Lundgren, Rylan - University of Alberta

研究领域

Our research group is broadly interested in catalysis, organometallic chemistry, synthesis and reactivity. We seek to address problems and limitations in chemical synthesis by devising new concepts and tools related to homogeneous catalysis involving both transition metal and organic moieties. Specific interests include novel oxidative coupling reactions inspired by the reactivity of oxidase enzymes; simultaneous dual substrate activation strategies to enable, for example, olefin functionalizations; the development of new dehydrogenative processes; and alternative methods to generate single-electron reductants. Additionally, we are also interested in developing and exploiting strained unsaturated cyclic molecules as potential reagents for bioconjugation and click reactions.

近期论文

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Enantioconvergent Cross-Couplings of Racemic Alkylmetal Reagents with Unactivated Secondary Alkyl Electrophiles: Catalytic Asymmetric Negishi α-Alkylations of N-Boc-pyrrolidine Christopher J. Cordier, Rylan J. Lundgren, Gregory C. Fu; J. Am. Chem. Soc. 2013, 135, 10946. Transition Metal-Catalyzed Alkylations of Amines with Alkyl Halides: Photoinduced, Copper-Catalyzed Couplings of Carbazoles Alexander C. Bissember, Rylan J. Lundgren, Sidney Cruetz, Jonas C. Peters, Gregory C. Fu; Angew. Chem. Int. Ed. 2013, 52, 5129.paper 21 Catalytic Asymmetric C–N Bond Formation: Phosphine-Catalyzed Intra- and Intermolecular γ-Addition of Nitrogen Nucleophiles to Allenoates and Alkynoates Rylan J. Lundgren, Ashraf Wilsily, Nicolas Marion, Cong Ma, Ying Kit Chung, Gregory C. Fu; Angew. Chem. Int. Ed. 2013, 52, 2525.paper 20 Recent Advances in Buchwald-Hartwig Amination Enabled by the Application of Sterically Demanding Phosphine Ancillary Ligands Rylan J. Lundgren, Mark Stradiotto; Aldrichimica Acta 2012, 45, 59 (Review).paper 18 Palladium-Catalyzed Synthesis of Indoles via Ammonia Cross-Coupling-Alkyne Cyclization Pamela G. Alsabeh, Rylan J. Lundgren, Lauren E. Longobardi, Mark Stradiotto; Chem. Commun. 2011, 47, 6936.paper 14 Palladium-Catalyzed Mono-α-Arylation of Acetone with Aryl Halides and Tosylates Kevin D. Hesp, Rylan J. Lundgren, Mark Stradiotto; J. Am. Chem. Soc. 2011, 133, 5194.paper 13 Palladium Catalyzed Cross-Coupling of Aryl Chlorides and Tosylates with Hydrazine Rylan J. Lundgren, Mark Stradiotto; Angew. Chem. Int. Ed. 2010, 49, 8686.paper 12 A P,N-Ligand for Pd-Catalyzed Ammonia Arylation: Coupling of Deactivated Aryl Chlorides, Chemoselective Aminations, and Room Temperature Reactions Rylan J. Lundgren, Brendan D. Peters, Pamela G. Alsabeh, Mark Stradiotto; Angew. Chem. Int. Ed. 2010, 49, 4071.paper 11 Zwitterionic Relatives of Cationic Platinum Group Metal Complexes: Applications in Stoichiometric and Catalytic Sigma-Bond Activation Mark Stradiotto, Kevin D. Hesp, Rylan J. Lundgren; Angew. Chem. Int. Ed. 2010, 49, 494 (Review).