个人简介

Dr. Richeson’s team designs, synthesizes, and explores the reactivity of inorganic and organometallic complexes with the goals of: (1) discovering novel catalytic and stoichiometric chemical transformations and (2) employing these complexes as molecular precursors in non-traditional routes to solid state materials.

研究领域

Inorganic and Organometallic Chemistry Solid state

Our group has broad interests spanning main group and transition metal chemistry. This provides a unique and stimulating learning and research environment. Discovery of new reactivity, fundamental concepts and cool chemistry is at the heart of our efforts.

近期论文

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G. K. Rao, W. Pell, I. Korobkov, D. Richeson “Electrocatalytic Reduction of CO2 using Mn Complexes with Unconventional Coordination Environments” Chem. Commun. 2016,52, 8010-8013. T. Jurca, S. Ouanounou, W.-C. Shih, T.-G. Ong, G. P. A. Yap, I. Korobkov, S. Gorelsky, D.Richeson “Structural and Electronic Trends for Five Coordinate 1st Row Transition Metal Complexes: Mn(II) to Zn(II) Captured in a Bis(iminopyridine) Framework” Dalton Transactions, 2016, 45, 14327 - 14334. L. Kobera, S. A. Southern, G. K. Rao, D. S. Richeson, D. L. Bryce “New Experimental Insight into the Nature of Metal-Metal Bonds in Digallium Compounds: J-Coupling Between Quadrupolar Nuclei” Chem. Eur. J. 2016. P. Bulsink, A. Al-Ghamdi, P. Josh, I. Korobkov, Tom Woo, D. Richeson “Capturing Re(I) in an Neutral N,N,N Pincer Scaffold and Resulting Enhanced Absorption of Visible Light.” Dalton Trans. 2016 , 45, 8885 - 8896 T. Jurca, O.Ramadan, I. Korobkov, D. Richeson “Employing Sterically Encumbered Bis(imino)pyridine Ligands in Support of fac-Rhenium(I) Carbonyls ” J. Organomet. Chem. 2016, 802, 27-31 G. K. Rao, S. Gorelsky, I. Korobkov, D. Richeson “Coinage Metal Complexes of a Neutral Pincer Ligand with a “PN3P” Scaffold.” Dalton Trans. 2015, 44, 19153 - 19162. T. Jurca, L. K. Hiscock, C. N. Rowley D. S. Richeson “The Tipping Point of the Inert Pair Effect: Experimental and Computational Comparison of In(I) and Sn(II) bis(imino)pyridine Complexes ” Dalton Trans. 2014, 43, 690. T. Jurca, I. Korobkov, S. I. Gorelsky, D. S. Richeson “Non-Covalent Interactions of Metal Cations and Arenes Probed with Thallium(I) Complexes” Inorg. Chem. 2013, 52 , 5749–5756 http://dx.doi.org/10.1021/ic302552v. T. Jurca, W.-C. Chen, S. Michel, I. Korobkov, T.-G. Ong, D. S. Richeson “Changing the fac on Re(I) carbonyl chemistry: a unique metal environment displaying a redox non-innocent pincer ligand and elaborated photophysical features.” Chemistry, A European J. 2013, 19, 4278. F. F. Said, B. F. Ali, D. Richeson, Q. Abusalem, T. Kell “Three Dimensional Framework Structures of Tricyclcohexylguandinium Halides” J. Chem. Cryst. 2012, 42, 1022. F. F. Said, B. F. Ali, D. S. Richeson, I. Korobkov Supramolecular structure of bis(N,N’,N”-triisopropylguanidinium) phthalate. Arabian Journal of Chemistry 2012, http://dx.doi.org/10.1016/j.arabjc.2012.06.012 I. Mallov, H.Spinney, T. Jurca, S. Gorelsky, T. Burchell, D. S. Richeson “The 2,2’-Diindolylmethane Dianion Supporting Scaffold for Group 15 Compounds” Inorg. Chimica Acta 2012, 392, 5. F. F. Said, B. F. Ali, D. Richeson, I. Korobkov “Bis(N,N’,N”-triisopropylguanidinium) fumarate–fumaric acid (1/1)” Acta Cryst. 2012, E68, o1906. T. Jurca, S.Ouanounou, S. I. Gorelsky, I. Korobkov, D. S. Richeson “The Interplay of Metal and Supporting Ligand in Labile Coordination to Pincer Complexes of Ag(I).” Dalton Trans. 2012, 41, 4765. C. M. Widdifield, T. Jurca, D. S. Richeson, D. L. Bryce “Using 69/71Ga solid-state NMR and 127I NQR as probes to elucidate the composition of ‘GaI’ ” Polyhedron 2012, 35, 96. F. F. Said, B. F. Ali, D. Richeson “N,N’,N”-Tricyclohexylguanidinium iodide” Acta Cryst. 2011 E67, o3467. T. Jurca, A. Farghal, P.-H. Lin, I. Korobkov, M. Murugesu, D. S. Richeson “Single-Molecule Magnet Behavior with a Single Metal Center Enhanced through Peripheral Ligand Modifications.” J. Am Chem Soc. 2011, 133, 15814. T. Jurca, S. I. Gorelsky, I. Korobkov, D. S. Richeson “Novel pincer complexes of Ag(I), coordination of toluene and their comparison with indium analogues.” Dalton Trans. 2011, 40, 4394. T. Jurca, I. Korobkov, G. P. A. Yap, S. I. Gorelsky, D. S. Richeson “Harnessing Low-Valent Metal Centers through Non-Bonding Orbital Interactions” Inorg. Chem. 2010, 49, 10635. A. Y. H. Lo, T. Jurca, D. S. Richeson, D. L. Bryce “Multinuclear Solid-State Magnetic Resonance Study of In+ and Ag+ in Neutral Weakly Coordinating Environments” J. Phys. Chem. Lett. 2010, 1, 3078. N.Lavoie, S. I. Gorelsky, Z. Liu, T. J. Burchell, G. P. A. Yap, D.S. Richeson “Disubstituted 1,8-Diamidonaphthalene Ligands as a Flexible, Responsive, and Reactive Framework for Tantalum Complexes.” Inorg. Chem 2010, 49, 5231. T.Jurca, K. Dawson, I. Mallov, T. J. Burchell, G. P. A. Yap, D. S. Richeson “Disproportionation and radical formation in the coordination of “GaI” with bis(imino)pyridines.” Dalton Trans. 2010 39, 1266. D. C. Kennedy, D.R. Duguay, L.-L.Tay, D. S. Richeson, J. P. Pezacki “SERS detection and boron delivery to cancer cells using carborane labelled nanoparticles”Chem. Commun. 2009, 6750. T. Jurca, J. Lummiss, T. J. Burchell, S. I. Gorelsky, D. S. Richeson “Capturing In+ Monomers in a Neutral Weakly Coordinating Environment”J. Am Chem Soc. 2009131, 4608. C. N. Rowley, T.-G. Ong, J. Priem, D. S. Richeson, T. K. Woo “Analysis of the Critical Step in Catalytic Carbodiimide Transformation: Proton Transfer from Amines, Phosphines, and Alkynes to Guanidinates, Phosphaguanidinates, and Propiolamidinates with Li and Al Catalysts” Inorg. Chem. 2008, 47, 1202.