Elsheimer, Seth - University of Central Florida

研究领域

Our research group is studying a variety of pure and applied topics. We are particularly interested in, but not limited to, organic molecules that contain fluorine. These fascinating compounds are almost non-existent in nature and therefore the work is based on an entirely synthetic branch of organic chemistry. Several aspects of substituent effects, reaction mechanisms, and synthesis are under investigation.

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"Thermal Rearrangement of 1,1-Difluorospiropentane", W.R. Dolbier, Jr., S.F. Sellers, B.H. Al-Sader, S. Elsheimer,J. Am. Chem. Soc. 1981, 103, 715. "Thermal Isomerizations of Fluorinated Spiropentanes", W.R. Dolbier, Jr., S.F. Sellers, B.H. Al-Sader, T.H. Fielder, Jr., S. Elsheimer, B.E. Smart, Israel J. Chem. 1981, 21, 176. "Difluorodiiodomethane: Its Preparation, Properties, and Free-Radical Reactions", S. Elsheimer, W.R. Dolbier, Jr., M. Murla, K. Seppelt, G. Paprott, J. Org. Chem. 1984, 49, 205. "The Thermolysis of gem-Difluorospiropentane, the Kinetic Effect of Fluorine on the Homodienyl Hydrogen Shift, and Preparation and Reactions of Difluorodiiodomethane", S.R. Elsheimer, Diss. Abst. Int. 1985, 46, 840-B. "The Thermal Rearrangement of cis, cis-1-Fluoro-2-methyl-3-vinylcyclopropane. The Kinetic Effect of a Single Fluorine Substituent", S. Elsheimer, W.R. Dolbier, Jr., J. Fluorine Chem. 1988, 40, 119. "Unexpected Products from the Reactions of 1-(Bromodifluoromethyl)-2-bromocyclohexanes with Potassium Hydroxide", S. Elsheimer, M. Michael, A. Landavazo, D.K. Slattery, J. Weeks, J. Org. Chem. 1988, 53, 6151. "Alkaline Hydrolysis of 1,3-Dibromo-1,1-difluoroalkanes: A Two-Step Vinyl Carboxylation", S. Elsheimer, D.K. Slattery, M. Michael, J. Weeks, K. Topoleski, J. Org. Chem., 1989, 54, 3992. "Difluoromethylation of Alkenes via Borohydride Reduction of 1,3-Dibromo-1,1-difluoroalkanes", S. Elsheimer, J. Gonzalez, and C. Foti, J. Org. Chem. 1991, 56, 4323. "Origin of `Hetero Effect' on Nitrogen Inversion. Comparison of Hydroxylamines and Aminoxide Anions", C.L. Perrin, J.D. Thoburn, S. Elsheimer, J. Org. Chem. 1991, 56, 7034. "3,3-Difluoroallyltrimethylsilane" J. Gonzalez, M.J. Foti, S. Elsheimer, Organic Syntheses 1995, 72, 225. "Halogenation", chapter in book The Chemistry of Organic Fluorine Compounds II , Edited by M. Hudlicky and A.E. Pavlath. ACS Books, Wash., D.C. 1995. (Book review: K. O. Christe Synthesis 1997, 495.) "Reactions of 1,3-Dibromo-1,1-difluoro Compounds with DBU," S. Elsheimer, C. J. Foti, M. D. Bartberger, J. Org. Chem. 1996, 61, 6252. "Introduction to Organic Chemistry I " S. Elsheimer 11th Hour Series Blackwell Science Publishers, Malden MA 2000. "Mechanisms for the Alkaline Hydrolysis of Dibromodifluoromethane-Alkene Adducts to Alpha,Beta-Unsaturated Carboxylates" S. Elsheimer, J. L. Swanson, J. Gonzalez, J. Fluorine Chem. 2000, 102, 3. "Introduction to Organic Chemistry II" S. Elsheimer 11th Hour Series Blackwell Science Publishers, Malden MA 2000. "Electrochemical Fluorination of Organic Compounds" M. S. Gohil, A. D. Jethva, S. N. Misra, S. Elsheimer, G. Ramachandraiah, P. K. Ghosh, Indian Journal of Chemistry 2002 (accepted). "Selective Fluorination of Organic compounds using Reactive Inorganic Fluorides by Halogen Exchange Reactions" M. S. Gohil, A. D. Jethva, S. N. Misra, S. Elsheimer, Indian Journal of Chemistry 2002 (accepted).