Miller, Jeffrey T. - Purdue University - Davidson School of Chemical Engineering

个人简介

Argonne National Laboratory 2008-present Chemical Science and Engineering Senior Scientist and group leader of the heterogeneous catalysis group developing,testing and characterizing new catalytic materials for energy production. Catalytic reactions include conversion of biomass and natural gas to transportation fuels.Catalytic materials include supported nano-particles and alloys; single site, supported heterogeneous catalysts, colloidal nano-particles and homogenous catalysts. Special interest in characterization of catalysts under realistic reaction conditions of high temperature and pressure, especially X-ray absorption spectroscopy at the Advanced Photon Source. Industrial Chemical Engineering Experience BP Chemicals Company 2007-08 Aromatic Technology Development Team leader for development of new selective oxidation catalyst: responsible for labscale preparation, optimization and intermediate scale-up. Additional responsibilities include analytical characterizations of the new catalyst. 1998-06 Para-Xylene Business Unit Team leader for development of proprietary catalysts: responsibilities include material synthesis, pilot plant evaluations, transfer of proprietary methods to catalyst manufacturer and plant demonstrations. Additional responsibilities include development of advanced separation processes. AMOCO Oil Company 1994-97 Residual Oil Process Division Lead catalyst team for developed a new catalyst for conversion of asphalt to transportation fuels 1992-94 Fluid Catalytic Cracking Process Division Team leader for commercialization of a process for disposal of waste plastics to fuels 1988-92 Naphtha Reforming Process Division Team leader for the developed a new catalyst and process for conversion of light paraffins to aromatics 1985-88 Hydrotreating Process Division Commercialized catalyst and process improvements for a distillate hydrocracking process 1982-85 Synthetic Fuels Division Developed a catalyst and process to convert CO + H2 to iso-paraffins or higher alcohols 1980-82 Synthetic Fuels Division Developed a two-stage, shale oil hydrocracking catalyst and process for production of jet fuel Education 1980 Oregon State University, Corvallis, OR Ph. D., Inorganic Chemistry Advisor: C.W. DeKock 1973 University of New Mexico, Albuquerque, NM M. S., Inorganic Chemistry 1971 Memphis State University, Memphis, TN B. S., Chemistry

研究领域

We are a part of the Purdue Catalysis Center, which fosters interaction among faculty and students in catalysis research groups by collaborating on research projects, sharing resources and facilities, and holding weekly joint group meetings.

近期论文

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Effect of Cu content on the bimetallic Pt-Cu catalysts for propane dehydrogenation,” Z. Ma, Z. Wu, J.T. Miller, Catalysis Structure and Reactivity, 3, 43-53 (2107). Mechanism of Me-Re Bond Addition to Platinum(II) and Dioxygen Activation by the Resulting Pt-Re Bimetallic Center,” K.R. Pichaandi, L. Kabalan, H. Amini, G. Zhang, H. Zhi, H.I. Kentamma, P. Fanwick, J.T. Miller, S. Kais, M. Rashdi, S.M. Nabavizadeh, M. M. Abu-Omar, Inorg. Chem., 56, 2145-2152 (2017). BSMV as a Novel Biotemplate for Palladium Nanomaterial Synthesis," O.O. Adigun, E.L. Retzlaff-Roberts, G. Novikova, L. Wang, B.S. Kim, J. Ilavsky, J.T. Miller, L.S. Loesch-Fries, M.T. Harris, Langmuir, 33, 1716-1724 (2017). The Nature of the Isolated Gallium Active Center for Propane Dehydrogenation on Ga/SiO-2," V.J. Cybulskis, S.U. Pradhan, J.J. Lovon-Quintana, A.S. Hock, B. Hu, G, Zhang, W. N. Delgass, F.H. Ribeiro, J.T. Miller, Catal. Lett. 147, 1252-1262 (2017). Pd-In intermetallic alloy nanoparticles: highly selective ethane dehydrogenation catalysts," Z. Wu, E.C. Wegener, H.-T. Tseng, J.R. Gallagher, J.W. Harris, R.E. Diaz, Y. Ren, F.H. Ribeiro, J.T. Miller, Catal. Sci. & Tech., 6, 6965-6976 (2016). S. Guerrero, S. Schuyten, J.T. Miller, T. Shibata, M. Di Serio, E.E. Wolf, “Operando and In-Situ FTIR, EXAFS Studies of Cu on TiO2 Nanotubes Applied to the Preferential Oxidation of CO,” submitted to Appl. Catal. A: Gen. 2012. B. Bayram, I.I. Soykal, D. von Deak, J.T. Miller, U.S. Ozkan, “Ethanol Steam Reforming over Co-based catalysts: Investigation of Cobalt Coordination Environment under Reaction Conditions,” accepted J. Catal. 2012. Ryan C. Nelson and Jeffrey T. Miller, “An Introduction to X-ray Absorption Spectroscopy and Its In Situ Application to Organometallic Compounds and Homogeneous Catalysts,”accepted to Catalysis Science and Technology, 2012. J.H. Pazmiño, M. Shekhar, W.D. Williams, M.C. Akatay, J.T. Miller, W.N. Delgass, F.H. Ribeiro, “Metallic Pt as active sites for the Water-Gas Shift reaction on alkali-promoted supported catalysts,” accepted to J. Catal., 2012. J.-S. McEwen, T. Anggara, V. F. Kispersky, J. T. Miller, F.H .Ribeiro, W. N. Delgass, W.F. Schneider, “Exchanged Cu atoms in small pore zeolites: A combined first-principles and experimental study, accepted 2012. Biswas, S., Miller, J.T., Kumar, C.S.S.R., “High Throughput and Controlled Formation of Ultra-small Copper Nanoclusters in Milli-fluidic Space,” accepted to NanoLetters, 2012. T.-Z. Lin, T. Wu, R.C. Nelson, J.T. Miller, F.P. Gabbai, “ Lewis Acidic Properties of a Cationic Mercury-Antimony Complex,” submitted to JACS 2011. M. Shekhar, J. Wang, W.-S. Lee, W.D. Williams, S.M. Kim, E.A. Stach, J.T. Miller, W.N.Delgass, F.H. Ribeiro, “Size and Support Effects for the Water−Gas Shift Catalysis over Gold Nanoparticles Supported on Model Al2O3 and TiO2,” accepted 2012 JACS. N. Guo, L.A. Williams, A. Motta, I.L. Fragalà, C.L. Marshall, J.T. Miller, T.J. Marks,“Sulfated Alumina-Supported Zirconocenium Catalysis. A Periodic DFT and X-Ray Absorption Study of Cationic Catalysts Having Virtually 100% Active Sites,” submitted JACS 2012. L. Bollmann, W. D. Williams, V. Kispersky, D. Zemlyyanov, J. T. Miller, W. N. Delgass,F. H. Ribeiro, “Promotion of Palladium and Platinum by Iron in Low Temperature Water Gas Shift Catalysts,” submitted to J. Catalysis, 2012. Y.S. Choi, E.C. Moschetta, R.M. Rioux, J.T. Miller, M. Fasulo, M.J. McMurdo, T.D.Tilley, “Highly Dispersed Pd-SBA-15 Materials from Tris(tert-butoxy)siloxy Complexes of Pd(II),” submitted 2012. R. Zhang, T. Wu, J.T. Miller, C.D. Baertsch, “Identification of Active Oxygen Sites for CO Preferential Oxidation in Mixed Copper Cerium Oxides by In-situ X-ray Absorption Spectroscopy at the Ce L3-edge and Anaerobic Titrations,” submitted 2012. D. Williams, L. Bollmann, J. T. Miller, W. N. Delgass, F. H. Ribeiro, “The Effect of Molybdenum Addition on Supported Pt Catalysts for the Water Gas Shift Reaction,”submitted to Appl. Catal. B., Env. 2012. R. Zhang, J.T. Miller, C.D. Baertsch, “Identifying the Active Oxygen Sites in a Mixed Cu and Ce Oxide Catalyst by In-situ X-ray Absorption Spectroscopy and Anaerobic Titrations with CO in Concentrated H2,” submitted J. Catal. 2012.