叶青 - 南方科技大学

个人简介

叶青博士，2004年本科毕业于复旦大学化学系，后前往德国维尔茨堡大学化学系继续深造，师从Holger Braunschweig教授，主要从事亚硼烷金属络合物的合成与研究，并与导师共同提出了以过渡金属为媒介来实现可控的硼原子成链反应，以及实现了以硼原子为中心的路易斯碱的合成。2012年，叶博士获得国家优秀自费留学生奖学金，并于同年获得维尔茨堡大学最高荣誉（summa cum laude）博士学位，并被授予该校下法兰肯学术纪念奖。2015年获得德国科学基金会（DFG）科研奖学金资助，前往加州大学伯克利分校T. Don Tilley教授课题组开展了为期一年的博士后研究，期间主要从事二配位过渡金属配合物的合成与研究。其后叶青博士以DFG回访学者的身份加入维尔茨堡大学化学系Todd B. Marder教授课题组。2017年叶青博士加盟南方科技大学化学系开展独立研究。同年被评定为深圳市海外高层次人才“孔雀计划（B类）”。迄今为止，叶青博士已以第一作者完成“硼宾化学”领域诸多具有世界影响力的工作，并在《自然》、《自然化学》、《美国化学会志》以及德国《应用化学》等国际顶尖期刊发表多篇有重要影响力的论文。

研究领域

主要从事亚硼烷金属络合物的合成与研究，并与导师共同提出了以过渡金属为媒介来实现可控的硼原子成链反应，以及实现了以硼原子为中心的路易斯碱的合成。 1）双炔基硼烷的配位化学 2）硼基超级给电子体 3）硼杂环三维无机类似物 4）主族元素参与的均相催化反应。

近期论文

查看导师新发文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

C. Zhang, J. Wang, W. Su, Z. Lin*, Q. Ye*, Synthesis, Characterization and Density Functional Theory Studies of Three-Dimensional Inorganic Analogues of 9,10-Diboraanthracene – a New Class of Lewis Superacids, J. Am. Chem. Soc. 143, 10.1021/jacs.1c03057 (2021). W. Su, Y. Ma, L. Xiang, J. Wang, S. Wang, L. Zhao*, G. Frenking*, Q. Ye*, Isolation of a Uranium(III)‐Carbon Multiple Bond Complex, Chem. Eur. J. 10.1002/chem.202100699 (2021). W. Ming, X. Liu, L. Mao, X. Gu and Q. Ye*, Transition-Metal-Catalyzed Synthesis of Chiral Allylboronates, Chin. J. Chem. 39, 1716 (2021). H. Zhang,# J. Wang,# W. Yang,# L. Xiang, W. Sun, W. Ming, Y. Li, Z. Lin*, Q. Ye*, Solution-Phase Synthesis of a Base-Free Benzoborirene and a Three-Dimensional Inorganic Analogue, J. Am. Chem. Soc. 142, 17243 (2020). (# equal contribution) W. Ma, I. Douair, L. Maron*, Q. Ye*, Incorporation of Boron into Uranium Metallacycles: Synthesis, Structure and Reactivity of Boron‐containing Uranacycles Derived from Bis(alkynyl)boranes, Chem. Eur. J. 26, 13573 (2020). Highlighted as the Cover Feature. J. Maier, M. Deutsch, J. Merz, Q. Ye, O. Diamond, M.-T. Schilling, A. Friedrich, B. Engels*, T. B. Marder*, Highly Conjugated π‐Systems Arising from Cannibalistic Hexadehydro‐Diels‐Alder Couplings: Cleavage of C‒C Single and Triple Bonds, Chem. Eur. J. 26, 15989 (2020). L. Ma,# X. Zhang,# W. Ming,# S. Su, X. Chang, Q. Ye*, Reactions of Dihaloboranes with Electron-Rich 1,4-Bis(trimethylsilyl)-1,4-diaza-2,5-cyclohexadienes, invited paper for Todd B. Marder 65th birthday issue, Molecules 25, 2857 (2020). (# equal contribution) Y. Cui,# L. Xiang,# J. Wang, C. Li, W. Hao, Q. Ye*, Storage and release of two electrons from an electron-rich carbon-carbon bond: boron mediated reversible coupling of DMAP and 9-azajulolidine, Chem. Commun. 56, 6794 (2020). (# equal contribution) L. Mao,# C. Li,# L. Xiang, D. Fu, W. Ma, Q. Ye*, Synthesis of Allenyl-Bdan via a Cu(I)-catalyzed Borylation of Propargylic Alcohols with the Unsymmetric Diboron Reagent (Bpin-Bdan), J. Org. Chem. 85, 2823 (2020). (# equal contribution) S. K. Mellerup, Y. Cui, F. Fantuzzi, P. Schmid, J. T. Goettel, G. Bélanger-Chabot, M. Arrowsmith, I. Krummenacher, Q. Ye, V. Engel, B. Engels, H. Braunschweig*, Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions, J. Am. Chem. Soc. 141, 16954 (2019) W. Ma, J.-X. Zhang, Z. Lin*, T. D. Tilley, Q. Ye*, Synthesis, structure and DFT calculations of mononuclear cyclic (alkyl)(amino) carbene supported titanium (II) complexes, Dalton. Trans. 48, 14962 (2019) J. Wang, Y. Cui, Q. Ye*, Bis(alkynyl)borane: A New Class of Acyclic Boron-Containing π Ligands in η5-Coordination Mode, Inorg. Chem. 58, 11279 (2019) Highlighted in "Science Progress". Q. Ye, M. S. Ziegler, K. V. Lakshmi, T. D. Tilley*, Titanium Imido Complexes via Displacement of –SiMe3 and C–H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC), Eur. J. Inorg. Chem. 18, 2484 (2017) H. Braunschweig*, I. Krummenacher, M.-A. Légaré, A. Matler, K. Radacki, Q. Ye, Main-Group Metallomimetics — Unprecedented Transition Metal-like Photolytic CO Substitution at Boron, J. Am. Chem. Soc.139, 1802 (2017) H. Braunschweig*, A. Damme, R. D. Dewhurst, K. Radacki, F. Weißenberger, B. Wennemann, Q. Ye, Fundamental differences between group 8 metals: divergent oxidation state preferences and mechanisms in Fe/Ru borylene formation, Chem. Eur. J. 8471 (2016) H. Braunschweig,* R. D. Dewhurst, L. Pentecost, K. Radacki, A. Vargas, Q. Ye, Dative Bonding Between Group 13 Elements Using a Boron-Centered Lewis Base, Angew. Chem. Int. Ed. 55, 436 (2016) H. Braunschweig*, R. D. Dewhurst, F. Hupp, M. Nutz, K. Radacki, C. W. Tate, A. Vargas, Q. Ye, Multiple complexation of CO and related ligands to a main-group element, Nature 522, 327 (2015) H. Braunschweig*, Q. Ye, M. A. Celik, K. Radacki, R. D. Dewhurst, Cyclization of a 1,4-Diborabutadiene Ligand with Both Atoms of CO, Angew. Chem. Int. Ed. 54, 5065 (2015) H. Braunschweig*, R. D. Dewhurst, K. Radacki, B. Wennemann, Q. Ye, 1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group, Chem. Commun. 51, 15468 (2015) H. Braunschweig*, A. Damme, R. D. Dewhurst, H. Kelch, B. B. Macha, K. Radacki, A. Vargas, Q. Ye, Platinum trans-Bis(borirene) Complexes Displaying Coplanarity and Communication Across a Platinum Metal Center, Chem. Eur. J. 21, 2377 (2015)