolecules 2022, 55, 8892-8898. Tuning the Azo Location in Conjugated Polymers Toward High Performance Lithium-Ion Batteries Sen Zhang, Fangfang Xing, Ling Chen, Xiujuan Wang,* Xiaoming He* Chem. Mater. 2022, 34, 9031-9041. Bio-Derived Four-Electron-Accepting Carbonyl-N-methylpyridinium Species for High-Performance Lithium/Organic Batteries Xiujuan Wang, Wenhao Xue, Guangyuan Gao, Ling Chen, Thomas Baumgartner, Xiaoming He* Cell Rep. Phys. Sci. 2022, 3, 100951. Supramolecular Polymerization of BODIPY Dyes Extended with Rationally Designed Pyrazole-based Motif Y. Zhang, N. Zhou, X. Zhu*, X. He* Polym. Chem. 2021, 12, 5535-5541. Fibrous Thiazolothiazole-bridged Viologen Polymer for High-Performance Lithium-Ion Batteries L. Chen, X. Zhu*, Y. Zhang, G. Gao, W. Xue, S. Zhang, X. Wang, Q. Zhang, X. He* J. Mater. Chem. A 2021, 9, 18506-18514. Conjugated Polymers with Benzoyl-N-methylpyridinium units：An Effective Design Strategy for High-Performance Lithium-Ion Batteries G. Gao, X Wang, L. Chen, T. Baumgartner, X. He* Chem. Mater. 2021, 33, 4596-4605. In Situ Heterogeneous Interface Construction Boosting Fast Ion/Electron Transfer For High-Performances Lithium/Potassium Storage X. Wang, S. Zhang, Y. Shan, L. Chen, G. Gao, X. Zhu, B. Cao,* X. He* Energy Stor. Mater. 2021, 37, 55-66. Developing Luminescent Ratiometric Thermometers Based on Copolymers Containing Platinum(II) Isocyanide Complex. N. Zhou, Y. Zhang, Z. Chen, X. Zhu,* X. He.* Dyes Pigm. 2021, 184, 108815. Living Crystallization-Driven Self-Assembly of Polymeric Amphiphiles: Low Dispersity Fiber-Like Micelles from Crystallizable Phosphonium-Capped Polycarbonate Homopolymers X. He, J. R. Finnegan, D. W. Hayward, L. R. MacFarlane, R. L. Harniman, I. Manners* Macromolecules. 2020, 53, 10591-10600. Photocatalytic Hydrogen Evolution Based on the Nitrogen-Containing Donor-Acceptor (D-A) Organic Conjugated Small Molecules. J. Yu, S. Chang, X. Xu,* X. He,* C. Zhang* ACS Sustain. Chem. Eng. 2020, 8, 14253–14261. The effect of single atom substitution (O, S or Se) on photocatalytic hydrogen evolution for triazine-based conjugated porous polymers. J. Yu, S. Chang, X. Xu,* X. He,* C. Zhang*. J. Mater. Chem. C. 2020, 8, 8887-8895. Rh(III)-Catalyzed Atroposelective Synthesis of Biaryls via C-H Activation and Intermolecular Coupling with Sterically Hindered Alkynes. F. Wang, Z. Qi, Y. Zhao, S. Zhai, G. Zheng, R. Mi, Z. Huang, X. Zhu, X.He, X. Li*. Angew. Chem. Int. Ed. 2020, 59, 13288-13294. Controlling the Supramolecular Polymerization of dinuclear isocyanide gold(I) arylethylene complexes through tuning the central pi-conjugated moiety. N. Zhou, R. Hailes, Y. Zhang, Z. Chen, I. Manners, X He*. Polym. Chem. 2020, 11, 2700-2707. Poly(5-vinylbenzothiadiazole) for High-Performance Lithium-Ion Batteries. L. Chen, C. R. Bridges, G. Gao, T. Baumgartner,* X. He*. ACS Appl. Energy Mater. 2019, 2, 7315-7320. Uniform, High-Aspect-Ratio, and Patchy 2D Platelets by Living Crystallization-Driven Self-Assembly of Crystallizable Poly(ferrocenyldimethylsilane)-Based Homopolymers with Hydrophilic Charged Termini S. Pearce, X. He, M.-S. Hsiao, R. L. Harniman, L. R. MacFarlane, I. Manners* Macromolecules 2019, 52, 6068-6079. Controlling the Supramolecular Polymerization and Metallogel Formation of Pt(II) Complexes via Delicate Tuning of Non-Covalent Interactions. L. Li, N. Zhou, H. Kong, X. He*. Polym. Chem. 2019, 10, 5465-5472 . Donor-Acceptor Type Triazine-based Conjugated Porous Polymer for Visible-Light-Driven Photocatalytic Hydrogen Evolution. J. Yu, X. Sun, X. Xu*, C. Zhang*, X. He*. Appl. Catal. B: Environ., 2019, 257, 117935. Rational construction of self-supported triangle-like MOF-derived hollow (Ni,Co)Se2 arrays for electrocatalysis and supercapacitor. W. Song, X. Teng, Y. Liu, J. Wang, Y. Niu, X. He, C. Zhang, Z. Chen*. Nanoscale . 2019, 11, 6401-6409. High-performance 2.5 V flexible aqueous asymmetric supercapacitors based on K+/Na+-inserted MnO2 nanosheets. Y. Liu, L. Guo, X. Teng, J. Wang, T. Hao, X. He*, Z. Chen*. Electrochimica Acta . 2019, 300, 9-17. Living Supramolecular Polymerisation of Perylene Diimide Amphiphiles by Seeded Growth under Kinetic Control. C. Jarrett-Wilkins, X. He, H. E. Symons, R. L. Harniman, C. F. J. Faul,* I. Manners*. Chem. Eur. J. 2018, 24, 15556-15565. Extending the Scope of “Living” Crystallization-Driven Self-Assembly: Well-Defined 1D Micelles and Block Comicelles from Crystallizable Polycarbonate Block Copolymers. J. R. Finnegan, X. He, S. T. G. Street, J. D. Garcia-Hernandez, D. W. Hayward, R. L. Harniman, R. M. Richardson, G. R. Whittell, I. Manners*. J. Am. Chem. Soc. 2018, 140, 17127-17140. A Novel Bimetallic Nickel–Molybdenum Carbide Nanowire Array for Efficient Hydrogen Evolution. L. Guo, J. Wang, X. Teng, Y. Liu, X. He, Z. Chen*. ChemSusChem . 2018, 11, 2717-2723. N,P-Doped Molybdenum Carbide Nanofibers for Efficient Hydrogen Production. L. Ji, J. Wang, X. Teng, H. Dong, X. He, Z. Chen*. ACS Appl. Mater. Interfaces, 2018, 10, 14632–14640. Narrow‐Bandgap Chalcogenoviologens for Electrochromism and Visible‐Light‐Driven Hydrogen Evolution. G. Li, L. Xu, W. Zhang, K. Zhou, Y. Ding, F. Liu, X. He, G. He*. Angew. Chem. Int. Ed. 2018, 57, 4897-4910. Understanding the Effects of a High Surface Area Nanostructured ITO Electrode on Organic Solar Cell Performance. B. Cao, X. He, J. Sorge, A. Lalany, K. Ahadi, A. Afshar, B. C. Olsen, T. C Hauger, M. H. Mobarok, P. Li, K. C Cadien, M. J. Brett, E. J. Luber*, J. M. Buriak*. ACS Appl. Mater. Interfaces . 2017, 9, 38706-38715. Two-dimensional Assemblies From Crystallizable Homopolymers with Charged Termini. X. He, M.-S. Hsiao, C. E. Boott, R. L. Harniman, A. Nazemi, X. Li, M. A. Winnik, I. Manners*. Nature Mater. 2017 , 16, 481-488. Complex and Hierachical 2D Assemblies via Crystallization-Driven Self-Assembly of Poly(L-lactide) Homopolymers with Charged Termini. X. He, Y. He, M.-S. Hsiao, R. L. Harniman, S. Pearce, M.A. Winnik, I. Manners*. J. Am. Chem. Soc. 2017, 139, 9221-9228. Uniform “Patchy” Platelets by Seeded Heteroexpitaxial Growth of Crystallizable Polymer Blends in Two Dimentions. A. Nazemi, X. He, L. R. MacFarlane, R. Harniman, M. A. Winnik, I. Manners*. J. Am. Chem. Soc. 2017, 139, 4409-4417. Role of Interfacial Layers in Organic Solar Cells: Energy Level Pinning versus Phase Segregation. B. Cao, X. He, C. Fetterly, B. Olsen, E. Luber, J. Buriak*. ACS Appl. Mater. Interfaces. 2016, 8, 18238-18248. Cleavage of P-N Bond in a Urea-Containing (Ph2PRPPh2)-Bridged Dinuclear Gold(I) Thiolate Complex by Fluoride and its Mechanistic Insight. X. He, W. H. Lam, E. C.-C. Cheng, V. W.-W. Yam. Chem. Eur. J. 2015, 21, 8447-8454. Donor-Acceptor Small Molecules for Organic Photovoltaics: Single Atom Substitution (Se or S). X. He, B. Cao, T. Hauger, M. Kang, E. Luber, S. Gusaroy, J. Buriak*. ACS Appl. Mater. Interfaces . 2015, 7, 8188-8199. Synthesis and Properties of Cholesteric Click-Phospholes. X. He, J.-B. Lin, W. H. Kan, S. Trudel, T. Baumgartner*. Org. Lett. 2014, 16, 1366-1369. Molecular Engineering of "Click"-Phosphole Towards Self-Assembled Luminescent Soft Materials. X. He, J.-B. Lin, W. H. Kan, P. Dong, S. Trudel, T. Baumgartner*. Adv. Funct. Mater. 2014, 24, 897-906. Synthesis and Properties of a Dicationic p-Extended Dithieno[3,2-c:2¢,3¢-e]-2,7-diketophosphepin. X. He, T. Baumgartner*. Organometallics . 2013, 32, 7625-7628. Synthesis of P-Triazole Dithienophospholes and a Cyclodextrin-based Sensor via Click Chemistry. X. He, P. Zhang, J.-B., Lin, H. V. Huynh, S. E. Navarro Nuñoz, C.-C. Ling, T. Baumgartner*. Org. Lett. 2013 , 15, 5322-5325. Phosphinine-lipids: A successful marriage between electron acceptor and self assembly features. X. He, J.-B. Lin, W. K. Han, T. Baumgartner*. Angew. Chem. Int. Ed. 2013, 52, 8990-8994. Halochromic generation of white light emission using a single dithienophosphole luminophore. H. V. Huynh, X. He, T. Baumgartner*. Chem. Commun. 2013, 4899-4910. Conjugated main-group polymers for optoelectronics. X. He, T. Baumgartner*. RSC Adv. 2013, 3, 11334-11350. Dithiazolo[5,4-b:4’,5’-d]phosphole: A Highly Luminescent Electron-Accepting Building Block. X. He, A. Y. Y. Woo, J. Borau-Garcia, T. Baumgartner*. Chem. Eur. J. 2013, 19, 7620-7630. Dithieno[3,2-c:2¢,3¢-e]-2,7-diketophosphepin: A Unique Building Block for Multifunctional p-Conjugated Materials. X. He, J. Borau-Garcia, A. Y. Y. Woo, S. Trudel, T. Baumgartner*. J. Am. Chem. Soc. 2013, 135, 1137-1147. Tuning Reactivity of Diphenylpropynone Derivatives with Metal-Associated Amyloid-β Species via Structural Modifications. Y. Liu, A. Kochi, A. Pithadia, S. Lee, Y. Nam, M. Beck, X. He, D. K. Lee, M. H. Lim*. Inorg. Chem. 2013, 52, 8121-8130. Exploring the reactivity of flavonoid compounds with metal-associated amyloid-b species. X. He, H. M. Park, S.-J. Hyung, A. S. Detoma, C. Kim, B. T. Ruotolo, M. H. Lim*. Dalton Trans. 2012, 41, 6558-6566. Luminescent gold(I) complexes for chemosensing. X. He, V. W.-W. Yam*. Coord. Chem. Rev. 2011, 255, 2111-2123. Highly selective ion probe for Al3+ based on Au(I)···Au(I) interations in a bis-alkynyl calix[4]arene Au(I)isocyanide scafford. F. K.-W. Hau, X. He, W. H. Lam, V. W.-W. Yam*. Chem. Commun. 2011 , 47, 8778-8780. A highly selective bifunctional luminescence probe for potassium and fluoride ions. X. He, Vi. W.-W. Yam*. Org. Lett. 2011, 13, 2172-2175. Design and Synthesis of Luminescence Chemosensor Based on Alkynyl Phosphine Gold(I)-Copper(I) Aggregates. X. He, Vivian W.-W. Yam*. Dalton Trans. 2011, 40, 9703-9710. Design, Synthesis, Photophysics and Ion-binding Studies of a Ditopic Receptor Based on Gold(I) Phosphine Thiolate Complex Functionalized with Crown Ether and Urea Binding Units. X. He, V. W.-W. Yam*. Inorg. Chem. 2010 , 49, 2273-2279. Design, Synthesis, Photophysics and Anion-binding Studies of Dcpm-Containing Dinuclear Gold(I) Thiolate Complexes with Urea Receptors. X. He, F. Herranz, E. C.-C. Cheng, R. Vilar*, V. W.-W. Yam*. Chem. Eur. J. 2010, 16, 9123-9131. Selective ion probe for Mg2+ based on Au(I)∙∙∙Au(I) interactions in tripodal alkynylgold(I) complex with oligoether pendants. X. He, E. C.-C. Cheng, N. Zhu, V. W.-W. Yam*. Chem. Commun. 2009, 4016-4018. Synthesis, Characterization, Structure and Selective Cu2+ Sensing Studies of an Alkynylgold(I) Complex Containing the Dipicolylamine Receptor. X. He, N. Zhu, V. W.-W. Yam*. Organometallics . 2009, 28, 3621-3624. Design and Synthesis of Calixarene-based Bis-alkynyl-bridged Dinuclear Au(I) Isonitrile Complexes as Luminescent Ion Probes via the Modulation of Au∙∙∙Au Interactions. X. He, W. H. Lam, N. Zhu, V. W.-W. Yam*. Chem. Eur. J. 2009, 15, 8842-8851. Oxidized Bis(indolyl)methane: A Simple and Efficient Chromogenic-Sensing Molecule Based on the Proton Transfer Signaling Mode. X. He, S. Hu, K. Liu, Y. Guo, J. Xu, S. Shao*. Org. Lett. 2006, 8, 333-336. Calix[4]pyrrole–TCBQ assembly: a signal magnifier of TCBQ for colorimetric determining amino acids and amines. Kai Liu, Lijun He, Xiaoming He, Yong Guo, Shijun Shao*, Shengxiang Jiang. Tetrahedron Lett. 2007, 48, 4275-4279. Tris(indolyl)methene molecule as an anion receptor and colorimetric chemosensor: tunable selectivity and sensitivity for anions. L. Wang, X. He, Yo. Guo, J. Xu, S. Shao*. Org. Bio. Chem. 2011, 9, x752-757. Anion Binding and Sensing Properties of Bis(3-indolyl)methene Derivatives Based on Proton Transfer Process. L. Wang, X. He, Y. Guo, J. Xu, S. Shao*. Letters in Organic Chemistry. 2011, 8, 60-65. pH-Responsive chromogenic-sensing molecule based on bis(indolyl)methene for the highly selective recognition of aspartate and glutamate. L. Wang, X. He, Y. Guo, J. Xu, S. Shao*. Beilstein J. Org. Chem. 2011, 7, 218-221.