朱军 - 厦门大学 - 固体表面物理化学国家重点实验室

个人简介

Education B.S., Xiamen University, 1996-2000 PhD, The Hong Kong University of Science and Technology (2003-2007) Professional Experience Research Associate, Hong Kong University (2007 - 2008) Postdoctoral Research Associate, Uppsala University (2008 - 2010) Associate Professor, Xiamen University　( 2010 - 2017 ) Professor, Xiamen University ( 2018 - 2023) Professor, the Chinese University of Hong Kong, Shenzhen ( 2023 - ) Honors and Awards New Century Excellent Talents in University (教育部新世纪优秀人才, 2013) The Top-Notch Young Talents Program of China (中组部万人计划青年拔尖人才, 2014)

研究领域

Physical Organic Chemistry: Investigate the structure and bonding, reaction mechanisms in organic/organometallic chemistry via quantum calculations and test our predictions via tight collaborations with top experimental groups.

近期论文

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π-Aromaticity Dominating in a Saturated Ring: Neutral Aromatic Silicon Analogues of Cyclobutane-1,3-diyls. Yang Li, Shicheng Dong, Junjie Guo, Yazhou Ding, Jianying Zhang, Jun Zhu*, Chunming Cui*, J. Am. Chem. Soc. 2023, 145, ASAP. DOI: 10.1021/jacs.3c06555. Adaptive Aromaticity in 18e Metallapentalenes. Qingfu Ye, Yifei Fang, Jun Zhu*, Inorg. Chem. 2023, 62, 14764–14772. DOI: 10.1021/acs.inorgchem.3c02223. Harmonic Oscillator Model of Aromaticity for Organometallics Containing the Os–C Bond. Qingfu Ye, Jun Zhu*, Organometallics. 2023, 42, 2369–2377. DOI: 10.1021/acs.organomet.3c00257. Probing Near-infrared Absorbance of E and Z Diazene Isomers via Antiaromaticity. Shuwen Chen, Jun Zhu*, J. Org. Chem. 2023, 88, 12183–12193. DOI: 10.1021/acs.joc.3c00010. Adaptive σ aromaticity in the rhenacyclopropene rings. Qianqian Deng, Jun Zhu*, J. Comput. Chem. 2023, 44, 2294-2301. DOI: 10.1002/jcc.27192. FP(μ-N)2S: A Sulfur-Pnictogen Four-Membered Ring with 6π Electrons. Bifeng Zhu, Yanlin Song, Jun Zhu, Guntrum Rauhut, Junjie Jiang, Xiaoqing Zeng*, Chem. Eur. J. 2023, 29, e202300251. DOI: 10.1002/chem.202300251. Exploiting heterocycle aromaticity to fabricate new hot exciton materials. Shaoting Guo, Long Wang*, Qianqian Deng, Guoliang Wang, Xiangbin Tian, Xiyu Wang, Zuyuan Liu, Mengfan Zhang, Senhao Wang, Yanqin Miao*, Jun Zhu*, Hua Wang*, J. Mater. Chem. C. 2023, 11, 6847-6855. DOI: 10.1039/D3TC01192E. Probing the Origin of Higher Efficiency of Terphenyl Phosphine over the Biaryl Framework in Pd-catalyzed C-N Coupling: A Combined DFT and Machine Learning Study. Qingfu Ye, Yu Zhao, Jun Zhu*, Artif. Intell. Chem. 2023, 1, 100005. DOI: 10.1016/j.aichem.2023.100005. Dynamic Evolving Exothermicity Steers Ultrafast Formation of a Correlated Triplet Pair State. Yishi Wu*, Lina Lu, Buyang Yu, San Zhang, Pengdong Luo, Mingxing Chen, Jingping He, Yongyao Li, Chunfeng Zhang*, Jun Zhu*, Jiannian Yao, Hongbing Fu*, J. Phys. Chem. Lett. 2023, 14, 4233-4240. DOI: 10.1021/acs.jpclett.3c00193. The application of aromaticity and antiaromaticity to reaction mechanisms. Qin Zhu, Shuwen Chen, Dandan Chen, Lu Lin, Kui Xiao, Liang Zhao, Miquel Sola, Jun Zhu*, Fundam. Res. 2023, 3, In Press. DOI: 10.1016/j.fmre.2023.04.004. An unprecedented route to achieve persistent 1H-azirine. Alvi Muhammad*, Jun Zhu*, Phys. Chem. Chem. Phys. 2023, 25, 12602-12606. DOI: 10.1039/D2CP05915K. Mechanism of metalated pyrrole-singlet oxygen chemiluminescent reaction. Meng Xue, Dan-Ling Zhuang, Li-Zhi Fu, Guo Chen, Jiaying Su, Jun Zhu*, Xiao-Yi Yi*, Polyhedron. 2023, 238, 116421. DOI: 10.1016/j.poly.2023.116421. A class of non-aromatic 1,3-disilapyrroles acting as stable organosilicon-based triplet diradicals. Yun Xiong, Shicheng Dong, Shenglai Yao, Christian Lorent, Konstantin B. Krause, Gonela Vijaykumar, Jun Zhu, Christian Limberg, Matthias Driess*, Nat. Synth. 2023, 2, 678–687. DOI: 10.1038/s44160-023-00279-6. Synthesis and Reactivity of an Anti-van’t Hoff/Le Bel Compound with a Planar Tetracoordinate Silicon(II) Atom. Changkai Shan, Shicheng Dong, Shenglai Yao, Jun Zhu, Matthias Driess*, J. Am. Chem. Soc. 2023, 145, 7084-7089. DOI: 10.1021/jacs.3c00722. Synthesis and characterization of Craig-type antiaromatic species with [4n + 2] π electrons. Lina Chen, Lu Lin, Amit Ranjan Nath, Qin Zhu, Zhixin Chen, Jingjing Wu, Hongjian Wang, Qian Li, Wen-Feng Lin, Jun Zhu*, Haiping Xia*, Natl. Acad. Sci. U.S.A. 2023, 145, e2215900120. DOI: 10.1073/pnas.2215900120. Helical Trilayer Nanographenes with Tunable Interlayer Overlaps. Yang-Yang Ju, Ling Chai, Kang Li, Jiang-Feng Xing, Xiao-Hui Ma, Zhen-Lin Qiu, Xin-Jing Zhao, Jun Zhu, Yuan-Zhi Tan*, J. Am. Chem. Soc. 2023, 145, 2815–2821. DOI: 10.1021/jacs.2c08746. Screening Carbon-Boron Frustrated Lewis Pairs for Small-Molecule Activation including N2, O2, CO, CO2, CS2, H2O and CH4: A Computational Study. Jie Zeng, Rulin Qiu, Jun Zhu*, Chem. Asian J. 2023, 18, e202201236. DOI: 10.1002/asia.202201236. Aromaticity Concerto in Polycyclic Conjugated Hydrocarbons: Fusion Pattern on Combined Aromaticity Strategy Leads to Distinctive Excited State Photophysics of Dinaphthopentalenes. Long Wang*, Lu Lin, Teng-Shuo Zhang, Shaoting Guo, Zuyuan Liu, Mengfan Zhang, Senhao Wang, Ganglong Cui*, Wei-Hai Fang, Jun Zhu*, Hongbing Fu, Jiannian Yao, CCS Chem. 2023, 5, IOA Article. DOI: 10.31635/ccschem.022.202202430. Probing the Mechanism of Adaptive Aromaticity in Metallapyridiniums. Qianqian Deng, Jiaying Su, Jun Zhu*, Inorg. Chem. Front. 2023, 10, 934-941. DOI: 10.1039/D2QI02119F. Catalytic Mechanisms of Transfer Hydrogenation of Azobenzene with Ammonia Borane by Pincer Bismuth Complex: Crucial Role of C=N Functional Group on the Pincer Ligand. Qin Zhu, Shuoqi Zhang, Jing Ma, Jun Zhu*, Shuhua Li*, Guixiang Zeng*, Chem. Asian J. 2022, 17, e202201069. DOI: 10.1002/asia.202201069. Direct Conversion of N2 and O2 to Nitric Oxide at Room Temperature Initiated by Double Aromaticity in the Y2BO+ Cation. Ming Wang, Fei-Ying You, Min Gao, Zhi-Ying Chen, Lan-Ye Chu, Lian-Rui Hu*, Jun Zhu*, Jia-Bi Ma*, J. Phys. Chem. Lett. 2022, 13, 10697–10704. DOI: 10.1021/acs.jpclett.2c02925. Predicting Small Molecule Activation including Catalytic Hydrogenation of Dinitrogen Promoted by a Dual Lewis Acid. Shicheng Dong, Jun Zhu*, Chem. Asian J. 2022, 17, e202200991. DOI: 10.1002/asia.202200991. Probing a General Strategy to Break the C-C Bond of Benzene by a Cyclic (Alkyl)(Amino)Aluminyl Anion. Fangzhou Xu, Jun Zhu*, Chem. Eur. J. 2022, 28, e202203216. DOI: 10.1002/chem.202203216. Chiral polycyclic benzosultams from photocatalytic diastereo- and enantioselective benzylic C–H functionalization. Shaonan Zhang, Shicheng Dong, Xiuliang Cheng, Ziqi Ye, Lu Lin, Jun Zhu*, Lei Gong*, Org. Chem. Front. 2022, 9, 6853-6860. DOI: 10.1039/D2QO01491B. Adaptive Aromaticity in Osmapentalene and Osmapyridinium Complexes with Carbone Ligands. Feiying You, Rulin Qiu, Jun Zhu*, J. Phys. Org. Chem. 2022, 35, e4450. DOI: 10.1021/10.1002/poc.4450. A Conjugated Diosma-Octacyclic Complex and Its Mixed-Valence Singly Reduced State. Yuxuan Hu, Qianqian Deng, Ya-Ping Ou, Xiaofei Yang, Jing Zhang, Emily K. Garrett, Jun Zhu*, Shenghua Liu* and Frantisek Hartl*, Inorg. Chem. Front. 2022, 9, 5893-5902. DOI: 10.1039/D2QI01523D. Probing the Hyperconjugative Aromaticity of Cyclopentadiene and Pyrroliums Containing Group 7 Transition Metal Substituents. Shuwen Chen, Jun Zhu*, Organometallics. 2022, 41, 2742–2752. DOI: 10.1021/acs.organomet.2c00352. Understanding reaction mechanisms of metal-free dinitrogen activation by methyleneboranes. Jie Zeng, Jiaying Su, Feiying You, Jun Zhu*, Chin. Chem. Lett. 2023, 34, 107759. DOI: 10.1016/j.cclet.2022.107759. An Isolable 2,5-Disila-3,4-Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N-Bis(Silylenyl)Aniline. Yun Xiong, Shicheng Dong, Shenglai Yao, Chenshu Dai, Jun Zhu, Sebastian Kemper, Matthias Driess*, Angew. Chem. Int. Ed. 2022, 61, e202209250. DOI: 10.1002/anie.202209250. A Bis(silylene)pyridine Pincer Ligand Can Stabilize Mononuclear Manganese(0) Complexes: Facile Access to Isolable Analogues of the Elusive d7-Mn(CO)5 Radical. Shweta Kalra, Daniel Pividori, Dominik Fehn, Chenshu Dai, Shicheng Dong, Shenglai Yao, Jun Zhu, Karsten Meyer, Matthias Driess*, Chem. Sci. 2022, 13, 8634-8641. DOI: 10.1039/D2SC03352F. Mechanistic Insight into the Ni-Catalyzed Kumada Cross-Coupling: Alkylmagnesium Halide Promotes C–F Bond Activation and Electron-Deficient Metal Center Slows Down β-H Elimination. Yuanyuan Li, Jun Zhu*, J. Org. Chem. 2022, 87, 8902–8909. DOI: 10.1021/acs.joc.2c00586. Asymmetric Construction of α,γ-Disubstituted α,β-Butenolides Directly from Allylic Ynoates Using a Chiral Bifunctional Phosphine Ligand Enables Cooperative Au Catalysis. Ting Li*, Shicheng Dong, Conghui Tang, Meiling Zhu, Nan Wang, Weiguang Kong, Wenchao Gao, Jun Zhu*, and Liming Zhang*, Org. Lett. 2022, 24, 4427-4432. DOI: 10.1021/acs.orglett.2c01652. Stabilizing a 20-Electron Metallaazulyne by Aromaticity. Rulin Qiu, Jiashun Wu, Jun Zhu*, Inorg. Chem. 2022, 61, 9073–9081. DOI: 10.1021/acs.inorgchem.2c00594. Predicting Dinitrogen Activation by Carborane-Based Frustrated Lewis Pairs. Chenshu Dai, Yuanyuan Huang, Jun Zhu*, Organometallics. 2022, 41, 1480–1487. DOI: 10.1021/acs.organomet.2c00069.