个人简介

B.S., 2004, Moscow State University M.S., 2004, Moscow State University Ph.D., 2011, Colorado State University Postdoctoral Research Associate, 2011-2013, Massachusetts Institute of Technology

研究领域

Inorganic

Research areas: Inorganic chemistry and catalysis, organometallics, carboranes, CO2 reduction. Research in the group involves the synthesis of molecular catalysts for activation of important substrates such as dihydrogen, carbon dioxide, and alkenes. Students with interest in catalysis, inorganic, and organometallic chemistry are encouraged to join. Group members will receive a rigorous training in inorganic and organometallic chemistry, catalysis, air-free synthetic methods, and spectroscopic methods. Catalytic Small-Molecule Activation with Transition Metal Complexes Supported by Carboranyl-Based Ligands. High-valent transition metal complexes with multiply-bonded ligands active in group-transfer reactions to organic substrates are pursued. The oxo, nitrido, and imido complexes of abundant metals such as V, Mn, Fe, Co, and Ni with multidentate ligands are the main targets. We use carborane clusters as a chemically versatile platform for stabilization of reactive transition metal complexes designed for small molecule activation and group transfer. Pre-Organized Frustrated Lewis Pairs for Small Molecule Activation.Frustrated Lewis pairs (FLPs) are an emerging class of bifunctional intermolecular complexes comprised of sterically encumbered Lewis acidic and basic components. FLPs have demonstrated unique reactivity through metal-free activation of H2, CO2, NO, etc. The use of FLPs is generally limited to donor-free substrates due to inactivation of the Lewis acid center of an FLP by basic functionalities. We develop the new types of organocatalysts that are pre-organized into an intramolecular complex to prevent undesired reactions. Heterometallic molecular complexes for catalytic photoactivation of small molecules. Photocatalytic conversion of common inert molecules such as water and carbon dioxide is a focus of extensive research for solar energy conversion and sustainability. We design molecular heterometallic complexes and study their reactivity in photocatalytic activation of inert molecules such as CO2.

近期论文

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Conley, M. P.; Mougel, V.; Peryshkov, D. V.; Forrest, Jr. W. P.; Gajan, D.; Lesage, A.; Emsley, L.; Copéret, C.; Schrock, R. R. ""A Well-Defined Silica-Supported Tungsten Oxo Alkylidene Is a Highly Active Alkene Metathesis Catalyst."" J. Am. Chem. Soc. 2013, 135, 19068–19070. Cain, M. F.; Forrest, Jr. W. P.; Peryshkov, D. V.; Schrock, R. R.; Müller, P. ""Synthesis of a TREN in Which the Aryl Substituents are Part of a 45 Atom Macrocycle."" J. Am. Chem. Soc. 2013, 135, 15338–15341. Peryshkov, D. V.; Forrest, Jr. W. P.; Schrock, R. R.; Smith, S. J.; Müller, P. ""B(C6F5)3 Activation of Oxo Tungsten Complexes That Are Relevant to Olefin Metathesis."" Organometallics, 2013, 32, 5256–5259. Peryshkov, D. V. and Schrock, R. R. ""Synthesis of Tungsten Oxo Alkylidene Complexes."" Organometallics, 2012, 31, 7278–7286. Ivanov, S. V.; Peryshkov, D. V.; Miller, S. M.; Anderson, O. P.; Rappé, A. K.; Strauss, S. H. ""Synthesis, structure, and reactivity of AlMe2(1-Me-CB11F11): An AlMe2+ cation-like species bonded to a superweak anion."" J. Fluor. Chem. 2012, 143, 99–102. Bukovsky, E. V.; Fiedler, S. R.; Peryshkov, D. V.; Popov, A. A.; Strauss, S. H. ""The Structure of (H3O)2B12F12.6H2O – a CCP Lattice of B12F122– Anions Intercalated with a Nonplanar Network of O–H...O Connected O6 Rings."" Eur. J. Inorg. Chem. 2012, 208–212. Peryshkov, D. V.; Schrock, R. R.; Takase, M. K.; Mueller, P.; Hoveyda, A. H. ""Z-Selective Olefin Metathesis Reactions Promoted by Tungsten Oxo Alkylidene Complexes."" J. Am. Chem. Soc. 2011, 133, 20754–20757. Peryshkov, D. V.; Popov, A. A.; Strauss, S. H. ""Latent Porosity in Potassium Dodecafluoro-closo-dodecaborate(2–). Structures and Rapid Room Temperature Interconversions of Crystalline K2B12F12, K2(H2O)2B12F12, and K2(H2O)4B12F12 in the Presence of Water Vapor."" J. Am. Chem. Soc. 2010, 132, 13902–13913. Peryshkov, D. V.; Popov, A. A.; Strauss, S. H. ""Direct Perfluorination of K2B12H12 in Acetonitrile Occurs at the Gas Bubble-Solution Interface and Is Inhibited by HF. Experimental and DFT Study of Inhibition by Protic Acids and Soft, Polarizable Anions."" J. Am. Chem. Soc. 2009, 131, 18393–18403.