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Totally >140 publications (with 34 highlighted by Synfacts, 2 highlighted by ACS “Heart Cut”, 2 by ACS “Noteworthy Chemistry”, and 1 by JACS Spotlights, and 12 selected as journal cover articles.); 13 Chinese Patents, 2 US Patents. Conformational Locking Induced Enantioselective Diarylcarbene Insertion into B-H and O-H Bonds Using a Cationic Rh(I)/Diene Catalyst Weici Xu, Zengwei Wang,Weici Xu, Takeshi Yamakawa, Meiling Huang, Peilin Tian, Zhigen Jiang, and Ming-Hua Xu*Angew. Chem. Int. Ed. 2024, xx, xx-xx.
Asymmetric Cyclopropanation of Primary N-Vinylamides via Carbene Transfer Catalyzed by Cationic Rh(I)/Diene Complexes: An Unexpected Outer-Sphere Mechanism Junyou Zhang, Zhifeng Ma, Weici Xu, Zengwei Wang, Lung Wa Chung*, and Ming-Hua Xu*ACS Catal. 2024, 14, 9385−9396.
Enantioselective Si−H Insertion of Arylvinyldiazoesters Promoted by Rhodium(I)/Diene Complexes Ziyan Li , Jian-Guo Liu, Wen-Ping Zhang, Ming-Hua Xu*Adv. Synth. Catal. 2024, 366, 2514-251.
The Advance in Transition Metal-Catalyzed Asymmetric O–H, S–H Insertion Reactions Junyou Zhang, and Ming-Hua Xu*Sci. Sin. Chem. 2023, xxx. DOI: 10.1360/SSC-2022-0219
Rhodium(I)-Catalyzed Direct Enantioselective C-H Functionalization of Indoles Dong-Xing Zhu, and Ming-Hua Xu*J. Org. Chem. 2023, 88, xxx.
Design of A Coumarin-Based Fluorescent Probe for Efficient in Vivo Imaging of Amyloid-β Plaques Yangyang Cao, Xiaohui Liu, Jingjing Zhang, Zhongmin Liu, Yan Fu, Dong Zhang, Mingyue Zheng,* Haiyan Zhang,* and Ming-Hua Xu*ACS Chem. Neurosci. 2023, 14, xxx.
Low Coordination State Rh(I)-Complex as High Performance Catalyst for Asymmetric Intramolecular Cyclopropanation: Construction of penta-Substituted Cyclopropanes Junyou Zhang, Weici Xu, and Ming-Hua Xu*Angew. Chem. Int. Ed. 2023, e202216799.
Rhodium-Catalyzed Asymmetric 1,4-Addition of α/β-(N-Indolyl) Acrylates Shuting Tan, Jian-Guo Liu, and Ming-Hua Xu*Org. Lett. 2022, 24, 9349-9354.
Rhodium(I) Carbene-Promoted Enantioselective C-H Functionalization of Simple Unprotected Indoles, Pyrroles and Heteroanalogues: New Mechanistic Insights Tian-Yi Wang, Xiao-Xuan Chen, Dong-Xing Zhu, Lung Wa Chung, and Ming-Hua Xu* Angew. Chem. Int. Ed. 2022, e202207008
Rhodium(i)-catalyzed C-S bond formation via enantioselective carbenoid S-H insertion: catalytic asymmetric synthesis of α-thioesters Yu-Tuo Sun, Xiaofeng Rao, Weici Xu and Ming-Hua Xu* Org. Chem. Front. 2022, DOI:10.1039/D2QO00164K
Applications of Asymmetric Petasis Reaction in the Synthesis of Chiral Amines Yi Li,Ming-Hua Xu* Acta Chimica Sinica 2021, 79, 1345-1359.
Stereodivergent Synthesis of Enantioenriched 2,3-Disubstituted Dihydrobenzofurans via a One-Pot C–H Functionalization/Oxa-Michael Addition Cascade Dong-Xing Zhu, Jian-Guo Liu, and Ming-Hua Xu* J. Am. Chem. Soc. 2021, 143, 8583–8589
Transition Metal-Catalyzed Asymmetric Carbene Insertion for Synthesis of Chiral Amines Bo Liu, and Ming-Hua Xu* Chinese Science Bulletin, 2021, 66, 3251-3260. (in Chinese) (Invited contribution, Special issue)
Facile Synthesis of Coumaronochromones through Palladium-Catalyzed Intramolecular Cross Dehydrogenative Coupling Chang-Xue Gu, Jian-Guo Liu, Wen-Wen Chen,* and Ming-Hua Xu* Tetrahedron 2021, 85, 132048-132054.(Invited contribution, Special issue in honor of Professor Guo-Qiang Lin)
Rhodium(I)-Catalyzed Enantioselective C(sp3)-H Functionalization via Carbene-Induced Asymmetric Intermolecular C-H Insertion BoLiu, and Ming-Hua Xu* Chin. J. Chem. 2021, 39, 1911-1915 (Invited contribution, Special issue: Dedicated to Department of Chemistry, SUSTech, on the Occasion of Her 10th Anniversary)
Regiospecific and Enantioselective Arylvinylcarbene Insertion of a C-H bond of Aniline Derivatives Enabled by a Rh(I)-Diene Catalyst Dong-Xing Zhu, Hui Xia, Jian-Guo Liu, Lung Wa Chung,* and Ming-Hua Xu* J. Am. Chem. Soc. 2021, 143. 2608-2619
Water as a Direct Proton Source for Asymmetric Hydroarylation Catalyzed by a Rh(I)–Diene: Access to Nonproteinogenic β2/γ2/δ2-Amino Acid Derivatives Jian-Ping Chen, Yi Li, Chao Liu, Tianyi Wang, Lung Wa Chung, and Ming-Hua Xu* Org. Lett. 2021, 23, 571–577 (Highlighted by Synfacts, 2021, 17(4), 0462)
Development of Bisindole-Substituted Aminopyrazoles as Novel GSK-3β Inhibitors with Suppressive Effects against Microglial Inflammation and Oxidative Neurotoxicity Jian-Guo Liu, Danfeng Zhao, Qi Gong, Fengxia Bao, Wen-Wen Chen*, Haiyan Zhang*, and Ming-Hua Xu* ACS Chem. Neurosci. 2020,11(20), 3398–3408
Chiral diene-promoted room temperature conjugate arylation: highly enantioselective synthesis of substituted chiral phenylalanine derivatives and α,α-di(arylmethyl)acetates Jian-Ping Chen, and Ming-Hua Xu* Org. Biomol. Chem. 2020, 18, 4569-4574
Pd(II)-Catalyzed Asymmetric Annulation toward the Synthesis of 2,3-Disubstituted Chiral Indenols Chang-Xue Gu, Wen-Wen Chen,* and Ming-Hua Xu* J. Org. Chem. 2020, 85, 3887-3893
Palladium-Catalyzed Highly Enantioselective Arylation of Cyclic N-sulfonyl α-Ketimino Esters towards the Synthesis of α-Quaternary Chiral Amino Acid Derivatives Chun-Yan Wu, and Ming-Hua Xu* ChemCatChem 2020, 12, 1129-1133 (Very Important Paper, Invited contribution, topic on Sustainable and Affordable Chemistry to Meet Future Challenges in the Pharmaceutical Industry)
Transition Metal-Catalyzed Asymmetric Addition of Organoboron Reagents to Aldehydes and Ketones Chin. J. Org. Chem. 2020, 40, 255-275. Dong-Xing Zhu, and Ming-Hua Xu*
The enantioselective construction of trifluoromethylated quaternary stereocenters via the Rh-catalyzed asymmetric dehydrated arylation of unprotected hemiaminals Yu-Tuo Sun, Dong-Xing Zhu, Xiaofeng Rao, and Ming-Hua Xu* Org. Chem. Front. 2020, 7, 340-344.
Rhodium-Catalyzed Enantioselective Addition of Arylboroxines to Isatin-Derived N-Boc Ketimines Using Chiral Phosphite–Olefin Ligands: Asymmetric Synthesis of 3-Aryl-3-amino-2-oxindoles Yue-Na Yu, Wei-Yi Qi, Chun-Yan Wu and Ming-Hua Xu* Org. Lett. 2019, 21(18), 7493-7497.
Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids to Glyoxylates:Access to Optically Active Substituted Mandelic Acid Esters Diao Chen, Jian-Guo Liu, Xu Zhang, and Ming-Hua Xu* Synlett 2019, 30, 1693-1697 (Invited contribution, Synlett Cluster issue on Organosulfur and Organoselenium Compounds in Catalysis)
Construction of Chiral 1,3-Diamines through Rhodium-Catalyzed Asymmetric Arylation of Cyclic N-Sulfonyl Imines Chun-Yan Wu and Ming-Hua Xu* Org. Lett. 2019, 21(13), 5035-5039.
Synthesis of indolo[2,3-c]coumarins and indolo[2,3-c]quinolinones via microwave-assisted base-free intramolecular cross dehydrogenative coupling Chang-Xue Gu, Wen-Wen Chen, Bin Xu,and Ming-Hua Xu* Tetrahedron 2019, 75, 1605-1611 (Invited contribution, Special issue in memory of Professor Wei-Shan Zhou)
Highly Enantioselective Synthesis of α-Tertiary Chiral Amino Acid Derivatives through Rhodium-Catalyzed Asymmetric Arylation of Cyclic N-Sulfonyl α-Ketimino Esters Zheng Wang, and Ming-Hua Xu* Org. Biomol. Chem. 2018, 16, 4633-4640 (Cover Article, Highlighted by Synfacts, 2018, 14(9), 0943)