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个人简介

Peng was born in Yilong, Sichuan. He obtained his BS with honors in chemistry under the supervision of Prof. Jun-An Ma at Tianjin University in July 2007, and obtained his PhD in organic chemistry under the supervision of Prof. Yong Tang at Shanghai Institute of Organic Chemistry (SIOC). Then he moved to the Scripps Research Institute (TSRI), and conducted his postdoc research with Prof. Jin-Quan Yu, focusing on ligand accelerated regioselective carbon-hydrogen (C-H) bond activation and non-directed C-H functionalization. After that, Dr. Wang joined SIOC as a full professor in early 2018. His research focuses on the transition metal catalysis and main group chemistry. Experience 2018 – present, Professor, State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, CAS , CHN 2013 – 2017, Research Associate, Department of Chemistry, The Scripps Research Institute, CA, USA (with Prof. Jin-Quan Yu) Education 2008 – 2013, PhD in Organic Chemistry, Shanghai Institute of Organic Chemistry, Shanghai, CHN (with Prof. Yong Tang) 2003 – 2007, BS in Applied Chemistry, Tianjin University, Tianjin, CHN (with Prof. Jun-An Ma) Awards Thieme Chemistry Journals Award (2020) Shanghai Rising-Star Program (2020) Thousand Youth Talents Plan (2018) 100 Talented Progarm (2017)

研究领域

Research in the Wang group focuses on addressing the long-standing challenges in synthetic chemistry by leveraging transition metal catalysis. Our group’s goal is to advance the efficiency, effectiveness, and sustainability of chemical synthesis by the development of novel reaction processes, catalysts and reagents. We are practically interested in efficiently constructing functionally diverse small-molecule products and functional materials. 1. Chiral Ligand Development 2. Main Group Chemistry 3. Reaction Discovery

近期论文

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Wu, Y.*; Qian, H.-Y.; Zou, J.-Y.; Wu, Q.-Y.; Nie, X.-X.; Zheng, L.; Wang, P.* Rh-Catalyzed Enantioselective Hydrosilylation of Unactivated Alkenes. Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-3tlq2. She, L.-Q.; Wang, D.-M.; Wu, Y.; Wang, P.* Ligand-Enabled Ni-Catalyzed Dicarbofunctionalization of Alkenyl Alcohols. Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-hrv2f. Chen, S.-H.; Zhang, S.; Chen, Z.-Y.; Wu, Y.; Wang, P.* The Development and Application of SPSiBox Ligands: Cu-Catalyzed Enantioselective Carbene Insertion of Ge–H Bonds. Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-105l3. Wang, J.-P.; Liu, T.; Wu, Y.; Wang, P.* Pd-Catalysed Migratory 1,1-Cycloannulation Reaction of Alkenes. in revision. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-jxsfc.) Wang, D.-M.; Shan, H.-M.; She, L.-Q.; He, Y.-Q.; Wu, Y.; Tang, Y.; Xu, L.-P.*; Wang, P.* Ligand-Enabled Ni-Catalysed Dicarbofunctionalisation of Alkenes with Diverse Native Directing Groups. Nat. Commun. 2024, in press. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-h02wc.) Zheng, L.*; Li, Y.-C.; Wu, Y.; Wang, P.* Photoinduced Copper-Catalyzed Cross-Coupling of Acylsilanes with Heteroarenes via Bimetallic Relay. Adv. Sci.2024, 11, 2409457. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-6x3q7.) Wang, D.-M.; He, Y.-Q.; Wu, Y.; Tang, Y.; Wang, P.* Construction of Lactones via Ligand-Enabled Ni-Catalyzed Alkene Hydroxylarylation/Lactonization. Org. Lett.2024, 26, 8171–8176. Shen, H.-C.; Li, J.-J.; Wang, P.*, Yu, J.-Q.* meta-C–H Functionalization of Phenylethyl and Benzylic Alcohol Derivatives via Pd/NBE Relay Catalysis. Chem. Sci. 2024, 15, 15819–15824. Li, Z.-D.; Ren, F.; Wu, Y.; Li, J.-J.; Luo, J.*; Wang, P.* Development and Application of SPOSiPs: A Class of Diphosphine Ligands Based on SPOSiOL. Org. Lett.2024, 26, 7436–7441. Wang, J.-P.; Wang, P.* Phosphine Ligand-Dependent Nickel-Catalyzed Regiodivergent Isomerization of Alkenes. Chem Catal.2024, 4, 101089. Cao, Z.-W.; Zhang, J.-C.; Wang, J.-T.; Li, L.; Chen, X.-Y.; Jin, S.; Cao, Z.-Y.*; Wang, P.* Palladium-Catalyzed Hiyama-Type Coupling of Thianthrenium and Phenoxathiinium Salts. Org. Lett. 2024, 26, 6681−6686. Wang, D.-M.; Yang, L.; Chen, D.-P.; Wu, Y.; Tang, Y.; Wang, P.* Pd(II)-Catalyzed 1,2-Oxyarylation of Alkenes with O-Acylhydroxylamines as the Oxygen Source. Org. Lett.2024,26, 3691–3696. Gou, F.-H.; Ren, F.; Wu, Y.; Wang, P.* Catalytic Kinetic Resolution of Monohydrosilanes via Rhodium-Catalyzed Enantioselective Intramolecular Hydrosilylation.  Angew. Chem. Int. Ed.2024, 63, e202404732. (Preprint: Chemrxiv 2024, DOI: 10.26434/chemrxiv-2024-7wxck.) Hu, J.-L.; Wu, Y.; Gao, Y.; Wang, Y.*; Wang, P.* Recent Advances in Catalytic Nitrogen–Nitrogen Bond Formation Reactions. ACS Catal. 2024,14, 5735–5778. Zhao, J.-H.; Zheng, L.; Zou, J.-Y.; Zhang, S.-Y.; Shen, H.-C.; Wu, Y.; Wang, P.* Construction of Si-Stereogenic Silanols by Pd-Catalyzed Enantioselective C–H Alkenylation. Angew. Chem. Int. Ed.2024, 63, e202402612. (Preprint: Chemrxiv 2023, DOI: 10.26434/chemrxiv-2023-57wf2.) Liu, S.; Chen, Y.-S.; Wu, Y.; Wang, P.* Pd-Catalyzed Intermolecular Si–O Formation via Si–C Activation. Sci. China Chem.2024, DOI: 10.1007/s11426-024-1951-0. (Preprint: Chemrxiv 2023, DOI: 10.26434/chemrxiv-2023-z5bsp.) He, H.-D.; Chitrakar, R.; Cao, Z.-W.; Wang, D.-M.; She, L.-Q.; Zhao, P.-G.; Wu, Y.; Xu, Y.-Q.; Cao, Z.-Y.*; Wang, P.* Diphosphine Ligand-Enabled Ni-Catalyzed Chelate-Assisted Inner-Selective Migratory Hydroarylation of Alkenes. Angew. Chem. Int. Ed. 2024, 63, e202313336.  Kuang, X.; Li, J.-J.; Liu, T.; Ding, C.-H.; Wu, K.; Wang, P.*; Yu, J.-Q.* Cu-Mediated Enantioselective C–H Alkynylation of Ferrocenes with Chiral BINOL Ligands. Nat. Commun.2023, 14, 7698.                                           Wu, Y.; Zheng, L.; Wang, Y.*; Wang, P.* Catalytic Asymmetric Synthesis of Silicon-Stereogenic Organosilanes. Chem 2023, 9, 3461–3514.                           Li, M.-H.; Cao, Z.-Y.*; Wang, P.* Programmatic Functionalization of Multihydrosilanes by Hydrogen-Atom-Transfer Photocatalysis. Chem Catal.2023, 3, 100674.       Wang, D.-M.; She, L.-Q.; Yuan, H.; Wu, Y.; Wang, P.* Ligand-Enabled Ni(II)-Catalyzed Hydroxylarylation of Alkenes with Molecular Oxygen. Angew. Chem. Int. Ed.2023, 62, e202304573 .  Li, H.; Zhao, P.-G.; Wang, C.-Y.; Zhang, R.-Y.; Li, J.-J.; Wu, Y.; Wang, P.* SPSiPs, A Class of Diphosphine Ligands Based on SPSiOL with a Large Dihedral Angle. Org. Lett. 2023, 25, 3859–3863. Li, J.-J.; Zhao, J.-H.; Shen, H.-C.; Wu, K.; Kuang, X.; Wang, P.*; Yu, J.-Q.* Atroposelective Remote meta-C–H Activation. Chem 2023, 9, 1452–1463. Kuang, X.; Ding, C.-H.; Wu, Y.; Wang, P.* Catalytic Enantioselective Preparation of Chiral Allylsilanes. Chin. J. Org. Chem. 2023, 43, 3367–3387.         Chen, X.-Y.; Li, Y.-N.; Wu, Y.; Bai, J.-H.; Guo, Y.-L.*; Wang, P.* Cu-Mediated Thianthrenation and Phenoxathiination of Arylborons. J. Am. Chem. Soc.2023, 145, 10431–10440.  Chen, X.-Y.; Kuang, X.; Wu, Y.*; Zhou, J.*; Wang, P.* Thianthrene Radical Cation as a Transient SET Mediator: Photoinduced Thiocyanation and Selenocyanation of Arylthianthrenium Salts. Chin. J. Chem. 2023, 41, 1979–1986.  Meng, G.; Wang, Z.; Chan, H. S. S.; Chekshin, N.; Li, Z.; Wang, P.; Yu, J.-Q.* Dual-Ligand Catalyst for the Nondirected C–H Olefination of Heteroarenes. J. Am. Chem. Soc.2023, 145, 8198–8208. Ye, Z.-H.; Gou, F.-H.; Wu, Y.; Li, C.-Y.*; Wang, P.* Diverse Synthesis of Alkenylsilanes via d-Catalyzed Alkenyl C–H Silylation. Org. Lett. 2023, 25, 2145–2150. Liu T.; Mao, X.-R.; Song, S. Chen, Z.-Y.; Wu, Y.; Xu, L.-P.*; Wang, P.* Enantioselective Nickel-Catalyzed Hydrosilylation of 1,1- Disubstituted Allenes. Angew. Chem. Int. Ed. 2023, 62, e202216878. Zheng L.; Guo, X.; Li, Y.-C.; Wu, Y.; Xue, X.-S.*; Wang, P.* Cu/SaBox-Catalyzed Photoinduced Coupling of Acylsilanes with Alkynes. Angew. Chem. Int. Ed. 2023, 62, e202216373. Wang, D.-M.; She, L.-Q.; Wu, Y.; Zhu, C.; Wang, P.* Ligand-Enabled Ni-Catalyzed Hydroarylation and Hydroalkenylation of Internal Alkenes with Organoborons. Nat. Commun. 2022, 13, 6878. Dong, Z.-Y.; Zhao, J.-H.; Wang, P.*; Yu, J.-Q.* MPAI-Ligand Accelerated Pd-Catalyzed C(sp3)–H Arylation of Free Aliphatic Acids. Org. Lett. 2022, 24, 7732–7736. Wang, J.-P.; Song, S.; Wu, Y.; Wang, P.* Construction of Azaheterocycles via Pd-Catalyzed Migratory Cycloannulation Reaction of Unactivated Alkenes. Nat. Commun. 2022, 13, 5059. Chen, X.-Y.; Wu, Y.; Wang, P.* Recent Advances in Thianthrenation/Phenoxathiination Enabled Site-Selective Functionalization of Arenes. Synthesis, 2022, 54, 3928–3940. Wu, Y.; Wang, P.* Silicon-Stereogenic Monohydrosilane: Synthesis and Applications. Angew. Chem. Int. Ed. 2022, 61, e202205382. Chen, H.; Wu, Y.; Yu, Y.; Wang, P.* Pd-Catalyzed Isomerization of Alkenes. Chin. J. Org. Chem. 2022, 42, 742–757. Huang, Y.-H.; Wu, Y.; Zhu, Z.; Zheng, S.; Ye, Z.; Peng, Q.*; Wang, P.* Enantioselective Synthesis of Silicon-Stereogenic Monohydrosilanes by Rhodium-Catalyzed Intramolecular Hydrosilylation. Angew. Chem. Int. Ed. 2022, 61, e202113052. Yang, L.; Xu, W.-Q.; Liu, T.; Wu, Y.; Wang, B.-Q.*; Wang, P.* Concise Synthesis and Application of Enantiopure Spirobiphenoxasilin-Diol and Its Related Chiral Ligands. Chem. Commun. 2021, 57, 13365–13368. Zhang, Y.-L.; Wang, G.-H.; Wu, Y.; Zhu, C.-Y.*; Wang, P.* Construction of α-Amino Azines via Thianthrenation Enabled Photocatalyzed Hydroarylation of Azine-Substituted Enamides with Arenes. Org. Lett. 2021, 23, 8522–8526. Zheng, L.; Nie, X.-X.; Wu, Y.; Wang, P.* Construction of Si-Stereogenic Silanes via C-H Activation Approach. Eur. J. Org. Chem. 2021, 6006–6014. Zheng, L.; Wang, P.* Efficient Synthesis of Diarylmethanamines via Transition-Metal-Free Double-Insertive Coupling of Isocyanides with Arylboronic Acids. Chin. J. Org. Chem. 2021, 41, 1272–1273. Wang, D.-M.; Feng, W.; Wu, Y.; Liu, T.; Wang, P.* Redox-Neutral Nickel(II) Catalysis: Hydroarylation of Unactivated Alkenes with Arylboronic Acids. Angew. Chem. Int. Ed. 2020, 59, 20399–20404. Chen, H.-C.; Chang, X.* A Journey to SPSiOL, a New Type of Chiral Ligand Scaffold. Chin. J. Chem. 2020, 38, 1203–1204. Chang, X.; Ma, P.-L.; Chen, H.-C.; Li, C.-Y.*; Wang, P.* Asymmetric Synthesis and Application of Chiral Spirosilabiindanes. Angew. Chem. Int. Ed. 2020, 59, 8937–8940. Nie, X.-X.; Huang, Y.-H.; Wang, P.* Thianthrenation Enabled α-Arylation of Carbonyl Compounds with Arenes. Org. Lett. 2020, 22, 7716-7720. Zhang, Y.-L.; Yang, L.; Wu, J.; Zhu, C.*; Wang, P.* Vinyl Sulfonium Salts as the Radical Acceptor for Metal-Free Decarboxylative Alkenylation. Org. Lett. 2020, 22, 7768-7772. Wu, Y.; Huang, Y.-H.; Chen, X.-Y.; Wang,P.* Site-Selective Silylation of Simple Arenes Mediated by Thianthrene S-Oxide. Org. Lett. 2020, 22, 6657–6661. Chen, X.-Y.; Wu, Y.; Zhou, J.*; Wang, P.* Pd-Catalyzed Site-Selective Borylation of Simple Arenes via Thianthrenation. Chin. J. Chem. 2020, 38, 1269–1272.

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