Iwai, Tomohiro - Hokkaido University - Department of Chemistry, Faculty of Science

个人简介

1984 Born in Gumma 2011 Ph.D. Kyoto University 2011 Assistant Professor, Hokkaido University Awards and Honors 2010 Student Poster Presentation Award in 57th Symposium on Organometallic Chemistry, Japan 2010 Otsu Academy Fellow 2012 Reaxys Prize 2012 Finalist 2013 Inoue Research Award for Young Scientists 2013 Oral Presentation Award for Young Scientists in 112th Symposium on Catalysis, Japan 2014 Takasago Award Synthetic Organic Chemistry, Japan 2016 Hokkaido University President's Award for Outstanding Research 2017 CSJ Presentation Award 2017 2018 The Encouragement Award from Hokkaido Branch of the Chemical Society of Japan

近期论文

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Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines.Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M.J. Am. Chem. Soc. 2019, 141, 7261–7265.. (DOI: 10.1021/jacs.9b02751) Iridium-catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds.Reyes, R. L.; Iwai, T.; Maeda, S.; Sawamura, M.J. Am. Chem. Soc. 2019, 141, 6817–6821. (DOI: 10.1021/jacs.9b01952) Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes.Y. Ueda, T. Iwai, M. Sawamura Chem. Eur. J. in press. (DOI: 10.1002/chem.201900822.) Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2019, 361, 2250–2254. (DOI: 10.1002/adsc.201801713) A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides Arashima, J.; Iwai, T.; Sawamura, M. Chem. Asian J. 2019, 14, 411–415. (DOI: 10.1002/asia.201801651) P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization Iwai, T.; Shibaike, K.; Sawamura, M. Chem. Lett. 2018, 47, 1162–1164. (DOI: 10.1246/cl.180501) Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 9465–9469. (DOI: 10.1002/anie.201802821) Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand Konishi, S.; Iwai, T.; Sawamura, M. Organometallics 2018, 37, 1876–1883. (DOI: 10.1021/acs.organomet.8b00113) Transmission of Point Chirality to Axial Chirality for Strong Circular Dichroism in Triarylmethylium-o,o-dimer Ishigaki, Y.; Iwai, T.; Hayashi, Y.; Nagaki, A.; Katoono, R.; Fujiwara, K.; Yoshida, J.; Suzuki, T.Synlett 2018, 29, 2147–2154. (DOI: 10.1055/s-0037-1610190) Phosphine-Catalyzed Anti-Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multi-Substituted g-Borylallylboranes Yamazaki, A.; Nagao, K.; Iwai, T.; Ohmiya, H.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 3196–3199. (DOI: 10.1002/anie.201712351) Nickel-Catalyzed Amination of Aryl Fluorides with Primary Amines Harada, T.; Ueda, Y.; Iwai, T.; Sawamura, M. Chem. Commun. 2018, 54, 1718–1721. (DOI: 10.1039/C7CC08181B) Synthesis of Cyclobutene-Fused Eight-Membered Carbocycles through Gold-Catalyzed Intramolecular Enyne [2+2] Cycloaddition Iwai, T.; Ueno, M.; Okochi, H.; Sawamura, M. Adv. Synth. Catal. 2018, 360, 670–675. (DOI: 10.1002/adsc.201701193) Enantioselective Rh- or Ir-Catalyzed Directed C(sp3)–H Borylation with Phosphoramidite Chiral Ligands Reyes, R. L.; Harada, T.; Taniguchi, T.; Monde, K.; Iwai, T.; Sawamura, M. Chem. Lett. 2017, 46, 1747–1750. (DOI: 10.1246/cl.170853) Polystyrene-Cross-Linking Ortho-Substituted Triphenylphosphines: Synthesis, Coordination Properties, and Application to Pd-Catalyzed Cross-Coupling of Aryl Chlorides.Iwai, T.; Asano, K.; Harada, T.; Sawamura, M.Bull. Chem. Soc. Jpn. 2017, 90, 943–949. (DOI: 10.1246/bcsj.20170141). Asymmetric Synthesis of β-Lactams through Copper-Catalyzed Alkyne–Nitrone Coupling with Prolinol-Phosphine Chiral Ligand.Takayama, Y.; Ishii, T.; Ohmiya, H.; Iwai, T.; Schwarzer, M. C.; Mori, S.; Taniguchi, T.; Monde, K.; Sawamura, M. Chem. Eur. J. 2017, 23, 8400–8404. DOI: 10.1002/chem.201702070 A Polystyrene-Cross-Linking Bisphosphine: Controlled Metal Monochelation and Ligand-Enabled First-Row Transition Metal Catalysis. Iwai, T.; Harada, T.; Shimada, H.; Asano, K.; Sawamura, M. ACS Catal. 2017, 7, 1681–1692. DOI: 10.1021/acscatal.6b02988 Synthesis, Coordination Properties, and Catalytic Application of Triarylmethane-Monophosphines.Iwai, T.; Tanaka, R.; Sawamura, M. Organometallics, 2016, 35, 3959-3969. DOI: 10.1021/acs.organomet.6b00752 Site-selective and Stereoselective C(sp3)–H Borylation of Alkyl Side Chains of 1,3-Azoles with a Silica-Supported Monophosphine-Ir Catalyst.Murakami, R.; Iwai, T.; Sawamura, M.Synlett, 2016, 27, 1187-1192. DOI: 10.1055/s-0035-1561599 Silica-supported Triptycene-type Phosphine. Synthesis, Characterization, and Application to Pd-Catalyzed Suzuki–Miyaura Cross-coupling of Chloroarenes.Iwai, T.; Konishi, S.; Miyazaki, T.; Kawamorita, S.; Yokokawa, N.; Ohmiya, H.; Sawamura, M. ACS Catal., 2015, 5, 7254–7264. DOI: 10.1021/acscatal.5b00904 Synthesis and Structures of a Chiral Phosphine-Phosphoric Acid Ligand and Its Rhodium(I) Complexes.Iwai, T.; Akiyama, Y.; Tsunoda, K.; Sawamura, M.Tetrahedron: Asymmetry, 2015, 26, 1245-1250. DOI: 10.1016/j.tetasy.2015.09.016