个人简介
1961 Born in Kochi
1989 Ph.D. Kyoto University
1989 Assistant Professor, Kyoto University
1993 Visiting Researcher, Harvard University (–94)
1995 Assistant Professor, Tokyo Institute of Technology
1995 Assistant Professor, The University of Tokyo
1996 Lecturer
1997 Associate Professor
2001 Professor, Hokkaido University
2016 Distinguished Professor
研究领域
"Discovery by New Molecule". Having these words in minds, we are seeking for new synthetic organic reactions that afford environmentally benign processes for the production of important chemicals such as pharmaceuticals, agrichemicals, functional plastics and organic electronic materials. This is generally called "Green Chemistry". Crucial for the advance of green chemistry are "innovative, high performing catalysts" and "new reactions that allow for efficient molecular transformations".
近期论文
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Asymmetric remote C–H borylation of aliphatic amides and esters with a modular iridium catalyst Reyes, R. L.; Sato, M.; Iwai T.; Suzuki,K.; Maeda, S.; Sawamura, M.Science 2020, 369, 970–974. DOI: 10.1126/science.abc8320
Polystyrene-Cross-Linking Triphenylphosphine on Porous Monolith: Enhanced Catalytic Activity for Aryl Chloride Cross-Coupling in Biphasic Flow Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. Ind. Eng. Chem. Res. in press. DOI: 10.1021/acs.iecr.0c02404
Iridium-Catalyzed Enantioselective Transfer Hydrogenation of Ketones Controlled by Alcohol Hydrogen-Bonding and sp3-C–H Noncovalent Interactions Murayama, H.; Heike, Y.; Higashida, K.; Shimizu, Y.; Yodsin, N.; Wongnongwa, Y.; Jungsuttiwong, S.; Mori, S.; Sawamura, M. Adv. Synth. Catal., in press. DOI: 10.1002/adsc.202000615
Ir-Catalyzed Reversible Acceptorless Dehydrogenation/Hydrogenation of N-Substituted and Unsubstituted Heterocycles Enabled by a Polymer-Cross-Linking Bisphosphine Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2020, 22, 5240–5245. DOI: 10.1021/acs.orglett.0c01905
Polystyrene‐Supported PPh3 in Macroporous Monolith: Effect of Cross‐Linking Degree on Coordination Mode and Catalytic Activity in Pd‐Catalyzed C‐C Cross‐Coupling of Aryl Chlorides Matsumoto, H.; Hoshino, Y.; Iwai, T.; Sawamura, M.; Miura, Y. ChemCatChem 2020, 12, 4034–4037. DOI: 10.1002/cctc.202000651
Copper-Catalyzed Enantioselective Conjugate Reduction of α,β-Unsaturated Esters with Phenol-Carbene Chiral Ligand Mimura, S.; Mizushima, S.; Shimizu, Y.; Sawamura, M. Beilstein J. Org. Chem. 2020, 16, 537–543. DOI: 10.3762/bjoc.16.50
Asymmetric Synthesis of α-Aminoboronates via Rhodium-Catalyzed Enantioselective C(sp3)–H Borylation Reyes, R. L.; Sato, M.; Iwai T.; Sawamura, M. J. Am. Chem. Soc. 2020, 142, 589–597. DOI: 10.1021/jacs.9b12013
Boron-Catalyzed α-Amination of Carboxylic Acids Morisawa, T.; Sawamura, M.; Shimizu, Y. Org. Lett. 2019, 21, 7466–7469. DOI: 10.1021/acs.orglett.9b02769
Iridium-Catalyzed Alkene-Selective Transfer Hydrogenation with 1,4-Dioxane as Hydrogen Donor Zhang, D.; Iwai, T.; Sawamura, M. Org. Lett. 2019, 21, 5867–5872 DOI: 10.1021/acs.orglett.9b01989
Nickel-Catalyzed Decarboxylation of Aryl Carbamates for Converting Phenols into Aromatic Amines. Nishizawa, A.; Takahira, T.; Yasui, K.; Fujimoto, H.; Iwai, T.; Sawamura, M.; Chatani, N.; Tobisu, M. J. Am. Chem. Soc. 2019, 141, 7261–7265. DOI: 10.1021/jacs.9b02751
Iridium-catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds Reyes, R. L.; Iwai, T.; Maeda, S.; Sawamura, M. J. Am. Chem. Soc. 2019, 141, 6817–6821. DOI: 10.1021/jacs.9b01952
Nickel-Copper-Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes Ueda, Y.; Iwai, T.; Sawamura, M Chem. Eur. J. 2019, 25, 9410–9414. DOI: 10.1002/chem.201900822.
Heterogeneous Nickel-Catalyzed Cross-Coupling between Aryl Chlorides and Alkyllithiums Using a Polystyrene-Cross-Linking Bisphosphine Ligand Yamazaki, Y.; Arima, N.; Iwai, T.; Sawamura, M. Adv. Synth. Catal. 2019, 361, 2250–2254. DOI: 10.1002/adsc.201801713
Asymmetric Synthesis of α-Alkylidene-β-Lactams through Copper Catalysis with a Prolinol-Phosphine Chiral Ligand Imai, K.; Takayama, Y.; Murayama, H.; Ohmiya, H.; Shimizu Y.,; Sawamura, M. Org. Lett. 2019, 21, 1717–1721. DOI:10.1021/acs.orglett.9b00276
A Polystyrene-Cross-Linking Tricyclohexylphosphine: Synthesis, Characterization and Applications to Pd-Catalyzed Cross-Coupling Reactions of Aryl Chlorides Arashima, J.; Iwai, T.; Sawamura, M. Chem. Asian J. 2019, 14, 411–415. DOI: 10.1002/asia.201801651
P,P,P’,P’-Tetraethynylated Bisphosphine and P-C-P Pincer Ligands with Bulky End Caps: Synthesis, Coordination Properties and Application to Platinum-Catalyzed 1,8-Enyne Cycloisomerization Iwai, T.; Shibaike, M.; Sawamura, M. Chem. Lett. 2018, 47, 1162–1164. DOI: 10.1246/cl.180501
Palladium-Catalyzed Asymmetric C(sp3)-H Allylation of 2-Alkylpyridines Murakami, R.; Sano, K.; Iwai, T.; Taniguchi, T.; Monde, K.; Sawamura, M. Angew. Chem. Int. Ed. 2018, 57, 9465–9469. DOI: 10.1002/anie.201802821
Synthesis, Properties, and Catalytic Application of a Triptycene-Type Borate-Phosphine Ligand Konishi, S.; Iwai, T.; Sawamura, M. Organometallics 2018, 37, 1876–1883. DOI: 10.1021/acs.organomet.8b00113
Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes Nagao, K.; Yamazaki, A.; Ohmiya, H.; Sawamura, M. Org. Lett. 2018, 20, 1861–1865. DOI: 10.1021/acs.orglett.8b00390
Enantiocontrol by Assembled Attractive Interactions in Copper-catalyzed Asymmetric Direct Alkynylation of a-Ketoesters with Terminal Alkynes: OH···O/sp3-CH···O Two-point Hydrogen-bonding Combined with Dispersive Attractions Schwarzer, M. C.; Fujioka, A.; Ishii, T.; Ohmiya, H.; Mori, S.; Sawamura, M. Chem. Sci. 2018, 9, 3484–3493. DOI: 10.1039/C8SC00527C
Copper-Catalyzed Enantioselective Intramolecular Alkylboron Allylic Alkylation Hojoh, K.; Shido, Y.; Ohmiya, H.; Sawamura, M. Chem. Lett. 2018, 47, 632–635. DOI: 10.1246/cl.180147