Sawamura, Masaya - Hokkaido University - Department of Chemistry, Faculty of Science

个人简介

1961 Born in Kochi 1989 Ph.D. Kyoto University 1989 Assistant Professor, Kyoto University 1993 Visiting Researcher, Harvard University (–94) 1995 Assistant Professor, Tokyo Institute of Technology 1995 Assistant Professor, The University of Tokyo 1996 Lecturer 1997 Associate Professor 2001 Professor, Hokkaido University 2016 Distinguished Professor

研究领域

"Discovery by New Molecule". Having these words in minds, we are seeking for new synthetic organic reactions that afford environmentally benign processes for the production of important chemicals such as pharmaceuticals, agrichemicals, functional plastics and organic electronic materials. This is generally called "Green Chemistry". Crucial for the advance of green chemistry are "innovative, high performing catalysts" and "new reactions that allow for efficient molecular transformations".

近期论文

查看导师最新文章（温馨提示：请注意重名现象，建议点开原文通过作者单位确认）

Asymmetric remote C–H borylation of aliphatic amides and esters with a modular iridium catalyst Reyes, R. L.; Sato, M.; Iwai T.; Suzuki,K.; Maeda, S.; Sawamura, M.Science 2020, 369, 970–974. DOI: 10.1126/science.abc8320 Polystyrene-Cross-Linking Triphenylphosphine on Porous Monolith: Enhanced Catalytic Activity for Aryl Chloride Cross-Coupling in Biphasic Flow Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. Ind. Eng. Chem. Res. in press. DOI: 10.1021/acs.iecr.0c02404 Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.; Mori, S.; Sawamura, M. Adv. Synth. Catal., in press. DOI: 10.1002/adsc.202000615 Ir-Catalyzed Reversible Acceptorless Dehydrogenation/Hydrogenation of N-Substituted and Unsubstituted Heterocycles Enabled by a Polymer-Cross-Linking Bisphosphine Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2020, 22, 5240–5245. DOI: 10.1021/acs.orglett.0c01905 Polystyrene‐Supported PPh3 in Macroporous Monolith: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C‐C Cross‐Coupling of Aryl Chlorides Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. ChemCatChem 2020, 12, 4034–4037. DOI: 10.1002/cctc.202000651 Copper-Catalyzed Enantioselective Conjugate Reduction of α,β-Unsaturated Esters with Phenol-Carbene Chiral Ligand Mimura, S.; Mizushima, S.; Shimizu, Y.; Sawamura, M. Beilstein J. Org. Chem. 2020, 16, 537–543. DOI: 10.3762/bjoc.16.50 Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)–H Borylation Reyes, R. L.; Sato, M.; Iwai T.; Sawamura, M. J. Am. Chem. Soc. 2020, 142, 589–597. DOI: 10.1021/jacs.9b12013 Boron-Catalyzed α-Amination of Carboxylic Acids Morisawa, T.; Sawamura, M.; Shimizu, Y. Org. Lett. 2019, 21, 7466–7469. DOI: 10.1021/acs.orglett.9b02769 Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2019, 21, 5867–5872 DOI: 10.1021/acs.orglett.9b01989 Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines. Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M. J. Am. Chem. Soc. 2019, 141, 7261–7265. DOI: 10.1021/jacs.9b02751 Iridium-catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds Reyes, R. L.; Iwai, T.; Maeda, S.; Sawamura, M. J. Am. Chem. Soc. 2019, 141, 6817–6821. DOI: 10.1021/jacs.9b01952 Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes Ueda, Y.; Iwai, T.; Sawamura, M Chem. Eur. J. 2019, 25, 9410–9414. DOI: 10.1002/chem.201900822. Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2019, 361, 2250–2254. DOI: 10.1002/adsc.201801713 Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand Imai, K.; Takayama, Y.; Murayama, H.; Ohmiya, H.; Shimizu Y.,; Sawamura, M. Org. Lett. 2019, 21, 1717–1721. DOI:10.1021/acs.orglett.9b00276 A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides Arashima, J.; Iwai, T.; Sawamura, M. Chem. Asian J. 2019, 14, 411–415. DOI: 10.1002/asia.201801651 P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization Iwai, T.; Shibaike, M.; Sawamura, M. Chem. Lett. 2018, 47, 1162–1164. DOI: 10.1246/cl.180501 Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 9465–9469. DOI: 10.1002/anie.201802821 Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand Konishi, S.; Iwai, T.; Sawamura, M. Organometallics 2018, 37, 1876–1883. DOI: 10.1021/acs.organomet.8b00113 Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M. Org. Lett. 2018, 20, 1861–1865. DOI: 10.1021/acs.orglett.8b00390 Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of a-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M. Chem. Sci. 2018, 9, 3484–3493. DOI: 10.1039/C8SC00527C Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M. Chem. Lett. 2018, 47, 632–635. DOI: 10.1246/cl.180147